ABSTRACT In this study, the Ni-TiO2 coatings were deposited on copper substrates by pulse plating. The effect of multi-step current cycles on the metallurgical properties of produced coatings was investigated. The results showed that the values of applied currents within the periods significantly affect the surface properties of all coatings. Using the negative current cycles, the surface morphologies completely changed from regular and compact to irregular, compared to the deposits that did not have a negative cycle in the coating process. Also, the surface roughness increased by 1.5 times in the best case. Applying the 8-step cycle increased the percentage of TiO2 content inside the Ni-TiO2 layer from 13.13 vol.% to 31.58%. The corrosion and wear analysis results showed that the coating applied by a 4-step cycle with a 90-second off time has the best properties. Therefore, the corrosion and wear properties were not necessarily directly related to the participation percentage of TiO2 particles. Compact morphology with high current efficiency, wide distribution of TiO2 particles (6.31 vol.%) with minimal agglomeration, low coating roughness (Ra = 0.32 µm), high hardness value (436 Vickers), and the participation of (111) plane in the preferred texture improved the corrosion and wear behaviour of the optimal coating.
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