We investigate the role of the |$\mathrm{H}_2^+$| channel on H2 molecule formation during the collapse of primordial gas clouds immersed in strong radiation fields which are assumed to have the shape of a diluted blackbody spectra with temperature Trad. Since the photodissociation rate of |$\mathrm{H_2^+}$| depends on its level population, we take full account of the vibrationally resolved |$\mathrm{H}_2^+$| kinetics. We find that in clouds under soft but intense radiation fields with spectral temperature Trad ≲ 7000 K, the |$\mathrm{H_2^+}$| channel is the dominant H2 formation process. On the other hand, for harder spectra with Trad ≳ 7000 K, the H− channel takes over |$\mathrm{H_2^+}$| in the production of molecular hydrogen. We calculate the critical radiation intensity needed for supermassive star formation by direct collapse and examine its dependence on the |$\mathrm{H_2^+}$| level population. Under the assumption of local thermodynamic equilibrium (LTE) level population, the critical intensity is underestimated by a factor of a few for soft spectra with Trad ≲ 7000 K. For harder spectra, the value of the critical intensity is not affected by the level population of |$\mathrm{H_2^+}$|. This result justifies previous estimates of the critical intensity assuming LTE populations since radiation sources like young and/or metal-poor galaxies are predicted to have rather hard spectra.
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