Biochar addition to soil is a promising option for climate change mitigation and is recognized to exert beneficial effects on soil fertility. However, recent meta-analysis documented controversial effects on soil–plant interactions and on crop yields response.The data presented in this paper are the results of a field experiment on a processing tomato crop aiming to enhance the knowledge on the real applicability of biochar at farm scale in a high fertility alkaline soil. The effects of two biochar types on soil properties and on quantitative and qualitative parameters of processing tomato were evaluated. Biochar application significantly increased the soil carbon content, the soil cation exchange capacity and the availability of NH4+, P and K. Moreover, it stimulated plant growth and N, P and base cation contents at harvest, reducing the leaf water potential in the warmer period. These results demonstrate that also intensive cultivations in fertile soil can benefit from biochar amendment.