Polycyclic Aromatic Hydrocarbons Ratios Research Articles

Emission factors, characteristics, and gas-particle partitioning of polycyclic aromatic hydrocarbons in PM2.5 emitted for the typical solid fuel combustions in rural Guanzhong Plain, China

Solid fuel is a the most dominant energy source for household usages in developing countries. In this study, emission characteristics on organic carbon (OC), elemental carbon (EC) and fifty-two polycyclic aromatic hydrocarbons (PAHs) in gaseous and particulate phases from seven fuel-stove combinations were studied in a typical rural village in northwest China. For the PAHs, the highest gaseous and particulate phase emission factors (EFs) were both observed for bituminous coal with one-stage stoves, ranging from 459 ± 154 to 1.09 ± 0.36 × 103 mg kg−1. In contrast, the PAHs EFs for the clean briquette coal with two-stage stoves were two orders of magnitude lower than those of the bituminous coals. For parent PAHs (pPAHs) and total quantified PAHs (∑PAHs), they mainly contributed in gaseous phases with compositions of 69–79% and 64–70%, respectively. The gas-to-particle partitioning was mostly governed by the absorption. Moreover, the correlation coefficient (r) between EC and ∑PAHs, OC and parent PAHs (pPAHs), OC and nitro PAHs (nPAHs) were 0.81, 0.67 and 0.85, respectively, supporting that the PAHs species were potential precursors to the EC formation during the solid fuel combustion. The correlation analyses in this study further deduced that the formations of pPAHs and nPAHs were more closely related to that of OC than alkylated PAHs (aPAHs) and oxygenated PAHs (oPAHs). Diagnostic ratios of selective PAHs were calculated and evaluated as well. Among those, the ratio of retene (RET)/[RET + chyrene (CHR)] was found to be an efficient tool to distinguish coal combustion and biomass burning. In general, it was found that the amounts of pollutant emissions from clean briquette coal combustion were definitely lower than those from bituminous coal and biomass combustions. It is thus necessary to introduce and recommend the use of cleaner briquette coal as energy source.

Variations and characteristics of carbonaceous substances emitted from a heavy fuel oil ship engine under different operating loads

Heavy fuel oil (HFO) accounts for approximately 80% of the fuel consumption of ocean-going ships in the world. Multiple toxic species are found in HFO exhaust, however, carbonaceous substances emitted from low-speed marine engine exhaust at different operating loads have not been thoroughly addressed. Therefore, a bench test for a low-speed marine engine with HFO fuel under different operating modes was carried out in this study. Emission factors and characteristics of CO2, CO, organic carbon (OC), elemental carbon (EC), as well as OC and EC fragments, organic matters of n-alkanes and polycyclic aromatic hydrocarbons (PAHs) are given and discussed. Combined with the correlation analysis results among the measured species and engine technical parameters, the formation processes and influence factors of carbonaceous components are also inferred in this study. Besides, together with OC to EC ratio, n-alkanes to PAHs ratio, etc., EC1 to soot-EC ratio in PM can be considered as tracer characteristic of high-sulfur-content HFO ship distinguished from diesel fuel ships. Profiles of n-alkanes and PAHs in PM can be used to distinguish shipping emission source from other combustion sources. Moreover, characteristics of carbonaceous components in size-segregated particles are also discussed, including OC, EC, OC and EC fragments, as well as organic matters. Results show that most of the particle mass, OC, EC, and organic matters are concentrated in fine particles with size of less than 1.1 μm, indicating the significance of ultrafine particles. Formation processes of OC and EC fragments, EC1 and soot-EC are also deduced and proved combined with the characteristics of OC and EC fragments, organic matters, and especially PAHs. Besides, the large variations of OC to EC ratios and speciated profiles of n-alkanes and PAHs in different particle size bins indicate that particle size should be considered when they are used as characteristic tracer in source apportionment studies.

Calculating source contributions to urban atmospheric polycyclic aromatic hydrocarbons and nitropolycyclic aromatic hydrocarbons using 1-nitropyrene and pyrene: An application to an Asian dust event

A method to calculate source contributions to atmospheric polycyclic aromatic hydrocarbons (PAHs) and their nitrated congeners (NPAHs) is proposed, using pyrene (Pyr) and 1-nitropyrene (1-NP), as respective representatives of PAHs and NPAHs. This is based on the known increases in NPAH to PAH ratios as combustion temperatures increase. The fractions of 1-NP and Pyr from high temperature combustion sources in total 1-NP and Pyr are respectively calculated as a (0 <a <1) and b (0 <b < 1). By using atmospheric concentrations of Pyr and 1-NP obtained at monitoring sites, contributions of high and low temperature combustion sources were calculated. Using this method, the contributions of automobiles and coal combustion facilities/industries to atmospheric Pyr and 1-NP concentrations were calculated for atmospheric samples collected in Kanazawa, Japan during a seasonal Asian dust event. The results show that Pyr was almost entirely emitted from industries in China and transported long-range to Japan. By contrast, 1-NP was emitted primarily from automobiles in Kanazawa and its surrounding areas, with a small amount of 1-NP possibly transported from China. The proposed method can provide greater clarity on source identification compared to the typically used PAH isomer pairs.

Temporal Trend of Polycyclic Aromatic Hydrocarbons in Atmosphere Within 24 Hours After Snowfall

The atmosphere is a significant medium for the transportation and diffusion of volatile and semi-volatile pollutants. Furthermore, the atmosphere is the primary exposure route for pollutants to enter the human body. Therefore, the study of the environmental fate of pollutants in the atmosphere is essential. In this study, 16 polycyclic aromatic hydrocarbons (PAHs) were analyzed in snow samples and air samples within 24 hours after a snowfall, and the temporal trend of PAHs in the atmosphere was comprehensively studied. The results indicated that the detection rate of the 16 PAHs in snow was 100%, and the concentration of phenanthrene (538.3 ng·L-1) was the highest, followed by naphthalene (509.1 ng·L-1) and fluoranthene (429.9 ng·L-1), indicating that snowfall can remove PAHs from the atmosphere. After the snowfall, a falling-rising-falling temporal trend of the concentrations of PAHs in the atmosphere was observed. Higher concentrations appeared during rush hour, with the largest automobile exhaust emissions, while lower concentrations appeared during periods with the lowest human activity. The results indicated that the atmospheric concentrations of PAHs were predominantly influenced by human activities. Within 24 hours after snowfall, the ratio of PAHs between the gas phase and particle phase, which depends primarily on the physical and chemical properties of PAHs, had not changed substantially. The diagnostic ratios indicated that within 24 hours after snowfall, the PAHs in the atmosphere originated mostly from the emissions of solid fuel and liquid fuel combustion.

On the nature of polycyclic aromatic hydrocarbons associated with sporting walkways dust: Concentrations, sources and relative health risk.

Sporting walkways (SW) are a new innovation which may prove popular in many cities. As there is currently no information on possible health risks associated with their use, concentrations of polycyclic aromatic hydrocarbons (PAHs) associated with deposited dust sampled on SW in Jeddah, Saudi Arabia, have been measured and interpreted in relation to sources and cancer risk. The average ∑PAHs (16 compounds) ranged between 1357 ng/g in residential areas and 3764 ng/g in central urban areas, with suburban areas between. The congener profile and diagnostic ratios of PAHs indicate a predominant source associated with petroleum combustion (pyrogenic source), most probably vehicular emissions. Carcinogenic potential is estimated from the sum of carcinogenic compound concentrations weighted by their individual potency relative to benzo(a)pyrene, and is found to be similar to household dust sampled in the same city, and lower than many other indoor and outdoor (road) dusts sampled across the world.

Characteristics and Health Risks of Polycyclic Aromatic Hydrocarbons and Nitro-PAHs in Xinxiang, China in 2015 and 2017

Fine particulate matter (PM2.5) samples were collected in the summer and winter of 2015 and 2017 in Xinxiang, China. Nine polycyclic aromatic hydrocarbons (PAHs) and three nitro-PAHs (NPAHs) in PM2.5 were detected via high-performance liquid chromatography (HPLC). The PAHs concentration in summer and winter decreased from 6.37 ± 1.30 ng/m3 and 96.9 ± 69.9 ng/m3 to 4.89 ± 2.67 ng/m3 and 49.8 ± 43.4 ng/m3 from 2015 to 2017. NPAHs decreased in winter (from 1707 ± 708 pg/m3 to 1192 ± 1113 pg/m3), but increased in summer from 2015 (336 ± 77.2 pg/m3) to 2017 (456 ± 312 pg/m3). Diagnostic ratios of PAHs indicated that petroleum combustion was the main emission source in summer, and pollutants originating from the combustion of petroleum, coal and biomass dominated in winter. The 2-nitrofluoranthene (2-NFR)/2-nitropyrene (2-NP) ratio in this study demonstrated that the OH radical pathway was the main pathway for the formation of 2-NP and 2-NFR. The mean total benzo[a]pyrene-equivalent concentrations (BaPeq) and incremental lifetime cancer risk (ILCR) values decreased from 2013 to 2017. The high value of total BaPeq in the winter of 2017 in Xinxiang revealed that a high-risk of cancer remained for residents. The results of this study demonstrate that the decreases in PAHs and NPAHS concentrations from 2015 to 2017. Combined with reducing gaseous pollutants concentration, the reduction in this study might be attributable to emissions reductions by implementing the air pollution control regulations in Xinxiang city in 2016.

Temporal Distribution and Gas/Particle Partitioning of Polycyclic Aromatic Hydrocarbons (PAHs) in the Atmosphere of Strasbourg, France

Gas and particulate phase ambient air concentrations of polycyclic aromatic hydrocarbons (Ʃ16PAHs) were determined in Strasbourg, a large city located in the Alsace region of northeastern France, from May 2018 to March 2020, to study the evolution of their temporal variations and their potential origins. The analysis of PAHs was performed using a global analytical method permitting the quantification of pesticides, PAHs, and polychlorobiphenyls (PCBs). Filters and Carbon doped silicon carbide NMC@SiC foams were extracted by accelerated solvent extraction (ASE) followed by a solid-phase extraction (SPE). Afterwards, extracts were analyzed using gas chromatography coupled to tandem mass spectrometry (GC-MS/MS). Prior to analysis, a pre-concentration step based on solid-phase microextraction (SPME) was used with a polydimethylsiloxane (PDMS) 100 µm fiber. The average total (gas plus particulate) concentration of Ʃ16PAHs varied from 0.51 to 117.31 ng m−3 with a mean of 16.87 ng m−3, with higher concentrations in the cold season of more than 2.5-fold and 6-fold that in the warm season for the gas and particulate phases, respectively. Moreover, low molecular weight (LMW) (2-ring and 3-ring) and medium molecular weight (MMW) (4-ring) PAHs contribute dominantly to the gas phase, while the particulate phase is associated with MMW (4-ring) and high molecular weight (HMW) (5-ring and 6-ring) PAHs. Gas/particle partitioning coefficient (log Kp) was calculated, and values varied between −4.13 and −1.49. It can be seen that the log Kp increased with the molecular weight of the PAHs and that the log Kp is different between cold and warm seasons for HMW PAHs but not for LMW PAHs. Diagnostic ratios of PAHs, which were employed to estimate the primary source of PAHs in Strasbourg, indicate that fuel combustion and biomass/coal burning are the possible origins of PAHs in Strasbourg’s atmosphere.

Persistent Organic Pollutants in Urban Soils of Central of London, England, UK: Measurement and Spatial Modelling of Black Carbon (BC), Petroleum Hydrocarbons (TPH), Polycyclic Aromatic Hydrocarbons (PAH) and Polychlorinated Biphenyls (PCB)

Total organic carbon (TOC), black carbon (BC), total petroleum hydrocarbons (TPH), polycyclic aromatic hydrocarbons (PAH) and polychlorinated biphenyls (PCB) were determined in 73 surface (0-2 cm) and subsurface (5-20 cm) soil samples taken from a 142 km2 area in Central London, UK. Soils were assessed to provide a baseline chemistry for site owners, developers, occupiers and regulators involved in understanding the potential risk to human health and the environment. TOC range was 1.75-11.85 % (mean 5.82 %), BC 3.72-32.71 mg.g-1 (mean 13.8 mg.g-1), TPH 72-4673 mg.g-1 (mean 443 mg.g-1), Σ16PAH 1.64-421.23 mg.g-1 (mean 47.99 mg.g-1) and Σ7PCB 2.56-148.72 µg.kg-1 (mean 20.82 µg.kg-1). Surface soils were less polluted than sub-surface soils due to a decline in industry, power generation, coal burning and traffic. PAH and PCB showed a stronger affinity for BC than TOC and were higher than many other international cities. South east London (Greenwich, Woolwich, Deptford) had the highest PAH pollution. Source PAH ratios confirmed a combustion/urban road run-off origin with minor petroleum inputs. Random Forest spatial modelling (machine learning) revealed large scale pollution trends across London soils. Normal background concentrations (NBC) were calculated and compared to risk-based human health generic assessment criteria (GAC). Benz[a]anthracene, benzo[a]pyrene, benzo[b]fluoranthene, and dibenzo[a]anthracene exceeded the Land Quality Management GACs for three land uses (residential, allotments and public open space near residential housing). The NBC determined for ∑7PCBs (110 µg.kg-1) and dioxin-like PCB 118 (59 µg.kg-1) exceeded the residential and allotment soil guideline values.

Rhizosphere effect on removal and bioavailability of PAHs in contaminated agricultural soil

The rhizosphere effect of ryegrass (Lolium perenne L.) on polycyclic aromatic hydrocarbons (PAHs) dissipation, bioavailability and the structure change of microbial community was investigated using a compartmented device-rhizobox. The PAHs removal efficiency, bioavailability and the change in structure of the microbial community were ascertained using HPLC, Tenax-TA extraction and PCR-DGGE, respectively. The results showed that in the root area (R1) and bulk soil (CK), the removal of 3-ring PAHs were 97.72 ± 0.34% and 95.51 ± 0.75%, 4-ring PAHs were 89.01 ± 1.61% and 78.65 ± 0.47%, 5-ring PAHs were 77.64 ± 4.05% and 48.63 ± 3.19%, 6-ring PAHs were 68.69 ± 3.68% and 36.09 ± 1.78%, respectively. The average removal efficiency of the total PAHs after 80 days followed the order: R1M (91.1%) > CKM (84.9%) > CK (77.6%), indicating that planted soil with inoculation of Mycobacterium sp. as well as non-planted soil inoculated with Mycobacterium sp. could both significantly accelerate the removal of PAHs compared to control soil. The bioavailability ratio of PAHs with 3 and 4 rings tended to decrease (from 59.9% to 14.8% for 3-ring and 7.61% to 5.08% for 4-ring, respectively in R1) while those with 5 rings increased significantly (from 2.41% to 33.78% in R1) during the last 40 days, indicating that bioavailability alteration varies with the number of rings in the PAHs. In addition, PAH bioavailability generally did not show a significant difference between treated soil and control soil. These results suggest that ryegrass rhizosphere effect as well as inoculation of Mycobacterium sp. can accelerate PAH removal in polluted soil. The bacteria community structure demonstrated a complex interplay of soil, bacteria and ryegrass root, and potential PAH degraders were present in abundance. This study provides the exploring data of rhizosphere and bioaugmentation effect on PAH dissipation in agricultural soil, as well as the change of bioavailability and microbial composition thereof.

Parent and methyl polycyclic aromatic hydrocarbons and n-alkanes emitted by construction machinery in China

Construction machinery emits considerable quantities of organic pollutants, such as polycyclic aromatic hydrocarbons (PAHs) and n-alkanes, which significantly affect air quality, human health, and climate change. However, actions to reduce the pollution caused by these pollutants are insufficient due to a lack of comprehensive studies. Therefore, 16 United States Environmental Protection Agency (EPA) priority control PAHs (pPAHs), nine methyl PAHs (mPAHs), and 27 n-alkanes (C12-C38) in particulate matter (PM2.5) emitted by 20 construction machines of different types and emission standards, operated under three modes, were measured in this study. The results showed that (1) the total fuel-based emission factors of pPAHs, mPAHs, and n-alkanes for construction machinery were in the ranges 0.033–1.43, 0.027–1.37, and 1.32–87 mg/kg fuel, respectively. (2) The average emission factors of pPAHs, mPAHs, and n-alkanes in excavator and bulldozer emissions were higher than those in loader and forklift emissions, which can be attributed to machine type, operation mode, emission standards, and engine power. (3) Pry, Phe, C18-C22, 1-mNaP, and mFluo emissions were significantly dominant. Some diagnostic ratios of PAHs (e.g., Ant/(Ant + Phe), Flu/(Flu + Pry), BaA/(BaA + Chry), and IP/(IP + BghiP)) were consistent with those emitted by liquid fossil fuel combustion, whereas the ratios of low molecular weight n-alkanes (C ≤ 24) to high molecular weight (C > 24) n-alkanes from construction machines were higher than those for on-road gasoline vehicles, diesel vehicles, and vessels. (4) The benzo(a)pyrene equivalents (BaPeq) and lifetime cancer risk (LCR) values of PAHs from bulldozer and forklift emissions were higher than those from excavator and loader emissions, especially under working modes. Furthermore, the BaPeq and LCR values of PAHs from construction machineries were higher than that specified by GB3095-2012 and 10^−4, respectively, thereby indicating that PAHs emitted from construction machines pose high health risks.

Characterization of polycyclic aromatic hydrocarbons in the surface sediments around the sunken Sanchi oil tanker

The Sanchi oil tanker collision has attracted worldwide attention for its uniqueness in history. This study investigates the contamination level, spatial distribution, sources, and ecological risk level of polycyclic aromatic hydrocarbons (PAHs) present in the surface sediments collected from around the sunken tanker. The results indicated that the total PAH contents in the study area were in the range of 26.42–226.94 ngˑg−1, with an average of 106.86 ngˑg−1. The highest PAH concentration was observed at the station closest to the Sanchi wreckage, indicating potential PAH contamination due to the accident. The PAH ratios and statistical analysis revealed that the PAHs were mainly generated by coal and fuel oil combustion, with certain petrogenic inputs. The ecological risk assessment results suggested that adverse ecological effects to the benthic ecosystem due to PAH contamination was rare. However, long-term monitoring of the local sedimentary environment is highly recommended because of the prominent presence of high molecular weight PAHs.

Fuel Aromaticity Promotes Low-Temperature Nucleation Processes of Elemental Carbon from Biomass and Coal Combustion.

Significant elemental carbon (EC) emissions from low-temperature solid fuel combustion cannot be explained by classical mechanisms ascribing EC to higher-temperature condensation (> 850 °C). The importance of fuel composition in promoting EC nucleation was investigated by studying EC and polycyclic aromatic hydrocarbon (PAH) formation at multiple-ignition temperatures (300-900 °C) using fuels with different aromatic contents (i.e., straw, wood, and coal). Biomass and coal combustion at 300 °C can produce substantial EC containing a large amount of soot-EC, a known high-temperature condensation product, possibly because aromatics reduce EC nucleation barriers, corresponding to the increasing ratios of soot-EC to char-EC from straw to coal (1.22 to 3.61). High- to low-molecular-weight PAH ratios in biomass combustion were four times lower than those in coal combustion, resulting in different EC formation atmospheres. Specifically, 31.4% of PAHs from biomass combustion were indene, compared to only 0.24% for coal, indicating that resonance-stabilized hydrocarbon-radical chain reactions dominated EC nucleation in biomass combustion. Five- to six-membered PAH ratios were always higher than one in biomass combustion but increased significantly from 0.5 to 2 with increasing temperature in coal combustion, indicating that PAHs generated through aromatic decomposition in coal could form EC through van-der-Waals forces and phenyl addition/cyclization-based covalent bonding at low and high temperatures, respectively.

Improvements in identification and quantitation of alkylated PAHs and forensic ratio sourcing

Parent and alkylated polycyclic aromatic hydrocarbons (PAHs) are present in a number of different sources in varying proportions depending on the source material and weathering. This range of PAH sources can make it difficult to determine the origin of exposure(s). Ratios of alkylated and parent PAHs have been applied as a forensic tool to distinguish between different sources. However, few studies have examined PAH ratios comprehensively as indicators for sourcing beyond a single study area or matrix type. In this paper, we introduce an expanded analytical method based on ASTM D7363-13a which we adapted for a gas chromatography triple quadrupole mass spectrometry instrument. The modifications increase selectivity and sensitivity compared to the ASTM method. We added five alkylated series to the method. This method has then been applied to 22 independent forensic ratios. We evaluated the method and the forensic ratios with certified reference materials and known environmental samples. This analytical method and thirteen PAH ratios were found to accurately predict sources of PAHs.Graphical abstract

Distribution, sources, and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in surface sediments from Daya Bay, South China.

In this study, the concentrations of 16 kinds of polycyclic aromatic hydrocarbons (PAHs) in surface sediments of Daya Bay were determined and analyzed. Results showed that 16 PAHs were detected in all the samples, and the total PAH concentration ranged from 70.18 to 128.04 ng g-1, with an average of 103.17 ng g-1. The cyclic number distribution of PAHs in the sediments was mainly 4 and 5 rings. Six classic PAH ratios named Ant/(Ant + Phe), Fla/(Fla + Pyr), [InP/(InP + BghiP)], [BaA/(BaA + Chr)], BaA/BghiP, and LMW/HMW, and principal component analyses showed that the main source of PAHs in this region was combustion (biomass, coal, and petroleum combustion), and the secondary source was petroleum. The ecological risk analysis of PAHs by using effect range low/median method and mean effects range-median quotient method showed that all of PAHs are lower than the effect range low (ERL) level and the effects range-median quotient (M-ERM-Q) value of all stations is 0.0027-0.0067, with an average value of 0.0046. Thus, it can be seen that PAHs are at a low-risk level in surface sediments of Daya Bay.

Simultaneous Monitoring of Particle-Bound PAHs Inside a Low-Energy School Building and Outdoors over Two Weeks in France

The emergence of new super-insulated buildings to reduce energy consumption can lead to a degradation of the indoor air quality. While some studies were carried out to assess the air quality in these super-insulated buildings, they were usually focused on the measurement of gas phase pollutants such as carbon dioxide and volatile organic compounds. This work reports the first measurements of Polycyclic Aromatic Hydrocarbons (PAHs) associated with particles as a function of time and particle size in a low-energy building. The airborne particles were collected indoors and outdoors over three to four days of sampling using two three-stage cascade impactors allowing to sample simultaneously particles with aerodynamic diameter Dae &gt; 10 µm, 2.5 µm &lt; Dae &lt; 10 µm, 1 µm &lt; Dae &lt; 2.5 µm, and Dae &lt; 1 µm. The 16 US-EPA priority PAHs were then extracted and quantified by high-performance liquid chromatography (HPLC) coupled to fluorescence detection. The resulting total particle concentrations were low, in the ranges 3.73 to 9.66 and 0.60 to 8.83 µg m-3 for indoors and outdoors, respectively. Thirteen PAHs were always detected in all the samples. The total PAH concentrations varied between 290 and 415 pg m−3 depending on the particle size, the environment (indoors or outdoors) and the sampling period considered. More interestingly, the temporal variations of individual PAHs highlighted that high molecular weight PAHs were mainly associated to the finest particles and some of them exhibited similar temporal behaviors, suggesting a common emission source. The indoor-to-outdoor concentration ratios of individual PAH were usually found close to or less than 1, except during the event combining rainy conditions and limited indoor ventilation rate.

Determining priority sources of PM2.5-bound polycyclic aromatic hydrocarbons by their contribution to disability adjusted life years

Polycyclic aromatic hydrocarbons (PAHs) are the main toxic components bound to PM2.5 that have carcinogenic, teratogenic and mutagenic toxicity. Priority control sources were determined by integrating source apportionment with a comparative health risk index of disability adjusted life years (DALYs). The positive matrix factorization (PMF) method was applied to 255 daily PM2.5-bound PAH concentrations detected during 2017 in urban Beijing. Three sources and mass contributions were determined: vehicle emissions (62.6%); coal and natural gas combustion and petroleum volatilization (29.5%); and biomass combustion (8.0%). The conditional probability function (CPF) analysis of the three sources revealed that the near-distance potential source direction was southeast of Beijing. The higher ratio of (3 + 4) ring PAHs/(5 + 6) ring PAHs in the summer implied a longer transport distance of PAHs and a larger emission region for the summer than for the other three seasons. The source-attributed DALYs were estimated based on the source mass contribution from PMF, the inhalation unit risk of PAHs for each disease and the individual DALYs for each disease. The total burden of some typical diseases attributable to PM2.5-bound PAHs was 923.44 DALYs/year, or 6.82 × 10−5 DALYs/person/year. Among these diseases, the carcinogenic effect imposed the greatest burden, accounting for 99.6% of the total burden of disease (upper respiratory cancer accounted for 16.0% and tracheal, bronchial and lung cancer accounted for 83.6%). Although the order of sources by disease burden was identical to that by mass contribution, vehicle emissions contributed a much larger disease burden (79.7%) and thus should be reduced further. The DALYs index breaks the barrier between noncarcinogenic and carcinogenic risk assessments. This enables comparison of the disease burden among different regions and pollutants and is thus helpful for source control and risk management.

Chemical characterization, source identification and health risk assessment of polycyclic aromatic hydrocarbons in ambient particulate matter over central Indo-Gangetic Plain

Polycyclic aromatic hydrocarbons (PAHs) are the carcinogenic component of carbonaceous aerosols and the toxicity of PAHs depends on their molecular structure. PM2.5-bound PAHs concentration, their isomeric ratios and health impacts during wintertime (fog and non-fog episodes) are assessed at two heavily polluted sites (Allahabad and Kanpur) in central IGP (Indo-Gangetic plains) to better understand the spatial-temporal variability of PAHs as well as identification of their major sources. The highest contribution to PAH loading is reported from indeno (1,2,3-c,d) pyrene, benzo(g,h,i) perylene, benzo (b,j) fluoranthene and benzo (a) pyrene at the two sites during studied winter campaigns. Significantly higher contribution from 6-ring PAHs to total PAH concentration at Allahabad has been observed as compared to Kanpur. Moreover, lower PAHs concentration observed during dense fog episodes can be attributed to wet scavenging of aerosols by fog droplets. Isomeric ratios of PAHs indicated significant contribution from diesel engine exhaust at Allahabad and gasoline combustion at Kanpur. Substantial contribution from coal combustion and biomass burning emissions during wintertime over these sites was also observed. Estimation of health risk due to PAHs indicate potential health hazard to adults as well as children at both the sites. Furthermore, health risk observed due to carcinogenic metals (Cr(VI), Cd, Ni, As) and PAHs is nearly twice at Allahabad as compared to Kanpur. Diesel exhaust emissions (a dominant source of Cd and PAHs) appeared to be responsible for increased cancer risk at Allahabad. Whereas, higher Cr(VI) and PAHs concentration in the ambient aerosol is aggravating cancer risk at Kanpur.

Chemical Characteristics of Atmospheric PM10 and PM2.5 at a Rural Site of Lijiang City, China.

Emissions from biomass burning are very serious in Southeast Asia and South Asia in April. In order to explore the effect of long-range transport of biomass emissions from the Indochina Peninsula in Southwest China during the period of the southeast monsoon season and to find out the main pollution sources in local atmospheric PM2.5, a field campaign was conducted from 6–26 April 2011 in Lijiang, China. Twenty-four-hour PM10 and PM2.5 filter samples were collected, and inorganic ions, elements, and carbonaceous components (including organic carbon (OC) and elemental carbon (EC), polycyclic aromatic hydrocarbons (PAHs) and nitrated PAHs (NPAHs)) were measured. The monthly mean mass concentrations of particulate matter (PM) were 40.4 and 14.4 μg/m3 for PM10 and PM2.5, respectively. The monthly mean concentrations of OC and EC in PM10 were 6.2 and 1.6 μg/m3, respectively. The weekly mean concentrations of ∑PAHs and ∑NPAHs were 11.9 ng/m3 and 289 pg/m3, respectively, in atmospheric PM10 of Lijiang. The diagnostic ratios of PAH and NPAH isomers were used to analyze the sources of PAHs and NPAHs in PM10. The ratios of Benz(a)anthracene/(Chrysene+Benz(a)anthracen), Fluoranthene/(Fluoranthene+Pyrene) and Indeno(1,2,3-cd)pyrene/(Benzo(g,h,i)perylene+Indeno(1,2,3-cd)pyrene) were 0.45 ± 0.04, 0.61 ± 0.01, and 0.53 ± 0.03, respectively, indicating the contribution from coal combustion and biomass burning. The 1-nitropyrene/Pyrene (1-NP/Pyr) ratio was 0.004 ± 0.001, suggesting that the contribution to NPAHs mainly came from coal combustion. Sulfate was the most prominent inorganic ionic species, with monthly mean levels of 2.28 and 1.39 μg/m3 in PM10 and PM2.5, respectively. The monthly mean mass ratios of NO3−/SO42− were 0.40 and 0.23 in PM10 and PM2.5, respectively, indicating that the contribution of atmospheric anions from coal combustion sources was much more important than that from other sources. Based on the relatively high SO42− concentrations and low NO3−/SO42− ratios, combined with the data analysis of isomer ratios of PAHs and NPAHs, we can conclude that coal combustion, traffic, and dust were the major contributors to local atmospheric PM in Lijiang city, while biomass burning may also have contributed to local atmospheric PM in Lijiang city to some degree.

Influence of photolysis on source characterization and health risk of polycyclic aromatic hydrocarbons (PAHs), and carbonyl-, nitro-, hydroxy- PAHs in urban road dust.

In this study, PAHs and their transformed PAH products (TPPs) in road dust were subjected to UV driven photolysis, and then extracted using simultaneous pressurized fluid extraction, and analysed using Shimadzu Triple Quadrupole GC/MS. The results of the analysis were used to investigate the robustness and reliability of 14 existing diagnostic ratios (DRs) and two newly proposed molecular DRs that are relevant for characterizing the sources of PAHs and TPPs. The influence of photolysis on the carcinogenic health risk posed to humans by these hazardous pollutants was then assessed. The findings indicated that the DRs segregated into stable, moderately stable and non-stable classes of source characteristics under the influence of photolysis. Only two of the existing DRs, namely, benzo(a)pyrene/benzo(ghi)perylene (BaP/BghiP) and total index exhibited consistent stability to photolysis, whilst fluoranthene/(fluoranthene+pyrene) (FRT/(FRT+PYR)) showed moderate stability. The two newly proposed DRs, naphthalene/1-nitronaphthalene (NAP/NNAP) and pyrene/(1-nitropyrene+1-hydroxypyrene) (PYR/(1NPY+HPY)) were found to be highly reliable in post-emission source characterization. The cross-plots of the most stable DRs showed that traffic emissions is the primary source of PAHs, whilst post-emission photolysis is the secondary source of nitro-PAH (NPAH) TPPs. The percent resonance energy thermodynamic stability of the PAH pollutants does not exert any direct influence on the source characteristics of the DRs. Adults are more vulnerable to potential carcinogenic risks as a result of PAH and TPPs photolysis whereas negligible risk exist for children. This study contributes to a more reliable diagnosis of PAH and TPP sources and thus, to the regulatory mitigation of these hazardous pollutants thereby, promoting enhanced protection of human health and the environment.

Sediment contamination by PAHs in Northern Aegean Sea, Gökçeada: Seasonal variations, source determination, and ecological risks

In this study, concentrations of 16 PAHs (polycyclic aromatic hydrocarbons) have been determined in surface sediments from Gökçeada being the largest island of Turkey and located in the North Aegean Sea, during winter, spring, summer, and fall seasons in 2017. The main object of this study is to understand the levels, seasonal distribution, and the origins of PAHs in the sediments of Gökçeada. During the sampling period, the total PAH (TPAH − Σ16PAH) values varied between 26 and 5408.7 ng/g dw. TPAH values in winter season have been found considerably higher due to residential heating. Besides, the origins of PAH pollution were investigated by using certain PAH ratios. The source of the pollution at all stations during the sampling period was found to be both petrogenic and pyrolytic origin so far as to the phenanthrene/anthracene (PHE/AN) and benzo(a)anthracene/chrysene (BaA/CHR) ratios.