In this paper, all biderivations of solvable Lie algebras of maximal rank g = Q ⊕ N are characterized. Namely, we consider a solvable Lie algebra of the form g = Q ⊕ N , where Q is the maximal torus subalgebra of g , N is the nilradical of g and dim Q = dim N / N 2 .In the case dim Q = N we characterize the form of skew-symmetric and symmetric biderivations of g . As applications, the forms of linear commuting (skew-commuting) maps and the commutative post-Lie algebra structures on g are given.