Preparation Of Porous Carbon Research Articles

Fungus-mediated preparation of porous carbon based on wheat straw: Efficient removal of chromium and enhanced electrochemical properties

Herein, a lignocellulose-degrading fungus (Irpex lacteus) was used to solidly ferment wheat straw to enhance its performance by improving its native structure and introducing an additional nitrogen source. Subsequently, the fungal-mediated wheat straw porous carbon (IL-WSPC-700) was prepared by the NaOH-activated etching method. The results of the characterization confirmed that the fungal treatment could successfully disrupt the natural structure of the wheat straw, resulting in better etching during the subsequent alkali activation process. The IL-WSPC-700 exhibited a larger specific surface area (3452.42 m2 g−1) with more micropores, which positively impacted the adsorption of heavy metal Chromium (Cr, the oxidation number was 6) by the material, and the highest adsorption capacity (678.41 mg g−1) was observed at pH value = 1. In addition, the electrode prepared by IL-WSPC-700 had a high specific capacitance of 310.7 F g−1 at 1 A g−1 current density and maintained 95.83 % of the specific capacitance after 5000 cycles in the two-electrode system. The above experiments confirmed the success of the fungal treatment strategy, IL-WSPC-700 had excellent adsorption and electrochemical performances. This study is an attempt to design and prepare adsorbents and electrode materials using microbial hypha and agricultural wastes. It could provide a reference for the preparation of high-performance materials via the synergistic effect of microbial assistance and alkali etching.

Facile Recycling of Waste Biomass for Preparation of Hierarchical Porous Carbon with High-Performance Electromagnetic Wave Absorption.

Hierarchical-porous-structured materials have been widely used in the field of electromagnetic wave (EMW) absorption, playing a critical role in minimizing EMW interference and pollution. High-quality EMW absorbers, characterized by a lower thickness, lighter weight, wider absorption band, and stronger absorption capacity, have been instrumental in reducing damage and preventing malfunctions in the automotive and aviation industries. The utilization of discarded nut shells through recycling can not only alleviate environmental problems but relieve resource constraints. Herein, a facile method for the preparation of hierarchical porous biomass carbon derived from abandoned Xanthoceras Sorbifolium Bunge Shell (XSS) biomass was developed for high-performance EMW absorption. The porous structures of XSS biochar were studied by using different levels of the K2CO3 activator and simple carbonization. The effect of K2CO3 on the EMW parameters, including the complex permittivity, complex permeability, polarization relaxation, and impedance matching, was analyzed. The best EMW absorption performance of the XSS biochar was observed at a mass ratio of activator-to-biomass of 2:1. A minimum reflection loss (RLmin) of -38.9 dB was achieved at 9.12 GHz, and a maximum effective absorption bandwidth (EABmax) of up to 3.28 GHz (14.72~18.0 GHz) could be obtained at a 1.8 mm thickness. These results demonstrated that hierarchical porous XSS carbon was prepared successfully. Simultaneously, the prepared XSS biochar was confirmed as a potential and powerfully attractive EMW-absorbing material. The proposal also provided a simple strategy for the development of a green, low-cost, and sustainable biochar as a lightweight high-performance absorbing material.

Preparation of porous carbon with high performance as lithium-ion battery anode utilizing FeCl3/ZnCl2 as modifying agents

The anode materials for lithium-ion batteries (LIBs) are prepared by one-step carbonization using urea-impregnated cotton stalk (CS) as a carbon precursor and ZnCl2 and FeCl3 as an activator and catalyst, respectively. The addition of ZnCl2 contributes to the development of mesopore. Incorporating FeCl3 improves the graphitization of porous carbon, but has no significant effect on layer spacing. In addition, FeCl3 catalysis can increase the specific surface area and pore volume of porous carbon, especially the development of pore structure below 10 nm. In terms of electrochemical performance, the porous carbon is prepared at CS: ZnCl2: FeCl3 = 1:1:1 and possessed the best performance, with a reversible capacity of 487.7 mAhg−1 after 100 charge–discharge cycles at 0.1 Ag−1 and specific capacity retention of 83.61 %. This study greatly improves the cycling stability of the battery while reducing the amount of mixed salt, which is extremely significant for subsequent research.

Pitch-based porous carbon via the solid–liquid synergistic oxidation of K2FeO4 for excellent electrocapacitive desalination

To address limited desalination capacity and insufficient charge efficiency for carbon materials in capacitive deionization (CDI), a solid–liquid synergistic oxidation strategy of potassium pertechnetate (VI) for pitch was proposed to construct porous carbon with a reasonable pore structure and high reactive surface. On the one hand, K2FeO4 is first utilized for the solid-phase oxidation (SPO) of pitch by a high-energy ball mill, introducing rich oxygen-containing groups such as ether bonds. Meanwhile, dehydro-condensation reactions occurred during SPO, resulting in the formation of the oxidized pitch with a high degree of condensation. Importantly, the pyrolysis yield of the oxidized pitch is as high as 46.9 % at 800 °C, almost twice that of the pristine pitch, meaning that the oxidized pitch with high polymer degree and rich C-O bridge bonds facilitates the carbon fixation and emission reduction during carbonization. On the other hand, the self-oxidation of K2FeO4 in aqueous solution forms bifunctional activators (KOH and Fe(OH)3) for the preparation of pitch-based porous carbon. Benefiting from the crosslinking structure of oxidized pitch and the multi-effective activation, the prepared porous carbon (H-CBPF) exhibits a robust layered stacking topology with a high surface area and oxygen content. Thereby, it can deliver an excellent salt adsorption capacity (SAC) of 22.1 mg g−1 with an average desalination rate of 1.89 mg g−1 min−1 and a high charge efficiency of 85 % at 1.2 V in 500 mg L-1 NaCl solution. This work opens up a green and economical route for the preparation of pitch-derived porous carbon for high-performance CDI.

Preparation of porous carbon from Cogongrass leaves as raw material for batteries (electrical energy)

Cogongrass (Imperata cylindrica) can be processed into a positive electrode as a battery component to generate electricity by utilizing its carbon element. This study used various activators, KOH and H3PO4, and characterized using XRD, FTIR, and SEM-EDX and electrical tests with electric conductivity analysis. The analysis results using XRD diffraction showed that when using both KOH and H3PO4 activators, Cogongrass carbon has graphite (C) and silicon (Si) crystals but at different peaks. The carbon has the same functional groups for both activators: OH-bending, C=C-bending, C-O-bending, and C=C-bending. Cogongrass carbon with KOH activator has a pore size of 235-980 nm with a percentage of carbon atoms of 71.29%, while with H3PO4 activator has a pore size of 110-960 nm with a higher percentage of carbon atoms of 75.04%. The elements contained in carbon are the same for both activators, namely carbon, oxygen, silicon, indium, potassium, calcium, iron, chlorine, phosphorus, magnesium, and sodium. EC analysis showed that carbon from Cogongrasss showed electric conductivity reaching 140 µs/cm at 60 minutes pyrolysis time.

Iodine intercalation-assisted alkali activation constructs coal-based porous carbon for high-performance supercapacitors

Supercapacitors have the advantages of fast charging and discharging speeds, high power density, long cycle life, and wide operating temperature range. They are widely used in portable electronic equipment, rail transit, industry, military, aerospace, and other fields. The design and preparation of low-cost, high-performance electrode materials still pose a bottleneck that hinders the development of supercapacitors. In this paper, coal was used as the raw material, and the coal-based porous carbon electrode material was constructed using the iodine intercalation-assisted activation method and used for supercapacitors. The CK-700 electrode exhibits excellent charge storage performance in a 6 M potassium hydroxide (KOH) electrolyte, with a maximum specific capacitance of 350 F/g at a current density of 0.5 A/g. In addition, it has an excellent rate performance (310 F/g at 1 A/g) and cycle stability (capacitance retention up to 91.7 % after 30000 cycles). This work provides a method for realizing high-quality, high-yield and low-cost preparation of coal-based porous carbon, and an idea for improving the performance of supercapacitors.

Chitosan-derived large surface area porous carbon via microphase separation engineering of pore-regulation and nitrogen-doping coupling for high-performance supercapacitors

In the face of the contradiction between the shortage of fossil raw materials, global warming and growing energy demand, it is of great practical significance to apply biomass, which is widely available in nature, environmentally friendly and renewable, to energy storage. Based on the coupling mechanism of pore-regulation and N-doping, this study implements pre-carbonization through microphase separation engineering in the chitosan (CS) and aniline (AN) co-hydrothermal. Using hydrochar as the precursor, porous carbon with good electrochemical properties has been prepared by a multi-step process consisting of KOH activation, pyrolysis, pickling and water washing. The CS/AN co-doped porous carbons (1830.08–2576.53 m2/g) show an enhancement of 8.48%–52.73 % in specific surface area compared to the CS porous carbon (1687.02 m2/g). The hierarchical network structure of the micro-mesoporous interconnects enables fast ion transport and the ultra-micropores further increase the specific capacitance of the electrodes. Theoretical calculation shows that N doping can effectively activate the chemically inert carbon structure and enhance the adsorption capacity of electrolyte ions, thus increasing the specific capacitance. Using 6 M KOH as the electrolyte, CS-AN60-220-800 exhibits a specific capacitance of 368.6 F/g (1.0 A/g) in the three-electrode system. In the two-electrode system, the supercapacitor device constructed with CS-AN60-220-800 demonstrates a capacitance retention of 95.32 % (after 10,000 cycles) along with an energy density of 14.16 Wh/kg (with a power density of 125 W/kg), which is at a high level among similar biomass symmetric supercapacitors. The preparation strategy provides a valuable reference for the preparation of other biomass-based porous carbon, as well as for applications in energy storage.

Preparation of nitrogen-rich porous carbon by microwave-assisted two-step co-pyrolysis of kapok wood and Chlorella vulgaris

In this work, nitrogen-rich porous carbon with abundant pore size distribution was fabricated by microwave-assisted two-step co-pyrolysis of kapok wood (KW) with Chlorella vulgaris (CS), which revealed two nitrogen doping ways of CS as a green nitrogen source. The porous carbon K3C7PC obtained at a mixing ratio of 3:7 between KW and CS possesses the highest specific surface area (SSA) of 2909.78 m2/g, and its pore volume reaches 3.44 cm3/g. The weight loss curves show that the KW biochar retains some of the nitrogenous compounds produced by CS. The three-electrode test shows that the specific capacitance of KWPC obtained from the pyrolysis of KW is only 253.8 F/g, while the specific capacitance of K3C7PC reaches 380 F/g after 70% of CS is mixed with KW. Besides, the symmetric supercapacitors of K3C7PC exabits the maximum energy density of 8.09 Wh/kg at 125 W/kg power density, and after 10,000 cycles, the capacitance retention rate is still 98.49%. This work is convenient for directing the co-pyrolysis of lignocellulosic and algal biomass for the preparation of nitrogen-rich porous carbon.

Direct activation and hydrophobic modification of biomass-derived hierarchical porous carbon for toluene adsorption under high humidity

Hierarchical porous starch-based carbon (PSC) with tunable pore structure (surface area 1974 ∼ 2721 m2/g and pore volume 0.80 ∼ 1.74 cm3/g) was prepared through direct activation. Due to its high surface area and large pore volume, PSC shows great potential for volatile organic compounds (VOCs) removal. Water vapor commonly exists along with VOCs and the competitive adsorption between VOCs and water vapor would significantly restrict the VOCs adsorption of PSC under high humidity. To address this issue, hydrophobic porous starch-based carbon composite (PSCC) was also prepared by physically mixing PSC with poly-divinylbenzene (PDVB) for toluene adsorption under high humidity to suppress the influence of water vapor. As relative humidity increased from 0 % to 80 %, the toluene adsorption capacity of PSC-2 decreased by 46 % while PSCC only experienced a decrease of 22 %. PSCC could also maintain its toluene adsorption performance (close to 100 %) after five adsorption–desorption cycles. Theoretical computations were also proved that the addition of PDVB inhibits water vapor adsorption and promotes its desorption, thereby enhancing the toluene adsorption of PSCC under high humidity. This work provides a controllable preparation and facile modification of porous carbon to improve its toluene adsorption under high humidity, offering a great application prospect for VOCs removal.

Exploring the Micropore Functional Mechanism of N2O Adsorption by the Eucalyptus Bark-based Porous Carbon.

Nitrous oxide (N2O), recognized as a significant greenhouse gas, has received insufficient research attention in the past. In view of their low energy consumption and cost-effectiveness, the application of porous materials in adsorption is increasingly regarded as a potent strategy to reduce N2O pollution. In this study, a series of microporous porous carbons with a preeminent specific surface area (244.54-2018.08 m2 g-1), which are derived from the fast-growing eucalyptus bark, were synthesized by KOH activation at high temperatures. The obtained materials demonstrated a relatively fine N2O capture capability (0.19-0.68 mmol g-1) at normal temperature and pressure. More importantly, the optimal pore size affecting N2O adsorption (0.8 and 1.0 nm) has been detected, which is a meaningful view that has never been put forward in previous studies. The rationality of the N2O adsorption mechanism was also validated by combining the experimental analysis and Grand Canonical Monte Carlo (GCMC) simulation. The calculated results showed that 0.8 and 1.0 nm of the porous carbon were the preferred pore sizes for N2O adsorption, and the interaction force between N2O and the pore wall decreased with the increase of distance. This study provides a significant theoretical basis for the preparation of biomass porous carbon with excellent N2O adsorption performance and practical adsorption application.

Insights into mechanochemical assisted preparation of lignin-based N-doped porous carbon with tunable porosity and ultrahigh surface oxygen content for efficient CO2 capture

Biomass based porous carbon is a green and low-cost promising adsorbents for CO2 capture. However, most of these porous carbon were prepared under high-temperature and even multistep pyrolysis, and possessed poor textural properties and controllability. Here, enzymatic hydrolysis lignin (EHL) was used as carbon source to prepare O-rich N-doped porous carbon (LNPC) through a synthesis strategy that coupled hydrothermal treatment, mechanochemical assistance, and low-temperature activation for the first time. These porous carbon had the large specific surface areas (602.2 ∼ 2030.7 m2/g), high microporosity, and abundant ultramicroporous (Vultra) (0.19 cm3/g), as well as significant N doping and high O content (30.93 ∼ 55.32 %). And the effects of the coupling method, activation temperature, and mechanical pressure and residence time on structural properties of lignin based porous carbon were investigated in detail. We found that the residence time had a good linear correlation for surface areas and micropore volume, respectively, meanwhile, the mechanical pressing exhibited better linear correlation for O content of LNPC, implied the preparation method had good controllability. LSY-P20-T20 prepared at activation temperature of 600 ℃ with the mechanical pressure and time (20 MPa and 20 min) had the highest Vultra, and high O content, and possessed the highest CO2 uptake (5.00 mmol/g). Subsequently, we found that the narrow micropore volume (with d < 1.0 nm) was the main factor for CO2 adsorption capacity, while O content showed more significant impact on determining CO2/N2 selectivity and isosteric heat of adsorption (Qst) of LNPCs. This work provided a new feasible approach for cost-effective carbon-based adsorbents for CO2 capture.

In-situ electropolymerized polyaniline nanoparticles grown on longan shell-derived porous carbon for high-performance supercapacitor electrode

In this study, novel in-situ electropolymerized polyaniline nanoparticles grown on longan shell-derived porous carbon were prepared for high-performance supercapacitor electrode, which exhibited a high specific capacitance of 486F·g−1 at the current density of 0.5 A·g−1 in 1 M H2SO4 electrolyte via a three-electrode test. Further, the asymmetric supercapacitor was constructed with the energy density as high as 47.3 Wh·kg−1 at the power density of 800 W·kg−1 and excellent durability, in which the retention rate of specific capacitance was still as high as 85 % over 10,000 cycles. The excellent electrochemical performance of the as-prepared composite electrode material can be attributed to the large specific surface area of longan shell-derived porous carbon with honeycomb-like morphology up to 1613.2 m2·g−1, as well as the homogeneous electropolymerization of polyaniline nanoparticles grown on porous carbon, resulting in efficient pseudocapacitive charge storage. Noteworthily, natural longan shell as a renewable carbon source can be suitable for the preparation of high-quality and low-cost porous carbon to significantly improve the performance of supercapacitor electrode, which also provides a feasible pathway for high-value utilization of waste biomass resources.

Easily Prepared Wood–Derived Hierarchically Porous Carbon for High–Performance Supercapacitors

AbstractHierarchical porous carbon exhibits enormous application potential in the field of energy storage. In this paper, we develop a facile method to prepare hierarchical porous carbon (HPC) derived from wood powder and using KMnO4 as the activator. The optimized HPC‐600 samples possess the large specific surface area with hierarchical porous structure and massive oxygen–containing functional groups. The HPC‐600 electrode shows a specific capacitance of 362.7 F g−1 at 0.5 A g−1 and a capacitance retention of 101.5 % after 10, 000 cycles. In addition, the assembled HPC‐600//HPC‐600 symmetric supercapacitor delivers an energy density of 18.4 Wh kg−1 at a power density of 600 W kg−1. This paper provides a new and convenient method for the preparation of hierarchical porous carbon for high performance supercapacitor.

Modulating three-dimensional porous carbon from paper mulberry juice by a hydrothermal process for a supercapacitor with excellent performance

Paper mulberry fruit juice, as a sugar-based biomass waste product, was used to make porous carbon by hydrothermal treatment and KOH activation as supercapacitor electrodes. Under different hydrothermal conditions, we investigated the response of hydrochars and the performance of porous carbon as an electrode material. The results showed that the hydrochar obtained at low temperatures and a short duration retained more abundant oxygen-containing functional groups, and had a better surface morphology of well-dispersed carbon microspheres, which facilitated its activation. The maximum specific surface area of porous carbon (AHCT8C180) obtained in this study was 3543.8 m2 g−1 under hydrothermal conditions of 180 °C for 8 h. The corresponding porous carbon, as the material of the electrode in the supercapacitor, achieved a good specific capacitance of 428 F g−1 at a current density of 0.5 A g−1. The symmetric supercapacitor fabricated using AHCT8C180 achieved an energy density of 9.56 Wh kg−1 at a power density of 125 W kg−1, In summary, hydrothermal conditions can optimize the specific surface area (SBET) and pore structure of carbon biomass materials through modulating the structure of hydrochar and the construction of the precursor, guiding the preparation of porous carbon used as an electrode material with superior capacitance.

Triphenylene-derived oxygen-enriched hierarchical porous carbon nanosheets: Carbonization mechanism and application in zinc-ion hybrid capacitors

Since zinc-ion hybrid capacitor (ZIHC) was first proposed, it has become an international study hotspot in the field of secondary energy for some time. Unfortunately, the unsatisfactory specific capacity of ZIHCs has limited its application in industrial development. Thus, there is an urgent need to synthesize carbon cathode with abundant pore structure and heteroatoms to construct high performance ZIHCs. Herein, we investigate the mechanism of FeCl3-induced carbon formation of triphenylene using FeCl3 as a catalyst and template. And the oxygen-enriched hierarchical porous carbon nanosheets with large specific surface area and abundant pores are successfully synthesized with the assistance of KOH activation strategy. Due to the addition of FeCl3 and KOH, the hierarchical porous carbon nanosheets have a unique pore structure and extremely high pore volume, and oxygen atoms are introduced to provide additional pseudocapacitance. As expected, ZIHCs constructed with the best sample exhibits an impressive specific capacity of 134.1 mAh g−1, a distinguished energy density of 102.04 Wh kg−1 (80 W kg−1) and outstanding cycling stability. This work clearly elucidates the carbon formation mechanism of triphenylene under the catalytic action of FeCl3, and provides another insight for the preparation and optimization of porous carbon for ZIHCs cathode.

Enhancement of CH4/N2 separation capacity of coal-based porous carbons via hydrothermal coupled KOH activation

The separation of CH4 and N2 is an important technology for the effective utilization of low-concentration CBM. To improve CH4/N2 separation properties of coal-based porous carbons, Shaanxi long-flame coal was hydrothermally treated followed by KOH activation for the preparation of porous carbons. The impact of hydrothermal treatment on the pore structure and CH4/N2 separation properties of porous carbons was investigated. The results show that hydrothermal decomposes the macromolecular structure of coal, which enlarges the pore size of the raw coal and facilitates the KOH penetrate deeper into the coal particles. Meanwhile, more release of methylene/methyl groups and in-stiu growth of carbon nanotubes develop the pore structure during the activation process of treated coal. The pore structure of porous carbons can be precisely controlled by adjusting the water-coal ratio in the hydrothermal process. Among them, C-TC1.25 shows a 22% increase in CH4 adsorption capacity over C-RC, which is mainly due to a significant increase in the micropore volume at 0.5–1.0 nm and generation of carbon nanotubes as gas transport channels. At 298 K and 101 kPa, C-TC1.25 exhibits a CH4 adsorption capacity reaching 1.72 mmol/g, which surpasses that of most known adsorbents, while the IAST selectivity is as high as 5.5. The breakthrough experiment confirms that the porous carbons effectively enable separation of CH4/N2 mixed gas. Kinetic studies show the CH4 adsorption process on C-TC1.25 conform to the pseudo-first-order model and exhibit surface-attached physical adsorption.

Rapid preparation of P/O doped nano-porous carbon by microwave method for high-performance supercapacitors

This paper proposes a simple and rapid microwave-assisted phosphorus-oxygen doped porous carbon (P/O-PC) preparation strategy is proposed using potassium citrate, Phytic acid (PA), and ethanol under air atmosphere. PA can be used as both a phosphorus source and a microwave absorbing agent. The P/O-PC500–0.75 has a large specific surface area of 905 cm2/g. P/O doping introduces defects into the carbon structure, which enhances the capacitance of the porous carbon. The P/O-PC500–0.75 demonstrates excellent capacitance values of 330 F/g and 389.4 F/g in 6.0 M KOH and 1.0 M H2SO4, respectively (1 A/g). In addition, the symmetrical supercapacitors assembled with the P/O-PC500–0.75 exhibit good electrochemical stability over 5000 cycles at 5 A/g, with a capacitance loss of only 3.6%. This microwave-assisted strategy offers simplicity in operation and low energy consumption, providing a new and efficient pathway to prepare carbon materials in a fast and simple manner.

Recent Advances in Preparation and Supercapacitor Applications of Lignin-Derived Porous Carbon: A Review

&lt;p&gt;Lignin-derived porous carbon has been identified as a versatile electrode material for supercapacitors (SCs) in energy storage systems (ESSs) owing to their intrinsic advantages including good electrical conductivity, low cost, high thermal and chemical stability, and high porosity, which stem from high surface, appropriate pore distribution, tailored morphologies, heterostructures, and diverse derivates. In this review, to provide a fundamental understanding of the properties of lignin, we first summarize the origin, historical development, and basic physicochemical properties. Next, we describe essential strategies for the preparation of lignin-derived porous carbon electrode materials and then highlight the latest advances in the utilization of lignin-derived porous carbon materials as advanced electrode materials. Finally, we provide some of our own insights into the major challenges and prospective research directions of lignin-derived porous carbon materials for supercapacitors. We believe that this review will provide general guidance for the design of next-generation electrode materials for supercapacitors.&lt;/p&gt;

Preparation of inexpensive S-doped porous carbons for high-performance supercapacitors

Low-cost sulfur-doped porous carbons were prepared through hard template method by using inexpensive colloidal SiO2 nanoparticles as template, glucose as carbon source, H2SO4 as pre‑carbonized reagent and sulfur source. The effects of H2SO4 and carbonization temperature on the microscopic morphology, the pore structure and the specific surface area of porous carbons were explored through multiple characterization methods. The capacitive performance of porous carbons was investigated by multiple electrochemical methods. It was found that the pore structure, specific surface area and the content of sulfur element of carbon are highly dependent on the carbonization temperature. The sulfur-doped porous carbon SPC-900 has much larger surface area and larger pore volume, and thus much better capacitive performance than un-doped PC-900, indicating that H2SO4 can increase the surface area and the pore volume during the preparation process. SPC-900 offers the advantages of lower cost, larger pore size, higher pore volume, better capacitive performance and better rate performance compared to expensive mesoporous carbon CMK-3. In the three-electrode system, the specific capacitance of SPC-900 can reach 363 F g−1, whereas that of PC-900 is only 164 F g−1 at a current density of 0.5 A g−1. The double layer capacitance (EDLC) and pseudocapacitance can both be increased by the sulfur element, according to the capacitive contribution study. Additionally, the SPC-900 can maintain its initial specific capacitance of 98.1 % for 10,000 cycles at a current density of 0.5 A g−1, demonstrating both its high cycling performance and potential for practical applications.

One-step molten salt-assisted preparation of crab shell-based hierarchical porous carbon for capacitive energy storage

Carbon-based materials have become the most commonly used electrode materials for supercapacitors due to their simple production and low preparation cost. The preparation of hierarchical porous carbon materials with excellent properties using biomass materials is a very valuable study. Therefore, we used crab shells as carbon precursors to prepare crab shell-based carbon materials by using the self-templating method (CaCO3) combined with low-temperature eutectic molten salt. When the composition of the eutectic salt was CaCl2/KCl (molar ratio of 43:57) and the mass ratio of crab shells to eutectic salt was 1:5, the prepared crab-shell-based carbon material (CC-CaK-5) exhibited excellent physical and electrochemical properties with high specific surface area (1193.7 m2g−1), rich heteroatom doping (O (7.83 %) and N (6.71 %)), and high specific capacitance (290 Fg−1 at 0.5 Ag−1).The CC-CaK-5//CC-CaK-5 devices assembled with CC-CaK-5 as the electrode material exhibited excellent electrochemical performance. At a current density of 1 Ag−1, the capacitance value of the device remained at 93.11 % of the initial capacitance value after 5000 cycles. The energy density reached 6.95 Whkg−1 at a power density of 302.09 Wkg−1 and remained at 4.71 Whkg−1 at a power density of 13,037.54 Wkg−1.