Soil Pore Research Articles

Characterization and Classifications of Saline/Sodic Soils of Ambo Area of Irrigated Farm Land in Golina Watershed in Raya Valley, Amhara Region, Ethiopia

All soils are known to contain a certain amount of soluble salts and exchangeable sodium, magnesium, potassium, and calcium. However, excessive enrichment of any one of them can interfere with many soil processes, including plant growth, and the effects depend on the degree of enrichment and the type of plant. Therefore, the objective of this study was to characterize the salt-affected soils of the Ambo area for irrigated farmlands in the Golina Watershed in Raya Kobo Woreda, Amhara region. One profile was excavated from an irrigated field to carry out this activity. One profile was excavated from the irrigated field to conduct this activity. Ten soil samples were taken from the soil profile at 2 m depth at 20 cm depth intervals. The samples were analyzed for several soil physical properties, including soil pH, soluble cations and anions, soluble salts (electrical conductivity, EC), exchangeable cations (Ca, Mg, Na, K), total nitrogen, organic carbon, soluble phosphorus, percent exchangeable sodium, sodium absorption, and soil physical properties (soil color, texture, bulk density, and soil porosity). Chemical properties were also analyzed. The analysis showed that the irrigated farmland soils had a pH of 7.6 to 8.8, electrical conductivity of 1.3 to 14 dsm-1, organic carbon of 0.3 to 1.2%, total nitrogen of 0.11 to 0.35%, soluble phosphorus of 24 to 41.4 mg kg-1, and cation exchange capacity of 50.3 to 65.5 cmol(+) kg-1. The distribution of exchangeable calcium was not consistent across the soil profiles of the irrigated farmlands. In general, the top layer of soil at both sites (because of its agricultural use) was considered for EC, ESP, and pH values. The irrigated farmland soils were classified as saline soils.

Impact of petroleum contamination on soil properties in Absheron Peninsula, Azerbaijan

This study aims to assess the extent of hydrocarbon and heavy metal contamination in soils from specific areas on Azerbaijan's Absheron Peninsula, including Absheron, Suraxanı, and Baku, and to evaluate the impact of this contamination on soil properties. Soil samples were analyzed for Total Petroleum Hydrocarbons (TPH) and heavy metals, including aluminum, arsenic, cadmium, lead, and iron, alongside assessments of soil physical, chemical and biological properties. The results revealed significant contamination across all studied areas, particularly in Suraxanı, where TPH levels reached 190 ± 20 mg/kg, exceeding the environmental standard of 100 mg/kg. Similarly, Suraxanı soils exhibited alarmingly high concentrations of heavy metals, with aluminum at 30,128 ± 1,500 mg/kg, arsenic at 50.94 ± 2.5 mg/kg, and cadmium at 0.153 ± 0.01 mg/kg, all surpassing acceptable limits. These contaminants severely degraded soil health, evidenced by increased bulk density (1.7 g/cm³ in Suraxanı) and reduced soil porosity. Microbial activity, a key indicator of soil fertility, was also markedly lower in contaminated regions, with the total bacterial count in Suraxanı being less than half that of the uncontaminated area. The findings underscore the urgent need for comprehensive soil management practices and stricter environmental regulations to mitigate contamination's adverse effects and protect both ecosystems and public health in Azerbaijan’s petroleum contaminated areas.

Effect of In Situ Polymerization of Super Absorbent Polymers on the Protection of Earthen Heritage Sites in Semi-Arid Regions

As precious cultural heritage, earthen sites are susceptible to various natural factors, leading to diverse forms of degradation. To protect earthen sites, the effects of super absorbent polymers (SAPs) on soil water retention, physical properties, and color compatibility at different concentrations were studied. After applying SAP treatment to an earthen site with different degrees of weathering, we drew the following conclusions. SAP-2 improved soil water retention capacity, increased soil water content, and slowed down the precipitation of soluble salts. At the same time, SAP-2 had the least effect on soil color difference and reduced the development of cracks by filling soil pores and enhancing the cohesion between soil particles, thus giving the earthen sites better weathering resistance. Therefore, the results provide a useful reference for the surface cracking of earthen sites in semi-arid areas and the degradation caused by flaking and block spalling.

Estudio palinológico de las Licofitas (Lycopodiopsida) de las Sierras Pampeanas centrales de Argentina

Background and aims: The Sierras Pampeanas Centrales of Argentina constitute the fourth centre of diversity of lycophytes and ferns in the Cono Sur, where representatives of four families of lycophytes live: Huperziaceae, Lycopodiaceae, Isoetaceae and Selaginellaceae. The aim of this work is to provide data of the morphology of their spores observed with optical and scanning electron microscopes, as a contribution to the taxonomy and conservation. M&M: The materials were analysed without prior chemical treatment and photographic records were obtained with both observation equipments. Results: The morphological diagnostic features of the spores are presented. The Huperziaceae and Lycopodiaceae are isosporous with trilete spores. Huperziaceae presents foveolated or fossulated spores, while Lycopodiaceae spores are reticulate, scabrate and baculate. In Isoetes hieronymi (heterosporate), the microspores are monolete with echinate ornamentation, while the megaspores are trilete, with reticulate ornamentation. The Selaginellaceae, all heterosporate, produce trilete microspores and megaspores, both with varied ornamentation. Conclusions: Spore characteristics provide relevant information for regional floristic studies as well as for taxonomic assignments, both of extant flora and fossil records. Also, for studies of the composition of soil spore banks as a tool for the conservation of local floristic biodiversity.

Assessment of High-Severity Post-Fire Soil Quality and Its Recovery in Dry/Warm Valley Forestlands in Southwest China through Selecting the Minimum Data Set and Soil Quality Index

Recurrent wildfires can negatively affect soil quality, and post-fire soil quality recovery is critical for maintaining sustainable ecosystem development. The objective of this study was to evaluate the changes and recovery of soil properties and soil quality in the forests of dry/warm river valleys in southwest China after disturbance by high-severity fires. In this study, the impact of fire on soil properties and soil quality was investigated for three years post-fire. Unburned forest land with a similar natural environment compared to the fire area was used as a control. Soil samples were collected from three different depths of 0–10 cm, 10–20 cm, and 20–30 cm, respectively. Principal component analysis (PCA) combined with the Norm value was used to select the minimum data set (MDS), thus calculating the soil quality index (SQI). The results showed that the soil properties changed significantly after high-severity fires. On average, soil bulk density (0.91 g/cm3, p = 0.001), total nitrogen (0.12 g/kg, p = 0.000), total phosphorus (0.10 g/kg, p = 0.000), and total potassium (5.55 g/kg, p = 0.000) were significantly lower in the burned areas than in the unburned areas at the first sampling. These indicators increased in the following three years but still did not recover to unburned levels. Compared with the above indicators, soil porosity and organic matter increased post-fire, but gradually decreased over time. Soil clay, geometric mean diameter, and total potassium were included in the MDS. The SQI was ranked as unburned > 3 years > 2 years > 1 year > 6 months. The SQI was significantly (p = 0.001) reduced six months post-fire by an average of 36%, and, after three years of recovery, the soil quality of the post-fire areas could be restored to 81% of soil in unburned areas. Apparently, high-severity fires caused changes in soil properties, thereby significantly decreasing soil quality. Soil quality gradually improved with increasing restoration time. However, the complete recovery of soil quality post-fire in forest land in the dry/warm river valley will take a longer time.

Regulatory mechanism of soil and water conservation measures on understorey erosion in a subtropical hilly region

Vegetation restoration affects soil erosion by altering near soil-surface characteristics and hydrodynamic mechanisms. However, the regulatory mechanisms of vegetation restoration in reducing soil erosion under forests are not fully clear. Five soil and water conservation measures (SWCM) with different vegetation structures and characteristics were used in the pure forest of Pinus massoniana which included the grass and shrub, grass, grass and shrub + level furrow, grass, shrub and trees and grass + fish-scale pits, to analyze the impact of vegetation restoration on near soil-surface characteristics and soil erosion. The data were analyzed using Structural Equation Modeling (SEM) to find the key indicators affecting soil erosion under forest. The findings revealed that, as opposed to the control plots (CK), there were significant alterations in the near soil-surface attribute following the application of SWCM. These changes were characterized by an increase in soil porosity, soil water content, soil nutrient content, root biomass, litter, and vegetation cover, and a decrease in soil compaction, disintegration coefficient, and bulk density, with the most significant improvement occurring in 0–10 cm soil layer. The SWCM significantly reduced soil erosion, with runoff and soil loss reduction ranging from 60.46 % to 74.09 % and 67.62 % to 79.99 %, respectively. Structural equation models revealed the influence of SWCM on soil erosion. Specifically, soil water content and litter had a favourable influence on reducing soil erosion, root biomass had a direct positive impact on soil erosion, and vegetation cover directly leads to a reduction in soil erosion. Soil physical properties primarily influenced soil erosion through their effect on vegetation cover. Combining bioengineering and vegetation measures is superior at enhancing soil structure, improving nutrient content, and decreasing soil erosion compared to single vegetation measures. It is recommended to combine bioengineering with vegetation strategies to effectively curb understory forest erosion and enhance soil quality in pine forests.

Isotropic compression behavior of salinized unsaturated agricultural soil: An experimental and constitutive investigation

Salinity-induced soil degradation is a significant challenge in coastal reclamation areas, impacting agricultural productivity and infrastructure development. Variations in soil compression and deformation caused by changes in salinity warrant further investigation, particularly for agricultural applications. This study explores the relationship between soil pore water salinity and compressibility by conducting isotropic compression tests on salinized unsaturated agricultural soils treated with distilled water, 0.5 mol/L and 1 mol/L sodium chloride (NaCl) and calcium chloride (CaCl2) solutions. The results demonstrate that the type and concentration of salts significantly affect the compression behavior of these soils. The constitutive parameters were calibrated based on the experimental data. To account for osmotic suction, Barcelona Basic Model (BBM) was adjusted. The findings indicate that as pore water salinity increases, soil compressibility decreases, reflected by a compression index (Cc), and higher pre-consolidation stress (py). This modification aimed to quantify the impact of pore water salinity on soil compression. To validate the constitutive model, a numerical analysis of an isotropic compression test was carried out. This study contributes to our understanding of the isotropic compression behavior of coastal saline soil, proposes a constitutive framework for predicting soil responses under different salt conditions, and provides theoretical support for engineering construction in coastal reclamation areas.

Behaviour of ionic herbicides in different forestry soils derived from volcanic ash

Background: Weed control has been one of the most significant factors in forest establishment practices that can improve biomass production, and herbicides represent the most effective and convenient way to control weeds. The environmental concern about herbicides in this industry is because the herbicide-treated area is often located near water reservoirs or areas where rivers and creeks originate. This study aimed to determine the adsorption and degradation behaviours of seven ionic herbicides used in forestry production in five Chilean forestry soils and their relation to the leaching and to generate information to validate environmental predictive models. Methods: Adsorption and degradation of ionisable herbicides such as simazine, terbuthylazine, hexazinone, metsulfuron-methyl, indaziflam, flazasulfuron and glyphosate were studied in Andisol, Ultisol, Inceptisol, Entisol and Alfisol forestry soils, to be related to their leaching in 100-cm high and 11-cm diameter soil disturbed lysimeters. Herbicides were quantified using high-pressure liquid chromatography and gas chromatography. Relationships between soil physicochemical properties, herbicide adsorption and degradation, and herbicide leaching were determined. Results: In decreasing order, the herbicides were mobile in Entisol>Alfisol>Ultisol>Inceptisol>Andisol soils. On the other hand, the more leachable herbicides, from high to low, were: hexazinone, metsulfuron-methyl, simazine, glyphosate, terbuthylazine, flazasulfuron and indaziflam. The last two herbicides were not detected below 60 cm soil depth. In general, the maximum soil depth herbicide reached and the percentage mass leached up to 90 cm soil depth were inversely related to soil adsorption (1/Kd), soil porosity, humidity, silt, aluminium, and calcium soil content. Herbicide degradations were generally faster than referential published values. Conclusions: The environmental coefficients of ionic herbicides were more related to soil properties than their physicochemical properties. Persistence of herbicides in soil was smaller than that commonly reported in other studies or international databases and soil adsorption averages were generally higher than international reference values. The stronger relationship between ionic herbicide behaviour and forestry soil properties endorses the requirement to determine the environmental herbicides parameters in situ, avoiding using parameters estimated in other soils.

Enhancing Agroecology in Pepper (Piper nigrum L.) Cultivation with Centrosema pubescens Ground Cover: A Study from Central Bangka, Indonesia

<p>Pepper cultivation in Bangka Island primarily takes place on sandy land. Legume cover crops, such as <em>Centrosema pubescens</em>, which has been widely used as a ground cover, are anticipated to improve land quality by maintaining soil temperature and humidity, increasing soil organic carbon content, increasing soil porosity, and improving soil fertility. This research aims to analyze the agroecosystem of pepper plants, by comparing the use of the cover plant <em>C. pubescens</em> as a soil treatment and the absence of using these cover plants as a control. The research was conducted in farmers’ pepper gardens in Perlang Village, Central Bangka Regency, Bangka Belitung Province. The research employed a randomized block design, with <em>C. pubescens</em> and natural vegetation as treatments, each replicated 3 times. The variables measured were soil temperature and humidity; abundance of microorganisms; weed density, frequency, and dominance; chlorophyll a, chlorophyll b, and anthocyanin content of pepper leaves; photosynthesis rate; transpiration rate; stomatal conductance; soil chemical and physical properties. The results showed that <em>C. pubescens</em> as ground cover could reduce the dominance of the <em>Bidens pilosa</em> weed (relative dominance of 36.16%) but led to an increase in the dominance of <em>Chromolaena odorata</em> (relative dominance of 38.7%). <em>C</em>.<em> pubescens</em> ground cover could also maintain stable soil temperature and moisture, and increase P, K, Ca, and Mg soil content by 100%, 100%, 43.6%, and 48.3%, respectively. Furthermore, pepper plants grown with <em>C. pubescens</em> exhibited 25%, 23.7%, and 16% higher chlorophyll a, total chlorophyll, and carotenoid content, respectively, compared to those grown without the cover crop.</p>

The Effect of Hydrate Formation Conditions on the Mechanics of Laboratory Methane Hydrate‐Bearing Sediments

AbstractThe mechanics of methane hydrate‐bearing sediments (MHBS) have been broadly investigated over recent years in the context of methane‐gas production or climate‐change effects. Their mechanical investigation has mainly been carried out using models constructed from experimental data obtained for laboratory‐formed MHBS. Along with the dominant effects of hydrate saturation and morphology within the host soil pores, this study recognizes the effective pressure at which the hydrate is formed as a key factor in the MHBS mechanics. A state‐of‐the‐art experimental study has been conducted in order to isolate the effect of the hydrate formation pressure, for use as a model parameter. Two generalized mechanical prediction models that incorporate the effect of the hydrate formation pressure are developed in this work: (a) an analytical shear strength prediction, and (b) an empiric graphical model for predicting volumetric changes along a given stress path. The models are related to a novel data representation which enables the analysis of a few individual test outcomes as a whole, through a volume‐change mapping that describes the complex influence of the volumetric effect of hydrate in MHBS, under combined hydrostatic and deviatoric loading scenarios. In this study, we delve into a specific configuration of hydrate morphology, hydrate saturation, and host soil type, enabling a distinctive fundamental geotechnical investigation and the development of a conceptual modeling approach. The paper describes the approaches by which the MHBS properties can be extracted for other MHBS samples (than those examined in this work) having different host soils and hydrate pore‐space morphologies.

Exploring the Effects of Fissures on Hydraulic Parameters in Subsurface Flows from the Perspective of Energy Changes

Reynolds number (Re), pore water pressure (P), and water flow shear force (τ) are primary indicators reflecting the characteristics of subsurface flow. Exploring the calculation of these parameters will facilitate the understanding of the hydrodynamic characteristics in different subsurface flows and quantify their differences. Hence, we conducted a study to monitor soil water content, matrix potential, and pore water pressure in two typical soil profiles (with and without fissures). The distribution of Re, P, and τ in both matrix flow (MF) and preferential flow (PF) were calculated with an improved calculation method, focusing on their energy changes. Results showed that these hydrologic parameters are quite different between MF and PF. Re values in MF remained below 0.1, indicating lower water flow velocities, while the Re values ranged from 0.8 to 2 in PF, indicating higher flow velocities. The P values in PF was tens to hundreds of times higher than that in MF, which is mainly due to the rapid accumulation and leakage of water within soil fissures. Additionally, the larger hydraulic radius and gradient in PF also resulted in higher τ values in PF (2~6 N m−2) than in MF (0~1.5 N m−2). In PF, the pressure potential was the significant factor for τ, while τ in MF was dominated by the matrix potential and varies with the magnitude of the matrix potential gradient. This study suggests that Re, P, and τ could be considered as the major indexes to reflect dynamic characteristics of subsurface flow.

Characteristics of soil pore structure response to electric field strength and their effects on Cr(VI) removal from a historically chromium-contaminated soil

The characteristics of soil pore structure response to electric field strength and their effects on the migration of hexavalent chromium during electrokinetic remediation remain unclear. This paper investigates the effects of soil actual voltage and pore redistribution on hexavalent chromium removal under various voltage gradients during electrokinetic remediation. The electric field across the soil was the dominant factor that affected the soil properties, pore structure, and transportation of hexavalent chromium. The removal efficiency of dissolved hexavalent chromium was significantly enhanced from 36.1 % to 80.5 % as the theoretical voltage gradients increased from 0.5 V·cm−1 to 3 V·cm−1 due to the highest voltage proportion (52.7 %) of the soil chamber at 3 V·cm−1, while it only increased to 82.0 % at 4 V·cm−1. The optimal actual electric field strength of 1.00–1.50 V·cm−1 across the soil matrix facilitated the efficient electromigration of hexavalent chromium. The electric field force exerted a direct (0.70) or indirect action intensity (1.55) on soil pore structure by altering soil chemical properties. Soil mesopores and ultra-micropores transformed into micropores through collapsing, shrinking, ion migration, weakening electrostatic repulsion, and enhancing adhesive bonding among particles with increasing electric field. The distribution and structure of soil pores were more homogenous under optimal electric field conditions, thereby improving the migration path of hexavalent chromium. Soil mesopores facilitated hexavalent chromium removal and the formed micropores were opposite. These findings have significant scientific and practical implications for applying the in-situ electrokinetic techniques in the remediation of metal-contaminated soils.

Effects of Fertilization and Drip Irrigation on the Growth of Populus × canadensis ‘Zhongliao 1’ Plantation and on Soil Physicochemical Properties and Enzyme Activities

Poplars are crucial for timber supply and ecological protection in China. Enhancing the growth of poplar plantations and improving soil fertility in arid, and semi-arid poor soil regions are key aspects of sustainable forest management. Fertilization (FTL) and drip irrigation (DI) are among the most widely used methods globally for increasing yield and soil productivity. This study conducted field experiments on FTL and DI in a 10-year-old Populus × canadensis ‘Zhongliao 1’ (cultivation varieties of P. canadensis in northern China) plantation. DI limits were set according to soil moisture at 60% (S1), 70% (S2), and 80% (S3) of field capacity; nitrogen FTL rates were set at 100% of the baseline fertilization amount (100% BFA, N 643.20 g·year−1, P 473.37 g·year−1, and K 492.29 g·year−1) (F1), 70% BFA (F2), 130% BFA (F3), and 160% BFA (F4). The treatments of drip irrigation and fertigation (DIF) were H1 (100% BFA, 60% FC), H2 (100% BFA, 80% FC), H3 (160% BFA, 60% FC), and H4 (160% BFA, 80% FC), along with a control group (CK) without any management, totaling 12 experimental combinations. The results showed that the H4 had the most significant promoting effect on the height, DBH, and volume increments. All treatments had little effect on the soil bulk density of the plantation but significantly impacted soil capillary porosity and pH. Compared to DI, soil nutrient and organic matter content were more sensitive to FTL. Appropriate FTL and DI can increase soil sucrase activity. Soil urease activity tended to increase with higher FTL rates, and higher DI levels also positively influenced urease activity. Excessive or insufficient soil moisture and nutrients negatively impacted soil cellulase and catalase activities. Correlation analysis revealed no significant correlation between the growth of P. × canadensis ‘Zhongliao 1’ and soil nutrient content, but significant or highly significant correlations existed between growth and soil porosity and related enzyme activities. Comprehensive evaluation using a membership function indicated that high FTL levels (F4) were more conducive to the simultaneous improvement of the growth and soil fertility of the plantation, followed by H4 and F1, suggesting that high FTL is the key factor affecting the growth of 10-year-old P. × canadensis ‘Zhongliao 1’ plantations and the restoration of stand productivity, with moisture being secondary.

Biochar and wood vinegar altered the composition of inorganic phosphorus bacteria community in saline-alkali soils and promoted the bioavailability of phosphorus

As an important part of the ecosystem, saline-alkali soils are in urgent need of efficient and environmentally friendly soil conditioners. Biochar and wood vinegar are regarded as organic soil improvement and plant growth regulators to improve soil physicochemical properties and promote crop growth. However, the mechanism of how inorganic phosphorus bacteria increase phosphorus when biochar and wood vinegar applied to saline-alkali soils is not clear. Herein, the present study was designed to investigate the effects of biochar and wood vinegar with different rates on physicochemical properties of saline-alkali soils and inorganic phosphorus bacteria diversities and to discuss the mechanism of biochar and wood vinegar on available phosphorus by pot experiments. The application of biochar and wood vinegar exhibited an effect on the decrease in pH and salt contents and the increase in soil porosity, soil nutrients, and hundred-grain weight of rice. The 600 kg ha−1 biochar and 1800 kg ha−1 wood vinegar group showed the most significant increment in available phosphorus, alkaline phosphatase, acid phosphatase, and neutral phosphatase activities, with the increases of 49.24%, 40.35%, 48%, and 149%, respectively. The 600 kg ha−1 biochar and 1200 kg ha−1 wood vinegar group significantly enhanced microbial biomass phosphorus concentrations by 41.29%. Moreover, biochar and wood vinegar shifted inorganic phosphorus bacteria composition structure and promoted its diversities, more so at a higher rate of wood vinegar application. The dominant species of inorganic phosphorus bacteria were Proteobacteria, Gammaproteobacteria, Alphaproteobacteria, Pseudomonas, and Rhizobium in saline-alkali soils. The Alphaproteobacteria and Hydrogenophaga were the key microorganisms reducing pH and salt contents and increasing available phosphorus contents in saline-alkali soils. In conclusion, the application of biochar and wood vinegar was a useful strategy to improve saline-alkali soils.

Moderate effects of distance to air-filled macropores on denitrification potentials in soils

AbstractDenitrification is a major source of the greenhouse gas N2O. As a result of spatial heterogeneity of organic carbon, oxygen and nitrate, denitrification is observed even under relatively dry conditions. However, it is unclear whether denitrification potentials of microbial communities exhibit spatial patterns relative to variations in distance to soil pores facilitating oxygen exchange and nutrient transfer. Thus, we determined genetic and process-level denitrification potentials in two contrasting soils, a cropland and a grassland, with respect to the distance to air-filled pores. An X-ray computed tomography aided sampling strategy was applied for precise sampling of soil material. Process-level and genetic denitrification potentials in both soils were spatially variable, and similar with respect to distance to macropores. In the cropland soil, a minor increase of process-level potentials with distance to pores was observed and related to changes in NO3− rather than oxygen availability. Genetic denitrification potentials after the short-term incubations revealed a certain robustness of the local community. Thus, distance to macropores has a minor impact on denitrification potentials relative to the observed spatial variability. Our findings support the notion that the impact of macropore induced changes of the environmental conditions in soil does not overrule the high spatial variability due to other controlling factors, so that the rather minor proportion of spatial heterogeneity of functional genes and activity potentials related to macropore distances in soil need not be considered explicitly in modelling denitrification.

Enhancing pyromorphite formation through hydroxyapatite application in lead-contaminated, water-unsaturated soils: influence of low percolation velocity and high soil porosity

Abstract Purpose Chemical immobilization using hydroxyapatite (HAP) is a cost effective and environmentally sound strategy for remediating lead-contaminated soils, such as shooting range soils. Understanding the combined impact of soil chemical and physical properties on enhancing the formation of pyromorphite, a lead-insoluble phase, is crucial for mitigating environmental risks associate with contaminated soil. This study aimed to elucidate the relationship between percolation velocity and lead leaching as well as pyromorphite transformation to optimize pyromorphite formation in water-unsaturated soils. Methods Two up-flow suction percolation tests were performed: one varying percolation velocity with soil porosity achieved by incorporating clay minerals, and the other varying percolation velocity while keeping soil porosity constant. Results Application of HAP substantially suppressed lead leaching in both percolation tests. Enhanced pyromorphite formation was observed with higher percolation velocities relative to soil porosity. Pyromorphite formation was more pronounced at lower percolation velocities compared to higher velocities at equivalent soil porosity level. The percentages of lead formed as pyromorphite in HAP-treated soil were higher than those of lead leached in non-HAP-treated soil among the lower percolation velocities. Conclusions This study provides experimental evidence indicating pyromorphite formation is favored in soils with lower percolation velocities and higher soil porosities. Therefore, considering both soil chemical and physical properties is essential for understanding immobilization mechanisms in contaminated soils.

Predicting soil hydraulic conductivity using random forest, SVM, and LSSVM models

AbstractUnderstanding the hydraulic properties of soil is essential to solve many management problems in agriculture and the environment. Water quality affects soil hydraulic conductivity. Soil hydraulic properties play an important role in nature's water cycle and are used as basic information in designing irrigation and drainage systems, hydrological issues, and soil quality assessment. In the current study, soil sampling is performed from different areas and its hydraulic conductivity was measured using the drop load method and then predicted using support vector machine (SVM) and least‐squares support vector machine (LSSVM) models. The model inputs were: soil texture (percentage of sand, silt, and clay particles), salinity (electrical conductivity), pH, sodium adsorption ratio, soil porosity, and bulk density and the output was soil hydraulic conductivity. Correlation coefficient, root mean square error (RMSE), mean bias error (MBE), and Nash–Sutcliffe efficiency (NSE) were used to evaluate the models and compare them. Based on evaluation criteria the best performance was obtained for random forest (RF) (R = 0.89, RMSE = 0.53, mean absolute error (MAE) = 0.54, and NSE = 0.72). Following RF, the SVM with (R = 0.69, RMSE = 1.32, MAE = 0.69, and NSE = 0.48) performed better than LSSVM model.

High salinity restrains microplastic transport and increases the risk of pollution in coastal wetlands

Microplastics (MPs) pollution in coastal wetlands has attracted global attention. However, few studies have focused on the effect of soil properties and structure on MP transport in coastal wetlands. Salinity is one of the most pivotal environmental factors and varies in coastal wetlands. Here, we conducted column experiments and employed fluorescent labeling combined with Derjaguin–Landau–Verwey–Overbeek (DLVO) theoretical calculations to reveal the vertical transport behavior of MPs. Specifically, we investigated the influence of five salinity levels (0, 0.035, 0.35, 3.5, and 35 PSU) on MP transport in different coastal wetlands soils and a sand through the X-ray photoelectron spectroscopy and nondestructive computed tomography technique. The results indicated that the migration capability of MPs in soils is significantly lower than in quartz sand, and that the migration capability varies depending on the soil type. This variability may be due to soil minerals and microporous structures providing numerous attachment sites for MPs and may be explained by the DLVO energy barrier of MP-Soil (6568–7767 KT) and MP-sand (5250 KT). Salinity plays a crucial role in modifying the chemical properties of pore water (i.e., zeta potential) as well as altering the soil elemental composition and pore structure. At 0 PSU, the maximum C/C0 of MPs through the sand, Soil 1, and Soil 2 transport columns were 37.86 ± 2.36 %, 23.96 ± 1.71 %, and 3.94 ± 0.68 %, respectively. When salinity increased to 3.5 PSU, MP mobility decreased by over 20 %. Additionally, a salinity of 35 PSU may alter the soil pore distribution, thereby changing water flow paths and velocities to constrain the migration of MPs in soils. These findings could provide valuable insights into understanding the environmental behavior and transport mechanisms of MPs, and lay a solid scientific basis for accurately simulating and predicting the fate of MPs in coastal wetland water–soil systems. We highlight the effect of salinity on the fate of MPs and the corresponding priority management of MPs risks under the background of global climate change.

Spectral induced polarization (SIP) measurements across a PFAS-contaminated source zone

There is a need to develop field-scale, in situ screening technologies for assessing variations in aqueous film-forming foam (AFFF) concentrations in soils at former fire training and storage sites. Field-scale Spectral Induced Polarization (SIP) geophysical measurements were acquired on a transect crossing an AFFF source zone. Soil samples were acquired to determine variations in poly- and per-fluoroalkyl substances (PFAS) concentrations in soils, characterize soil texture, and create triplicate soil columns for laboratory SIP measurements. Field and laboratory observations show that SIP measurements are sensitive to the concentration of AFFF constituents associated with soil pore surface area. The specific polarizability and the phase of the SIP measurements for the laboratory samples were linearly correlated with total soil-sorbed PFAS concentration. The phase from the field SIP measurements was highest over the location of maximum PFAS concentration measured on the laboratory samples. However, a significant correlation between field-measured phase and laboratory-measured total PFAS concentration still needs to be established. These observations, along with the demonstrated sensitivity of the SIP response to the removal of soil PFAS using a methanol wash procedure, support the case for SIP characterization of AFFF source zones.

Chestnut soil organic carbon is regulated through pore morphology and micropores during the seasonal freeze–thaw process

Soil aggregates are basic structural units in soil organic carbon (SOC) protection. In alpine ecosystems, the seasonal freeze–thaw (FT) process characterizes soil formation and nutrient cycling. However, previous studies were mostly based on simulated FT experiments, which amplified the effects of natural FT processes. And, the regulations of pore structure on SOC protection/loss of aggregates during the FT processes were still not well understood. To investigate the effect of the seasonal FT process on SOC and pore structure of aggregates, as well as the interactions among them, soil samples were selected during a whole seasonal FT cycle, which can be divided into four periods: unstable freezing (UFP), stable frozen (SFP), unstable thawing (UTP), and stable thawed periods (STP). The results demonstrated that freezing increased SOC concentration as the total organic carbon (TOC) content of all aggregate fractions peaked in the SFP (17.46 g/kg on average). The TOC content of aggregates in the UFP dropped to 7.91 g/kg on average, which revealed a dramatic SOC loss after thawing began. Thawing also decreased the proportions of particulate organic carbon (POC) compared with mineral-associated organic carbon (MAOC). The highest microbial abundance was also found in the SFP. Freezing promoted the formation of pores > 80 μm while thawing increased the regularity of pore morphology. Pore structure explained 48.77 % of the SOC variance in the thawing period, but only 19.29 % of that in the freezing period. Overall, in the freezing process, soil pore structure impacted the SOC input by mediating pore morphology. In the thawing process, soil pore structure inhibited SOC loss by enhancing the formation of pores < 15 μm. These results demonstrate new perspectives on the soil aggregate microstructure–microbe–SOC interactions.