Ratio Of Precipitation Research Articles

Assessing Climate Change Impact on the Spatial Dependence of Extreme Snow Depth Maxima in the French Alps

AbstractModeling extreme snow depths in space is important for water storage, tourism industry, mountain ecosystems, collapse of buildings, and avalanche prevention. However, studies modeling the spatial dependence structure of extremes generally assume temporal stationarity which is clearly questionable in a climate change context. We model climatic trends within the spatial dependence structure of extremes, with application to a data set of snow depth winter maxima. From 82 stations spanning the 1970–2012 period in the French Alps, we infer a strong decrease in the range of spatial extremal dependence. This finding is related to a strong decrease in both the snow precipitation ratio and the winter cumulated snowfall, due to increasing temperatures. Hence, we demonstrate that the spatial dependence of extreme snow depths is impacted by climate change in a similar way as has been observed for extreme snowfalls. Furthermore, snow depths maxima are more spatially dependent than snowfalls. The space‐time approach that we introduce may be very useful for assessing past and future evolutions under ongoing climate change in various hydrological quantities.

Contributions of Atmospheric Transport and Rain–Vapor Exchange to Near-Surface Water Vapor in the Zhanjiang Mangrove Reserve, Southern China: An Isotopic Perspective

Coastal mangroves are increasingly recognized as valuable natural resources and important sites of water and carbon exchange. In this study, we examine atmospheric water cycling in the boundary layer above a coastal mangrove forest in southern China. We collected site observations of isotopic ratios in water vapor and precipitation along with core meteorological variables during July 2017. Our evaluation of these data highlights the influences of large-scale atmospheric transport and rain–vapor exchange in the boundary layer water budget. Rain–vapor exchange takes different forms for different types of rainfall events. The evolution of isotopic ratios in water vapor suggests that substantial rain recycling occurs during the passage of large-scale organized convective systems, but that this process is much weaker during rainfall associated with less organized events of local origin. We further examine the influences of large-scale transport during the observation period using a Lagrangian trajectory-based moisture source analysis. More than half (63%) of the boundary layer moisture during the study period traced back to the South China Sea, consistent with prevailing southerly to southwesterly flow. Other important moisture sources included mainland Southeast Asia and the Indian Ocean, local land areas (e.g., Hainan Island and the Leizhou Peninsula), and the Pacific Ocean. Together, these five regions contributed more than 90% of the water vapor. The most pronounced changes in isotopic content due to large-scale transport during the study period were related to the passage of Tropical Storm Talas. The outer rain bands of this tropical cyclone passed over the measurement site on 15–17 July, causing a sharp reduction in the heavy isotopic content of boundary layer water vapor and a substantial increase in deuterium excess. These changes are consistent with extensive isotopic distillation and rain–vapor exchange in downdrafts associated with the intense convective systems produced by this storm.

Effects of Long- and Short-Term Atmospheric Water Cycles on the Water Balance over the Maritime Continent

Abstract This study investigated atmospheric water cycles over several time scales to understand the maintenance processes that control heavy precipitation over the islands of the Maritime Continent. Large island regions can be divided into land, coastal, and ocean areas based on the characteristics of both the hydrologic cycle and the diurnal variation in precipitation. Within the Maritime Continent, the major islands of Borneo and New Guinea exhibit different hydrologic cycles. Large-scale circulation variations, such as the seasonal cycle and the Madden–Julian oscillation, have a lesser effect on the hydrologic cycle over Borneo than over New Guinea because the effects depend on their shapes and locations. The impact of diurnal variations on both regional-scale circulation and water exchange between land and coastal regions is pronounced over both islands. The recycling ratio of precipitation, which can be related to stronger diurnal variation in the atmospheric water cycle that results from enhanced evapotranspiration over tropical rain forests, is higher over Borneo than over New Guinea.

Atmospheric water resource and precipitation conversion

The concept of water resources is largely limited only to water in rivers, lakes, underground aquifers, and other sources that can be used by humans directly––blue It does not normally include water that directly evaporates from the land surface and transpires from vegetation––green Generally speaking, the sum of blue water and green water is equivalent to total precipitation. Considering the global land surface, as much as about 65% of the total precipitation is converted into green water, and only the remaining 35% is converted into blue water. The concept of green water clearly extends the scope of research and management of water resources to the total amount of land precipitation, but the source of terrestrial water resources has not been intensively studied. In terms of a complete water cycle, water resources should refer to the renewal/replenishment of the fluxes of fresh water in different processes in the hydrosphere. The storage of water in the atmosphere is relatively small, but the huge flux of water transport in the atmosphere is the fundamental source of terrestrial water resources. In the contexts of existing water shortages, future water demands (including for ecological protection), and global climate change impacts on water resources, accurate quantitative studies on the formation of terrestrial water resources from the atmosphere are becoming increasingly important. Such studies require a clear definition of the concept of atmospheric water resource and particular focus on its precipitation conversion. Such research can indeed enhance our theoretical knowledge about the functions of water resources systems and further broaden our view of traditional water resources management. Motivated by this, the present paper attempts to improve our understanding of atmospheric water resources. This is done through: (1) a review of the concept of atmospheric water resource; (2) proposing a quantitative estimation method for atmospheric water resource; and (3) quantifying the precipitation conversion characteristics of atmospheric water resources. For a given period of time, we define the atmospheric water resource as the accumulated atmospheric water matter with potential to precipitate, and call it as Therefore, in a sense, white water is also a renewable/replenishable flux, whose volume is generally considered over a longer period (e.g., per year). However, since the horizontal transportation of water matter in the atmosphere spreads over the entire sphere (as opposed to surface water that is bounded in one-dimensional river channels), the dimension of white water at one point should be in L2T-1. With this, for any given point, the quotient of precipitation rate over white water flux is defined as the white water precipitation efficiency ( WPE ) (dimension: L-1). Therefore, the WPE refers to the proportion of precipitation converted from white water while transported in unit distance. To calculate the quantity of atmospheric water matter that has the potential to precipitate, a background value should be subtracted from the measured vertically integrated water vapor (IWV). In this study, the clear-sky IWV of an ordinal day in a year is used as the background value. With the above, the concept of white water is also extended to surface river basins. In this, the white water flux entering a river basin is defined in the L3T-1 dimension, and the corresponding white water precipitation ratio ( WPR , dimensionless) is obtained by integrating the WPE over each transport path and then calculating the weighted average over all the paths. Therefore, the WPR is essentially the proportion of total precipitation in the basin that is converted from the incoming white water. Finally, the reanalysis data are used to analyze the distribution of white water and the pattern of WPE within the range 5°~50°N and 75°~135°E region. A comparative analysis of the atmospheric-terrestrial water resources characteristics in the Yangtze River, the Yellow River, and the Pearl River basins, as well as in the Sanjiangyuan region is also conducted. The results show that the WPE is a fair measure of the conversion efficiency from white water to precipitation, and the WPR in a river basin is useful for quantitative analysis of the atmospheric-terrestrial coupling relationship.

Woody bioenergy crop selection can have large effects on water yield: A southeastern United States case study

Short-rotation woody crops in the southeastern United States will make a significant contribution to the growing renewable energy supply over the 21st century; however, there are few studies that investigate how species selection may affect water yield. Here we assessed the impact of species selection on annual and seasonal water budgets in unvegetated plots and late-rotation 14–15-year-old intensively managed loblolly pine (Pinus taeda L.) and sweetgum (Liquidambar styraciflua L.) stands in South Carolina USA. We found that while annual aboveground net primary productivity and bioenergy produced was similar between species, sweetgum transpiration was 53% higher than loblolly pine annually and 92% greater during the growing season. Canopy interception was 10.5% of annual precipitation and was not significantly different between the two species. Soil evaporation was less than 1.3% of annual precipitation and did not differ between species, but was 26% of precipitation in unvegetated plots. Annual water yield was 69% lower for sweetgum than loblolly pine, with water yield to precipitation ratios of 0.13 and 0.39 for sweetgum and loblolly pine, respectively. If planted at a large scale, the high transpiration and low water yield in sweetgum could result in declines in downstream water availability relative to loblolly pine by the end of the growing season when storage in groundwater, streams, and water supply reservoirs are typically at their lowest. Our results suggest that species selection is of critical importance when establishing forest plantations for woody bioenergy production due to potential impacts on downstream water yield.

The relative impact of urbanization and precipitation on long-term water level variations in the Yangtze River Delta

The combined and individual hydrological impacts of climate variation and urbanization have been extensively discussed over the past few decades, yet little is known about the relative impact of each. In this paper we took one of the most developed regions worldwide, Yangtze River Delta, as an example to analyse the long-term relative impacts of precipitation and urbanization change on water level alterations, based on precipitation, water level series, and annual impervious area data from 1960 to 2015. Abrupt changes detection in the water level series divided the data into the pre-impact period (1960–1988) and impacted period (1989–2015), and relative impacts of precipitation and urbanization on the water level increase from pre-impacted to impacted period, as well as their spatial and seasonal variations were estimated with the elasticity method. The results indicated that the urbanization change showed no distinct influence on the water level rise in the pre-impact period, while the precipitation played distinct roles only during summer months in the impacted period; the precipitation dominated two thirds of the water level rise in flood season, and in non-flood season the urbanization controlled the two thirds of the water level rise; spatially, the water level variations in old and new urban area were dominated by precipitation and urbanization process respectively; compared with precipitation amount, the water level correlated more strongly to the contribution ratio of precipitation. The results would provide a good reference for flood control and water resource management in the river basin, especially in the economically developed areas.

Current Thyrotropin Immunoassays Recognize Macro-Thyrotropin Leading to Hyperthyrotropinemia in Females of Reproductive Age.

Macro-thyrotropin (macro-TSH) is a high molecular weight form of TSH that leads to hyperthyrotropinemia. This study was undertaken to examine the prevalence and nature of macro-TSH in females of reproductive age. Blood samples were taken from 1794 female patients who visited the Hamada Obstetrics and Gynecology Hospital in Tokyo, Japan, complaining of infertility. The serum of 305 patients with TSH concentrations >2.5 mIU/L was screened for macro-TSH by the polyethylene glycol method. Samples with TSH precipitation ratios by polyethylene glycol >70% were further analyzed using gel filtration chromatography (GFC), protein G columns, and 125I-TSH binding experiments. Screening of the 305 patients revealed that 63 had serum TSH precipitation ratios >70%. GFC revealed that immunoreactive TSH, with a molecular weight of approximately 150 kDa, eluted at higher ratios (79.6 ± 24.4%) in 27 of the 63 patients compared to 0.4 ± 2.0% in the control group. Serum TSH concentrations in 24 of the 27 patients were spuriously elevated due to human anti-mouse antibodies. Macro-TSH was found in the other three patients, and one of them had detectable anti-TSH autoantibodies. Eight of the remaining 36 patients who did not have high-molecular-weight TSH assessed by GFC had immunoglobulin G-associated TSH. Three commercially available TSH immunoassays (Elecsys®, Centaur®, and Architect®) all recognized macro-TSH leading to the elevated serum TSH concentrations. Macro-TSH was present in 0.17% of infertile women. Commercial TSH immunoassays recognized macro-TSH, resulting in the diagnosis of hyperthyrotropinemia.

Climate Elasticity of Low Flows in the Maritime Western U.S. Mountains

AbstractSummer streamflow is an important water resource during the dry summers in the western United States, but the sensitivity of summer minimum streamflow (low flow) to antecedent winter precipitation as compared with summer evaporative demand has not been quantified for the region. We estimate climatic elasticity of low flow (percent change in low flow divided by percent change in climatic forcing variable) with respect to annual maximum snow water equivalent (ESWE), winter precipitation (EPPT), and summer potential evapotranspiration (EPET) for 110 unmanaged headwater catchments in the maritime western U.S. mountains. We find that |EPET| is larger than |EPPT| and |ESWE| in every catchment studied and is 4–5 times larger than both, on average. Spatial variations in E are dominated by three patterns. First, |EPPT|, |ESWE|, and |EPET| are largest and most variable among semiarid catchments and decrease nonlinearly with increasing values of the humidity index (the ratio of annual precipitation to annual evaporative demand). Second, |EPPT| and |EPET| are lower in snow‐dominated catchments than in rain‐dominated catchments, suggesting that snow cover reduces the proportional response of low flows to climatic variability. Third, |EPPT|, |ESWE|, and |EPET| are lower in slow‐draining catchments than in fast‐draining catchments, for which baseflow recession storage coefficients are used to represent the rate at which catchment water storage is translated into streamflow. Our results provide the first comparison of summer low‐flow elasticity to PPT versus PET and its spatial variation in the maritime western U.S. mountains.

Development of a Rapid and Simple Method for Preparing Tea-Leaf Saponins and Investigation on Their Surface Tension Differences Compared with Tea-Seed Saponins.

The relative overcapacity in China's tea-leaf production and the potential application of tea-leaf saponins in soil remediation encouraged in-depth developments and comprehensive utilizations of tea-leaf resources. Through variables optimizations using Box–Behnken designs for ultrasonic power, temperature as well as ultrasonic treatment time in ultrasonic-assisted water extraction and single-variable experiments for acetone-extraction solution ratio in acetone precipitation, a rapid and simple method was developed for preparing tea-leaf saponins. Tea-leaf saponins with the concentration of 3.832 ± 0.055 mg/mL and the purity of 76.5% ± 1.13% were acquired under the optimal values of 78 w, 60 °C, 20 min and 0.1 ratio of acetone-extraction solution. Both Fourier transform-infrared (FT-IR) spectra and ultraviolet (UV) spectra revealed slight composition differences between tea-leaf saponins and tea-seed saponins, while these differences were not reflected in the critical micelle concentration (CMC) and the surface tension of tea-leaf saponins and tea-seed saponins, indicating there was no need to distinguish them at the CMC. Further research attention on where tea-leaf saponins were in low concentrations is deserved to discover whether they had differences in comparison with tea-seed saponins, which was beneficial to apply them in the phytoremediation of contaminated soils.

Spatiotemporal variations of aridity in China during 1961–2015: decomposition and attribution

Changes in global climate intensify the hydrological cycle, directly influence precipitation, evaporation, runoff, and cause the re-distribution of water resources in time and space. The aridity index (AI), defined as the ratio of annual precipitation to annual potential evapotranspiration, is a widely used numerical indicator to quantify the degree of dryness at a given location. This study examined the effects of climate change on AI in China during 1961–2015. The results showed that the nationally averaged AI experienced a notable interdecadal transition in 1993, characterized by increasing AI (wetter) between 1961 and 1993, and decreasing AI (drier) after 1993. Overall, the decreased solar radiation (solar dimming) was the main factor affected the nationally averaged AI during 1961–1993, while the relative humidity dominated the variations of nationally averaged AI during 1993–2015. However, the roles of individual factors on the changes in AI vary in different subregions. Precipitation is one of the important contributing factors for the changes of AI in almost all subregions, except the Mid-Lower Yangtze and Huaihe basins. Solar radiation has been significantly decreased during 1961–1993 in South China, Southwest China, Mid-Lower Yangtze and Huaihe basins, and the Tibetan Plateau. Therefore, it dominated the trends of AI in these subregions. The relative humidity mainly affected the Mid-Lower Yangtze and Huaihe basins, Southwest China, and the Tibetan Plateau during 1993–2015, hence dominated the trends of AI in these subregions. The changes of temperature and wind speed, however, played a relatively weak role in the variations of AI.

Changes in Madden‐Julian Oscillation Precipitation and Wind Variance Under Global Warming

AbstractThe Madden‐Julian oscillation (MJO) is the leading mode of tropical intraseasonal variability, having profound impacts on many weather and climate phenomena across the tropics and extratropics. Previous studies using a limited number of models have suggested complex changes in MJO activity in a warmer climate. While most studies have argued that MJO precipitation amplitude will increase in a future warmer climate, others note that this is not necessarily the case for MJO wind variability. This distinction is important since MJO wind fluctuations are responsible for producing remote impacts on extreme weather through teleconnections. In this study, we examine projected changes of MJO precipitation and wind variance at the end of the 21st century in Representative Concentration Pathway 8.5 using the multimodel Coupled Model Intercomparison Project phase 5 data set. Under global warming, most models show an increase in MJO band precipitation variance, while wind variability decreases. The discrepancy between MJO precipitation and wind variance changes under global warming is shown to be due to increases in tropical static stability in a warmer climate. The multimodel mean shows a 20% increase in both the 500‐hPa vertical tropical dry static energy gradient and the ratio of intraseasonal precipitation to 500 hPa omega fluctuations, consistent with scaling by weak temperature gradient theory. These results imply that tropical static stability increases may weaken the MJO's ability to influence extreme events in future warmer climate by weakening wind teleconnections, even though MJO precipitation amplitude may increase.

Changes in the Proportion of Precipitation Occurring as Rain in Northern Canada during Spring–Summer from 1979–2015

Changes in the form of precipitation have a considerable impact on the Arctic cryosphere and ecological system by influencing the energy balance and surface runoff. In this study, station observations and ERA-Interim data were used to analyze changes in the rainfall to precipitation ratio (RPR) in northern Canada during the spring–summer season (March–July) from 1979–2015. Our results indicate that ERA-Interim describes the spring–summer variations and trends in temperature and the RPR well. Both the spring–summer mean temperature [0.4°C–1°C (10 yr)-1] and the RPR [2%–6% (10 yr)-1] increased significantly in the Canadian Arctic Archipelago from 1979–2015. Moreover, we suggest that, aside from the contribution of climate warming, the North Atlantic Oscillation is probably another key factor influencing temporal and spatial differences in the RPR over northern Canada.

Isotope hydrology of a tropical coffee agroforestry watershed: Seasonal and event‐based analyses

AbstractStable isotope variations are extremely useful for flow partitioning within the hydrologic cycle but remain poorly understood throughout the tropics, particularly in watersheds with rapidly infiltrating soils, such as Andisols in Central America. This study examines the fluctuations of stable isotope ratios (δ18O and δ2H) in the hydrologic components of a tropical coffee agroforestry watershed (~1 km2) with Andisol soils in Costa Rica. Samples were collected in precipitation, groundwater, springs, and stream water over 2 years. The local meteoric water line for the study site was δ2H = 8.5 δ18O + 18.02 (r2 = 0.97, n = 198). The isotope ratios in precipitation exhibited an enriched trend during the dry season and a notable depletion at the beginning of the wet season. The δ18O compositions in groundwater (average = −6.4‰, σ = 0.7) and stream water (average = −6.7‰, σ = 0.6) were relatively stable over time, and both components exhibited more enriched values in 2013, which was the drier year. No strong correlation was observed between the isotope ratios and the precipitation amount at the event or daily time‐step, but a correlation was observed on a monthly scale. Stream water and base flow hydrograph separations based on isotope end‐member estimations showed that pre‐event water originating from base flow was prevalent. However, isotope data indicate that event water originating from springs appears to have been the primary driver of initial rises in stream flow and peak flows. These results indicate that isotope sampling improves the understanding of water balance components, even in a tropical humid location, where significant variations in rainfall challenge current modelling efforts. Further research using fine‐scale hydrometric and isotopic data would enhance understanding the processes driving spring flow generation in watersheds.

Groundwater recharge amidst focused stormwater infiltration

AbstractDistributed, infiltration‐based approaches to stormwater management are being implemented to mitigate effects of urban development on water resources. One of the goals of this type of storm water management, sometimes called low impact development or green infrastructure, is to maintain groundwater recharge and stream base flow at predevelopment levels. However, the connection between infiltration‐based stormwater management and groundwater recharge is not straightforward. Water infiltrated through stormwater facilities may be stored in soil moisture, taken up by evapotranspiration or contribute to recharge and eventually base flow. This study focused on a 1.1 km2 suburban, low impact development watershed in Clarksburg, Maryland, USA, that was urbanized and contained 73 infiltration‐based stormwater facilities. Continuous water table measurements were used to quantify the movement of infiltrated stormwater. Time series analyses were performed on hydrographs of 7 wells, and the episodic master recession method was used. Persistence in water levels, as measured by autocorrelation function, was found to be positively related to depth to water. Storm properties (precipitation rate and duration) and well location (proximity to the nearest stream) were significant in driving episodic recharge to precipitation ratios. The well that had the highest recharge to precipitation ratios and water table rises of up to 1.5 m in response to storm events was located furthest from the stream and down gradient of stormwater infiltration locations. This work may be considered in evaluating the effects of planned watershed‐scale infiltration‐based stormwater management on groundwater flow systems.

Earliest Eocene cold period and polar amplification - Insights from δ2H values of lignin methoxyl groups of mummified wood

Three well-preserved mummified wood specimens have been excavated from three earliest Eocene (~55.5, 55.2 and 53.3 Ma) kimberlite pipes in the subarctic Northwest Territories, Canada (~64°N). Each specimen contained multi-decadal length tree-ring series and allowed measurements of stable hydrogen isotope ratios (δ2H values) of the lignin methoxyl groups (commonly used cellulose was largely degraded). We used these δ2H signatures for the reconstruction of three representative δ2H values of the local precipitation by applying calibrated isotope fractionations to investigate deep-time paleoclimatology. Our reconstructions indicate unprecedented low values for the subarctic early Eocene which, however, show within ~2.2 Myr an increasing trend from −206 ± 17, −202 ± 17 to −168 ± 17‰. These values were interpreted along with other Arctic, subarctic and mid-latitudinal proxy records of that time period indicating in total a period of low stable hydrogen and oxygen isotope ratios in precipitation (onset between ~55.7 and 54.9 Ma and a recovery at 53.3 ± 0.6 Ma) which is assumed to have been primarily caused by a continental cold period. An increased magnitude of this cold period was noted for our subarctic reconstructions pointing to a polar amplification where surface air temperature changes in the Arctic exceed the global trend (in response to climate forcing). In an attempt to quantify the polar amplification magnitude we estimated Arctic temperature changes using our δ2H results in combination with existing relationships between early Eocene temperatures and stable water isotopes. Comparing the Arctic temperature change with a global estimation proposes a polar amplification of magnitude <4. Our estimate for the earliest Eocene shows either agreement or indicates a lower magnitude when compared to previously described Cenozoic polar amplifications commonly ranging between 2 and 4.

A practical approach to scale-adaptive deep convection in a GCM by controlling the cumulus base mass flux

As the horizontal resolution of general circulation model (GCM) is increased, the sub-grid scale vertical transport has to be decreased appropriately. In the present study, a resolution-dependent (so-called scale-adaptive or scale-aware) deep convection was formulated by controlling the cumulus base mass flux. Using a three-dimensional cloud resolving model simulation, we estimated the appropriate ratios of the sub-grid scale vertical transport to the total vertical transport of moist static energy for different horizontal resolutions, whose values are about 0.8 for 100 km resolution and about 0.6 for 50 km resolution. Those values were used as a guideline to decrease to the ratio of convective precipitation to the total precipitation in a high-resolution GCM. The cumulus base mass flux is reduced by multiplying a reduction coefficient, which is 0.2 for the 100 km resolution and 0.09 for the 50 km resolution in the present GCM. The GCM with the scale-adaptive deep convection produces the climatological mean precipitation similar to that of the original GCM, whereas it simulates the heavy precipitation frequency and the Madden and Julian Oscillation much better than those of the original GCM.

Impact of water transfer on interaction between surface water and groundwater in the lowland area of North China Plain

AbstractThe contradiction between the freshwater shortage and the large demand of freshwater by irrigation was the key point in cultivated lowland area of North China Plain. Water transfer project brings fresh water from water resource‐rich area to water shortage area, which can in turn change the hydrological cycle in this region. Major ions and stable isotopes were used to study the temporal variations of interaction between surface water and groundwater in a hydrological year after a water transfer event in November 2014. Irrigation canal received transferred Yellow River, with 2.9% loss by evaporation during water transfer process. The effect of transferred water on shallow groundwater decreased with increasing distance from the irrigation canal. Pit pond without water transfer receives groundwater discharge. During dry season after water transfer event, shallow groundwater near the irrigation canal was recharged by lateral seepage and deep percolation of irrigation, whereas shallow groundwater far from irrigation canal was recharged by deep percolation of deep groundwater irrigation. Canal water lost by evaporation was 2.7–17.4%. Influence of water transfer gradually disappeared until March as the water usage of agricultural irrigation increased. In the dry season, groundwater discharged to irrigation canal and pond; 2.2–31.6% canal water and 11.3–20.0% pond water were lost by evaporation. In the rainy season (June to September), surface water was fed mainly by precipitation and surface run‐off, whereas groundwater was recharged by infiltration of precipitation. The two‐end member mix model showed that the mixing ratio of precipitation in pond and irrigation canal were 73–83.4% (except one pond with 28.1%) and 77.3–99.9%, respectively. Transferred water and precipitation were the important recharge sources for shallow groundwater, which decreased groundwater salinity in cultivated lowland area of North China Plain. With the temporary and spatial limitation of water transfer effects, increased water transfer amounts and frequency may be an effective way of mitigating regional water shortage. In addition, reducing the evaporation of surface water is also an important way to increase the utilization of transfer water.

On observed aridity changes over the semiarid regions of India in a warming climate

In this study, a quantitative assessment of observed aridity variations over the semiarid regions of India is performed for the period 1951–2005 using a dimensionless ratio of annual precipitation (P) and potential evapotranspiration (PET), estimated from five different observed gridded precipitation data sets. The climatological values and changes of this aridity index are found to be sensitive to the choice of the precipitation observations. An assessment of P/PET estimated using the ensemble mean precipitation shows an increase in aridity over several semiarid regions of India, despite the sensitivity of P/PET variations across individual precipitation data sets. Our results indicate that precipitation variations over the semiarid regions of India are outpacing the changes in potential evapotranspiration and, thereby, influencing aridity changes in a significant manner. Our results further reveal a 10% expansion in the area of the semiarid regions during recent decades relative to previous decades, thus highlighting the need for better adaptation strategies and mitigation planning for the semiarid regions in India. The sensitivity of aridity index to multiple PET data sets can be an additional source of uncertainty and will be addressed in a future study.

Effect of pH on the selective separation of metals from acidic wastewater by controlling potential

Abstract In the face of difficulties in separating similar metals from acidic wastewater, a new process is proposed to selectively separate metals from acidic wastewater by controlling potential. In this paper, the effect of pH value on precipitation ratio and separation efficiency is investigated. Through thermodynamic calculations, a 3D E -pH diagram of the Me-S-H 2 O system was plotted. The results reveal that rising pH value is helpful for metal precipitation, but high pH value may cause co-precipitation of metals impurity. The crystallinity and size of precipitates are obviously affected by pH value. Co can be effectively separated from Zn by xanthate precipitation under controlling potential, and the xanthate dosage is dependent on pH value. Mn-inclusions appear in Zn-precipitate due to high Mn 2+ concentration. The optimal pH value for Cu 2+ , Co 2+ , and Zn 2+ precipitation were 1, 2, and 2, respectively. Mn 2+ could be recovered by carbonate precipitation from the solution after Zn removal. Cu 2+ , Co 2+ , Zn 2+ , and Mn 2+ precipitation ratios reached to 99%.

Effect of solution potential on selective separation of metals from acid wastewater by controlling potential

Abstract In view of the difficulties in separating similar metals from acidic wastewater, a new process is proposed to selectively separate metals by controlling potential. In this study, the effects of solution potential on precipitation ratio and separation efficiency were investigated. The potential was controlled by adding sodium sulfide or xanthate and was monitored by an MT320-SpH instrument with a Pt electrode and a calomel electrode. E-pH diagrams of Me-S-H2O system were plotted through thermodynamic calculations. The results revealed that with the drop of solution potential, the metal precipitation ratios increased. Cu2+, Co2+, and Zn2+ can be selectively separated and completely precipitated under controlling potential at 330 mV, 125 mV and 30 mV, respectively. Mn2+ could be recovered by carbonate precipitation from the residual solution after Zn removal. The precipitation ratios of Cu2+, Co2+, Zn2+, and Mn2+ were as high as 99%.