Allowed and forbidden transitions of singlet helium from 2s1S to ns1S, np1P, and nd1D states have been measured between n=8 and 31 by optogalvanic spectroscopy in a dc discharge positive column. The addition of neon in the discharge was found to increase the relative intensities of the forbidden transitions. For similar photon flux, the optogalvanic signal reaches a maximum at n=11 and decreases thereafter. Neutral collisional ionization of the excited states from n=13 and above was found to be responsible for the increased ionization efficiency of the high Rydberg states.
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