Pressure Plasma Research Articles

Development of chitosan-acrylic acid based hydrogels with incorporated polyaniline and plasma treatment

Hybrid hydrogels are materials that incorporate features from multicomponent systems of polymers, significantly improving their functionality and making them ideal for biomedical applications. Both natural and synthetic polymers are utilized, further enhancing their functionality. The combination of polyaniline (PANI), chitosan (CS), and acrylic acid (AA) can result in a multifunctional hybrid hydrogel that is antibacterial, hydrophilic, and salt-sensitive. A multifunctional PANI-CS-AA with varying PANI weight ratio was synthesized in this study. In addition, improving the surface of the multifunctional hydrogels by atmospheric pressure plasma (APP) treatment was also investigated. During APP treatment, the production of reactive species (e.g., OH and N2 radicals) responsible for the functionalization of the hydrogel surface was confirmed through optical emission spectroscopy. The integration of three polymer components in the synthesized hydrogels was confirmed through the presence of their mid-FTIR spectral characteristics, particularly in the AA and CS C=O, PANI quinonoid and benzenoid units, AA COO−, and the PANI aromatic and C—H vibration regions. Moreover, the hybrid hydrogels with incorporated PANI and APP treatment improved their wettability and surface free energy (SFE) characteristics. The hybrid hydrogels with 0.25 wt. % PANI and exposed to 2 min air plasma yielded the highest hydrophilicity and total SFE with values 41.27° ± 2.15° and 135.68 ± 4.72 mJ/m2, respectively. The plasma-treated 0.25PANI-2.5CS-4AA samples exhibit improved swelling response in water (Smax = 1310 ± 100; ks = 0.005) and saline media (Smax = 1280 ± 80; ks = 0.001) due to enhanced polymeric chains and affinity toward polar liquids. Synthesized hydrogels exhibited antibacterial activity, as evidenced by the zone of inhibition test. Clearing zones measured were in the range of 16–27 mm. The study developed an APP-treated tricomponent hydrogel consisting of PANI, CS, and AA that has improved hydrophilicity, salt sensitivity, and antibacterial features.

Design a double-layer nozzle device that generates a multi-beam atmospheric plasma jet to achieve large-area processing

A double-layer (DL) nozzle device mounted on a dielectric tube for expanding the range of atmospheric pressure plasma jet is designed. Using the hierarchical structure of the nozzle, multiple discrete currents are obtained to form multiple discharge channels. The results show that the discrete flow can be divided into three categories: upper jet, middle jet and lower jet. For media tubes that are not equipped with the nozzle, the range of active substances of the DL nozzle device can be expanded to 5 times, the area can reach 1017 mm2, and the treatment of Escherichia coli (E. coli) for 120 s can achieve 100 % inactivation. A numerical model is established to analyze the distribution of the air flow field and helium mass fraction of the DL nozzle device. The DL nozzle device was used to treat deionized water (DIW), and plasma activated water (PAW) with better physical and chemical properties was obtained. In particular, the PH value was reduced from 7.39 before treatment to 4.16 after 180 s treatment. The concentration of H2O2 increased significantly from 23.5 to 64.56 μM in 90 s.

Toward 95.5% Efficient Red Emissive Carbon Dots: Oxidation State Enhancing Radiative Electron-Transition of Indole Fluorophore.

Red fluorescence carbon dots (CDs) are promising for diverse applications and have attracted tremendous research interest. However, it is still challenging to achieve red fluorescence CDs with high fluorescence quantum yields (QYs > 50%). Herein, three kinds of red fluorescence CDs with QYs of 53.48, 85.21, and 59.18% are prepared. Benefiting from the oxidation induced by atmospheric-pressure O2 plasma processing, 95.5% efficient red fluorescence emission is achieved. It is revealed that the indole based fluorophores act as the red-emitting photoluminescence center. The synergistic effect between the C-O-C structure and indole based fluorophores plays a key role in promoting the efficiency of radiative electron transition and controlling the red fluorescence QYs. Additionally, the CDs show promising prospects for in vivo bioimaging and low in vivo toxicity. This work shows a new way for achieving high-efficiency red fluorescence CDs, and it may guide the development of high-performance CDs for diverse applications.

Evolution from a guided-streamer mode to a continuous-discharge mode in an atmospheric pressure argon plasma jet

Atmospheric pressure plasma jet (APPJ) has attracted much attention due to its versatile applications in various fields, which normally operates in either a guided-streamer mode or a continuous-discharge mode. In this paper, temporal evolution is observed from the guided-streamer mode to the continuous-discharge one in an argon APPJ excited by a sinusoidal voltage. Waveforms of voltage and current indicate that the voltage applied to the electrode is distorted severely from the ideal sine. For the guided-streamer mode, there is only one discharge pulse per half voltage cycle. For the mode transition or the continuous-discharge mode, there is only one discharge composed of a pulse and a hump per half voltage cycle. Fast photography implemented for the mode transition reveals that both the discharges in the positive and the negative voltage polarities evolve from the guided-streamer mode to the continuous-discharge one. In the guided-streamer mode of the mode transition, the discharge behaves as a positive streamer in the positive voltage polarity, while a negative streamer in the negative voltage polarity. In addition, the mode transition only occurs in a range of dissipated power and gap width. Based on optical emission spectroscopy, temporal evolutions of the mode transition are investigated for excited electron temperature, electron density, and field strength. Moreover, their spatial distributions along the argon stream are studied at different time instants. These results are of great importance for the discharge dynamics of APPJ.

High-Speed Removal Process for Organic Polymers by Non-Thermal Atmospheric-Pressure Spark Discharge at Room Temperature and Its Mechanism

Heel marks (HMs) are a type of dirt stain consisting of polyester-based urethane rubber on polyvinyl chloride (PVC) floor surfaces. The rapid removal of HMs was achieved by using non-thermal atmospheric-pressure plasma technology. Mimetic HMs were prepared by coating PVC floor samples with HMs to a thickness of 13.9 μm. The removal area, thickness, and volume were measured after applying spark discharges at high voltage and a repetition rate of 50 kHz. The treated surfaces were analyzed by using X-ray photoelectron spectroscopy (XPS) and pyrolysis–gas chromatography with time-of-flight mass spectrometry (Py-GC/TOFMS). Removal rates of 20 mm2/min in area, 52 mm3/min in volume, and 7 μm/min in depth were achieved with an inter-electrode distance of 10.0 mm and an air flow rate of 20 standard liters per minute. A removal depth of 10 μm/min was achieved without air supply. The mechanism of stain removal by spark discharge was modeled by decomposing the original high-molecular-weight molecules in polyester-based urethane rubber into low-molecular-weight molecules, such as methylene diisocyanate (MDI) components. The results of this study may facilitate the development of a novel electric vacuum cleaner capable of removing floor stains.

Influence of bias voltage and oxygen addition on the discharge aspects of a diffuse argon plume in an atmospheric pressure plasma jet

A remote plasma, also referred to as a plasma plume (diffuse or filamentary), is normally formed downstream of an atmospheric pressure plasma jet. In this study, a diffuse plume is formed by increasing the bias voltage (U b) applied to the downstream electrode of an argon plasma jet excited by a negatively pulsed voltage. The results indicate that the plume is filamentary when U b is low, which transits to the diffuse plume with increasing U b. The discharge initiated at the rising edge of the pulsed voltage is attributed to the diffuse plume, while that at the falling edge contributes to the filament in the plume. For the diffuse plume, the discharge intensity decreases with the increasing oxygen content (C o). Fast photography reveals that the diffuse plume results from a negative streamer, which has a dark region near the nozzle with C o = 0%. However, the dark region is absent with C o = 0.5%. From the optical emission spectrum, the electron density, electron excitation temperature, gas temperature, and oxygen atom concentration are investigated.

Tuning plasma chemistry by various excitation mechanisms for the H2O2 production of atmospheric pressure plasma jets

Abstract Atmospheric pressure plasmas (APPJs) are widely used for research purposes or industrial applications. There are plenty of different APPJs designed with various geometries and excitation frequencies ranging from kHz over RF (MHz) to fast ns pulses. A direct comparison of these APPJs is often challenging as the different geometries or the different excitation frequencies are not the same and can strongly influence plasma behaviour. In this work, this challenge is met and overcome by the use of an APPJ which can be operated at various excitation frequencies. kHz pulsing with a high voltage peak with µs rise time, sinusoidal voltage pulse at 13.56 MHz and fast high voltage ns pulse were applied to the plasma jet used. The production of H 2 O 2 was investigated by treating liquids and measuring the H 2 O 2 concentration in the treated liquid. Fast ns pulses and RF excitation show similar results, while the kHz excitation is less effective in the H 2 O 2 production.

Efficacy of Atmospheric Pressure Plasma Jet-Induced Surface Treatment on Wettability, Surface Topography, and Shear Bond Strength of Ceramic Surfaces for CAD-On Assembly

Efficacy of Atmospheric Pressure Plasma Jet-Induced Surface Treatment on Wettability, Surface Topography, and Shear Bond Strength of Ceramic Surfaces for CAD-On Assembly

Spectroscopic analysis of single and multiphase electrical discharge for clean energy conversion

Abstract In this study, we examined non-thermal atmospheric pressure plasma processes operating under varying conditions using different liquid and gaseous hydrocarbon materials. The light emission from the discharges were analyzed through optical emission spectroscopy to comprehend the products generated in different parameter space. The gaseous products from each of these analyses were also collected and analyzed through gas chromatography. Analysis of the optical emission from the discharge and concentration of the gaseous products show a linear trend between emission intensity ratio Hα/C2 and gas concentration ratio H2/C2Hx. Gas temperature and electronic excitation temperature of different experimental conditions were also compared and indicates that spark discharge relates to higher electronic excitation temperature compared to glow discharge of similar medium. Higher electronic excitation temperature leads to generation of different products from spark discharge compared to glow discharge. Glow discharge generates more of the intermediate products. Whereas spark discharge, because of its higher electronic excitation temperature, leads to higher rate of dissociation and therefore generates more of the dissociated products. Glow discharge, for example generates more of OH and H from the moisture present in the carrier gas as impurity, whereas spark discharge would generate more of Hα and O particles further breaking down the OH bonds. Finally, UV-Vis analysis was performed on the liquid products of the discharge and reveals that the photo-centers and the newly generated soot nano particles absorb the UV range lights and some of the visible range light emission mostly up to ~600nm.

Comparison of the transportation of reactive species from He and Ar atmospheric-pressure plasma jets to aqueous solutions

Comparison of the transportation of reactive species from He and Ar atmospheric-pressure plasma jets to aqueous solutions

Effects of atmospheric pressure plasma treatment and its aging behaviors on interfacial strength of PI/PEEK composite film

AbstractSince the properties of surface roughness with time and the wettability pattern of polymer surfaces transformed by plasma remain unclear. In order to understand the mechanism of aging effect on film properties, this paper analyzes the aging of plasma‐treated PI films. The optimal treatment conditions were first explored by adjusting the plasma treatment power. Based on the effect of plasma treatment power on the surface physicochemical properties and mechanical properties of PI films. It was found that the content of oxygen‐containing functional groups on the surface of the film was highest at a plasma treatment power of 800 W, and the surface energy reached a maximum value of 67.71 mJ/m2. As the treatment power increases, the surface etching of the PI film increases significantly, as does the roughness. However, if the power is too high, it can cause excessive etching, resulting in peeling of the film surface. In addition, the mechanical properties of the films decreased with increasing plasma treatment power. Based on the effect of plasma treatment power on the surface physicochemical and mechanical properties of PI films, the best overall modification effect of PI films was determined when the treatment power was 800 W and the speed was 6 mm/s. And at 800 W, the peel strength of the PI/PEEK composite film reached a maximum value of 9.55 N/cm, which was 77.84% higher than that of the untreated composite film. However, plasma‐treated PI films can experience surface remodeling after being exposed to air for a period of time. In this paper, the wettability as well as the mechanical properties of the films are analyzed for different aging times. The results showed that after 30 days of plasma treatment, the O/C and N/C contents on the surface of the PI film decreased, and the wettability performance decreased by 19.45% compared with that of the recently treated film.

The oxidative stress mechanism of Bacillus cereus spores induced by atmospheric pressure plasma jet

Emerging plasma technology has demonstrated its effectiveness in inactivating bacteria and spores, showing wide applicability in environment cleaning and in the food supply chain. Studies have revealed that the main reason of plasma-mediated bacterial inactivation were contributed to the oxidative damage on inner membranes (IMs) of cell, while few research paid attention to the oxidation stress process of lipid in spores’ IMs. This study investigated the impact of atmospheric pressure plasma jet (APPJ) treatment on spore inactivation, focusing on oxidative stress mechanisms and changes in membrane lipid composition. Results demonstrated that APPJ treatment induced significant oxidative stress within spores, characterized by elevated levels of reactive oxygen and nitrogen species (RONS). This oxidative stress led to the peroxidation of glycerophospholipids, particularly phosphatidylglycerol, phosphatidylcholine, and cardiolipin, major components of spore membranes. Subsequently, the rearrangement of membrane lipid and the formation of lipid hydroperoxide, caused by the released cations and RONS, accelerated membrane instability. These changes correlated with increased membrane permeability and structural damage observed via flow cytometry, indicating the critical role of membrane lipid peroxidation in spore inactivation. Furthermore, the study highlighted the potential of APPJ as a robust technology for enhancing food safety by targeting spore-forming pathogens throughout the food supply chain.

Development of Functionalized Iron Oxide Nanoparticles Through Non-Thermal Atmospheric Pressure Plasma Assisted Polymerization for Reducing Cytotoxicity

Development of Functionalized Iron Oxide Nanoparticles Through Non-Thermal Atmospheric Pressure Plasma Assisted Polymerization for Reducing Cytotoxicity

Sample Thickness and Edge Proximity Influence Spatial Behavior of Filaments and Treatment Uniformity of RF Cold Atmospheric Pressure Plasma Jet

AbstractThe ability of atmospheric pressure plasma jets to treat complex non-planar surfaces is often cited as their advantage over other atmospheric plasmas. However, the effect of complex surfaces on plasma parameters and treatment efficiency has seldom been studied. Herein, we investigate the interaction of the atmospheric pressure plasma slit jet (PSJ) with block polypropylene samples of different thicknesses (5 and 30 mm) moving at two different speeds. Even though the distance between the slit outlet and the sample surface was kept constant, the treatment efficiency of PSJ ignited in the Ar and $$\hbox {Ar/O}_2$$ Ar/O 2 gas feeds varied with the sample thickness due to the plasma parameters such as filament count and speed being affected by the different distances of the ground (the closer the ground is, the higher the discharge electric field). On the other hand, the $$\hbox {Ar/N}_2$$ Ar/N 2 PSJ diffuse plasma plumes were less affected by the changes in the electric field, and the treatment efficiency was the same for both sample thicknesses. Additionally, we observed a difference in the efficiency and uniformity of the PSJ treatment of the edges and the central areas in some working conditions. The treatment efficiency near the edges depended on the duration of the filament contact, i. e., how long the local electric field trapped the filaments. Conversely, the treatment uniformity near the edges and in the central areas was different if the number of filaments changed rapidly as the discharge moved on and off the sample (the 5 mm samples treated by easily sustained Ar PSJ).

Characteristics of Merging Plasma Plumes for Materials Process Using Two Atmospheric Pressure Plasma Jets

Atmospheric pressure plasma jets (APPJs) have attracted significant attention due to their ability to generate plasma without vacuum systems, facilitating their use in small areas of plasma processing applications across various fields, including medicine, surface treatment, and agriculture. In this study, we investigate the interaction between two helium plasma jets, focusing on the effects of varying flow rate, voltage, and directional angle. By examining both in-phase and out-of-phase configurations, this research aims to elucidate the fundamental mechanisms of plasma plume merging, which has critical implications for optimizing plasma-based material processing systems. We demonstrate that while increasing voltage and flow rate for the in-phase condition leads to an extended plasma plume length, the plumes do not merge, maintaining a minimal gap. Conversely, plasma plume merging is observed for the out-of-phase condition, facilitated by forming a channel between the jets. This study further explores the impact of these merging phenomena on plasma chemistry through optical emission spectroscopy, revealing substantial differences in the emission intensities of OH, the second positive system of N2, and the first negative system of N2+. These findings offer valuable insights into controlling plasma jet interactions for enhanced efficiency in plasma-assisted processes, particularly where plume merging can be leveraged to improve the treatment area and intensity.

Real-time live imaging of cytosolic hydrogen peroxide and Ca2+ of Marchantia polymorpha gemmalings reveal immediate initial responses of plant cells triggered by nonthermal plasma irradiation

Cold atmospheric pressure plasma generators capable of generating plasma under normal pressure and temperature conditions have recently been developed, and their biological applications have been extensively studied. Plasma irradiation has been reported to affect plant germination and growth; however, the molecular mechanism underlying these effects and initial cellular responses to plasma irradiation remains poorly understood. To unravel the molecular and cellular mechanisms underlying the effects of plasma irradiation on plants, we have been establishing novel experimental systems using a model liverwort Marchantia polymorpha. We here focused on the initial responses of plant cells to plasma irradiation. To investigate immediate cellular responses following plasma irradiation, we developed a new plasma device that allows irradiation under a microscope. Through integration with live fluorescence imaging, we established an experimental setup to track, the dynamics of intracellular concentration of H2O2 and Ca2+ as representative initial cellular responses. We revealed that plasma irradiation induced a rapid and transient increase in intracellular concentration of H2O2 and Ca2+ in Marchantia gemmalings. Pharmacological analyses suggested that the long-lived reactive species, H2O2, generated by the plasma generator was directly delivered into the plant cells. Competitive inhibitors of Ca2+ channels abolished the Ca2+ rise, suggesting that plasma irradiation immediately activate plasma membrane Ca2+ channel(s) to induce Ca2+ influx. Importantly, this study marks the inaugural demonstration of real-time monitoring of cytosolic H2O2 and Ca2+ dynamics in plants, triggered by plasma irradiation.

Apparent effective ionization coefficient in N2 and O2 gas mixtures determined with two separate methods

N2:O2 gas mixtures are important for applications of atmospheric pressure plasmas such as ozone production, air purification from VOCs and NOx and surface treatments. Fundamental parameters such as the effective ionization coefficient are inputs for theoretical plasma models for applications and must thus be accurately known. This work determined the apparent effective ionization coefficient in N2:O2 mixtures in a broad reduced electric field strength E/N range of 150–1200 Td with two separate methods and compared with BOLSIG+ calculations of reduced effective ionization coefficient. Additionally, the equilibrium distance required to establish a steady-state electron energy distribution was estimated from spatial profiles of optical emission.

The preliminary study of etching characteristics of atmospheric pressure trifluoromethane plasma jet etching

Abstract The capacitive coupling radio frequency atmospheric pressure plasma jet for silicon etching, through the carrier gas carrying trifluoromethane gas, varying the gas flow rate for plasma etching. It finds the impact of varying gas flow rates on plasma etching and analyzes the resulting two-dimensional and three-dimensional surface topographies using surface profilometer. Experimental findings indicate that at a trifluoromethane flow rate of 250 sccm and a working distance of 6 mm, the etching rate achieves 38.7 μm/min. Notably, the research emphasizes the crucial role of trifluoromethane (CHF3) gas in plasma etching, highlighting its fluorocarbon ratio and chemical structure as primary factors influencing the etching process on monocrystalline silicon. Ultimately, the study proposes a methodology involving trifluoromethane gas for silicon wafer etching, enabling the transformation of micro-patterns onto crystalline silicon using a mask. This research contributes valuable insights into optimizing plasma etching techniques for microfabrication processes in semiconductor technology.

Study on curing process using atmospheric pressure plasma for silicone-based and epoxy-based electrically conductive adhesive

A curing for silicone- and epoxy-based electrically conductive adhesives (ECAs) using atmospheric pressure plasma (APP) was investigated. The results show that the volume resistivities of both ECAs were decreased as a function of the plasma treatment time. It reveals that APP enables the curing treatment of silicone- and epoxy-based ECAs. It was found that the volume resistivity of silicone- and epoxy-based ECAs differed depending on the treatment method. We observed the surface of the sample with a field emission-scanning electron microscope and energy-dispersive X-ray spectroscopy. The results show that the carbon-derived membrane formed on the surface.

Plasma coloring of Ti via air atmospheric pressure plasma jet for dentistry

The aesthetic appeal of titanium dental implants is compromised by unattractive coloration, and extended exposure to bodily fluids can result in the release of ions, potentially causing infection or inflammation. This study introduces a direct method for oxidizing titanium through plasma coloring to enhance biocompatibility. Utilizing a tornado-type atmospheric pressure plasma jet (APPJ) with compressed dry air as the working gas, sub-stoichiometric titanium oxide was produced on sample surfaces. Analysis of reactive oxygen species (ROS) in air plasma via optical emission spectroscopy offers valuable insights into the interaction between plasma and the surface during the oxidation process. Quantification of surface coloration in titanium samples before and after treatment with air-APPJ was conducted using CIE chromaticity diagrams and color temperature analysis. This analytical approach enabled the assessment of thermal and plasma-chemical impacts of plasma coloring on the development of the sub-stoichiometric titanium oxide layer. The resulting oxide layers from the APPJ process exhibited a vibrant golden shade, along with enhanced surface hydrophilicity, improved anticorrosion properties, and enhanced cellular responses.