Evaporation Process Research Articles

Suppression of the coffee-ring effect by controlling the solid particle density

Previous studies show that the coffee-ring effect can be suppressed by altering the droplet's evaporation rate, surface tension, surface properties, and shape of particles. This experiment used five types of particles with different densities to analyze their behavior during the droplet evaporation process. The results showed that when the particle density is close to the fluid density, the particles move within the droplet and accumulate at the edges, forming a pronounced coffee-ring effect. Conversely, with the higher difference between the particle density and the fluid density increases, they tended to deposit uniformly at the bottom of the droplet and were less likely to be pushed to the edges by capillary effects, effectively suppressing the coffee-ring effect. We also observed that the movement speed of high-density particles relatively slowed down through particle image velocimetry tracking technology. By analyzing the Peclet number and the timescale between particle sinking speed and particle movement speed due to capillary flow, we explained how particle density influences the critical factors of particle sinking and suspension, thereby inhibiting the formation of the coffee-ring effect.

Vacuum evaporation coupled with anaerobic digestion for process intensification and ammonia recovery: Model development, validation and scenario analysis

A mathematical model for vacuum evaporation process was developed, which was experimentally validated at different initial pHs and temperatures for ammonia removal from anaerobically digested sludge. Six scenarios were evaluated by combining vacuum evaporation process with anaerobic digestion using anaerobic digestion model 1. These scenarios included a control, a pretreatment by vacuum evaporation, a post-treatment by vacuum evaporation at pH 9, a post-treatment by conventional evaporation (100 °C), an intensification with vacuum-concentrated recycled digestate back to the digester, and a second intensification at pH 9. Results indicated that using the evaporator as post-treatment at pH 9 or for intensification at pH 9 were the most favorable options, recovering more than 76 % of the nitrogen present in influent sludge with no negative effect on methane production. An economic analysis showed that the intensification at pH 9 was cost-neutral, significantly higher than the net present value of the control scenario (–22 M$).

Study on the Micro-explosion Mechanism and Influencing Factors of Oil Water Mixed Fuel

In this study, the mechanism of micro-explosion/puffing of diesel-water and tail oil-water single droplet during evaporation was investigated, and the influence of temperature, water content, eccentricity, and their interaction on fragmentation time was analyzed. Separate single droplets into composite droplets and mixed droplets based on different nucleation methods. During the evaporation process of a single droplet, it underwent nucleation, bubble generation and growth, and fragmentation. The fragmentation modes of composite droplets and mixed droplets are manifested as micro-explosion and puffing. Specifically, the micro-explosion of mixed droplets can be divided into strong micro-explosion and weak micro-explosion. The occurrence of weak micro-explosion can be attributed to the following reasons: insufficient development of water(bubbles) near the surface leading to premature ejection, and preferential bubble growth near the surface impeding internal bubble expansion. In addition, temperature and water content had a dual effect on the micro-explosion characteristics of diesel-water droplets, and higher temperature and water content were conducive to the occurrence of micro-explosion in tail oil-water droplets. Temperature had the least effect on fragmentation time, followed by water eccentricity, and water content had the most significant impact. And the interaction between water content and eccentricity substantially affected fragmentation time, equating to the minimum distance from the water to the outer surface of the fuel droplet.

Simultaneous realization of efficient solar evaporation and electricity collection through dual regulation of chemical composition and pore channels

The solar-driven interfacial evaporation is a recently developed zero-energy technology for seawater desalination. However, the low evaporation rate poses a significant obstacle to its industrial application, and the collection of streaming potential formed during the evaporation process remains challenging. In this paper, we constructed a solar evaporator capable of simultaneously achieving efficient solar evaporation and electricity collection. Specifically, a double network structure hydrogel comprising polyvinyl alcohol (PVA) and TEMPO-oxidized cellulose nanoparticles nanofibers (TOCNFs) was fabricated using ice templating, with the addition of sodium lignosulfonate (SLS) to further modulate water distribution within the network. The incorporation of carbon nanotubes (CNTs) enabled the achievement of a PVA/TOCNFs/SLS (PTFS) gel-based solar evaporator. The strong electronegativity carried by the TOCNFs enhances the electrostatic repulsion in the PVA-TOCNFs network, thus improving the mechanical properties of PTFS evaporator. The introduction of SLS, which contains abundant sulfonate groups, provides certain antibacterial properties to PTFS evaporator. Due to the presence of numerous hydrophilic groups, both TOCNFs and SLS can form weak hydrogen bonds with water. Through the synergistic effect of TOCNFs and SLS, the latent heat of water in PTFS evaporator is reduced to 924 kJ kg−1, enabling an evaporation rate of 3.70 kg m−2h−1 under 1 sun irradiation. Owing to the smaller pore size relative to the Debye radius and the presence of electronegative functional groups within the pores of PTFS evaporators, an overlapping bilayer is formed when water flows through, resulting in an open-circuit voltage increase of up to 270 mV. The integration of high-efficiency solar evaporation with streaming potential collection presents a novel avenue for enhancing the utilization of solar energy.

Comments: Running Hot and Cool for a Power Boost

_ Have data center operators become the major proponents of nuclear power? A flurry of recent announcements suggests so. But three major industry players are leveraging their oil and gas expertise to offer another process to help data center operators run their sites more sustainably—immersion cooling liquids. Nuclear power took top billing in the past 2 months with Amazon and nuclear reactor company X-Energy announcing a collaboration to bring online more than 5 GW of small modular reactors (SMRs) in the US by 2039. Google and Kairos Power will collaborate to deploy 500 MW with SMRs by 2030. Kairos will build them, then sell energy and ancillary services to Google under power purchase agreements (PPA). Microsoft has an eye on the restart of the retired 835-MW Three Mile Island Unit 1 and signed a 20-year PPA with Constellation Energy which owns the plant and plans to finance the work required with the PPA, its largest ever. These early plans could boost the available power supply while lowering carbon emissions, but hurdles remain. The Nuclear Regulatory Commission (NRC) must approve commercial deployment; SMRs are in relatively early stages and regulatory frameworks are evolving; the need for public acceptance; and the NRC comes into play again to regulate the management and disposal of radioactive nuclear waste. In other words, this will not be a speedy solution. Immersion Cooling for Data Centers—Shell, ExxonMobil, and BP Although the practice of liquid cooling isn’t a new concept in the oil and gas industry which uses water, oil, cooling towers, seawater, and engineered liquids to handle heat in various processes and plants, data center operators are exploring the use of a muscle car version—immersion cooling. Immersion cooling is gaining broader attention and consideration. Data Center Frontier called it “ready for its big moment.” The Cleantech Group forecasts that the market for immersion cooling could grow from $270 million to $2.54 billion by 2032. The process entails submerging servers with modified hardware into a bath of nonconductive liquid (e.g., fans are removed, protective coatings are applied, a controlled temperature range of the liquid is maintained) to allow the heat generated by components to be transmitted into the fluid and cooled using either a single-phase or two‑phase method. In the single-phase process, a thermally conductive dielectric liquid is used. It is circulated through immersion tanks, using pumps, to an external heat exchanger, then it is returned to the tanks. The two-phase method is more complicated. The dielectric fluid is one that will change from a liquid to a gas at a relatively low temperature (lower than the operating temperature of the electronic components). Because the immersion fluid has a low boiling point, the boiling causes the fluid to change state, from liquid to gas. This phase change is an efficient method of removing heat due to the vaporization process. As immersion cooling gains traction as a sustainable and efficient alternative to traditional air cooling, major energy companies are stepping in to drive innovation in this technology. Shell, ExxonMobil, and BP, each with their own specialized immersion cooling fluids and collaborative ventures, are helping to advance the commercial adoption of immersion cooling in data centers worldwide. Shell Lubricants joined Green Revolution Cooling (GRC), one of the first companies to develop immersion cooling, as one of the first members in GRC’s ElectroSafe Fluid Partner Partner Program in 2022 and has deployed GRC Immersion Cooling Systems in its Houston data center and with partner Asperitas in a high-performance cluster (HPC) in its Amsterdam facilities. Shell’s single-phase, synthetic immersion fluid is based on its proprietary gas-to-liquids technology. It is conducting pilot programs with Microsoft and Alibaba in China and working with Infosys to create an integrated immersion cooling system. ExxonMobil launched its “portfolio of synthetic and nonsynthetic fluid” last October. In April 2024, the company announced it is working with Intel to develop new liquid cooling technologies for data centers. BP’s lubricant subsidiary, Castrol, is offering a range of single-phase immersion cooling fluids. It is working with Submer on future fluids and has set up a UK test center for potential customers at its headquarters. Castrol joined the Research Institutes of Sweden (RISE) to study thermal management and materials science using RISE’s data center test bed. Immersion cooling may deliver efficiency gains and lower power demand at a lower cost than newbuild nuclear power, but will it be enough? Or is it a stopgap until power generation ramps up? Note: I’m pleased to announce that Trent Jacobs has been promoted to the position of JPT managing editor and will be this column’s new voice starting with our December issue.

Investigation of the flash vaporization technique as a novel anolyte separation method in a copper-chlorine thermochemical cycle for sustainable hydrogen production

Thermochemical water-splitting processes are a promising alternative to the conventional hydrogen production technologies. In this regard, the thermochemical copper-chlorine cycle is amongst the clean hydrogen production processes that have shown immense promise to achieve commercialization in the long term future through several investigations reported in the open literature. A primary reason for this is its moderate temperature requirements which can be harnessed through a wide variety of sources such as waste heat or solar thermal energy. More specifically, the four-step variant of the copper-chlorine cycle has exhibited the highest efficiencies compared to its three and five-step versions. However, certain aspects of the cycle need further attention. One such aspect is the fourth and the final step of the cycle – the anolyte separation step which ensures the complete replenishment of all chemical compounds within the cycle. The anolyte is a homogeneous solution that constitutes water, hydrochloric acid, copper (II) chloride, and copper (I) chloride. The existing methodology for the separation of all these chemicals considers a multi-step drying process that takes place at ambient pressure and temperatures over 100°C. These conditions have been concluded to contribute to lowering the energy efficiency and increasing the cost rate of hydrogen through various studies previously conducted and published by the authors. In this regard, the authors have investigated an alternative technique for the anolyte separation process – the flash vaporization method where the partial separation of various chemical species can be achieved under vacuum conditions resulting in lower required temperatures and ultimately making the anolyte separation process relatively less energy intensive. Thus, this paper develops a stand-alone experimental set-up to investigate the flash vaporization process on a lab scale to determine its feasibility and potential to be a replacement for the existing approach of anolyte separation in a four-step copper-chlorine thermochemical cycle. The experiments are conducted under a wide variety of conditions and the obtained results are quite promising. Further, this study also considers the development of an empirical model to enable an analytical quantitative prediction of the separated anolyte solution.

Теплоотдача при движении воды в трубе при температурах, близких к температурам кипения в переходном режиме

Currently, there is a problem of developing effective methods to calculate heat and mass transfer processes during steam condensation from a vapor-gas mixture in industrial devices. This is due to the need to create new reliable and highly efficient designs of heat exchangers for various purposes. The finite element method has been used in the ANSYS Fluent software package during the numerical simulation. An experimental plant is tested in the pipeline of an industrial enterprise at the production site of the Technopolis KHIMGRAD industrial park (Kazan-city). The applicability of the Lee model to solve problems of water flow in a pipeline with partial evaporation is proved. This model allows you to accurately account for the processes of evaporation and condensation, which is important for the design of cooling and air conditioning systems. The authors have designed a three-dimensional model of the flow area of the experimental module and a CFD model to calculate temperatures, phase velocities and their concentrations, considering the peculiarities of the ongoing processes of heat and mass transfer. A slight effect on the heat flow of a 180° rotation during the flow of a liquid medium in the range of the Reynolds numbers 1800–2600 is shown. The developed model is verified with the results obtained at the experimental plant. It is established that the model reproduces experimental data well. An analysis of studies of heat and mass transfer processes during the fluid flow in channels in the presence of phase transitions is carried out. The problems of calculating the parameters of heat transfer during the movement of a fluid in a transient mode are revealed, especially at values of the Reynolds number close to 2000. The experimental plant diagram is presented. It is found that in the range of Reynolds numbers of 2600–3600, the calculated temperature values differ from the temperature values obtained experimentally by less than 0,42 %. During the partial transition of water into steam in the range of Reynolds numbers of 1800–2600, the deviations were less than 6 %, which confirms the adequacy of numerical modeling of calculating the heat transfer process in a pipe. It is shown that considering the influence of temperature on surface tension, the coefficient of thermal conductivity of water and the coefficient of dynamic viscosity of water is important to obtain accurate results. The proposed approach can be used to optimize the operating parameters of condensers and evaporators, as well as to accurately calculate the heat transfer coefficient and determine the areas of vapor formation. It will improve the energy efficiency of industrial installations and reduce the cost of equipment operation.

Исследование работы термической опреснительной установки с контактным испарителем и компрессией паровоздушной смеси

One of the global issues of our time is the shortage of freshwater resources. Desalination of marine and brackish waters is a promising solution to this problem. The most common desalination technologies are thermal (distillation) and baromembrane (reverse osmosis and nanofiltration) processes. When designing demineralization stations with reverse osmosis units, it is necessary to consider a number of limitations associated with higher requirements for pretreatment of water entering the unit. The use of thermal desalination plants makes it possible to obtain fresh water of higher quality, and less stringent requirements are imposed on the preliminary preparation of water for this type of unit. However, during the operation of desalination plants of this type, scale forms on the heating surfaces, which negatively affects the efficiency of the unit. Scale is formed less intensively in the units with contact vapors, since in this case the evaporation process occurs in volume. Thus, the development of thermal scheme of such unit and the study of their operation is relevant. The tasks have been solved using the methods of experimental studies of heat and mass transfer processes, mathematical processing of experimental data, and balance calculations of power plants. A thermal scheme of a thermal desalination plant with a contact evaporator with compression of a vapor-air mixture has been developed. Thermal and material balance has been compiled, on the basis of which energy costs have been determined to obtain m3 of fresh water. The authors have proved the determining influence of the temperature of desalinated water in the bubbling zone on the productivity of desalination plants with a contact evaporator. An amendment has been obtained that allows the initial salinity of water and brine to be considered when calculating the operating cycle of the unit. As a result of the analysis of the results obtained, it is found that an increase in the water temperature in the bubbling zone allows us to increase the productivity of the unit, and an increase of the drying temperature of the vapor-air mixture leads to a decrease of the energy consumption of the desalination plant. The introduction of an amendment considering the salinity of the source water and brine makes it possible to increase the accuracy of calculating air humidification up to 15 %.

Improving a technique for producing a polycomponent semi-finished product with high degree of readiness for 3-D printing of functional food

The object of this study is the process of producing polycomponent semi-finished products of a high degree of readiness using a model structure of functional equipment, in particular, based on apple, Jerusalem artichoke, table beet, and sea buckthorn. A feature of the improved technique is the implementation of preliminary heat treatment with hot steam of raw materials: apple – 1.0...2.0 min, Jerusalem artichoke – 3...6 min, and table beet – 6...12 min, respectively. Sea buckthorn was not processed, only technological rinsing was used. Grinding of raw materials was carried out on a double grinding machine (apple, Jerusalem artichoke, and table beet – 0.2...0.5 10-3 m, and sea buckthorn – 0.5...1 mm). The combined production of polycomponent semi-finished products of a high degree of readiness (pastes/fractional powder) was implemented using a model structure of functional equipment. The boiling process in a rotary-film evaporator was carried out at a temperature of 55 °C for 65 seconds to a dry matter content of 25 %. Drying of the cooked multicomponent mass was carried out in a single-drum cylindrical IR dryer at a temperature of 50 °C to a final moisture content of 3...6 % and fractional grinding (0.3...0.6 mm). The rheological properties of the paste-like multicomponent semi-finished product were determined by the change in dynamic viscosity for composition 2, which is 485 Pa∙s, and in the control sample of applesauce, this indicator is 50 Pa∙s. When boiling in a rotary-film evaporator at a temperature of 55 °C to a content of 30 % of dry substances, there is an increase in the strength of dynamic viscosity by 3.2 times (600 Pa∙s), and in the control (apple paste) this indicator is 178 Pa∙s with a dry matter content of 25 %

Shadow effect in dual‐source thermally evaporated perovskite patterns

AbstractPerovskite light‐emitting diodes (PeLEDs) have recently emerged as a potential next‐generation display technology due to their wide color gamut, high external quantum efficiency (EQE), and low fabrication cost. The thermal evaporation process with no solvent involvement and offers low substrate selectivity and high compatibility with production lines has attracted significant academic interest. However, in thermal evaporation processes, the shadow effect greatly affects the deposition size and positioning accuracy of the patterns, consequently impacting the effective device area and process repeatability of PeLEDs. In this study, we calculated the shadow distance during the dual‐source thermal evaporation and analyzed the issues of misalignment and size deviation caused by shadow effects. Based on the calculation of shadow distance, we increased the substrate height from 33 to 38 cm to enhance the deposition angle. This adjustment led to an improvement in the characteristic parameter W1/Wdot from 0.178 to 0.365 during perovskite deposition. As a result, we successfully obtained a high‐resolution perovskite array with uniform morphology and photofluorescence (PL) emission at 600 pixels per inch (ppi). This demonstrated the reliable calculation and analysis of shadow distance, which is effective for fine deposition of high‐resolution perovskite patterns and PeLEDs.

Experimental study of vegetable oil droplets vaporization under low temperature conditions such as those found in diesel engine cold parts

This paper presents an analysis of three vegetable oil droplets vaporization process in the range temperature from 473 to 723 K corresponding to low temperature conditions found in diesel engine cold parts. This process is analyzed for a droplet evaporating in a hot environment at atmospheric pressure using the fiber-suspended droplet technique well used in the literature, and analyzing the droplet normalized square diameter and temperature evolution surrounding the droplet when vaporizing. The main difference between those already studied in literature is the range temperature which varies between 473 and 723 K in which vegetable oils vaporizing problems leading to deposits formation in the cold regions of diesel engines especially in direct injection. This presents a scientific challenge for resolving deposit formation. The findings reveal that vegetable oil droplets experience expansion and heating for temperatures below 623 K: no other changes are observed. Between temperatures of 623 and 683 K, an increase in temperature, expansion, and an inconsistent vaporization is observed. This is followed by a phase of low and constant vaporization. From 683 K, vegetable oils experience an initial stage of heating and expansion, which is accompanied by a phenomenon of puffing and bursting. Finally, in the last phase, residue formation occurs. Puffing and bursting phenomena manifest once the temperature reaches 683 K, indicating the emergence of substantial quantities of light compounds including carboxylic acids, aromatics, acrolein, ketene, and fatty acids. These compounds are formed through the thermal degradation and polymerization of vegetable oils. This process causes deposits to form in the colder areas of diesel engines.

Lumped Parameter Analysis of Autogenous Propellant Pressurization System for Nuclear Thermal Rocket

This work proposes a new propellant management configuration for an ammonia-fueled nuclear thermal propulsion system. The suggested configuration maximizes the advantage deriving from the autogenous pressurization of ammonia by exploiting the thermal power lost by the nuclear reactor toward the vacuum space due to leaking radiation. In this layout, a tank containing ammonia in saturated conditions is placed near the nuclear reactor and receives an input thermal power proportional to the dose of gamma rays and neutrons absorbed by the tank walls and the ammonia itself. Such a thermal power accelerates the vaporization process of the saturated ammonia, thus increasing the pressure in the tank. A pressure regulator valve exploits this overpressure to pressurize the ammonia propellant contained in a run tank to the level required by the mission by connecting the two ammonia volumes. The pressure achieved inside the run tank pushes the propellant with an adequate mass flow rate inside the nuclear reactor. The developed lumped parameter analysis shows how this propellant management system can provide a constant mass flow to the nuclear reactor without using a turbopump assembly. Moreover, it is shown how the proposed concept allows for a reduction in the radiation shield mass.

Dynamic Water Microskin Induced by Photothermally Responsive Interpenetrating Hydrogel Networks for High‐Performance Light‐Tracking Water Evaporation

AbstractSolar‐driven interfacial water evaporation is attracting increasing attention as a promising environmentally‐friendly solution to freshwater scarcity. It has been proven that a thin water layer on photothermal materials can prevent solar energy from invalidly heating the excess water to enhance the evaporation rate. However, the current water layers are usually formed on inelastic materials via confined capillarity, which are static and uncontrollable. Herein, we propose a flexible hydrogel‐based photothermal conversion material with thermal responsiveness by facile frontal polymerization, which can generate a unique dynamic water microskin (DWMS) during the solar evaporation process. The copolymerized hydrogel, introduced by the second polymeric poly(vinyl alcohol) network and thermally responsive poly(N‐isopropylacrylamide) (PNIPAM), exhibits reinforced mechanical strength and photothermally triggers reversible shrinking/swelling cycles that enable a thin water layer (≈32 µm) to balance the feedwater supply and photothermic energy input dynamically. As a result, a stable superior vaporization rate of 8.7 kg m−2 h−1 is achieved based on a cylindrical hydrogel with 6 cm height under 1 sun. Moreover, the simultaneous responsive bending allows efficient omnidirectional solar evaporation by light‐tracking to ensure maximum perpendicular solar absorption, which provides an alternative strategy for durable high‐efficiency solar evaporators for effective thermal management and solar utilization.

Growth of L-asparagine monohydrate organic single crystals: An experimental and DFT computational approach for nonlinear optical applications

Good optical quality of L-asparagine monohydrate (C4H8N2O3.H2O) organic single crystal has been grown by adopting natural slow evaporation process at room temperature from aqueous solutions. The lattice parameters obtained by powder X-ray diffraction data revealed orthorhombic crystal system of the harvested crystal. The morphology and planes of the crystal have been identified. The molecular vibrations and functional groups have been specified by Fourier transform infrared (FTIR) spectroscopy studies. Energy dispersive X-ray (EDX) study has been availed to find out the elements constituting the crystal. Scanning electron microscopy, (SEM), provided the surface morphology of the crystal. The dependence of dielectric properties on frequency and temperature have been investigated and the electronic polarizability (α) has been determined. UV–vis spectral analysis shows that the crystal possesses good optical transmittance in the visible part of the energy spectrum. The optical band gap and the Urbach energy have been determined from lower absorption edge. Third order nonlinear susceptibility χ(3), nonlinear refractive index (n2), and linear susceptibility χ(1) have been calculated by Miller's generalized rule. The first-principle computation of band structure of electrons and the electron density of states have been discussed, which suggest that the crystals possess direct band gap. Density Functional Theory (DFT) with B3LYP function by Gaussian09W software was utilized to calculate HOMO-LUMO energy gap as well as non-linear optical parameters namely, linear polarizability (α), hyperpolarizability (β and γ) and dipole moment (μ) of L-asparagine monohydrate crystal. All the findings prove that L-asparagine monohydrate is a promising NLO crystal.

The Effect of Doping Zinc Oxide Thin Films With (0.5 wt. %) Carbon Nanotubes by Vacuum Evaporation

The study included the production of nano-thin films made of zinc oxide doped with carbon nanotubes (ZnO:CNTs) at a doping ratio of 0.5 wt%. The materials are applied onto glass substrates using the vacuum evaporation process. The structural characteristics of the thin films of undiluted and doped ZnO were assessed using X-ray diffraction (XRD). Additionally, the surface properties of the films were examined using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The optical characteristics of the thin films were analyzed and described using UV-Vis spectroscopy. The ZnO thin films exhibited crystalline formations. The thin films exhibited significant orientations along the (100), (002), and (101) crystallographic planes, indicating their hexagonal phase structures. The crystal size of ZnO thin films exhibited a range of 30.87 nm to 19.96 nm after the process of doping. The study findings demonstrate that the addition of carbon nanotubes leads to an increase in the absorption ratio. Zinc-doped carbon nanotube thin films has features that make them suitable for many applications, such as gas detectors and UV detectors.

Heat and mass transfer and deformation during chiffon cake baking

The structural transformation from a foam liquid to a porous solid during cake baking involves pore development and solidification, resulting in complex coupled heat transfer, mass transfer, and deformation processes. Studying the mechanisms can provide important references for understanding the physical processes of numerous foods containing gas pores. We constructed a multiphase flow-deformation model for chiffon cake baking, and validated its accuracy by comparing the experimental results of temperature and height. Based on the model, the heat transfer, mass transfer, and deformation characteristics were investigated. In the pore-closed region, the evaporation-diffusion-condensation process of water vapor enhances heat transfer, and its contribution to heat transfer has an equivalent thermal conductivity of up to 0.64 W/(m·K), which increases the heating rate. In the pore-opening region, the water vapor evaporates from the high-temperature, high-water activity region and is transported towards the lower-temperature region and external environment. This process enhances heat transfer and induces an evaporative cooling effect, resulting in a uniform temperature distribution that remains below 100 °C across the majority of the region. Cake expansion occurs in the low-viscosity, pore-closed region, and the water vapor generated at high temperatures serves as the primary driving force source, contributing up to 84.6%.

Response of the upper ocean to northeast Pacific atmospheric rivers under climate change

Atmospheric rivers are important transport vehicles for Earth’s water cycle. Using a high-resolution, eddy-resolving Earth System Model, atmospheric river impacts on the upper ocean are investigated by analyzing historical and climate change simulations. For atmospheric rivers along the North American coastline, strong winds cause significant dynamic and thermodynamic upper ocean responses. They push ocean water towards the coast, measured by sea surface height, a process that is amplified under climate change. Mixed layers are deeper upstream of atmospheric rivers, and shallower downstream, however for climate change, shoaling downstream is subdued. Air-sea heat fluxes tend to promote ocean cooling upstream and warming downstream, although different regions have different climate change heat flux signals. Southern California heat flux changes due to warming are driven by evaporative processes and strengthen the ocean responses seen in historical simulations. The regions north are primarily dominated by sensible heat flux changes and counter the historical patterns.

Modeling and Analysis of Droplet Evaporation at the Interface of a Coupled Free-Flow–Porous Medium System

AbstractEvaporation of droplets formed at the interface of a coupled free-flow–porous medium system enormously affects the exchange of mass, momentum, and energy between the two domains. In this work, we develop a model to describe multiple droplets’ evaporation at the interface, in which new sets of coupling conditions including the evaporating droplets are developed to describe the interactions between the free flow and the porous medium. Employing pore-network modeling to describe the porous medium, we take the exchanges occurring on the droplet–pore and droplet–free-flow interfaces into account. In this model, we describe the droplet evaporation as a diffusion-driven process, where vapor from the droplet surface diffuses into the surrounding free flow due to the concentration gradient. To validate the model, we compare the simulation results for the evaporation of a single droplet in a channel with experimental data, demonstrating that our model accurately describes the evaporation process. Then, we examine the impact of free-flow and porous medium properties on droplet evaporation. The results show that, among other factors, velocity and relative humidity in the free-flow domain, as well as pore temperature in the porous medium, play key roles in the droplet evaporation process.

Empirical, computational studies and non-covalent interactions analysis of a novel salt with cadmium transition metal precursor

In this research paper, (C3H5N2)6[CdCl4][CdCl6] was successfully synthesized using a slow evaporation process. The structure was confirmed through single-crystal X-ray crystallography, FT-IR, and thermal analysis. The material was found to crystallize in the tetragonal system (space group I41/a) and the following parameters a = b = 12.0872 (8) Å; c = 24.6985 (16) Å, the crystal packing shows parallel layers of cations and stacks of discrete anions positioned at y = 1/4 and 3/4. The junction between the monoprotonated imidazolium cations and the anions, along with the crystal structure stability, relies on Cl···H−N, and Cl···H−C hydrogen bonds. Computational investigations, conducted using the B3LYP method with 6–311++G(d,p) and LANL2DZ mixed basis set, demonstrated close alignment between the computed and the experimental data, providing insights into the material's geometrical and vibrational properties. The non-covalent interactions were studied through Atoms-In-Molecule (AIM) and Reduced Density Gradient (RDG) analysis and quantitatively using the Hirshfeld surfaces associated with 2D fingerprint plots. Furthermore, thermal stability was assessed through Thermogravimetric and Differential Scanning Calorimetry (TG–DSC) analysis.

Flow characteristics and performance optimization of temperature and pressure reducing valve with droplets evaporation

The influence of water spray arrangement on temperature reduction performance is significant in temperature and pressure reducing valves (TPRV). A verified vapor-liquid two-phase flow in TPRV was established by Euler-Lagrange flow and droplets evaporation model. The heat and mass transfer processes in droplet evaporation are presented. The influence of nozzles number, spray position, injection direction on internal flow characteristics and temperature reduction performance of TPRV was analyzed. An optimized spray water arrangement was determined via nonlinear fitting model, the great temperature reduction performance was obtained. The results show that the mass flow rate of TPRV inlet and outlet has a non-linear variation with the valve opening. The significant pressure gradient occurs in the valve core and chamber. The upward oblique jet at throat makes the temperature near the spray area low and the temperature at throat downstream high. The range of high Mach numbers increases with the increasing of valve opening. The temperature variation of parallel injection and reverse injection is different with the increasing of the nozzles number. The vortex intensity and range have a stronger influence on temperature reduction performance ability. The temperature reduction performance of optimized TPRV is improved by 0.6 %- 3.98 %. The optimization of water spray arrangement on temperature reduction performance is applicable to various loads.