Polyethylene Pellets Research Articles

Terahertz Permittivity of Pressed ZnO and CuO Powder in Polyethylene Pellets: Effect of Porosity

Terahertz (THz) spectroscopy is used to measure permittivity (100 GHz-2.5 THz) of ZnO and CuO powders with low fill factor pressed into pellets in a polyethylene binder. We show that porosity (air) of such pressed pellets has a large effect on effective pellet permittivity (~10%) and on the extracted permittivity of the oxide constituent (~150%). We explore a two-step analysis based on sequential application of different effective medium models, first to account for the air, and subsequently to extract the oxide's dielectric properties. We show that the combination of Vegard's law and the Maxwell-Garnett model is the best combination to account, respectively, for the air and the oxide powders. In this regard, the capacity that this approach has to adapt to each phase's physical characteristics by using multiple EMMs is an advantage. The resulting oxide permittivities are significantly larger than previously reported for such pellets as a consequence of the porosity. We find for the real relative permittivities of CuO and ZnO ~12.1 and ~8.9, respectively, in the THz range.

Effect of polymer type on the colonization of plastic pellets by marine bacteria

Plastic is omnipresent in the oceans and serves as surface for biofilm-forming microorganisms. Plastic debris comprises different polymers, which may influence microbial colonization and here, we evaluated if polymer type affects bacterial biofilm formation. Quantifying the biofilm on polyethylene (PE), polypropylene (PP) or polystyrene (PS) pellets by six marine bacterial strains (Vibrio, Pseudoalteromonas, Phaeobacter) demonstrated that each strain had a unique colonization behavior with either a preference for PS or PP over the other polymer types or no preference for a specific plastic type. PE, PP, and PS pellets were exposed to natural seawater microbiota using free-living or total communities as inoculum. Microbial assembly as determined by 16S rRNA (V4) amplicon sequencing was affected by the composition of the initial inoculum and also by the plastic type. Known polymer and hydrocarbon degraders such as Paraglaciecola, Oleibacter, and Hydrogenophaga were found in the plastic biofilms. Thus, on a community level, bacterial colonization on plastic is influenced by the microorganisms as well as the polymer type, and also individual strains can demonstrate polymer-specific colonization.

<i>In Situ</i> Surface-Enhanced Raman Spectroscopy to Investigate Polyyne Formation During Pulsed Laser Ablation in Liquid

The synthesis of polyynes during their formation by pulsed laser ablation in liquid (i.e. acetonitrile) has been analyzed by in-situ surface-enhanced Raman spectroscopy (SERS). A polyethylene pellet, functionalized with silver nanoparticles and placed into the ablation medium, served as SERS active surface. This innovative approach granted the possibility to investigate the dynamics of formation and degradation of polyynes with a time-resolution of a few seconds, starting from the early stages of ablation when the concentration is low. The processes occurring during the synthesis have been studied comparing the in-situ SERS signal of polyynes and byproducts in the solution. The different kinetics of short and long polyynes have been investigated by their in-situ SERS signal, exploring the final distribution of chain lengths. Ex situ UV-Vis and high-performance liquid chromatography confirmed the observations gained from in-situ SERS data and validated this innovative in-situ and in-operando analysis.

An automatic flow-through system for exploration of the human bioaccessibility of endocrine disrupting compounds from microplastics.

This article reports on the first attempt towards investigating the leaching rates in the human gastrointestinal (GI) tract of plastic-borne contaminants that can be ingested accidentally using physiologically relevant body fluids. Oral bioaccessibility under fasted and fed states was determined in dynamic mode exploiting an automatic flow setup. The flow system is able to mimic the fast uptake of the released species from the polymeric matrix by absorption in the human digestive system by the in-line removal of the leached species. Complex GI extractants based on the Unified Bioaccessibility Method (UBM, fasted state) and Versantvoort test (fed-state) were brought through a microplastic-loaded metal microcolumn for semi-continuous leaching of plasticizers (phthalic acid ester congeners) and monomer/antioxidant species (bisphenol A, BPA) followed by in-line solid-phase extraction and clean-up of GI extracts prior to liquid chromatography analysis. The temporal extraction profiles were fitted to a first-order kinetic model for the estimation of maximum bioaccessibility pools and apparent leaching rates. Among all studied contaminants, only BPA, dimethylphthalate and diethylphthalate were appreciably released under dynamic GI conditions from high-density polyethylene pellets (average size of 110 μm), with average bioaccessibility values spanning from 51 to 84% and 48 to 87% for UBM and Versantvoort methods, respectively. No statistically significant differences in oral bioaccessibility pools were found under fed- and fasted-state dynamic extractions. The apparent kinetic constants under the fed state were greater by ≥30% as a consequence of the effect of the larger amounts of bile salts and digestive enzymes in the Versantvoort test on the leaching rates. The estimated average daily intake, in which bioaccessibility data are contemplated, indicated that plastic materials exceeding 0.3% (w/w) BPA might pose real risks to human health.

Recycling the low-density polyethylene pellets in the pervious concrete production

The main target of this study is to experimentally investigate the possibility of recycling of low-density polyethylene (LDPE) pellets as aggregate in pervious concrete manufacturing to achieve sustainable pervious concrete and contribute to plastic waste management. Therefore, two aggregate-to-cement ratios of 7 and 6 are chosen to produce two different pervious concrete series. Natural aggregate and LDPE pellets utilized in the production of pervious concrete are in a single size that remained on a 4.5-mm sieve and passed from 9.5-mm sieve. Natural aggregate was substituted with LDPE pellet at contents of 0, 10, 20, 30, 40, and 50% of total aggregate volume. Totally, 12 pervious concrete mixtures were designed. Basic engineering characteristics of pervious concrete were investigated in terms of permeability and compressive strength. Moreover, abrasion resistance and splitting tensile strength of concrete mixtures were also examined. Additionally, fresh/dry densities and void contents of produced pervious concrete mixtures were determined during the experimental study. The results showed that abrasion resistance of pervious concrete was enhanced by substituting natural aggregate with LDPE pellet whereas strength characteristics were adversely affected. In addition, reductions in fresh and dry densities, void content, and percolation rate of pervious concretes were observed due to the inclusion of the LDPE pellet.

Compressive Strength and Bulk Density of Concrete Hollow Blocks (CHB) Infused with Low-density Polyethylene (LDPE) Pellets

Infusing plastic waste to concrete and masonry structures is an increasingly common industry practice that has the potential to create an environment-friendly material that can improve some of the material’s properties, craft a novel means to repurpose plastic waste, and reduce the need for mining aggregates in the environment. This concept has been studied extensively in different forms of concrete, as shown by several studies; however, there is a dearth of studies focusing on the incorporation plastic waste in concrete hollow blocks (CHB). In this study, we aim to fill that gap by investigating on the effects of incorporating low-density polyethylene (LDPE), a commonly used plastic material, to CHB on its compressive strength and bulk density. Samples of varying percentages of LDPE replacement by volume (0, 10, 20, 30 and 40%) were fabricated and tested. Results showed a general trend of decreasing compressive strength and bulk density upon increasing the amount of LDPE pellets in CHB, which was also observed in previous studies. However, the compressive strength of CHB increased at 10% LDPE replacement, a result similar to a previous study. It was inferred that the strength of the plastic material could have a direct contribution to the compressive strength of CHB at low percentage of aggregate replacement. Statistical analysis showed that the mix with 10% LDPE pellets as replacement to sand was the best among the samples tested. It was shown that CHB infused with LDPE pellets has a higher compressive strength than what is normally used in the Philippines. It was concluded that based on compressive strength and bulk density, LDPE pellets is a viable material to use as partial replacement to sand in non-load bearing CHB.

Optical constants of CuO and ZnO particles in the terahertz frequency range

The optical constants (complex dielectric function) of CuO and ZnO particles in polyethylene pellets are measured by terahertz time-domain spectroscopy. The determination of the dielectric properties of these materials is of interest for energy-storage applications, for instance. Maxwell-Garnett theory is used to extract the contribution to the frequency-dependent optical constants of the oxide powders. The validity of the assumptions of Maxwell-Garnett theory are experimentally verified and self-consistency of the results of the model confirmed. On this basis, experimental complex permittivity values for isotropic CuO and ZnO oxide powders are reported in the 100 GHz-3 THz range.

Effects of Riser Diameter on Solids Holdup and Particle Velocity Profiles in Circulating Fluidized Bed Riser Systems

Abstract Tests were performed in a 0.1-m diameter small circulating fluidized bed (SCFB) and 0.3 m diameter cold flow circulating fluidized bed (CFCFB) riser systems located at the National Energy Technology Laboratory (NETL) to study the effects of riser diameter on the riser hydrodynamics. These tests were performed at solids circulation rates of Gs = 20 and 75 kg/m2 s and superficial gas velocities of Ug = 5.8 and 6.5 m/s using high-density polyethylene (HDPE) pellets with a density of 0.863 g/cm3, particle size range of 600–1400 µm (with a Sauter mean diameter of 871 µm, placing them in the Geldart B classification). Comparisons of riser axial pressure and solids fraction profiles, radial particle velocity profiles, and radial profiles of higher statistical moments and select chaos analysis parameters were considered. The results showed that for a given Ug and Gs, the smaller diameter riser exhibited characteristics associated with more dilute solids flow than that observed in the larger diameter riser. Additionally, the larger diameter riser exhibited a downward flow of solids near the wall under all test conditions, whereas the smaller diameter riser data exhibited little or no indications of solids downflow near the wall. These findings suggest that, from an industrial standpoint, a direct scaleup of small-scale tests cannot readily be accomplished as the solids holdup and the solids velocity profiles in small units (those normally tested in the laboratory) are not similar to those of large units and the performance of large units can therefore not be predicted from small-scale tests.

Life cycle assessment of bagasse fiber reinforced biocomposites

This study aims to evaluate the life cycle environmental implications of producing fiber-reinforced biocomposite pellets, compared with sugarcane- and petroleum-based polyethylene (PE) pellets. Life Cycle Assessment (LCA) methodology is used to evaluate the production of four types of pellets. LCA allows the evaluation of the benefits of improving the production of biobased materials by replacing part of the sugarcane bioPE with bagasse fibers. The functional unit selected was the production of 1 kg of plastic pellets. Primary data were collected from laboratory tests designed to obtain pulp fibers from bagasse and mix them with sugarcane bioPE. Two processes were studied to obtain fibers from bagasse: soda fractionation and hot water-soda fractionation. The results from the LCA show environmental improvements when reducing the amount of bioPE by replacing it with bagasse fibers in the categories of global warming, ozone formation, terrestrial acidification and fossil resource scarcity, when comparing to 100% sugarcane bioPE, and a reduction in global warming and fossil resource scarcity when compared to fossil-based PE. In contrast, results also indicate that there could be higher impacts in terms of ozone formation, freshwater eutrophication, and terrestrial acidification. Even though biocomposites result as a preferred option to bioPE, several challenges need to be overcome before a final recommendation is placed. The sensitivity analysis showed the importance of the energy source on the impacts of the processing of fibers. Thus, using clean energy to produce biobased materials may reduce the impacts related to the production stage. These results are intended to increase the attention of the revalorization of these residues and their application to generate more advanced materials. Further outlook should also consider a deeper evaluation of the impacts during the production of a plastic object and possible effects of the biobased materials during final disposal.

Metals and marine microplastics: Adsorption from the environment versus addition during manufacture, exemplified with lead

There are two means by which metals associate with microplastics in the aquatic environment. Firstly, they may be adsorbed to the plastic surface or hydrogenous-biogenic accumulations thereon, and secondly, they may be present in the polymeric matrix as functional additives or as reaction or recyclate residues. In this study, the relative significance of these associations is evaluated with respect to Pb in beached marine microplastics. Thus, adsorbed Pb was determined in <5 mm, neutrally-coloured polyethylene pellets that contained no detectable Pb added during manufacture by digestion in dilute aqua regia, while the bioaccessibility of this association was evaluated using an avian physiologically-based extraction test (PBET). Here, up to about 0.1 μg g−1 of Pb was adsorbed to the plastic and between about 60 and 70% of the metal was accessible. Lead present as additive or residue was determined by x-ray fluorescence analysis of a wider range of beached plastics (polyolefins and polyvinyl chloride), with a selection of positive samples grated to mm-dimensions and subjected to the PBET. Here, total Pb concentrations up to 40,000 μg g−1 and bioaccessibilities up to 16% were observed, with bioaccessible concentrations exceeding equivalent values for adsorbed Pb by several orders of magnitude. Ingestive exposure to Pb, and potentially other toxic metals, is more important through the presence of additives in historical plastics and recyclate residues in contemporary plastics than from adsorption, and it is recommended that future studies focus more on the environmental impacts and fate of metals bound in this form.

Estimating the mixture friction factor for the dense-phase transport of particulates in horizontal pipes with inner longitudinal spiral slots

This research was devoted to establishing a dimensionless model for estimating mixture friction factor based on the Buckingham Theorem. An experimental test-rig with conveying pipeline of 40 mm I.D was designed, assembled and used to collect the data needed to model the mixture friction factor. Experiments were carried out in four levels of slot depths (0, 0.35, 0.55 and 0.9 mm), three levels of air pressure (100, 200 and 300 kPa) and three pipeline lengths (3, 6 and 9 m). Conveying tests with three particulate materials of mung bean, corn, and polyethylene pellets were completed using three replications. Static air pressure across the conveyor, mass flow rate of discharge solids and inlet air mass flow rate were measured during the tests. The model developed can estimate the mixture friction factor within the range of variables studied. The comparison between predicted and measured mixture friction factor showed no significant difference. According to values of R 2 , RMSE, reduced chi-square and MRD parameters, mixture friction factor modelling of the pneumatic conveyor had good accuracy. Other results showed that the mixture friction factor was 65% less than that of pipelines with inner trapezoidal slots studied earlier, therefore lower upstream pressure was required for dense-phase pneumatic conveying of particulate materials in the new conveyor. The developed model showed acceptable error in predicting pressure drop from the experimental data.

Effects of spatial and seasonal factors on the characteristics and carbonyl index of (micro)plastics in a sandy beach in Aveiro, Portugal

Coastal environments are highly contaminated with plastics of various sizes. In order to understand the distribution and factors influencing (micro)plastics contamination in the environment, sampling of a sandy beach in Costa Nova, Aveiro, Portugal, was conducted by collecting plastic particles and sediments for density separation in transects from the mean low tide line to the dunes, during wet and dry seasons. For surface collection, microplastics comprised 69.4% of plastics, presenting concentrations of 3–6 items m−2 in the wet season, mostly polyethylene pellets carried ashore by storms, and <1 item m−2 for dry season, lower due to less backwashing, were found. Collection of infrared spectra of these particles allowed characterization by polymer type and carbonyl index of all particles. Variations in carbonyl index were found to be related to season, site and particle color. Density separated microplastics, mostly fibers, presented 23 times higher concentrations than surface collection (22 microplastics kg−1, 280 microplastics m−2), due to the identification of smaller sizes, and with higher concentrations in dry seasons, likely from accumulation in sediment and bathing season. Overall, different sampling methods allowed identification of different particle types and sizes, which may vary according to seasonal and spatial factors.

Plastic world

Plastic world

DESIGN OF AN EXPERIMENTAL DEVICE FOR THE MEASUREMENT OF THE COEFFICIENT OF RESTITUTION

In this work an experimental device was designed and built to measure the coefficient of restitution of particles of different type and size. The aim of the study is to analyze the dependence of the coefficient of restitution with the impact velocity, the shape and mass of the particles. Three types of particles of different origin and shape were used: lentils, urea granules and polyethylene pellets. Besides, two impact materials were evaluated: steel and polycarbonate. The images were captured with a high resolution camera, recording the moment at which the particles impact and bounce on the surface. Image processing software was used to obtain the position of the particle at the instants before and after the impact. The particle velocities before and after the collision were calculated and the coefficient of restitution of the particles were obtained. The experimental results showed the dependence of the coefficient of restitution with the studied variables, providing useful information about the energy dissipation for numerical simulations and a breakthrough in the study of gas-solid flow systems.

Chitosan-coated different particles in spouted bed and their use in dye continuous adsorption system.

In this work, three polymer suspensions were used for coating glass beads (GB), porcelain beads (PB), and polyethylene pellets (PP) in spouted bed. Subsequently, the continuous adsorption assays of the food dye Brilliant Blue FCF in a fixed bed column were performed, which was packed with the covered particles. Also, the static adsorption assays were carried out. The adsorption equilibrium isotherms were fitted by Freundlich, Langmuir, and Temkin models, being that the Temkin model was the most suitable to represent the equilibrium data. The particle coating in the spouted bed showed promising results due to the high efficiency of the process. The PB, GB, and PP obtained coating efficiency values in the range to 92-96% when using the suspension of chitosan and hydroxyethyl cellulose. However, only the polyethylene particles coated with the chitosan suspension maintained its coating efficiency (95%). The maximum adsorption capacities at equilibrium of the coated particles of PP and GB were achieved with the chitosan suspension, being the values of around 800mgg-1. Thus, the chitosan-coated polyethylene particles showed to be a promising adsorbent for fixed bed column. Graphical abstract.

Temperature Regulation in Colored Infrared-Transparent Polyethylene Textiles

Summary Effectively regulating heat flow between the human body and its environment not only increases thermal comfort but also presents a novel and potentially cost-effective approach to reducing building energy consumption. Infrared property-engineered textiles have been shown to passively regulate radiative heat dissipation for effective cooling and warming of the human body. However, a lack of dyes that can tune the textile color without compromising the infrared properties remains a major impediment to textile commercialization. Here, we report a new strategy utilizing inorganic nanoparticles as a coloring component for scalable brightly colored, infrared-transparent textiles. The as-fabricated composite textiles not only show a high infrared transparency of ∼80% and a passive cooling effect of ∼1.6°C–1.8°C but also exhibit intense visible colors with good stability against washing. This facile coloration approach will promote the commercialization of radiative cooling textiles in temperature-regulating wearable applications for effective energy savings.

Preparation of polyethylene–supported zero–valent iron buoyant catalyst and its performance for Ponceau 4R decolorization by photo–Fenton process

In this work, zero–valent iron powders were supported onto polyethylene pellet using thermal attachment method at low temperature (120 °C). Polyethylene–supported zero–valent iron was used as a photo–Fenton buoyant catalyst for the removal of Ponceau 4R dye from aqueous solution under visible light. The material was characterized by X–ray diffraction (XRD), scanning electron microscopy (SEM) coupled with energy dispersive X–ray spectroscopy (EDS), Fourier–transform infrared spectroscopy (FTIR) and photographic images. Through the results, excellent adherence of zero–valent iron powders onto the polyethylene pellet surface was obtained. The material showed satisfactory catalytic activity, reaching total decolorization of Ponceau 4R dye at 15 min of reaction. In addition, the buoyant catalyst exhibited other advantages such as easy separation from aqueous solution, good stability and recyclability. Therefore, this research exhibited the great potential of polyethylene–supported zero–valent iron as a photo–Fenton buoyant catalyst to apply in environmental remediation.

Trace elements in microplastics in Cartagena: A hotspot for plastic pollution at the Caribbean

Microplastics are new pollutants considered a source of concern for the oceans worldwide. This research reports the concentrations of trace metals on microplastics collected on beaches from Cartagena, an industrialized city in the Caribbean. Mercury (Hg) was quantified using a Hg analyzer and forty-seven trace elements were assessed by ICP/MS. Most abundant microplastics in beaches were those with the lower degree of surface degradation features (SDF), categorized as white-new polyethylene pellets, followed by secondary microplastics (SM). Greater Hg levels were found in SM, white-degraded (WDP) and black pellets. Trace elements concentrations were linked to the degree of SDF registered in examined pellets, with larger concentrations in WDP. Compared to white-new pellets, Ba, Cr, Rb, Sr, Ce, Zr, Ni, Pb were the most accumulated elements in WDP, as their surface enhance the sorption processes. Microplastic pollution represents a toxicological hazard because its ability to accumulate and transport toxic elements.

Fabrication and characterization of microwave cured high-density polyethylene/carbon nanotube and polypropylene/carbon nanotube composites

Carbon nanotubes have been used as reinforcements in polymers due to their high elasticity, flexibility, and thermal conductivity. In this study, pellets of high-density polyethylene +20 wt% carbon nanotube and polypropylene +20 wt% carbon nanotube were cured using microwave energy. X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, uniaxial tensile test, and scanning electron microscopy was used to study morphology, thermal stability, and mechanical performance of the microwave-cured composites. X-ray diffraction analysis confirmed the bonding between the polymer and carbon nanotube as the peaks shifted and intensified. From the thermal study, it was observed that melting point of the composites is affected by microwave curing and the crystallinity of high-density polyethylene/carbon nanotube and polypropylene/carbon nanotube changed by 57.67% and 47.28%, respectively. Results of the uniaxial tensile test indicated that Young’s modulus of microwave cured high-density polyethylene/carbon nanotube and polypropylene/carbon nanotube composites were improved by 295% and 787.8%, respectively. Scanning electron microscopic fractography shows the stretching of polymer over-lapped on carbon nanotubes in the direction of the applied load.

Questioning the predictive validity of the amphetamine-induced hyperactivity model for screening mood stabilizing drugs

The optical constants (complex dielectric function) of CuO and ZnO particles in polyethylene pellets are measured by terahertz time-domain spectroscopy. The determination of the dielectric properties of these materials is of interest for energy-storage applications, for instance. Maxwell-Garnett theory is used to extract the contribution to the frequency-dependent optical constants of the oxide powders. The validity of the assumptions of Maxwell-Garnett theory are experimentally verified and self-consistency of the results of the model confirmed. On this basis, experimental complex permittivity values for isotropic CuO and ZnO oxide powders are reported in the 100 GHz-3 THz range.