Polyethylene Resins Research Articles

Single-screw extrusion performance for LLDPE resin as a function of compression ratio

High-quality polyethylene film and sheet must be free of solid polymer fragments and degraded resin. Moreover, the products must be produced at high rates to minimize conversion costs. Thus, the extruder must produce a homogenous extrudate at the proper discharge temperature and pressure. The screw design and process operating parameters are key. A key screw design parameter is the compression ratio. This paper experimentally studies how the compression ratio affects a linear low-density polyethylene (LLDPE) resin extrusion process. A 2.8 compression ratio screw was optimal for LLDPE resin. Significant solid polymer fragments were observed in the extrudate for 2.8 to 3.6 compression ratio screws at 110 rpm and higher. For 2.0 and 2.4 compression ratio screws at less than 50 rpm, the internal pressures in the extruder were relatively low. At screw speeds 50 rpm and higher, the specific rates for all screws were higher than the calculated specific rotational rate, creating negative axial pressure gradients in the metering sections.

Study of Factors Affecting UV-Induced Photo-Degradation in Different Types of Polyethylene Sheets.

Enhancing the degradability of polyethylene plastics could provide a potential solution to the overwhelming crisis of plastic waste. Conventional studies have focused on the degradation of polyethylene thin films. This study investigated UV-induced photo-degradation according to ASTM D5208-14 in polyethylene sheets with thicknesses ranging from 0.4 to 1.2 mm. The impacts of sample thickness, metal pro-oxidants, polyethylene resin types and foaming were explored through the characterization of the carbonyl index, molecular weight, tensile properties and crystallinity. As pro-oxidants, single iron or manganese stearate demonstrated a concentration-dependent trend in accelerating the photo-degradation of polyethylene sheets. The thickness, foaming and resin type-such as low-density polyethylene (LDPE) and high-density polyethylene (HDPE)-significantly impacted the rate of photo-oxidation. Thick polyethylene sheets (1.2 mm) exhibited a heterogenous and depth-dependent degradation profile. As the photo-degradation progressed, the enhanced crystallinity, reduced UV transmittance and formation of crosslinks were able to prevent further oxidative cleavage of the polyethylene chain. This study investigated the time course and factors affecting the photo-degradation of polyethylene sheets, which could provide insights into the formulation design of photo-degradable polyethylene plastics.

Production of Thermoplastic Starch-Aloe Vera Gel Film Embedded with Polyethylene for Improved Tensile Strength and Water Absorption

The water absorption characteristics of thermoplastic starch (TPS) reveal its ability to interact with and absorb water, influencing its overall performance in various applications. The introduction of aloe vera (AV) gel into the TPS polymeric matrix film has proven beneficial in enhancing tensile strength but a notable deficiency is observed in lowering water absorption percentage. Therefore, this paper aims to reduce the water absorption of the TPS30AV polymer matrix film by utilizing polyethylene (PE) without reducing the tensile strength performance of the TPS30AV film. The TPS30AV film was produced using melt-blending and hot-press techniques. Six samples were presented consisting of a control film (TPS30AV) and TPS30AV film with different concentrations of PE resins (5%, 10%, 20%, 30%, and 40%). The film's performance was assessed by examining its mechanical properties, water absorption, and water solubility. The finding shows that TPS30AV with 40% PE has the highest improvement in water absorption percentage which reduces from 309.86% to 34.16% but a tremendous decrement in tensile strength performance. However, TPS30AV with 10% PE has the highest tensile strength, 9.65 MPa with a 20.99% improvement in water absorption reduction. The properties obtained for TPS30AV10PE were also good inYoung's modulus and water solubility percentage. It shows that the film formulated is comparable with previous studies, and improvement has been achieved. As a conclusion, adding PE improved the polymeric structure of TPS30AV and can be used as a biodegradable food-packaging film.

Direct synthesis of polar functionalized linear low density polyethylene (LLDPE) using slow-chain-walking palladium catalysts

Linear low-density polyethylene (LLDPE) is the most widely produced type of polyethylene resin. In this work, we detailed the synthesis and analysis of two bulky α-diimine Pd(II) complexes. These Pd(II) complexes can efficiently synthesize LLDPE-type polyethylene materials (ρ = 0.91–0.93 g/cm3) through ethylene slow-chain-walking polymerization. More interestingly, benefiting from the cationic bulky Pd(II) complexes, polar-functionalized LLDPEs (ρ = 0.91–0.92 g/cm3) are also produced by copolymerization of ethylene with various polar monomers such as 10-methyl undecanoate, methyl acrylate, 10-undecenoic acid. The copolymerization maintains the slow-chain-walking polymerization feature, resulting in a polar copolymer with a high melting point and low branching density. The results of 13C NMR spectral also reveal that polar groups are mainly located at the end of the branches in polar-functionalized LLDPEs.

Fabrication and Characterization of Jute Fibre Reinforced Polymer-based Decorative Composites: Effect of Gamma Radiation

The jute fibre (JF) reinforced polyethylene (PE), polypropylene (PP), and epoxy resin (ER) matrix composites were developed. The JF content was maintained to 30% by weight. Then tensile properties and impact strength were measured. The finest tensile properties were found for JF/PP composites. The tensile strength (TS), tensile modulus (TM), elongation at break (Eb%), and impact strength (IS) of the JF/PP composites were found to be 38.00 MPa, 1800 MPa, 12%, and 8.20 kJ/m2 respectively. The bonds between JF and polymers of the developed composites were investigated and found good adhesion. The composite samples were exposed to gamma ray and it was found that gamma radiation have the potential to improve the tensile and impact strength of the JF-based polymer composites. The JF content polymer-based decorative composites were also developed. The outcomes of this investigation showed a minor decrease of the tensile and impact strength of the composites but enhanced the beauty of the composites noticeably. The developed JF/polymer composites have sufficient mechanical strength for many applications pretty. J. of Sci. and Tech. Res. 5(1): 75-82, 2023

Pre-treatment and its effect on the thermal conductivity of natural lignocellulosic rice straw stubble waste boards: Analysis vis a vis potential for the civil engineering applications

Once built, the residential or commercial building must maintain a temperature suitable for human comfort. Presently, according to an estimate, building energy consumption contributes about 40 % to global greenhouse gas (GHG) emissions. Thus, it is necessary to develop building materials that not only have low or zero carbon footprints during their production stage but also provide thermal insulation for buildings amidst variable climates. Among such materials, the use of straw waste boards can not only offer an opportunity to reduce the use of GHG-intensive materials but also provide excellent thermal insulation. The objective of the present work is to fabricate, characterize, and evaluate the thermal conductivity of composite boards made from rice (Oryza sativa) straw. The effect of water and alkali pre-treatment is also evaluated. Three different mass fractions (Mf) with 50 %, 60 %, and 70 % of straw by weight are considered, and three different matrix materials, viz., Polyethylene (PE), Polylactic acid (PLA), and epoxy resin, have been used. Among these, the epoxy matrix is found to be most suitable owing to its uniform dispersion, which leads to superior adhesion in the straw laminates. Subsequent morphological characterization techniques, such as energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD), have been employed to evaluate the physicochemical structure changes of straw fibre and fibre boards. The microstructural characterization revealed that the alkali and water pre-treatment have a pronounced effect on the morphological properties of straw and composite boards. Thermal conductivity has been measured using the experimental setup based on the guarded hot plate method, and the lowest conductivity of heat is recorded in the order of 0.023 W/mK. The present research work attempts to demonstrate the development of a novel product using rice straw waste that can potentially replace/reduce the usage of EPS (Expanded Polystyrene) for building construction applications in the near future.

Comparison of chain structures between special polyethylene resins for natural gas pipes by preparative temperature rising elution fractionation and cross-fractionation

Comparison of chain structures between special polyethylene resins for natural gas pipes by preparative temperature rising elution fractionation and cross-fractionation

Elevating Recycling Standards: Global Requirements for Plastic Traceability and Quality Testing

Globally, we produced 489 million tonnes of plastic in 2023 and we recycled only 8.17%. This study navigates the landscape of recycling practices, highlighting the imperative to reevaluate and upgrade industry-standard protocols. The central focus of this study is on integrating more robust traceability criteria and advanced quality testing methodologies to improve recycled plastics with intrinsic value, particularly in anticipation of future market applications. The investigation examines the prevailing industry standard traceability and quality framework. It then assesses the applicability of those standards using technical datasheets for recycled high-density polyethylene resin grades. This study proposes a paradigm shift toward a more sophisticated analytical approach. This comprehensive framework aims to transcend traditional quality and traceability evaluation. This paper employs a mixed methodological approach, including a thematic analysis of relevant industry standard regulations and an in-depth literature review, to address the need for an operational framework for recycling quality. This study highlights that recycling quality depends on technical attributes determining functionality and application suitability. While some properties are measured, the conventional framework does not address the degradation level of recycled plastic. This study concludes with broader considerations, emphasising the need for a traceability model to disclose material history and composition. This study advocates an industry-wide upgrade in recycling standards, prioritising traceability and quality testing. The proposed enhancements in testing grids and the improved understanding of recycling quality collectively contribute to a holistic framework, unlocking the intrinsic value of recycled plastics for future market applications.

Microstructural design characteristics of high-density polyethylene for thick-walled pressure pipe applications

Advancements in process technology and structure-property relationship-based design of high-density polyethylene has led to development of high-performance bimodal polyethylene grades suitable for large diameter thick-walled pressure pipe applications. These high-density bimodal products have enhanced design life, high pressure rating and sag resistance for fabrication of large diameter thick-walled pipe. Achieving optimal balance of these performance properties require controlled microstructural characteristics. The design characteristics are intricately influenced by catalyst type and process technology employed in resin manufacturing. In this study, we systematically establish correlations between microstructural characteristics of seven commercially available bimodal PE resins, produced using dual slurry or gas phase reactors, and their most relevant performance properties. We conducted comprehensive microstructural characterization of all samples using GPC-IR (high-temperature gel permeation chromatography coupled with an infrared composition detector), 13C NMR (nuclear magnetic resonance), TREF (temperature rising elution fractionation) and DSC (differential scanning calorimetry) techniques. Additionally, we measured mechanical, thermal, and rheological properties, focusing on crystallization kinetics, density, slow crack growth resistance (PENT and strain hardening modulus SHM) and low-frequency shear rheology of these products. Comparisons were made between key properties of interest, including slow crack growth resistance and low-frequency rheology (relevant for sag resistance), and microstructural characteristics. Theoretical and empirical correlations based on phenomenological models were employed for this analysis. The detailed study contributes to determining the critical levels of short and long chain branching, as well as molecular weight distribution characteristics essential to produce bimodal PE-4710 certifiable high-density polyethylene resins with low sag resistance. These design principles may serve as a foundation for the efficient design of reactor recipes and post-reactor modification processes, contributing to the evolution of pressure pipe polyethylene resin development and paving the way for design of next-generation pressure pipe grades.

Differential impacts of polyethylene microplastic and additives on soil nitrogen cycling: A deeper dive into microbial interactions and transformation mechanisms

The impact of microplastics and their additives on soil nutrient cycling, particularly through microbial mechanisms, remains underexplored. This study investigated the effects of polyethylene microplastics, polyethylene resin, and plastic additives on soil nitrogen content, physicochemical properties, nitrogen cycling functional genes, microbial composition, and nitrogen transformation rates. Results showed that all amendments increased total nitrogen but decreased dissolved total nitrogen. Polyethylene microplastics and additives increased dissolved organic nitrogen, while polyethylene resin reduced it and exhibited higher microbial biomass. Amendments reduced or did not change inorganic nitrogen levels, with additives showing the lowest values. Polyethylene resin favored microbial nitrogen immobilization, while additives were more inhibitory. Amendment type and content significantly interacted with nitrogen cycling genes and microbial composition. Distinct functional microbial biomarkers and network structures were identified for different amendments. Polyethylene microplastics had higher gross ammonification, nitrification, and immobilization rates, followed by polyethylene resin and additives. Nitrogen transformation was driven by multiple functional genes, with Proteobacteria playing a significant role. Soil physicochemical properties affected nitrogen content through transformation rates, with C/N ratio having an indirect effect and water holding capacity directly impacting it. In summary, plastic additives, compared to polyethylene microplastics and resin, are less conducive to nitrogen degradation and microbial immobilization, exert significant effects on microbial community structure, inhibit transformation rates, and ultimately impact nitrogen cycling.

Utility of argon as a static charge and wall fouling suppressant in atmospheric gas-solid fluidized beds

This work aimed to study the usability of argon to mitigate electrostatic charging and fouling of polyethylene resin fluidized in a stainless-steel column. Nitrogen, argon, and their binary mixtures of various concentrations were utilized to fluidize polyethylene. Successive and intermittent fluidizations with argon and nitrogen were also carried out to explore the feasibility of using argon in commercial reactors. Fluidization with pure argon resulted in the lowest specific charge and substantially reduced the fouling by 90% relative to pure nitrogen. The results for the mixture trials showed a decreasing non-linear trend as the concentration of argon increased. Even presence of 10 vol% argon in the mixture reduced the wall fouling by 50%. Successive and intermittent fluidization also yielded fouling and specific charge values comparable to pure argon. The results are attributed to argon's relatively low dielectric strength and subsequent localized gas discharge within the particle-dense section of the bed.

Distribution characteristics and microbial synergistic degradation potential of polyethylene and polypropylene in freshwater estuarine sediments

The microbial degradation of polyethylene (PE) and polypropylene (PP) resins in rivers and lakes has emerged as a crucial issue in the management of microplastics. This study revealed that as the flow rate decreased longitudinally, ammonia nitrogen (NH4+-N), heavy fraction of organic carbon (HFOC), and small-size microplastics (< 1 mm) gradually accumulated in the deep and downstream estuarine sediments. Based on their surface morphology and carbonyl index, these sediments were identified as the potential hot zone for PE/PP degradation. Within the identified hot zone, concentrations of PE/PP-degrading genes, enzymes, and bacteria were significantly elevated compared to other zones, exhibiting strong intercorrelations. Analysis of niche differences revealed that the accumulation of NH4+-N and HFOC in the hot zone facilitated the synergistic coexistence of key bacteria responsible for PE/PP degradation within biofilms. The findings of this study offer a novel insight and comprehensive understanding of the distribution characteristics and synergistic degradation potential of PE/PP in natural freshwater environments.

Performance Comparison of Conventional and Biopolymer-modified Asphalt Mixtures for Airport Pavement

Raising the temperature of airport pavement softens its surface, leading to rutting or thermal cracking. As aircraft manufacturers lean toward heavier planes with higher tire pressures, challenges arise. To tackle these problems, incorporating polymers like high-density polyethylene into asphalt binders has emerged as a solution. This study investigates biopolymer-modified asphalt, blending conventional asphalt with highdensity polyethylene and pine resin. This study aims to compare the performance of asphalt mixtures using both conventional and biopolymer-modified asphalt binders. Various tests‒physical, Fourier transform infrared, energy dispersive X-ray, dynamic shear rheometer, volumetric properties, Marshall stability, retained stability, indirect tensile strength and Cantabro loss-were conducted. The results highlighted that integrating pine resin and high-density polyethylene increased the performance grade (PG) of the conventional asphalt from PG 64 to PG 82. Asphalt mixtures using biopolymer-modified binders exhibited superior stability, stiffness and resistance to moisture damage compared to those with conventional asphalt. These properties aligned with the specifications outlined in Item P-401 of the Federal Aviation Administration Advisory Circular 150/5370-10H. Keywords: Pine resin, High-density polyethylene, Biopolymer-modified asphalt, Performance grade 64, Performance grade 82

Manufacture and experimental evaluation of a hydrokinetic turbine for remote communities in Colombia

The manufacture and experimental evaluation of a hydrokinetic turbine of 1 kW are presented. A water velocity of 1.5 m/s, with a power coefficient of 0.4382, a tip speed ratio of 6.325, an angle of attack and pitch angle of 5 and 0 degrees, respectively, a blade length of 0.79 m, a drive train efficiency of 70% and a S822 hydrofoil profile were used for the design. The blades were designed and manufactured by Computer Aided Design (CAD) and Computer Aided Manufacturing techniques (CAM) with a solid cross-section in order to provide the required strength. They were made of Prolon MS (Castnylon + Molybdenum). The platform that supports the turbine was a modular floating raft simple to install, flexible, and durable made of high density polyethylene resin. The supporting structure of the turbine generator was made of stainless steel. The turbine was constructed of high quality and durable materials. To determine the efficiency of the designed turbine, the electrical power and kinetic energy of the river were measured. The experimental assays of the turbine were performed in the Sinú River located in Córdoba (Colombia), obtaining an overall equipment efficiency of 0.5359.

Model Simulation and Rheological Research on Crosslinking Behavior of Polyethylene Resin.

The crosslinking behavior of polyethylene (PE) determines its exceptional performance and application. In this study, we investigated the crosslinking behaviors of different PE resins through model simulation and rheological methods. Specifically, the mathematical equation of "S" model was established for PE resin. According to this equation, the optimal maximum gel content for high-density polyethylene (HDPE) was found to be around 85%. Moreover, the maximum crosslinking degrees for different PE resins depended largely on their density and molecular weight. The melt viscosities before crosslinking in PE resins were highly influenced by their melt index. The higher melt indexes resulted in the lower storage moduli, improving melt processability during processing. In addition, the crosslinking rates of PE resins were strongly influenced by peroxide concentration, independent of PE resin structures. For high molecular weight and low-density PE resins, they exhibited decreased ti values, increased A0 values, and decreased k6 values. However, there were no noticeable variations in the values of k2 and phi among different PE resins. All simulated modeling outcomes showed remarkable consistency with the experimental rheological data. These findings are of strong significance in the industrial manufacture of PE resin.

Splitting for strength: Manipulating polymerization reactor split ratios to control mechanical and rheological properties in bimodal polyethylene resins

AbstractThis study integrates advanced mathematical modeling and experimental methodologies to investigate the simultaneous impact of modifications in the split ratio and molecular weight (MW) of chains on the rheological and mechanical properties of bimodal polyethylene (BiPE) resins. The outcomes underscored the viability of fine‐tuning the molecular weight distribution (MWD) of a BiPE resin by augmenting the MW of high molecular weight (HMW) chains while simultaneously diminishing their proportion in the final alloy formulation. In addition, the experimental results illuminated the prospect of attaining a targeted melt flow index for the final polymers by elevating the MW of HMW chains alongside an increase in the proportion of low molecular weight chains. Significantly, these adjustments resulted in remarkable enhancements in the shear thinning index and strain hardening modulus of the fabricated resins.

Recycled carpet-reinforced composites from post-consumer polypropylene carpet and recycled HDPE resin

Carpets significantly contribute to landfills, forming 3.5 % of the U.S. landfill waste, with less than 10 % being recycled. This study uses intact carpets to create functional composites as a potential solution to this problem. This research introduces a feasible method for manufacturing recycled composites through compression molding of post-consumer polypropylene (PP) carpet and recycled high-density polyethylene (HDPE) resin. Optimal molding temperature and composition ranges were identified using a comprehensive three-level full factorial design of experiments (3D-DOE), resulting in impressive flexural strength (>40 MPa) and flexural modulus (>2000 MPa). Reproducibility tests of 10 specimens yielded 41.8 ± 2.0 MPa flexural strength and 2200 ± 150 MPa flexural modulus. These composites, containing up to 70 % potentially-landfilled carpet and 30 % recycled resin, surpassed the performance for the strength of commercialized thermoplastics, making them suitable for structural applications. The findings present a promising approach to address carpet landfilling while reducing reliance on additives.

Potential Use of COVID-19 Surgical Masks and Polyethylene Plastics in Developing Sustainable Concrete

Managing disposable waste surgical face masks and plastic made from polyethylene (PE) resin is a real challenge. Thus, these are considered a great threat to the environment. Generally, surgical face masks are made of microplastic made of polypropylene materials. Both polypropylene and PE are not easily decomposable in the soil. Consequently, the presence of these waste materials can have detrimental effects on terrestrial and aquatic ecosystems, exacerbating the ongoing crisis faced by the animal kingdom and the broader biosphere. Hence, it is imperative to identify alternate and efficient methods for waste management. Given its significant economic importance, the construction industry holds a prominent position among many industries globally. Consequently, waste masks within the construction sector might assume a crucial role in mitigating plastic pollution. Concrete, one of the most widely used construction materials, is being adapted with various waste materials as the partial or complete substitutes for natural constituents, such as cement and aggregates. This study focused on using different percentages of used COVID-19 surgical masks in fiber form and PE as partial replacements of natural coarse aggregates in producing sustainable concrete. Mask fibers were used in concrete production at percentages of 0%, 0.5%, 1%, 1.5%, and 2% of the total volume of concrete. Similarly, PE aggregates replaced the coarse aggregates by volume at 0%, 5%, 10%, and 15% in concrete. The results showed that the strength of concrete reduced as the percentages of mask fiber and PE aggregates increased. However, the strength and crack-bridging capability of mask concrete are still acceptable for some structural and non-structural applications. The results obtained from this research could also help engineers to design sustainable concrete materials with mask fibers.

Mechanical properties of rCB-pigment masterbatch in rLDPE: The effect of processing aids and water absorption test

Abstract Homogenization of pigment is the key to coloring a plastic product evenly. In this article, the tensile properties of recovered carbon black merge with low molecular weight lubricants and other compounding ingredients in the form of pigment masterbatch (PM) added in a recycled low-density polyethylene (rLDPE) resin were evaluated. The prepared masterbatch with the varying amount and types of processing aids (A and B) was first compounded using the heated two-roll mill. Subsequently, the manually mixed masterbatch in rLDPE was put through an injection molding machine for the shaping process to produce an rLDPE pigment masterbatch composite (PMC). The tensile test was performed on the samples to evaluate the mechanical properties of the PMC. Meanwhile, the melt flow index test was executed to justify the composite flow characteristics. Fourier-transform infrared spectroscopy analysis and scanning electron microscopy were also carried out to analyze the PM and PMC chemical properties and their constructed surface morphology. Besides, X-ray diffraction analysis was performed to determine the changes in degree of crystallinity before and after the water absorption test. The addition of PM in rLDPE has slightly increased the rLDPE matrix tensile properties. While, the usage of more processing aid B in the PMC has turned out to secure better tensile properties compared to the addition of higher amount of processing aid A in the PMC. Interestingly, the tensile properties of all composites after the water absorption test were enhanced, suggesting that a stronger bond was formed during the immersion period.

3D Printing of sustainable coal polymer composites: Thermophysical characteristics

Recently, there has been a growing interest in enlisting polymer-based additive manufacturing in high-volume structural applications such as wind turbine blade tooling and additive housing construction. However, the availability of sustainable and environmentally friendly 3D printable materials could present a serious challenge, precluding the technology expansion to such applications. This research was focused on developing sustainable and environmentally friendly coal-plastic composites for use in high-volume applications. Polylactic acid, polyethylene terephthalate glycol, high-density polyethylene, and polyamide-12 resins were melt-mixed with bituminous Pittsburgh No. 8 coal at loadings varying from 20 wt % to 70 wt % coal. Thermoplastic composite filaments were extruded and processed with commercial 3D printers. Important thermophysical properties including coefficients of thermal expansion, heat deflection temperatures, glass transition and melt temperatures, specific heat capacities, thermal conductivities, and thermal stabilities of the coal-plastic composites were investigated. Coefficient of thermal expansion values for the composites had an inverse relationship with coal content lending to decreased print warping and consistent 3D printing of high-density polyethylene materials. Coal increased the heat deflection temperature of high-density polyethylene composites while little to no effect was observed for the other plastics. All composites maintained comparable melt temperatures, allowing for processing with commercial equipment. Specific heat capacity and thermal conductivity decreased with coal loading for all composite materials. Thermogravimetric analysis under air showed that the introduction of coal improved the thermal stability of all plastics by increasing the decomposition temperatures at 5 % and 50 % weight loss and by reducing the maximum decomposition rates.