Grain Boundary Precipitation Research Articles

Improving the mechanical properties and corrosion resistance of a highly alloyed Al-Zn-Mg-Cu alloy through Pre-Treatment at 350°C prior to multi-stage solid solution treatment

This study proposed a new solution treatment process for optimizing the microstructure and properties of Al-Zn-Mg-Cu alloy, by introducing a pre-treatment process that can achieve sufficient recovery and trace recrystallization of the alloy, namely, 350 ° C pre-treatment (PT-350 ° C), prior to traditional solution treatment. Research has found that during the PT-350°C/12h process, a large amount of nanoscale η(Mg(Zn,Cu)2) phases in the extruded state dissolved, diffused, re-precipitated at the larger η(Mg(Zn,Cu)2) phases, and form a large particles, with a size of about 0.74 μm, mainly distributed at the grain boundaries of the matrix. In the subsequent multi-stage solid solution treatment (MST) process, while fully dissolving, they also had a certain inhibitory effect on the growth of matrix grains. More importantly, the alloy underwent sufficient recovery and slight recrystallization during the PT-350°C/12h, significantly reducing dislocation density, suppressing the degree of recrystallization, and refining the alloy grains of the alloy during MST process. The intragranular aging precipitate changed from the η '+ η phase of MST to the GP zone + η' phase of PT-350 °C/12h+MST, with an increase in content and a decrease in size. The distribution of grain boundary precipitates (GBPs) transformed from continuous to discontinuous. The yield strength, ultimate tensile strength, and elongation increased from 740 MPa, 755 MPa, and 2.9% to 778 MPa, 792 MPa, and 5.8%, respectively. The corrosion resistance of the alloy also had significantly improved, in 3.5 wt.%NaCl solution, the corrosion current density decreased from 4.02 × 10-6 A·cm-2 to 8.33 × 10-7 A·cm-2.

Enhancing mechanical and corrosion properties of Al-Zn-Mg-Cu alloy through electropulsing and aging alternate treatment

The contradiction between mechanical and corrosion properties restricts the further research and application of Al-Zn-Mg-Cu alloy. Studies report a new technique, electropulsing and aging alternate treatment (EPAAT), including twice electropulsing and aging treatment, to solve this contradiction by precisely controlling the intragranular precipitates and grain boundary precipitates (GBPs). The results show that the grain boundary precipitates (GBPs, η) are discontinuous and the intragranular precipitates (η’) are not coarsened after EPAAT. The precise regulation of precipitated phase by EPAAT can be attributed the differing effect of electropulsing current on the GBPs and the intragranular precipitates. Utilize electropulsing primary treatment to obtain the supersaturated solid solution. Following natural aging, the small continuous phases at the grain boundary and the GP zones within the grain were precipitated again. The small continuous GPBs of the sample diffuse along the grain boundaries and become discontinuously distributed, while the GP zones within the grain dissolve with under the electropulsing secondary treatment. After artificial aging, the intragranular phase is fully precipitated, yet the GBPs remain unchanged, thereby achieving phase regulation. Consequently, the icorr of Al-Zn-Mg-Cu alloy decreases from 28 to 5.87 μA/cm2 and the tensile strength increases from 511 MPa to 524 MPa. The EPAAT technology realizes the accurate treatment of Al-Zn-Mg-Cu alloys and provides a new solution for improving strength and corrosion properties.

Effect of precipitate evolution on galvanic corrosion behavior of friction stir welded AA6061-T6 joint after post-weld aging

The microstructural transformation of FSW AA6061-T6 joint after post-weld T6 and its effects on the mechanical properties and corrosion behavior was investigated through electrochemical tests, immersion experiments and transmission electron microscopy (TEM) observation. The research results show that the joint efficiency and strength can be enhanced by post-welding aging. The hardness of SZ is recovered to a level close to that of matrix due to the sufficient precipitation of the effective strengthening phase β''. The main β' precipitate in over-aged HAZ coarsens during post-weld aging and cannot effectively restore strength, resulting in the lowest hardness in HAZ and limited tensile strength of the joint. The presence of macro-galvanic effects in the whole joint was confirmed. In SZ, the highest level of aging characteristics is caused by the highest aging drive due to fully solidified atoms, and is confirmed by the continuous grain boundary precipitates (GBPs) and dense matrix precipitates, which lead to the most positive potentials. Whereas, in HAZ, discrete GBPs and coarsened matrix precipitates indicate over-aged features, which lead to the most negative potentials. The potential difference between SZ and HAZ results in a macro-galvanic effect in the joint, where SZ is protected as the cathode and HAZ is corroded faster as the anode.

Effect of heat treatment on microstructure, mechanical properties and corrosion resistance of 7075 aluminum alloys fabricated by improved friction stir additive manufacturing

The use of an improved stirrng pin broadened the effective bonding area in the friction stir additive manufacturing (FSAM) of 7075 aluminum alloy. A systematic investigation was conducted to examine the effects of different heat treatment (T6, T73, and RRA) processes on the microstructure, tensile strength and corrosion resistance of as-fabricated (AS) specimen. The findings revealed that different heat treatments had minimal impact on the grain size, texture strength, and dislocation density. Variations in strength and corrosion resistance were primarily attributed to the size and distribution of precipitates. Following T6 heat treatment, the intragranular precipitates (IGPs) were smaller, with a higher proportion of η', while the grain boundary precipitates (GBPs) were coarser η, continuously distributed along grain boundaries. Consequently, T6 specimen showed the highest tensile strength, reaching 568 MPa, but had lower corrosion resistance than AS specimen due to precipitate-induced disruption of the passive film. The T73 heat treatment resulted in significant coarsening of IGPs, with a substantial transformation of η' to η, thereby reducing the precipitation strengthening effect. The coarsening of GBPs led to their discontinuous distribution along grain boundaries, which significantly increased the corrosion resistance. After RRA heat treatment, IGPs consisted of numerous fine η', while the coarser GBPs sporadically dispersed along grain boundaries. The strength of RRA specimen was only about 6 % lower than that of T6 specimen, but its corrosion resistance was significantly improved.

Effect of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy

The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses, including electrical conductivity, mechanical properties, local corrosion properties, and slow strain rate tensile stress corrosion tests. Microstructure characterization techniques such as metallographic microscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM) were also employed. The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging, and it even exceeds 700 MPa. Furthermore, the yield strength increases by 52.7 MPa, reaching 654.8 MPa after T6I6 aging treatment. The maximum depths of intergranular corrosion (IGC) and exfoliation corrosion (EXCO) decrease from 116.3 and 468.5 µm to 89.5 and 324.3 µm, respectively. The stress corrosion factor also decreases from 2.1% to 1.6%. These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance. Similarly, when the alloy is treated with T6I4, T6I6 and T6I7 aging, the sizes of grain boundary precipitates (GBPs) are found to be 5.2, 18.4, and 32.8 nm, respectively. The sizes of matrix precipitates are 4.8, 5.7 and 15.7 nm, respectively. The atomic fractions of Zn in GBPs are 9.92 at.%, 8.23 at.% and 6.87 at.%, respectively, while the atomic fractions of Mg are 12.66 at.%, 8.43 at.% and 7.00 at.%, respectively. Additionally, the atomic fractions of Cu are 1.83 at.%, 2.47 at.% and 3.41 at.%, respectively.

Co-, Ni- and Fe-rich grain-boundary phases enhance creep resistance in θ′-strengthened Al-Cu alloys

Microstructural evolution and creep response were investigated in the cast Al-5.0Cu-0.3Mn-0.2Zr (wt.%) alloy with and without addition of slow-diffusing, intermetallic-forming elements Fe, Ni, or Co. Baseline Al-5.0Cu-0.3Mn-0.2Zr alloy exhibits high creep resistance at 300 °C, up to ∼75 MPa, which is attributed to high-aspect-ratio, intragranular θ′-Al2Cu precipitates that effectively suppress dislocation climb. However, θ′-Al2Cu precipitate-free zones form along grain boundaries upon heat treatment, whose extent is amplified during subsequent creep. Such weak regions experience dislocation creep, leading to strain localization and acceleration of grain-boundary sliding. Adding Ni and Co, individually or in combination, leads to the formation of grain-boundary precipitates (Al9Co2, Al3Ni2) which are resistant to coarsening, thus suppressing the formation of θ′-Al2Cu precipitate-free zones. This microstructure provides high creep resistance at stresses up to 75–80 MPa, with strain rates much lower than in unmodified Al-5.0Cu-0.3Mn-0.2Zr. Adding Fe, which results in extensive decoration of grain boundaries with coarsening-resistant Al7Cu2Fe, and then increasing the Cu content to compensate for the Cu loss to this new phase, leads to a new Al-7.4Cu-1.6Fe-0.3Mn-0.2Zr alloy with creep resistance at 300 °C that surpasses known cast aluminum alloys. Adding Fe to improve the creep resistance of Al-Cu alloys is both cost-effective and sustainable. Our findings offer guidelines applicable to various alloy systems on controlling the evolution of precipitate-free zones and its ensuing effects on creep deformation.

Inhibition of the intergranular brittleness of HR3C heat-resistant steel by strain-aging induced nano-M23C6 dispersion precipitation

M23C6 chromium-rich carbides are common grain-boundary precipitations in Cr-containing steel. The presence of grain-boundary carbides often leads to intergranular brittleness and decreases mechanical properties. This study proposes a deformation and aging technique to obtain a high-volume-fraction dispersion distribution of the hard nano-M23C6 phase by changing the nucleation sites from grain boundaries to deformation coherent twin boundaries produced during cold deformation. The M23C6 precipitation-strengthened austenitic stainless steel has a strength of up to 1.4 GPa but maintains favorable plasticity (> 11 %). This study provides a novel approach for the control of intergranular brittleness in metallic materials.

Orientation dependent grain boundary precipitate distribution and the weakened pinning effects on domain walls in sintered Sm2Co17-type magnet

In a typical sintered multi-component Sm2Co17-type magnet with strong fiber texture, we show that the distributions of grain boundary precipitates (GBPs) are heavily dependent on the grain boundary (GB) geometry with respect to the texture direction, which has significant effects on domain wall pinning. Results demonstrate that the continuous GBPs turn into discrete upon the angle between {0001} planes and GB increases from 0° to 90°, meanwhile the GBPs thickness and precipitation free zones (PFZs) width both increase linearly by a factor of 2.5–4. Transmission electron microscopy (TEM) reveals that the GBPs are alternatively stacked Cu-rich SmCo5 and Zr-rich Smn+1Co5n−1 (n = 2,3,4) compounds, while the PFZs are composed of 2:17R and intermediate 2:17R’ phases. Atomic-level elemental mappings and first-principles calculations indicate that Cu exists at the Co-2c site in the SmCo5 forming SmCo3Cu2 and Zr locates at the dumbbell Sm-6c sites in the Smn+1Co5n−1. The symbiotic GBPs have orientation relationships of [0001]GBPs//[0001]2:17R and [101¯0]GBPs//[21¯1¯0]2:17R. The formation of anisotropic GBPs is owing to the strong fiber texture, i.e., the larger angle between {0001} planes and GBs, the more {0001} diffusion channels for atoms to GBs, resulting in discrete and thick GBPs. In-situ Lorentz TEM shows that the domain walls interrupted by GBPs migrate easily under applied magnetic fields. Possible approaches to enhance the magnetic hardness via tuning the GBs are proposed.

Effect of total content of Zn and Mg on microstructure and mechanical properties of Al-3.2xZn-xMg-1.66Cu-0.15Zr aluminum alloy sheet

The effects of total Zn and Mg content on the microstructure, tensile properties, and fatigue properties of Al-3.2xZn-xMg-1.66Cu alloy sheets were systematically investigated after aging at 120 °C for 24 h. As the total content of Zn and Mg increased, the recrystallized grains were gradually refined, and the types of precipitate particles did not change, all of which comprised Guinier Preston (GP) zones and η′ metastable-phase particles, whereas both the number and volume fraction of η′-phase particles increased gradually, where the particles were first coarsened and then refined. The η′-phase particles were largest (∼8.2 nm) in the alloy with the total Zn and Mg content of 5.15 wt.%. The grain boundary precipitate (GBP) gradually coarsened and the width of the precipitates free zone (PFZ) gradually decreased. When the total content of Zn and Mg was increased from 2.61 to 11.40 wt.%, the yield strength and tensile strength increased from 173 and 309 MPa to 554 and 620 MPa, respectively, whereas the elongation decreased from 29.9% to 8.5%. However, the fatigue strength of the alloy sheet first decreased from 149 to 119 MPa and then increased to 183 MPa under the condition of R = 0.1. The fatigue strength of the alloy sheet with total Zn and Mg contents of 5.15 and 11.40 wt.% were the lowest one and the highest one, respectively, and the latter was 54% higher than the former.

Structure refinement and performance balance of high-strength aluminum alloys using an improved thermomechanical treatment process

The microstructure of 7A85 aluminum alloy forgings often contains coarse second-phase particles and grains. To improve the microstructures and balance the properties, we used an enhanced thermomechanical treatment process that included multiaxial hot forging, multiaxial cryoforging (MACF), and three-step aging treatment. We thoroughly investigated the effects of MACF with 1–3 passes on the evolution of microstructure, three-dimensional (3D) mechanical properties at the center and edge, fracture toughness, and corrosion resistance of the alloy. Our findings revealed that multiaxial hot forging had a limited ability to crush the coarse second-phase particles. However, the higher flow stress and compound brittleness of MACF resulted in a significant increase in particle fragmentation and driving force for precipitation. Additionally, under MACF, massive dislocations proliferated due to the inhibition of dynamic recovery, forming large orientation gradient regions, which promote static recrystallization and grain refinement during solution treatment. As the number of MACF passes increased from one to three, the effect of particle crushing initially increased and then plateaued, the 3D grain sizes first decreased and then slightly increased, and the spacing of grain boundary precipitates (GBPs) increased. The dense and uniform precipitates, finest equiaxed grains, a low fraction of coarse particles, and large GBP spacing in MACF2 resulted in the higher strength, highest elongation with minimal anisotropy, superior fracture toughness, and enhanced corrosion resistance. Ultimately, MACF2 demonstrated the best overall performance and good homogeneity, with an average 3D ultimate tensile strength, average 3D yield strength, average 3D elongation, and fracture toughness at the center of 548 MPa, 476 MPa, 13.4%, and 42.5 MPa m1/2, respectively. These values were respectively 4.2%, 1.9%, 50.6%, and 13.9% higher than those of the uncompressed sample.

Inhomogeneity and anisotropy of Al-Zn-Mg-Cu alloy manufactured by wire arc additive manufacturing: microstructure, mechanical properties, stress corrosion cracking susceptibility

ABSTRACT In this study, Al-Zn-Mg-Cu alloy components were prepared using wire arc additive manufacturing (WAAM). Through multi-scale characterisation technology, performance testing and slow strain rate tensile (SSRT) testing, the microstructure, mechanical properties and stress corrosion cracking (SCC) susceptibility of WAAM Al-Zn-Mg-Cu components were studied, revealing the generation mechanism of inhomogeneity and anisotropy. The results show that with the increase of WAAM thermal cycles, the matrix precipitates (MPs), grain boundary precipitates (GBPs) and precipitation-free zones (PFZ) evolve in different paths and increase to varying degrees, resulting in performance decrease and increase in stress corrosion susceptibility, so the inhomogeneity is mainly attributed to differences in precipitated phases. The Inter-layer inclined to the scanning direction and the Inner-layer inclined to the building direction led to anisotropy in tensile strength and SCC behaviour, so the anisotropy is mainly attributed to the grain orientation and fracture mode.

Mechanisms of grain boundary α precipitation in the metastable β-titanium Ti-5Al-5Mo-5V-3Cr

In this study, we investigated the early nucleation and growth of grain boundary α during the aging heat treatment of Ti-5553. Through a correlative approach using scanning electron microscopy, electron backscatter diffraction, transmission Kikuchi diffraction, transmission electron microscopy, and atom probe tomography, high-angle β-grain boundaries were investigated in detail to understand the evolution of the precipitation of grain boundary α through nucleation and subsequent growth. It is found that at grain boundaries there is a pronounced nucleation of α precipitates with similar orientations. Growth of these similarly orientated α precipitates, in the later stages, leads to their agglomeration and the formation of grain boundary α. This investigation provides insights into the formation of grain boundary α in its early stages of nucleation and growth.

Microscopic-plastic deformation behavior of grain boundary precipitates in an Al–Zn–Mg alloy

The nano-precipitates with minimal misfit strengthen Al–Zn–Mg alloys by impeding dislocation motion. However, grain boundary precipitates (GBPs) are known to have a completely incoherent relationship with the matrix, making them less effective in strengthening the alloys. Instead, GBPs are recognized for preoccupying elements such as Zn or Mg, thereby diminishing the quantity of nano-strengthening phases. GBPs significantly influence the deformation and fracture behaviors of Al–Zn–Mg alloys by accelerating stress localization and crack formation. In this study, we investigated how the accumulation of dislocations in the GBP areas leads to stress localization and subsequent cracking, using micropillar tests and crystal plasticity finite element method (CP-FEM) analysis. The dislocation pile-up in the GBPs causes stress localization around the grain boundaries, inducing crack initiation and leading to intergranular fracture. These findings enhance our understanding of the role of GBPs in the deformation and cracking of Al–Zn–Mg alloys and may pave the way for new concepts in managing GBPs.

Effect of final rolling temperature on microstructure and intergranular corrosion resistance of an Al–Cu–Mg–Ag alloy

Connection of microstructure with corrosion properties of an Al-3.62Cu-0.9Mg-0.45Ag alloy in natural aging (NA) state and peak aging (PA) state at different final rolling temperatures (20 °C, 180 °C and 280 °C) are studied by scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), transmission electron microscopy (TEM), X-ray diffraction (XRD), texture and electrochemical analysis. The results show that the deformation texture and recrystallization texture of T280-NA alloy account for the largest percentage with the largest degree of recrystallization. With the increase of final rolling temperature, the proportion of low angle grain boundaries (LAGBs) of NA alloy increases, the diameter, thickness and volume fraction of Ω phase in PA alloy decrease, and the grain boundary precipitates (GBPs) are gradually transformed from discontinuous distribution to continuous distribution. The grain boundary precipitates are also found to be consist of alternating S and θ phases and the width of precipitation free zones (PFZs) is essentially independent of final rolling temperature. The intergranular corrosion (IGC) resistance of T280-NA alloy and T20-PA alloy is the best, which is a result of the combined effect of GBPs, texture and grain boundary properties. In addition, this result is verified in this paper by studying the electrochemical properties of the alloy.

Effect of Retrogression with Different Cooling Ways on the Microstructure and Properties of T'/η' Strengthened Al-Zn-Mg-Cu Alloys.

Retrogression and re-aging (RRA) treatment has been proven to effectively overcome the trade-off between strength and corrosion resistance. Current research focuses on the heating rate, temperature, and holding time of retrogression treatment while ignoring the retrogression cooling ways. In this paper, the effects of RRA treatment with different retrogression cooling ways on the microstructure and properties of newly developed T'/η' strengthened Al-Zn-Mg-Cu alloys were investigated by performing tests on mechanical properties, intergranular corrosion (IGC) resistance, and electrochemical corrosion behavior. The results show that the mechanical properties of samples subject to RRA treatment with water-quenching retrogression (ultimate tensile strength, yield strength, and elongation of 419.2 MPa, 370.2 MPa, and 15.9, respectively) are better than those of air-cooled and furnace-cooled samples. The corrosion resistance of water-quenching (IGC depth of 162.2 μm, corrosion current density of 0.833 × 10-5 A/cm2) and furnace-cooled samples (IGC depth of 123.7 μm, corrosion current density of 0.712 × 10-5 A/cm2) is better than that of air-cooled samples. Microstructure characterization reveals that the effect of the retrogression cooling rate on mechanical properties is related to the size of T'/η' precipitates with grains as well as the proportion of T' and η', while the difference in corrosion resistance depends on the continuity of grain boundary precipitates (GBPs). With mechanical properties, corrosion resistance, and time cost taken into consideration, it is appropriate to select water quenching for retrogression. These findings offer valuable insights for further design to achieve superior performance in various applications.

Localized corrosion characteristics of Al-Mg-Si aluminum alloy with aging time and pre-delayed aging condition

The effects of single aging, delayed aging and pre-delayed aging treatment on the corrosion resistance of Al-Mg-Si alloy were studied by scanning Kelvin probe force microscopy (SKPFM), transmission electron microscopy (TEM), scanning electron microscopy (SEM), three-dimensional X-ray tomography (3D-XRT), confocal laser scanning microscopy (CLSM) and electrochemical measurements. The surface potentials of Al(MnFe)Si, Mg2Si, and Si-rich remnant phases are determined, identifying Al(MnFe)Si phase as the crucial cathodic site for corrosion initiation, and the increase in surface potential implies an accelerated corrosion rate after immersion. The intergranular corrosion susceptibility of the alloy is predominantly influenced by the microstructure caused by aging conditions. The factors affecting corrosion resistance are summarized as (i) adjustment of electrochemical reaction activity by controlling the area fraction of Al(MnFe)Si phase, (ii) the spacing of grain boundary precipitates (GBPs), and (iii) the width of the precipitation-free zone (PFZ). The delayed aging (DA) sample exhibits inferior corrosion resistance due to the continuous GBPs and extended sub-grain boundaries corrosion propagation paths. The pre-delayed aging treatment successfully mitigates the corrosion degree of DA by widening the GBPs spacing and narrowing the PFZ width. This suggests that pre-aging treatment is a potent strategy for enhancing corrosion resistance without compromising the alloy's strength.

High-pressure-torsion-induced segregation, precipitation and grain refinement of Al-(Si, Mg and Cu) binary alloys

To uncover the effects of segregation and precipitation on grain refinement of metals under severe plastic deformation, high-pressure-torsion (HPT) processing is performed on three binary Al-(Si, Mg, and Cu) alloys with different stability and segregation characteristics. Atom probe tomography analysis reveals that HPT processing induces significant decomposition of Al-1 at% Si and Al-1 at% Cu alloys with coarse Si particles and fine Al2Cu (θ) precipitates formed, but no decomposition of Al-1 at% Mg alloy, with dislocations segregated with Si, Cu, and Mg, and grain boundaries (GBs) only segregated with Cu and Mg. The GB segregation of Cu is stronger than that of Mg and Si, with Cu excess in the range of 1.5–7.0 atoms/nm2, Mg excess in the range of 0–4.0 atoms/nm2, but no Si excess. Interestingly, some GBs without Mg segregation develop a Mg-depletion zone along a single side. All evidences demonstrate that GB segregation and precipitation are responsible for HPT-induced grain refinement of Al-1Mg and Al-1Cu alloys but coarsening of the Al-1Si alloy. Engineering solute distribution is of significance in controlling the ultrafine grain of the Al alloys.

Effects of pre-deformation on microstructure, mechanical properties and corrosion performance of an Al-Cu-Mg-Ag alloys

The influence of pre-deformation on the microstructure, mechanical properties, and corrosion behavior of AA2029-T8 was investigated. The pre-deformation may potentially impede the formation of Mg-Ag clusters during the early stage of aging, altered the normal precipitation sequence of the alloy, and significantly increased dislocation density that facilitated non-uniform nucleation of S phase at dislocations, resulting in finer dispersion of precipitation. Moreover, it led to a decrease in Ω phase volume fraction and comparable aspect ratio(diameter/thickness). With increasing deformation, aging response was accelerated, leading to shorter time to peak strength but reduced plasticity. Additionally, the width of precipitate-free zone (PFZ) remained relatively unchanged with increasing pre-deformation; however, average size of grain boundary precipitates (GBPs) decreased while becoming more discontinuous. This resulted in narrowing intergranular corrosion (IGC) channels and decreased maximum corrosion depth as well as a transition from IGC to pitting corrosion behavior. These findings suggest that the mechanical properties and corrosion resistance of the alloy can be improved by increasing pre-deformation levels.

Developing a high-speed-extruded BMZQ5100 alloy with higher strength and microstructural thermal stability than AZ91 alloy

A new Mg-5Bi-1Mn-0.5Zn-0.2Ag (BMZQ5100, wt%) alloy is developed and analyzed comparatively its extrudability, microstructure, mechanical property and thermal stability with a commercial AZ91 alloy. The results show that the BMZQ5100 alloy can be successfully extruded at a high extrusion speed (ES) of 30 m/min without surface cracks, but there are a large number of hot cracks occurred on the low-speed-extruded AZ91 alloy surface (ES: 5 m/min). For the 30 m/min extruded BMZQ5100 alloy (BMZQ5100-E30), it exhibits a completely dynamic recrystallized (DRX) grain structure with a slightly larger grain size and stronger basal fiber texture than the 2 m/min extruded AZ91 alloy (AZ91-E2) without surface cracks. In terms of second phase, the former alloy contains submicron Mg3Bi2 phases at grain boundaries (GBs), nano-scale Mg3Bi2 and α-Mn particles within grain interiors, along with the co-segregation of Zn and Ag at GBs. The latter alloy has a continuous network of submicron Mg17Al12 phases along GBs, but no any solute segregation is observed at GBs. The BMZQ5100-E30 alloy exhibits more excellent mechanical properties with a tensile yield strength of ∼ 271 MPa, an ultimate tensile strength of ∼ 319 MPa and an acceptable elongation-to-failure of ∼ 8%, compared with the AZ91-E2 alloy. The GB strengthening, precipitation strengthening and solute segregation strengthening on the TYS occupy ∼ 46.2, ∼ 45.5 and ∼ 8.3%, respectively. In addition, the BMZQ5100-E30 alloy has higher microstructural thermal stability than the AZ91-E2 alloy, because of second phase pinning and solute segregation at GBs to effectively inhibit the grain growth during annealing.

The strengthening role of post-welded cryogenic treatment on the performance and microstructure of 304 austenitic stainless steel weldments

The metallurgical changes and micro defects after welding can influence the mechanical property, corrosion resistance and dimensional stability of the stainless steel wielding joints. It is necessary to explore an effective post-welded method to improve the service performance for stainless steel welding joints. Furthermore, the essential mechanism between microstructure changes and macro-property variation during this process needs deep reveal. Therefore, this paper aims at investigating the effects of different post-weld treatments including naturally aging, artificial aging and cryogenic treatment on the residual stress and mechanical properties of 304 stainless steel weldments. The microstructure evolution was also studied to reveal and establish the microstructure-performance relationship. The results showed that the distribution of residual stress was most uniform with lowest magnitude (decreased by up to 49%) after cryogenic treatment. At room temperature, weldments subjected to the three post treatments showed similar mechanical properties. At cryogenic temperature, cryogenic treatment exhibited an outstanding role on maintaining the mechanical properties of weldments. By contrast, the mechanical properties were obviously reduced by artificial aging. The transformation of δ-ferrite and the carbide precipitation in grain boundaries are the main reasons for the decrease of mechanical properties after artificially aging. Welding process was able to cause the transfer of the alloying elements and decrease the stability of austenite. Consequently, martensitic transformation can be induced during cryogenic treatment. The new formed martensite resulted in the refined microstructure and high mechanical properties of weldments, and also the release of residual stress after welding.