Pressure Condition Research Articles

Nix/TiO2 catalysts for enhancing the selectivity of methylcyclohexane dehydrogenation

The dehydrogenation of methylcyclohexane (MCH) is a widely used hydrogen storage technology, but nowadays, precious metal catalysts such Pt are used for this reaction and non-precious metal catalysts suffer from low selectivity and instability problems. Two catalysts, Ni20/TiO2 and Ni20/Al2O3, were prepared through the improved co-precipitation method and their dehydrogenation performance of MCH was compared. It was found that the application of TiO2 carrier could significantly reduce the acidity of the catalysts, and the nickel particles could be stably dispersed on the carriers, which could effectively improve the selectivity of the target product (toluene). In addition, the influences of different Ni contents, reaction temperatures, and weight hourly space velocity (WHSV) on the performance of the catalysts were also evaluated, and the results showed that the catalyst with 17.16 % Ni content exhibited high activity with up to 86.48 % conversion of MCH and 96.51 % selectivity of toluene, under atmospheric pressure condition with the reaction temperature of 375 °C and WHSV of 1.9 h−1, while 96.03 % and only 42.64 %, respectively, for the Ni20/Al2O3 catalyst. In addition, the catalyst exhibited excellent anti-coking ability, indicating that it has a promising future for industrial applications.

Investigation on the rock-breaking performance of specially-shaped PDC cutter under confining pressure conditions

Cutter shape has a significant influence on the rock-breaking performance of drill bit. Compared with conventional Polycrystalline Diamond Compact (PDC) cutter, the emergence of specially-shaped PDC cutters (SSPCs) with different geometric shapes is of great benefit to solve the problems of low rate of penetration (ROP) and rock-breaking efficiency in deep hard and hot dry rock formations. However, the high confining pressure and high in-situ stress (HCHS) have a significant influence on the rock-breaking performance of PDC cutter which cannot be ignored. Given that the above facts, this paper selects five kinds of PDC cutters with different cutter shapes, and implements a series of cutting experiments of granite under confining pressure conditions (CPCs) and atmospheric pressure condition (APC) using a true triaxial rock cutting device. The influence of cutter profile on the rock-breaking performance of PDC cutter was studied from the perspective of cutting force, mechanical specific energy (MSE), cuttings, coarseness index (CI) and fractal dimension. The results show that the rock breaking under CPC is more difficult than that under APC, resulting in the increased cutting force and MSE. Moreover, the cuttings obtained under CPC are smaller in size and the cutting grooves are smoother. Cutter shape has a great influence on the rock-breaking efficiency of PDC cutter, the rock-breaking efficiency of axe-shaped cutter is higher, while that of stinger cutter is lower. Moreover, PDC cutters with different shapes have different sensitivities to confining pressure, and stinger cutter has the lowest sensitivity to confining pressure, in other words, confining pressure has little influence on the rock breaking process of stinger cutter. What is more, the distribution of cuttings is characterized by the fractal dimension and particle size distribution parameter from the perspective of cuttings morphology and size respectively, and they present completely opposite changing trends. The obtained results are of great significance to the optimization of cutter profile, the design of bit cutter arrangement and the drilling of deep formation.

State of the Art of Modelling and Design Approaches for Ejectors in Proton Exchange Membrane Fuel Cell

Proton exchange membrane fuel cell (PEMFC) has a promising future in the power generation and transportation fields. Recirculation of unused anodic gases is fundamental to achieve a high-performance energy system, and this is usually attained employing ejectors or pumps. With respect to the latter, ejectors present no moving parts, thus resulting in both higher overall efficiency of the system and lower maintenance cost. Their main drawback is represented by the narrow optimal operative range: the entrainment ratio (ER) greatly depends on primary pressure, working pressure, and operative condition in general. In the last decade, numerous authors focused their efforts on fully comprehending and correctly simulating their working principles and analyzing how geometrical parameters influence ER and design different geometries to enlarge the operative range. The aim of this paper is to present in an ordered and clear manner the state of the art of ejector design, both from simulative (turbulence model, single or multiphase stream, etc.) and empirical (commonly used “rule of thumb”) points of view.

PENGARUH PENDIDIKAN KESEHATAN TERHADAP TINGKAT PENGETAHUAN TENTANG PENCEGAHAN KOMPLIKASI PENYAKIT HIPERTENSI DI DESA GAREN PANDEYAN NGEMPLAK BOYOLALI

Introduction: Hypertension is a condition of systolic blood pressure of more than 140 mmHg or diastolic blood pressure of more than 90 mmHg, which is measured twice with an interval of five minutes and in a condition of adequate rest and calm. Blood pressure is a description of a person's hemodynamic situation at a certain time, hemodynamics is a condition in which pressure and blood flow can maintain the exchange or perfusion of substances in tissues. The purpose of health education is to increase the knowledge of respondents. With the increase in respondents' knowledge, there is a change in attitude towards adaptive in accordance with the information obtained through health counseling. Objective: This study is to determine the effect of health education on the level of knowledge about the prevention of complications of hypertension in Garen Pandeyan Ngemplak Boyolali Village. Method: the research used is quantitative research with analytical correlation with Quasi-Experimental method with pre-test and post-test approaches one group control only. Data from this study was obtained from filling out questionnaires that had been tested for validity and reliability and analyzed using the Wilcoxon Signed Ranks Level Test before health education was carried out knowledge about preventing complications of hypertension, the average level of knowledge of 73 respondents was 5.94 with a minimum of 3 points and a maximum of 9 points. The level of knowledge after the implementation of health education, retrieval of knowledge data on the prevention of complications of hypertension was carried out. Results: The results of the study obtained an average level of knowledge from 73 respondents with post-test result criteria 7 with a minimum score of 6 points and a maximum of 10 points. Conclusion: Based on the results of the study, there is a significant difference between the level of . Keywords: health education, leve of knowledge, complications of hypertension

Evolution mechanism and parametric investigation of relative negative pressure zone in spiral groove gas face seal for aero-engine at high rotational speed

As an advanced sealing technology, spiral groove gas face seal has excellent sealing performance. However, it is rarely used in aero-engine. Previous investigation proposed that the relative negative pressure zone (RNPZ) in the spiral groove gas face seal can regulate the sealing performance. In this paper, further numerical simulation work is carried out. By quantifying the obstruction effect, viscous pumping effect and shear effect, the evolution mechanism of RNPZ under different film thicknesses and groove depths is revealed. Then, the parametric analysis of spiral groove configuration and groove number is carried out. Through the sub-regional quantitative analysis of the groove, the influence mechanism of structural configuration on RNPZ is revealed. Finally, combined with the hydrodynamic performance analysis, the spiral groove seal structure under optimal conditions is obtained. It is found that under the condition of high speed and low inlet pressure of aero-engine, RNPZ is suppressed by adjusting the structure of the spiral groove to enhance the shear effect, the pumping effect at the top of the groove and reduce the pumping effect at the bottom of the groove. When the number of grooves is 20 and the groove depth is 3 μm, the stiffness-leakage ratio of structure B and C can be increased by 10.15 % and 12.68 %, and the sealing performance is the strongest. This work can provide a theoretical and data basis for the subsequent optimization design of aero-engine gas face seals.

Effect of pressure on sintering behavior of polycrystalline diamond

Polycrystalline diamond composites (PDC) have been used as a cutting material in a multitude of fields, from mechanical processing to oil and gas drilling. In this study, PDC samples were prepared under high pressure and high temperature (HPHT) conditions within a pressure interval of 5.5 to 10.5 GPa by sintering diamond powder (average grain size ~3 μm) with WC-10 wt% Co substrate. Samples obtained with varying sintering pressures and temperatures were characterized using Vickers hardness tester, scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results revealed that: (1) within a specified material system, each distinct sintering pressure condition corresponds to a unique optimal sintering temperature that yields the pinnacle of consolidation efficiency in samples. This optimal temperature exhibits a linearly increasing trend with rising sintering pressure; (2) at the intersection where the sintering pressure attains its optimal match with temperature, an increase in pressure fosters more intimate contact and stronger inter-grain bonding among diamond particles, thus amplifying the DD bond formation effect, which consequently leads to a linear enhancement in the Vickers hardness values of PDC with increasing sintering pressure; (3) simultaneously, under conditions of optimal temperature matching, elevating the sintering pressure notably decreases the cobalt content within the polycrystalline diamond layer of PDC samples. These findings furnish crucial experimental evidence for optimizing PDC material properties, significantly contributing to the advancement of both theoretical exploration and technological innovation within the field, carrying profound academic value and practical guidance implications.

Comparison of collision dynamics of soccer balls with energy dissipation method

This study aimed to understand the collision characteristics of different soccer balls by determining energy dissipation (ED) during collisions. Soccer balls from five different brands were kicked towards a framed tempered glass. The kicks were performed with the balls inflated under three inner pressure conditions. The motion of each ball was recorded using two high-speed cameras at 6000 Hz. The contact surface area (CSA), ball indentation amount (IA), reaction forces (RF) and energetic coefficient of restitution (CoR) during contact were calculated via image processing methods. A new methodological approach was developed to determine the ED during the collision (EDDC). The accuracy of the estimated RF was validated using force plate data, and the CSA values validated the calculated IA. The EDDC were then reduced to a single value to compare with the CoR values obtained using the traditional formula. Differences between CoR and EDDC were statistically tested. One-way ANOVA tests were performed separately to compare the effect of the ball brand on the IA and EDDC for each inner pressure condition. The CoR and EDDC showed no significant difference, proving that the developed method is a valid measure of ED. At 1.0 bar inner pressure, IA and EDDC showed significant differences according to the brands. EDDC, depending on the ball quality, decreased at higher inner pressure values regardless of the brand. Consequently, the present study exhibited that ball quality becomes a critical factor in collision dynamics at high inner pressure values, considering that ball inner pressure may vary between 0.6 and 1.0 bar in official soccer matches.

Evaluating the Cost-Effectiveness of Folic Acid Versus Methyltetrahydrofolate in Preventing Preeclampsia in Makassar, Indonesia.

Preeclampsia is a condition of elevated blood pressure with proteinuria that occurs during pregnancy and is a complication of elevated blood pressure. It usually occurs after the 20th week of pregnancy. This could be fatal for the mother after birth and the baby if it occurs before birth. The goal of this study is to investigate the risk, cost-effectiveness, and effective doses of folic acid (B9). This study is an observational study with a cohort design and random simple sampling data collection. Data was collected from the Cahaya Ibu Pharmacy Store in Makassar from 164 patients. Chi-square statistical analysis data showed a significant risk relationship between pregnant women and the development of hypertension compared with nonpregnant patients, with a p-value of 0.001. Her risk level for the event reaches twice, as evidenced by her odds ratio reaching 6.9 times. The results of cost analytics showed folic acid had an equal effect on women's reduced risk of preeclampsia as methyltetrahydrofolate. Using folic acid early in pregnancy planning is a great opportunity to reduce the incidence of preeclampsia. The ICER value was obtained at $0.293, so an increase in the cost of that amount was needed to improve the effectiveness of therapy by patients using folic acid compared to patients with methyltetrahydrofolate therapy. Therefore, folic acid is more cost-effective compared to methyltetrahydrofolate.

Hysteretic water-retention behaviour of unsaturated hydrophobised soils

Hydrophobised soils found in the superficial region of earthen infrastructure can affect the hydrological processes of these structures. The hysteretic water-retention curve (WRC), which governs these processes, for hydrophobised soils has rarely been reported. Existing apparatus is unable to measure the WRC of unsaturated soils as it could not control the condition of pore water pressure (uw) in excess of pore air pressure (ua) when the contact angle was larger than 90°. In this study, a new apparatus was created, which sandwiches a soil sample between a high water-entry value (WEV) membrane and a high air-entry value (AEV) ceramic disc, to control the uw < ua and uw > ua conditions. Contact angle hysteresis and menisci evolution in the test materials during wet–dry cycles were measured to interpret the WRC. The WEV of soil increased with decreasing chemical heterogeneity and particle size. When drying the hydrophobised soils, they could retain water before reaching a certain negative uw. The WEV identified from the second wetting cycle was lower than that from the first cycle, whereas the AEV remained largely unchanged. The WEV and AEV decreased when the particle size of the hydrophobised materials was increased, resulting in a smaller hysteresis size.

Continental subduction in Paleoproterozoic: Insights from ∼ 1.9 Ga nepheline syenite in the North China craton

Subduction of continent is known as a feature of modern plate tectonics, and it is still unclear whether such a process also occurred in the early Precambrian. Despite of ultra-high pressure metamorphism of terrestrial rocks as a proxy of continental subduction, magmatism produced during continental subduction is also a potential alternative. The North China craton is well-known for the occurrence of 1.9 Ga retrograde eclogite, which was likely originated from the subducting oceanic crust along the Trans-North China Orogen (TNCO). Here a nepheline syenite (the Aohu pluton), the first of the kind from the TNCO, is discovered in Yunzhong Mts. It comprises nepheline (∼20 vol%), albite (50–55 vol%), K-feldspar (5–10 vol%), biotite (∼10 vol%), and calcite (∼5 vol%), with minor accessory minerals. No associated mafic or silicic rocks are outcropped in the pluton. SHRIMP zircon U-Pb analyses yield a crystallization age of 1893 ± 13 Ma and a metamorphic overprinting of 1871 ± 17 Ma. The rocks have medium SiO2 contents (51.9–58.9 wt%), low MgO (0.6–1.6 wt%) and Mg# (24–34), but high Al2O3 (20.0–22.9 wt%) and extremely high K2O + Na2O contents (10.0–13.6 wt%; Na2O/K2O = 1.3–2.6). They are enriched in light rare earth elements (REEs) and large ion lithophile elements, but relatively depleted in heavy REEs and high field strengthen elements. They have extremely low compatible elements (e.g., Ni and Cr). They show high (87Sr/86Sr)i ratios (0.706–0.707) but low εNd(t) values (−5.3 to −6.0; Nd T2DM = ca. 2.7 Ga). Their zircon in-situ εHf(t) values have a wide range (0 to −5.7; Hf T2DM = 2.5–2.85 Ga). The absence of mafic component and the extremely low-Mg feature, as well as their trace element patterns and initial Sr-Nd isotopes being compatible with melts derived from the Archean mafic crustal enclaves in the region, support a continental crust origin for the Aohu nepheline syenite. Based on comparison and modeling, we suggest that its generation was most likely under ultra-high pressure condition. It is thus proposed that continental subduction (into the mantle) might have occurred in the TNCO during the Paleoproterozoic.

Refined line-shape parameters for CO lines broadened by air predicted from requantized classical molecular dynamics simulations

Line-shape parameters and their temperature dependences for CO lines broadened by air have been predicted using requantized classical molecular dynamics simulations. The latter were carried out for mixtures of CO in air for five temperatures ranging from 200 K to 400 K, all at a pressure of 1 atm. For each temperature and pressure condition, various Doppler widths have been considered enabling the calculations of absorption spectra for a large range of collisional to Doppler widths ratios. The simulated spectra were then fitted with the speed-dependent Nelkin-Ghatak, speed-dependent Voigt and Voigt profiles, providing the corresponding line-shape parameters. First-order line-mixing parameters were also retrieved. The temperature dependences of these parameters were then determined using a single power law. Comparisons between the predicted parameters and available experimental values as well as those of the latest edition of the HITRAN database show good agreements. The theoretically predicted values and their temperature dependences can thus be used for the modeling of the absorption spectrum of CO in air and to complete spectroscopic databases when accurate experimentally-determined values are not available.

Chronic Stress as a Risk Factor for Type 2 Diabetes: Endocrine, Metabolic, and Immune Implications.

Chronic stress is a condition of pressure on the brain and whole body, which in the long term may lead to a frank disease status, even including type 2 diabetes (T2D). Stress activates the hypothalamus-pituitary-adrenal axis with release of glucocorticoids (GCs) and catecholamines, as well as activation of the inflammatory pathway of the immune system, which alters glucose and lipid metabolism, ultimately leading to beta-cell destruction, insulin resistance and T2D onset. Alteration of the glucose and lipid metabolism accounts for insulin resistance and T2D outcome. Furthermore, stress-related subversion of the intestinal microbiota leads to an imbalance of the gut-brain-immune axis, as evidenced by the stress-related depression often associated with T2D. A condition of generalized inflammation and subversion of the intestinal microbiota represents another facet of stress-induced disease. In fact, chronic stress acts on the gut-brain axis with multiorgan consequences, as evidenced by the association between depression and T2D. Oxidative stress with the production of reactive oxygen species and cytokine-mediated inflammation represents the main hallmarks of chronic stress. ROS production and pro-inflammatory cytokines represent the main hallmarks of stress-related disorders, and therefore, the use of natural antioxidant and anti-inflammatory substances (nutraceuticals) may offer an alternative therapeutic approach to combat stress-related T2D. Single or combined administration of nutraceuticals would be very beneficial in targeting the neuro-endocrine-immune axis, thus, regulating major pathways involved in T2D onset. However, more clinical trials are needed to establish the effectiveness of nutraceutical treatment, dosage, time of administration and the most favorable combinations of compounds. Therefore, in view of their antioxidant and anti-inflammatory properties, the use of natural products or nutraceuticals for the treatment of stress-related diseases, even including T2D, will be discussed. Several evidences suggest that chronic stress represents one of the main factors responsible for the outcome of T2D.

Efficacy and safety of triple therapy (elexacaftor/tezacaftor/ ivacaftor) in children with cystic fibrosis: 12-month follow-up

The most effective drug for targeted therapy of cystic fibrosis (CF) today is the CFTR modulator elexacaftor/tezacaftor/ivacaftor. It is a combination of two CFTR correctors and a CFTR potentiator that correct the main genetic defect in patients with CF who carry at least one genetic variant specified in the instructions for use of the drug. In the Russian Federation, children with CF at the age of 6 years and older are provided with a targeted drug at the expense of the Circle of Kindness Charitable Foundation.The aim of the study was to investigate the efficacy and safety of therapy with the CFTR modulator elexacaftor/thezacaftor/ivacaftor in children with cystic fibrosis during 12 months of follow-up.Methods. The data of 48 patients aged 6 to 18 years who received targeted therapy with elexacaftor/tezacaftor/ivacaftor in 2021 and were included in the “Targeted therapy” section of the Register of Patients with Cystic Fibrosis in the Russian Federation, were analyzed. To study the effectiveness and safety of the therapy, the patients’ nutritional status, sweat test, respiratory function, blood chemistry, blood pressure, and lens condition were monitored during the therapy.Results. During therapy, an increase in body weight was noted from 44.1 (± 8.8) to 50.1 (± 7.8) kg (M ± SD) (p < 0.001); height, from 158.2 (± 9.1) to 161.9 (± 8.7) cm (p < 0.001); and BMI, from 17.5 (± 2.3) to 19 (± 1.9) kg / m2 (p < 0.001). The conductivity of sweat decreased from 114.8 (± 17.4) at the start of triple therapy to 73.9 (± 20.6) mmol/l NaCl (p < 0.001) after 12 months of treatment. In 28.5%, the sweat test results returned to normal (the sweat conductivity was equivalent to < 50 mmol / l NaCl). Statistically significant changes in the indices of respiratory function were obtained: the forced vital capacity increased from 72.8%pred. (± 21.7) to 86.6%pred. (± 24.4) (p < 0.001), FEV1 – from 67.2%pred. (± 21.7) to 84.9%pred. (± 28.9) (p < 0.001).Conclusion. Analysis of the tolerability showed a consistent safety profile of the triple therapy.

Effect of gas content on cavitation nuclei

Cavitation inception originates from nuclei in a liquid. This paper proposes a Gibbs free energy approach that provides a smooth transition from homogeneous to heterogeneous nucleation when gas is present. The impact of gas content on nucleation is explored. It is found that the gas content stabilises nuclei, a phenomenon not present in pure liquid–vapour systems. This reduces the energy barrier over that required to nucleate a vapour bubble. Different gas saturation levels are studied. Gas content can significantly reduce the energy barrier required for nucleation, and under certain circumstances eliminate it. An analytic solution for the critical radius and activation energy is obtained that accounts for gas content. The classical Blake radius is recovered as a limiting case. The hysteresis between incipience and desinence is explained using the asymmetry observed in the critical radii. The solution is used to obtain the initial bubble radius, given a critical pressure condition in cavitation susceptibility meter experiments. The relationship between initial bubble diameter and critical pressure is described by an analytic solution that accounts for gas content. A model for the derivative of the cumulative nuclei histogram with respect to bubble diameter is proposed. An analytic expression is obtained that shows good agreement with decades worth of experimental data compiled by Khoo et al. (Exp. Fluids, vol. 61, issue 2, 2020, pp. 1–20) from ocean to water tunnels. The expression recovers the $-4$ power law that is observed experimentally.

Study on the macro–micro evolution of compaction characteristics of coal gangue with different grain sizes under side-limit compression conditions

Currently the main method of mine solid waste disposal and utilization is to apply gangue to underground filling. For the grading characteristics of coal gangue in the hollow zone in underground filling, the state of pressure and the mechanical properties of coal gangue filling materials under different particle sizes. In this paper, through laboratory tests and numerical simulations, the bearing characteristics and deformation damage of gangue are deeply investigated and analyzed from both macroscopic and microscopic perspectives. The results of the study show that when the axial pressure reaches a certain threshold, the strain increases accordingly with the increase in grain size. Under the axial pressure condition of 15MPa, the bearing capacity of gangue with different grain sizes under the lateral pressure of steel cylinder showed obvious positive correlation. In the software PFC3D simulation, as the particle size of gangue particles increases, it has a significant effect on the natural stacking porosity of the specimen, and gangue particles are more prone to force chain instability and failure. Mixed particle size gangue can significantly reduce the natural accumulation porosity of the specimen, thus improving its overall stability. Significant displacement triangles existed in the top and lateral directions of the B1 (0–5 mm), B2 (5–10 mm), and B5 (0–20 mm) specimens under the same circumferential pressure conditions. The results of the study are of great significance for further selection of reasonable gangue gradation and determination of its mechanical properties.

Determination of the Reserved Gap Between the Obturator Ring and the Breechblock in the Metallic Obturation Mechanism of a Large Caliber Gun Howitzer

A reserved gap between the obturator ring and the breechblock in the obturation mechanism of a large-caliber gun is required in the locked state of the gun, which is the main cause of gas leakage. In this study, the finite element analysis of the dynamic contact between the obturator ring and the breechblock and the computational fluid dynamics (CFD) analysis of the high-pressure gas flow through the gap between the obturator ring and the breechblock are conducted. The results show that the smaller the reserved gap is, the shorter the time period during which the contact pressure is zero after the obturator ring contacts with the breechblock will be under a low-bore pressure condition. The results also demonstrate that the leakage flow at the outlet of the gap and the gas flow in the external domain increase with the reserved gap size, and the gas flow in the external domain decays rapidly if the reserved gap is less than or equal to 0.02 mm under a high bore pressure condition. Based on the simulation results, the appropriate reserved gap value is determined and adopted in the studied gun, and good results are achieved in the firing tests.

Experiment of droplet contact angle hysteresis on PTFE fibrous membrane in pore-scale

The present paper aims to study the influence of pore-scale fiber structure on the Cassie-Baxter contact angle of droplets on PTFE fibrous hydrophobic membranes. The fiber structure is obtained by the Confocal Laser Scanning Microscope (CLSM), and an optical test bench is built to measure the Cassie-Baxter contact angles of a droplet on a PTFE membrane. The free energy of the solid-liquid interface is measured by the surface tension integral on the droplet profile. An iterative algorithm for liquid-vapor interface shrinking is brought forward to analyze the liquid-vapor interface area between the droplet and the membrane, and the interface parameters of the Cassie-Baxter model are recognized. The experiment shows that the Cassie-Baxter contact angles and the contact line radii along the droplet circumference are in a normal distribution due to random fiber structures, and the variance of the normal distribution increases with the membrane pore diameter. The normal distribution of Cassie-Baxter’s contact angle indicates the constraint of the solid-liquid interface to the liquid-vapor interface. On the same normal contact pressure condition, the liquid-vapor area ratio of the droplet and membrane interface changes little, and Cassie-Baxter’s contact angle increases with the solid-liquid interface area ratio.

Highly efficient synthesis of cyclic carbonates via deep eutectic solvents from CO2 at the gas-liquid interface of microdroplet under atmospheric pressure condition

The cycloaddition reaction of CO2 in traditional reactors is relatively slow due to insufficient gas–liquid contact. In this work, the microdroplet reactor was set up to research the intensification effect of increasing the volumetric mass transfer coefficient on the reaction. The [C1C2Im][I]/PhOH (1-ethyl-3-methylimidazolium iodide/Phenol) with a molar ratio of 2:1 exhibited excellent catalytic activity at room temperature. Up to 85% conversion of the substrate could be achieved in the microdroplet intensification device. The intensification reaction model of the microdroplet was established, which explored the effect of the microdroplet size and gas–liquid mass transfer on the reaction. The increase of the volumetric mass transfer coefficient (kLa) could improve the efficiency of the reaction at the gas–liquid interface of the microdroplet. The mathematical model of the microdroplet intensification reaction was established to clarify the intensification mechanism.

High-pressure minerals and new lunar mineral changesite-(Y) in Chang’e-5 regolith

Forty-five years after the Apollo and Luna missions, China’s Chang’e-5 (CE-5) mission collected ∼1.73 kg of new lunar materials from one of the youngest basalt units on the Moon. The CE-5 lunar samples provide opportunities to address some key scientific questions related to the Moon, including the discovery of high-pressure silica polymorphs (seifertite and stishovite) and a new lunar mineral, changesite-(Y). Seifertite was found to be coexist with stishovite in a silica fragment from CE-5 lunar regolith. This is the first confirmed seifertite in returned lunar samples. Seifertite has two space group symmetries (Pnc2 and Pbcn) and formed from an α-cristobalite-like phase during “cold” compression during a shock event. The aftershock heating process changes some seifertite to stishovite. Thus, this silica fragment records different stages of an impact process, and the peak shock pressure is estimated to be ∼11 to 40 GPa, which is much lower than the pressure condition for coexistence of seifertite and stishovite on the phase diagram. Changesite-(Y), with ideal formula (Ca8Y)□Fe2+(PO4)7 (where □ denotes a vacancy) is the first new lunar mineral to be discovered in CE-5 regolith samples. This newly identified phosphate mineral is in the form of columnar crystals and was found in CE-5 basalt fragments. It contains high concentrations of Y and rare earth elements (REE), reaching up to ∼14 wt. % (Y,REE)2O3. The occurrence of changesite-(Y) marks the late-stage fractional crystallization processes of CE-5 basalts combined with silicate liquid immiscibility. These new findings demonstrate the significance of studies on high-pressure minerals in lunar materials and the special nature of lunar magmatic evolution.

Experimental study on cavitation inhibition in a butterfly valve with different plate shapes

A valve is a kind of mechanical device used to control the flow of fluid in pipelines or systems, which has a wide range of uses in various industrial, commercial, and household applications. When the fluid passes through the valve, cavitation often occurs in the valve, resulting in the valve not working properly and even damaging the valve and related systems. In this paper, experimental visualization was used to investigate cavitation evolution through a butterfly valve with different plate shapes under different pressure conditions. The results show that with the increase in the curvature of both sides of the butterfly plate and the increase in the total pressure condition, the cavitation type inside the butterfly valve will change from non-attached cavitation to attached cavitation. In addition, the maximum length and thickness of the attached cavitation bubbles gradually increase as well. However, when the shape of both ends of the butterfly plate is triangular, the adhesion ability to cavitation bubbles is greatly reduced. As the curvature increases, the frequency of the shedding of cavitation bubble gradually decreases, the volume of cavitation bubble increases, and the shedding of the cavitation bubble caused by the shock wave is more obvious. When the shape of both sides of the butterfly plate is triangular, the position where the bubble collapses is closer to the front end of the butterfly plate, and the shock wave generated by the bubble collapse will lead to the collapse of the attached cavitation bubble.