Multicriteria decision analysis based on Thom’s [1] Catastrophe Theory (CT) has been applied extensively in solving various social, physical and natural sciences problems. It has become a key tool for identifying the groundwater potentiality of an area with a Geographic Information System (GIS). This paper aimed to apply catastrophe theory effectively by utilizing the standardization formulae suggested by Li et al. [2] and the modified formulae provided by Hongwei Zhu [3]. Depending on the nature of a hydrogeological parameter, CT formulae were chosen to ensure that the least important features also get attention during standardization using Hongwei Zhu's formulae where applicable, which were not possible using Li’s formulae. The standardized values of the features of all the themes obtained using four formulae were sorted in ascending order to estimate the normalized values to ensure that no normalized value of a feature exceeds the others having very close but lower standardized values. The effective use of CT technique was employed in a GIS environment to delineate groundwater recharge potential zones of the middle-west part of Kushtia district, Bangladesh, by integrating influential recharge factors, such as land type, slope, drainage density, distance from surface water bodies, soil permeability, surface clay thickness, rainfall, topographic ruggedness index, topographic curvature index, topographic wetness index and topographic position index. The groundwater recharge potential zones were classified as very good (28.76%), good (32.17%), and moderately good (39.05%) for effective CT technique. But in case of the improper use of CT covering area were 17.24%, 54.05% and 28.71% respectively, and the respective most sensitive factors are rainfall and drainage density. Finally, recharge potential zones were validated using groundwater recharge data with a determinant coefficient of 0.92 and 0.84 for effective and improper use of CT technique respectively.