Stability Properties Research Articles

Improved barrier, mechanical and antioxidant properties of pH-responsive film by incorporating dialdehyde starch and anthocyanins into rice protein/sodium alginate.

This study aimed to develop rice protein/sodium alginate (RP/SA) pH-responsive films with enhanced properties by incorporating dialdehyde starch (DAS) and Lycium ruthenicum anthocyanins (LRA) and the film was applied to monitor the fruit freshness. The effect of the DAS and LRA content on the morphology, mechanical, water barrier, oxygen barrier, ultraviolet-blocking and thermal stability properties of RP/SA-based films was investigated. The best water vapor permeability of the film was 3.33g·mm/(m2·d·kPa) with 10% DAS. With increasing the DAS content from 0% to 20%, the tensile strength of the film was increased by 66.3% compared with that of the film without DAS, while the thermal stability, oxygen barrier and ultraviolet light barrier properties were significantly enhanced. These results may be due to the formation of a compact structure observed by scanning electron microscopy, and stronger hydrogen bonding interactions and lower binding energy in the RP/SA/DAS/LRA system obtained by Fourier transform infrared spectroscopy, X-ray diffraction and molecular dynamics simulation. The RP/SA/DAS10/LRA5 film had 51.6 times higher antioxidant property than the film without LRA and exhibited significant color variations with changes in fresh-cut cantaloupe quality. The developed RP/SA-based films with improved properties are potential intelligent food packaging materials.

Gold as a Promising Electrode Material for LiNbO3-on-Insulator (LNOI) SH-SAW Resonators: An Experimental Study.

The need for wideband radio frequency front ends (RFFEs) with next-generation wireless protocols highlights the importance of electromechanical coupling [Formula: see text]. The hetero acoustic layered (HAL) surface acoustic wave (SAW) resonator with aluminum (Al) electrodes has shown superior performance compared to conventional SAW devices. Despite gold (Au) having excellent conductivity and stable properties, its high acoustic absorption and low phase velocity have made it less favorable for electrodes. This work demonstrates that high-performance shear horizontal (SH)-SAW resonators can be fabricated on the lithium niobate-on-insulator (LNOI) platform using a setup specifically designed for an Au electrodes. Experimental validation shows that the device achieves a high quality factor (Q) over 870, excellent [Formula: see text] up to 40%, and operates around 765 MHz. Unwanted transverse spurious modes are suppressed through adequate electrode design, and the temperature stability of LNOI SH-SAW with Au electrodes is discussed. This study highlights gold's potential as an electrode material for high [Formula: see text], clean spectrum, and wideband applications.

Cs/O, Cs/NF3, and Cs/Li/NF3 coadsorption on GaAs0.5P0.5 (001) β2(2×4) reconstruction surface: A first principle study

The activation process of p-type doped GaAs0.5P0.5 (001) β2(2 × 4) reconstruction surface is investigated based on first principle calculations. For Cs-only adsorption, the adsorption energy rises as the Cs coverage increases, and when the Cs coverage is at 0.75 ML, the work function hits its minimum. Cs/O and Cs/NF3 concurrent adsorption are conducive to increasing steadiness and lowering the work function of the reconstruction surface during the phase of high Cs coverage. The work function reaches its minimum when Cs coverage is 0.75 ML in Cs/O coadsorbed models while that occurs when Cs coverage is 1.00 ML in Cs/NF3 coadsorbed models. Results indicate that the Li atoms intercalation with low coverage in Cs/NF3 coadsorbed models is conducive to establishing dipole moments, strengthening stability, and lowering the work function. The optimal adsorption recipe is 6Cs/2Li/NF3, with which the surface owns the lowest work function and shows the most stable property.

All-electrochemical-prepared, efficient and robust superhydrophilic/underwater superoleophobic meshes for synchronously achieving oil-water separation and water-soluble pollutant photodegradation

Superhydrophilic/underwater superoleophobic “water-removing” type membranes can overcome the issue of surface themselves easily fouled or even blocked by oils that seriously affects the oil-water separation capacity and limits the recycle use, and thus attract a great deal of research attention. In this work, we employed the electrochemical deposition method to fabricate Cu3(PO4)2 nanosheets (NSs) vertically grown on a copper mesh (COM) to achieve efficient oil-water separation, followed by the deposition of titanium dioxide (TiO2) nanoparticles and graphitic carbon nitride (g-C3N4) nanosheets on the surface of Cu3(PO4)2 nanosheets-wrapped mesh (Cu3(PO4)2@COM), respectively. The composited meshes of TiO2@Cu3(PO4)2@COM and g-C3N4@Cu3(PO4)2@COM not only showed the considerable superhydrophilic/underwater superoleophobic property in the application of oil-water separation, but also simultaneously exhibited the desirable photocatalytic activity for the degradation of water-soluble pollutants as the water passed through the meshes. The oil-water separation efficiency of TiO2@Cu3(PO4)2@COM and g-C3N4@Cu3(PO4)2@COM can reach as high as 97 % and 96 % that both of meshes have the water flux of various water-oil mixtures above 3250 L/m2h, along with their degradation efficiency of 79 % and 90 % for RhB pollutant under full spectrum light irradiation, respectively. In addition, the as-prepared meshes have the robust, sustainable and stable properties through ten-cycles test of oil-water separation and photocatalytic degradation without significant performance decay. Our primary results provide a potential and simple route to construct multifunctional membrane materials for synchronously achieving water purification in oily wastewater.

Modulational instability, generation, and evolution of rogue waves in the generalized fractional nonlinear Schrödinger equations with power-law nonlinearity and rational potentials.

In this paper, we investigate several properties of the modulational instability (MI) and rogue waves (RWs) within the framework of the generalized fractional nonlinear Schrödinger (FNLS) equations with rational potentials. We derive the dispersion relation for a continuous wave (CW), elucidating the relationship between the wavenumber and the instability growth rate of the CW solution in the absence of potentials. This relationship is primarily influenced by the power parameter σ, the Lévy index α, and the nonlinear coefficient g. Our theoretical findings are corroborated by numerical simulations, which demonstrate that MI occurs in the focusing context. Furthermore, we study the RW generations in both cubic and quintic FNLS equations with two types of time-dependent rational potentials, which make both cubic and quintic NLS equations support the exact RW solutions. Specifically, we show that the introduction of these two potentials allows for the excitations of controllable RWs in the defocusing regime. When these two potentials become the time-independent cases such that the stable W-shaped solitons with non-zero backgrounds are generated in these cubic and quintic FNLS equations. Moreover, we consider the excitations of higher-order RWs and investigate the conditions necessary for their generations. Our analysis reveals the intricate interplay between the system parameters and the potential configurations, offering insights into the mechanisms that facilitate the emergence of higher-order RWs. Finally, we find the separated controllable multi-RWs in the defocusing cubic FNLS equation with time-dependent multi-potentials. This comprehensive study not only enhances our understanding of MI and RWs in the fractional nonlinear wave systems, but also paves the way for future research in related nonlinear wave phenomena.

Development, characterization and themo-physical analysis of energy storage material doped with TiO2 and CuO nano-additives

The paper presents the results of an experimental investigation on chemical stability, surface morphology, and thermo-physical properties of phase change material integrated with nano additives. The research aims to evaluate impact of varying nano-particle concentration on thermal performance of phase change material. The phase change material magnesium dichloride hexahydrate and potassium chloride mixed in different mass ratio along with different wt% concentration of nano-additives titanium dioxide and copper oxide to prepare novel phase change material. Characterization methods such as Fourier Transform Infrared Spectroscopy, Scanning electron microscope, Energy-dispersive X-ray analysis, and Differential scanning calorimeter analysis were employed. The Fourier transform infrared spectra indicated physical interactions between phase change material and nano-additives, while Energy-dispersive X-ray analysis confirmed elemental composition, and Scanning electron microscope demonstrated uniform distribution. The improved thermal properties of samples were reflected in their phase change enthalpy (284.57 J/g to 324.63 J/g), minimal energy loss (0.91 %–2.96 %), and low supercooling (0.3 %–5.26 %). Notably, doping with 1.5 wt% of titanium dioxide and copper oxide enhanced thermal conductivity by up to 117.07 % and specific heat capacity by up to 48.09 %. The introduction of nanoparticles significantly improves heat transfer characteristics, resulting in enhanced energy retention, reduced energy loss during phase transitions, decreased supercooling, and increased physical stability. These results suggest that optimized phase change material with nano-additives is highly effective for applications requiring stable and efficient thermal management.

Stirring-Controlled Synthesis of Ultrastable, Fluorescent Silver Nanoclusters.

This paper describes how macroscopic stirring of a reaction mixture can be used to produce nanostructures exhibiting properties not readily achievable via other protocols. In particular, it is shown that by simply adjusting the stirring rate, a standard glutathione-based method-to date, used to produce only marginally stable fluorescent silver nanoclusters, Ag NCs-can be boosted to yield nanoclusters retaining fluorescence for unprecedented periods of over 2 years. This enhancement derives not simply from increased homogenization of the reaction mixture but mainly from an appropriately timed delivery of oxygen from above the reaction mixture. In effect, oxygen serves as a reagent that dictates size, structure, stability, and functional properties of the growing nanoobjects.

CsPbBr3 Perovskite Quantum Dots with Excellent Water Stability and Optical Properties Synthetized through Modifying with 6-Aminohexanoic Acid

CsPbBr3 Perovskite Quantum Dots with Excellent Water Stability and Optical Properties Synthetized through Modifying with 6-Aminohexanoic Acid

The effect of productive and quality deposition strategies on residual stress for Directed Energy Deposition (DED) process

In the Directed Energy Deposition (DED) realm, challenges persist concerning process stability and mechanical properties in as-built components. Facts like inconsistent laser head feed rate and accumulated heat during multi-layer deposition result in variations in melt pool energy, causing variant clad widths and heights. Moreover, significant residual stress in as-built DED parts can induce excessive distortions and cracking. To tackle these challenges, offline energy control systems that adjust laser power or feed rate have been implemented to manage melt pool energy and improve productivity. Additionally, an innovative online clad height compensation system has been developed to achieve global height geometry, further boosting productivity. However, the impact of these productive and quality control systems on the mechanical properties of austenitic stainless-steel parts, specifically residual stress, remains unexplored. In this research, residual stress measurements in as-built DED thin wall parts fabricated with energy and/or height control strategies using neutron diffraction have been investigated. The control of three key DED parameters influencing residual stress distribution and magnitude has been identified and discussed. Measurements indicate that neither offline energy control nor online height control adversely affects the quality of the thin wall parts and offline LP-based energy control can reduce residual stress magnitude and its variation. Additionally, the height control results in compressive residual stress with elevated magnitudes. Furthermore, aggressive DED parameters hold the potential for further improvement by pairing with an energy control strategy. This study establishes a foundation for further developing comprehensive control strategies designed to enhance the productivity and quality of DED systems.

Stability and physical properties of brucite at high pressures and temperatures: Implication for Earth’s deep water cycle

Brucite is a common hydrous mineral on Earth and may contribute to the deep water cycle of the Earth, but its stability and structure under mantle conditions remain uncertain. In this study, we investigated the stability of brucite up to 60 GPa at 800 K and 45 GPa at 1850 K. Within the experiment P-T conditions, no theoretically predicted new phase was observed, and brucite remained in the P3¯m1 structure. With the determined thermal EoS of brucite and the elastic parameters of mantle minerals, we modeled the velocity and density profile of subducted hydrous harzburgite in the top lower mantle, assuming that the water was stored in brucite and phase D. Based on the modelling, 1 wt% water will reduce the velocity and density of harzburgite by ∼ 5 % and ∼ 2 %, respectively, yet whether the water is stored in brucite or phase D has weak influence on both density and velocity. With a water content up to 2.4 wt%, the density of hydrous harzburgite could be reduced to 2.2(2)%–2.8(2)% lower than the surrounding mantle, while the VP and VS of hydrous harzburgite are still 0.3(1)%–0.7(1)% and 0.7(2)%–1.8(2)% higher than that of the normal mantle. Thus, the low-density hydrous harzburgite may slow down the subducting of slab, despite being a high-velocity body in seismic observations.

Rheological Investigation of Heavy Oil-in-Water Pickering Emulsions for Potential Applications of Fracturing Fluids

Pickering emulsions as a kind of emulsified fracturing fluids can enhance the efficacy of shale fracturing. Investigation of the rheological properties of Pickering emulsions yields valuable insights for their in-situ fracturing applications. In this work, nano-clay particles and heavy crude oil were employed to form oil-in-water (O/W) Pickering emulsions. The impact of salinity, pH, and temperature on the rheological properties, including viscosity property and viscoelastic property, of Pickering emulsions were tested and analyzed. The results showed that the viscosity of heavy O/W Pickering emulsions were significantly affected by the change of salinity and pH values, with higher salinity or lower pH resulting in increased viscosity. Under ultra-high salinities (> 5 wt% NaCl), the coalescence stability of Pickering emulsion strengthens and creaming stability declines. The massive formation of clay clusters leads to a reduction in the number of nano-clay particles used to generate the network, causing instability in the emulsion creaming. The heavy O/W Pickering emulsions exhibited high stability and high viscosity characteristics, which were mainly caused by the change of surface charge of nano-clay particles and the corresponding change of particle adsorption on droplet surface and particle-particle interactions. At a salinity of 2.5% NaCl and a pH of 4.6, the emulsion system remained stable at a temperature up to 120 °C, holding a viscosity reaching 74.1 mPa·s at a shear rate of 6.81 s-1. Besides, heavy O/W Pickering emulsions were viscoelastic fluids, with both noticeable viscous property and elastic property at the same time. Elastic modulus (G′) and viscous modulus (G′′) of the emulsion increased with increasing salinity and decreasing pH, enhancing great deformation capacity. Remarkably, the Pickering emulsions could maintain its viscoelastic behavior at varying temperature conditions. For the first time, rheological study of Pickering emulsions formed by nano-clay nanoparticles as a single emulsifier to heavy oil. Our study underscores the emulsifying ability of nano-clay particles to heavy crude oils, under a wide range of salinity and pH, yielding Pickering emulsions with exceptional stability and rheological properties. This novel emulsion system, possessing high resistance to temperature and salinity, holds promise for a high-performance fracturing fluid design.

Effect of Magnesium Hydroxide on the Thermal Stability, Latent Heat and Flammability Properties of composite material based on Phase Change Materials

Abstract Polyurethane-Phase Change Materials (PU-PCM) composites are used for thermal regulation aiming to conserve and efficiently manage thermal energy. These materials combine the properties of PU, such as low thermal conductivity, low density and excellent mechanical properties as a thermal insulator, with the benefits of PCM allowing thermal energy storage, which greatly reduce energy consumption in heating and cooling. Adding a flame retardant to the PU-PCM composition improves fire resistance. The objective of this study is the preparation and characterization of a composite material based on PU rigid foam containing 30% by mass of commercial paraffin waxes as PCM, together with magnesium hydroxide as flame retardant. A series of samples were prepared by incorporating different percentages of Mg(OH)2, ranging from 1 % to 5 %, with and without the PCM. Various thermal and chemical characterization tests were carried out. The results indicate that the structure of the PU cells is not affected by the increase of the Mg(OH)2 incorporation rate. In terms of thermal properties, the addition of 1% flame retardant increases the latent heat from 25.9 J/g to 39.68 J/g. As the amount of Mg(OH)2 incorporated increases, the flame retardancy increases.

Enzymatic synthesis of vanillyl fatty acid esters from salmon oil in a solvent-free medium

This study hypothesizes that the solvent-free alcoholysis of oil recovered from salmon heads using vanillyl alcohol (VA) and immobilized lipase B can efficiently produce esters with enhanced stability and antioxidant properties. The objective was to investigate the selectivity and resulting ester profile, which may provide nutritional and functional advantages compared to supplementing oil with vanillyl alcohol. After 24 h, nearly complete conversion of vanillyl alcohol was achieved, leading to the production of various esters reflective of the oil's original fatty acid composition. The synthesis of esters like oleoyl and linolenoyl was favored over docosahexaenoyl and linoleoyl esters, influenced by fatty acid distribution and enzyme specificity, along with potential intra-molecular acyl transfer isomerization. The reaction medium demonstrated significant stability and antioxidant activity, highlighting the potential benefits of vanillyl esters over traditional supplementation methods. These findings suggest that the phenolic alcohol-based alcoholysis of fish oil offers a promising approach to generating stable, nutritionally valuable extracts with potent antioxidant capabilities.

Performance assessment of sustainable asphalt concrete using steel slag, with an artificial neural network prediction of asphalt concrete behavior

This research evaluated the possibility of using Moroccan steelworks slag as a substitute for natural aggregates in asphalt mixtures, using chemical and mechanical analyses to demonstrate its compatibility with this application. Two granular mixtures, M1 and M2, were developed, incorporating respectively 15% and 25% natural sand (0/1.25) with slag aggregates to obtain granular mixtures complying with local standards. These mixtures were then tested with three different asphalt contents (4.7%, 5.2%, and 5.7%). Mechanical tests, including a gyratory compactor, Marshall stability, and Duriez strength, were carried out. In particular, the M1:5.2 and M2:5.2 mixtures met compaction criteria and showed remarkable Marshall Stability values, reaching 23.49 kN and 21.81 kN respectively. In comparison, the control mixtures only achieved a maximum stability of 11 kN. Thermal properties were also assessed, showing that the maximum thermal conductivity was achieved at an asphalt content of 5.2%. The slag-based mixtures, M1 and M2, showed higher thermal conductivity than the control mix M0, with maximum values of 0.74W/mK for M1 and 0.86W/mK for M2, compared with 0.56W/mK for M0. The overall results show that the M1 and M2 mixtures had improved thermal and mechanical properties compared with the M0 control mix. Artificial neural network (ANN) modelling was carried out using Marshall Test data. It showed excellent performance in predicting the stability and flow properties of asphalt mixtures. These results suggest that incorporating steelmaking slag into asphalt concrete mixtures was an effective strategy for simultaneously improving their thermal and mechanical properties.

Influence of nano industrial waste and short coir fiber filler on hybrid inter and intra yarn bio fiber composites

Bio-polymer composites are emerging as a feasible substitute for conventional polymers in various major fields of applications. In the current research, the impact of hybridization of inter and intra-woven natural engineering fibers namely, brown flax, white flax, and jute of different amalgamations along with commingled SCF and novel nano IW filler has been studied. The composites are manufactured by hand layup process and physical and thermomechanical characteristics of the composites are experimentally studied. The composites mingled with IW filler demonstrated better dimensional stability and mechanical properties such as maximum tensile strength of 36.74 MPa, bending strength of 82.53 MPa, and hardness of 84.89 D compared to other composites. However, elastic and flexural modulus are maximum for composite without any filler. The composites mingled with SCF filler demonstrated the highest impact strength, energy absorption, and elongation. Thermogravimetric analysis and thermal conductivity study demonstrated that the composite with SCF filler exhibited better thermal stability and thermal resistance than the other hybrid composites. Fourier transform infrared spectroscopy study confirms the interaction of hydrogen bonds with different polymers, matrices, and fillers. It is established that the weaving pattern and the filler types greatly influences the mechanical and thermal characteristics of the composites. Filler addition and fabric hybridization optimizes the catastrophic failures and enhances the thermal stability, hence becoming more suitable for small interior structural components in aerospace and automobile applications.

Highly Robust, Processable and Multi-functional PDMS/Graphene Composite Aerogel Constructed by "Soft-Hard" Interface Engineering Strategy

Graphene aerogel (GA) has attracked wide attention for its potential applications in various fields. However, the graphene nanosheets in the GA framework often exhibit insufficient adhesion and interfacial contacts due to weak interactions, resulting in fragile cell walls and poor structural stability. Here, inspired by the principle of "soft-hard" compounding, a class of GA with extraordinary structural stability and mechanical property was prepared based on the in-situ bonding interfacial engineering between different phases in Pickering emulsion. Through interfacial engineering, the fatal compounding drawback between fusing oily polymer soft chains and water-soluble hard graphene oxide (GO) nanosheets is resolved, which enables polydimethylsiloxane (PDMS) chains to in-situ adhere onto GO nanosheets, eventually resulting in compelling structural-stable PDMS/GO aerogel (PGOA) backbone. Later, PDMS/GA (PGA) can be easily obtained by simple reduction of PGOA. The obtained PGA achieves excellent structural stability, 97.5% elasticity, 1.7 MPa compressive capacity, and unprecedented isotropic characteristics. The assembled flexible sensor based on PGA has a high sensitivity of 17.08 kPa-1. Additionally, PGA has low thermal conductivity (0.0245-0.0301 W/(m K)) and good flame retardancy (∼1000 °C). Because of these excellent properties, PGA has a wide range of potential applications in areas such as flexible sensing, thermal protection, and fire detection.

Flexible and antistatic carbon fiber/silicone rubber composite coating with improved thermal stability, mechanical and wave-transmittance properties

Flexible and antistatic carbon fiber/silicone rubber composite coating with improved thermal stability, mechanical and wave-transmittance properties

One-step microwave pyrolysis-H3PO4 activation of woody biomass: Insight into the product characteristics and life cycle assessment

Microwave-assisted pyrolysis coupled with chemical activation was developed to prepare the woody biomass-derived activated carbon (AC) with desirable structural characteristics. In this study, sawdust powder was impregnated with phosphoric acid before being microwave-pyrolyzed to achieve AC. The utilization of microwave greatly enhanced the transformation of volatiles into gaseous components, and the yield of char increased when phosphoric acid accelerated the secondary polymerization of volatile matters. Microwave-induced activation may alter the interaction between activator and sawdust-derived organic species, enriching the categories of oily components. The char originating from microwave-activation treatment has a high graphitization degree, exhibiting superior thermal stability and hydrophilic property. Moreover, one-step microwave-activation approach increased specific surface area (978.2 m2g−1 versus 13.0 m2g−1 in conventional pyrolysis) and improved the formation of porous structure. The life cycle assessment analysis revealed that microwave-activation technique had a low environmental impact due to enhanced heating efficiency and reduced energy consumption.

Effect of Replacing B2O3 with CuO on the Structural, Optical Absorption, Thermal, Mechanical, and Gamma-Ray Shielding Properties of B2O3-Bi2O3-K2O Glass

This paper delves into the effect of replacing B2O3 with CuO on the structural, optical absorption, thermal, mechanical, and gamma(γ)-ray shielding properties of four CKB glasses formulated as (65-y)B2O3-15Bi2O3-20K2O-yCuO (where y = 0, 0.3, 0.6, and 1.2 mol%). The glasses were created using the melt-quenching technique, and their non-crystalline structure was verified by X-ray diffraction (XRD) analysis. Fourier-transform infrared (FTIR) spectroscopy identified several structural groups, predominantly consisting of BO3, BO4 units, and B-O-B linkages. Thermal properties, assessed via Differential Scanning Calorimetry (DSC), indicated that the glass transition temperature was highest for the 0.3 mol% CuO sample (CKB0.3), demonstrating enhanced thermal stability in comparison to other compositions. Density measurements correlated positively with CuO concentration, peaking at 1.2 mol%, while molar volume, boron molar volume, oxygen packing density, and boron-boron separation distances showed a decreasing trend with increased CuO concentration. UV-Vis absorption spectroscopy indicated a decline in the optical energy gap and an increase in Urbach energy, attributed to the conversion of BO3 into BO4 units in the glass matrix. Mechanical properties, evaluated using the Makishima-Mackenzie model, demonstrated enhancements in elastic moduli and micro-hardness with rising CuO concentration. The γ-ray shielding properties (γ-RPs) were examined at energies of 0.662, 1.173, and 1.333 MeV, revealing that both the linear attenuation coefficient and effective atomic number reached their maximum values at 1.2 mol% CuO (CKB1.2). While CKB1.2 exhibited excellent mechanical and γ-ray shielding performance, CKB0.3 excelled in thermal stability and demonstrated γ-ray shielding efficiency comparable to CKB1.2. This suggests that CKB0.3 is a promising candidate for radiation shielding applications requiring a balanced combination of thermal stability and effective γ-ray attenuation properties, particularly at 0.662 MeV.

Perylene Bisimide-Functionalized Triphenylmethyl Radicals Showing High Stability and Reversible Electrochemical Redox Properties.

This study presents a series of triphenylmethyl monoradicals incorporating varying numbers of peripheral perylene bisimide (PBI) substituents (1PBI-TTM·, 2PBI-TTM· and 3PBI-TTM·). The incorporation of electron-withdrawing PBI substituents significantly enhances the stability of these carbon radicals, enabling them to display exceptional electrochemical redox reversibility. Notably, the electronic interplay between the PBI substituents and the central triphenylmethyl core facilitates unique and reversible multi-step redox reactions. Among the reported redicals, the tris-PBI functionalized radical (3PBI-TTM·) demonstrates the remarkable ability to accommodate up to seven electrons under negative potentials, forming high valence anions. This research pioneers the development of highly stable carbon radicals with superior electrochemical oxidation-reduction processes, presenting promising avenues for the advancement of electric energy storage technologies.