Abstract Interactions between pulsed electrical discharges and liquid dielectric materials is a growing research field with interests in fundamental discharge physics as well as in applications. Herein, we present an experimental study on the dynamics of nanosecond discharges in air with the presence of a water droplet with various electrical conductivities (EC) and at different applied voltages (Va). The discharges are characterized optically, by employing time-resolved ICCD imaging and optical emission spectroscopy, as well as electrically, by acquiring the current-voltage waveforms for every discharge. The results show that three modes of discharges can be obtained: i) streamer discharge between the cathode and the droplet, ii) streamer discharge between the cathode and the droplet as well as between the anode and the droplet, and iii) spark discharge that connects the two electrodes and propagates over the droplet. We find that the probability to obtain one of the three discharge modes is strongly related to the droplet’s EC as well as to Va. Although the ignition of the streamer is relatively insensitive to EC, its transition to a spark can be finely controlled by the droplet’s EC. The time-resolved ICCD images show that the discharge initiates in the gap between the cathode and the droplet, followed by ignition between the anode/ground electrode and the droplet. Then, an extinction phase is observed before the ignition of a secondary streamer, and depending on the conditions, the discharge may transition to a spark, i.e. a channel with high emission intensity. We find that the duration of each stage of discharge propagation as well as the corresponding emission (path and intensity) are sensitive to droplet’s EC. Finally, emissions from streamers (primary and secondary) as well as from sparks are analyzed using optical spectroscopy. We find that the emission from the streamers is dominated by the second positive system of N2, and that the droplet’s EC does not significantly influence the emission spectra nor the estimated rotational temperature of N2.