Poly Butylene Adipate Co-terephthalate Research Articles

A Deeper Microscopic Study of the Interaction between Gum Rosin Derivatives and a Mater-Bi Type Bioplastic.

The interaction between gum rosin and gum rosin derivatives with Mater-Bi type bioplastic, a biodegradable and compostable commercial bioplastic, were studied. Gum rosin and two pentaerythritol esters of gum rosin (Lurefor 125 resin and Unik Tack P100 resin) were assessed as sustainable compatibilizers for the components of Mater-Bi® NF 866 polymeric matrix. To study the influence of each additive in the polymeric matrix, each gum rosin-based additive was compounded in 15 wt % by melt-extrusion and further injection molding process. Then, the mechanical properties were assessed, and the tensile properties and impact resistance were determined. Microscopic analyses were carried out by field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM) and atomic force microscopy with nanomechanical assessment (AFM-QNM). The oxygen barrier and wettability properties were also assayed. The study revealed that the commercial thermoplastic starch is mainly composed of three phases: A polybutylene adipate-co-terephthalate (PBAT) phase, an amorphous phase of thermoplastic starch (TPSa), and a semi-crystalline phase of thermoplastic starch (TPSc). The poor miscibility among the components of the Mater-Bi type bioplastic was confirmed. Finally, the formulations with the gum rosin and its derivatives showed an improvement of the miscibility and the solubility of the components depending on the additive used.

Soil Biodegradation of Unidirectional Polyhydroxybutyrate-Co-Valerate (PHBV) Biocomposites Toughened With Polybutylene-Adipate-Co-Terephthalate (PBAT) and Epoxidized Natural Rubber (ENR)

The detrimental impact of discarded plastics on the environment has become of increasing concern and this has led to the development of environmentally friendly ‘green’ polymers. PHBV is one such green polymer that offers biodegradability and renewability, however its mechanical performance is quite limited. This can be improved by reinforcement with natural fibres to form green composites, which offer better mechanical properties while retaining biodegradability. There are, however, few studies examining the biodegradation of toughened PHBV composites. In this work, the biodegradation properties of PHBV/30 vol.% unidirectional flax composites both untoughened and toughened with PBAT and ENR, were studied. Composites were prepared by compression moulding PHBV powder interleaved with unidirectional flax fabric. The toughening agents were cryoground and mixed with the PHBV powder prior to moulding. Biodegradation was conducted in a natural outdoor soil environment and biodegradability was evaluated through weight loss analysis, optical microscopy and electron microscopy. The biodegradability of neat PHBV was minimal but was increased markedly by addition of flax fibres. The toughened composites showed a faster degradation rate than untoughened PHBV/flax, with PHBV/ENR/flax composites having the highest rate likely due to a specific strain of bacteria found worldwide in soil that attacks natural rubber. The biodegradation properties of the composites were superior to those of conventional plastics used in applications such as computer and mobile phone casings, which indicates potential suitability of this class of materials for these applications.

Electrospinning in the preparation of an electrochemical sensor based on carbon nanotubes

This paper reports the development of an electrochemical sensor using electrospun polymeric fibers of PBAT (poly (butylene adipate co-terephthalate))/PLA (poly (lactic acid) containing functionalized carbon nanotubes (MWCNTs) and further calcined (at 500 °C under N2). The morphologies of the electrospun fibers were verified by SEM and those containing MWCNTs presented lower average diameter of 1.76 ± 0.30 μm against 3.67 ± 0.88 μm for the fibers of neat PBAT/PLA. Fourier transform infrared (FTIR) spectra of the polymeric fibers indicated possible interactions between the MWCNTs and the CO functional group. Thermogravimetric analysis (TGA) curves demonstrated slight increase of the stability of the PLA and lower thermal stability of the PBAT. Analyzes through differential scanning calorimetry (DSC) data showed that the interactions occur preferentially with the aliphatic segments of polymer chains; and corroborated the data from FTIR. Also, FTIR and X-ray powder diffraction (DRX) indicated, respectively, decrease on carboxylic groups amount and lamella formation on functionalized MWCNTs due to the PBAT/PLA/MWCNTs electrospun fibers calcination. The electrochemical measurements performed using sensor built based on the as-obtained calcined material showed that the sensor is promising for the determination of metronidazole in aqueous environment.

Biodegradation of mulch films from poly(butylene adipate co‐terephthalate), carnauba wax, and sugarcane residue

ABSTRACTPlastic mulching for agricultural purposes is a technique which began in the last century and since then its use has been perfected. The fragments of some large‐scale mulch films used may accumulate in the soil, release toxic substances, and affect soil microbial activity. The environmental problems generated by fragments of plastic films accumulated in soil have prompted the development and large‐scale use of biodegradable plastic mulch films. The aim of this work is to develop biodegradable plastic mulch films from poly(butylene adipate co‐terephthalate (PBAT), sugarcane residue, and carnauba wax and to evaluate its biodegradation when buried in soil. The films, obtained by flat extrusion, contained 2.5 and 5.0% sugarcane residue and 0 and 2.0% carnauba wax. Their biodegradation after burial in soil was monitored by mass loss, visual inspection, Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Our data show biodegradation in soil to increase with sugarcane residue content and to be independent on carnauba wax addition. This behavior, confirmed by visual inspection, FTIR and SEM images, was associated with the biodegradability of lignocellulosic residues as microorganisms tend to attack this component first, thus eroding fiber/matrix interface and facilitating bio disintegration. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48240.

Rheology and sheet extrusion of Novatein thermoplastic protein/polybutylene adipate‐co‐terephthalate blends

ABSTRACTNovatein is a thermoplastic polymer made from blood meal proteins, but it has rheological properties very different from commodity thermoplastics. Capillary rheometry revealed an apparent time dependent shear viscosity for Novatein, evident from a decreasing pressure drop over time, measured at constant shear rate. However, blending with polybutylene adipate‐co‐terephthalate (PBAT) reduced the time dependence for uncompatibilized blends and virtually eliminated time dependence for compatibilized blends containing 30 wt % PBAT. Novatein's extensional viscosity is three orders of magnitude more than its shear viscosity and explained the difficulty in sheet extrusion. In contrast, 30% compatibilized blends had an extensional viscosity similar to neat PBAT and was also the only blend that could be successfully sheet extruded. Although uncompatibilized blends at the same or lower PBAT content also had a lower extensional viscosity, they could not be sheet extruded and the difference was the 30% compatibilized blends had a fine PBAT phase structure (co‐continuous in this case), which was sufficiently adhered to the Novatein phase. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47977.

Degradation and Recycling of Films Based on Biodegradable Polymers: A Short Review.

The environmental performance of biodegradable materials has attracted attention from the academic and the industrial research over the recent years. Currently, degradation behavior and possible recyclability features, as well as actual recycling paths of such systems, are crucial to give them both durability and eco-sustainability. This paper presents a review of the degradation behaviour of biodegradable polymers and related composites, with particular concern for multi-layer films. The processing of biodegradable polymeric films and the manufacturing and properties of multilayer films based on biodegradable polymers will be discussed. The results and data collected show that: poly-lactic acid (PLA), poly-butylene adipate-co-terephthalate (PBAT) and poly-caprolactone (PCL) are the most used biodegradable polymers, but are prone to hydrolytic degradation during processing; environmental degradation is favored by enzymes, and can take place within weeks, while in water it can take from months to years; thermal degradation during recycling basically follows a hydrolytic path, due to moisture and high temperatures (β-scissions and transesterification) which may compromise processing and recycling; ultraviolet (UV) and thermal stabilization can be adequately performed using suitable stabilizers.

Mechanical and flammability properties of poly(lactic acid)/poly(butylene adipate-co-terephthalate) blends and nanocomposites: Effects of compatibilizer and graphene

Poly(lactic acid) (PLA)/polybutylene adipate co-terephthalate (PBAT) blends were prepared by melt blending and compatibilized by glycidyl methacrylate (GMA). The effect of graphene nanoplatelets (GNP) on these compatibilized blends were investigated by incorporating GNP at different content. The formulated blend and nanocomposites were characterized for mechanical, morphological, thermal and flammability properties by using universal testing machine, impact tester, field emission scanning electron microscope (FESEM), x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), limiting oxygen index (LOI) and UL-94 respectively. The incorporation of 8 phr GMA into PLA/PBAT (75:25) blend as a compatibilizer results in a significant increase in impact strength (more than 14 times higher) compared to the uncompatibilized blend. Young's modulus and tensile strength of compatibilized PLA/PBAT nanocomposites increased upon addition of GNP and reached maximum values at 4 phr before decreasing slightly. However, impact strength decreased with increasing GNP contents. The thermal stability and the flame retardancy of the GNP reinforced blend nanocomposites were also improved with an increase in nanofiller content and the maximum values for the nanocomposites were achieved at 6 phr. Interestingly, the nanocomposites samples showed a UL-94 rating of V0 at 4 and 6 phr of GNP. Morphological studies using FESEM showed the GNP were evenly distributed and dispersed in the PLA/PBAT nanocomposites. The current methodology to prepare PLA/PBAT blend nanocomposite is an economical way to produce high strength biodegradable polymer which also has good flame retardancy.

Development of composite membrane PBAT: Zeolite Y for application as rhynchophorol release system

ABSTRACTComposite membranes consisting of biodegradable poly(butylene adipate‐co‐terephthalate (PBAT) and zeolite Y (0–10 wt %) were produced by extrusion. Zeolite Y is well dispersed in the membrane up to 5 wt %, but tends to agglomerate at higher contents. The presence of zeolite Y in the composite resulted in an improvement of the thermal stability, mechanical properties, and increased the barrier properties. The interaction of the composite membranes with rhynchophorol was investigated by different techniques, showing that the semiochemical progressively lixiviates PBAT monomers, causing thermal and mechanical properties to decrease. However, no interaction seemed to occur between the rhynchophorol and the zeolite. Studies of diffusion of pheromone through membranes have shown that the addition of the zeolite Y has not contributed significantly to a decrease in the release rate of rhynchophorol, but the presence of the zeolite Y helps to increase chemical, mechanical, and thermal stabilities of the membranes. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45757.

고분자 사슬연장제를 이용한 폴리유산 / 폴리부틸렌 아디페이트테레프탈레이트 복합필름의 제조 및 특성 분석

Poly lactic acid(PLA) and poly butylene adipate-co-terephthalate(PBAT) film was prepared using a twin extruder. PLA (25%) and PBAT (75%) were mixed with various ratio of chain extenders, such as Joncryl® and hexamethylene diisocyanate(HDI) to improve the mechanical and thermal properties of produced bio composite films. Tensile strengths of films were steadily increased with increasing ratio of chain extender. The tensile strength of control films was about 25 MPa, and the tensile strength of films with combined chain extenders was above 40 MPa. The films with Joncryl ® resulted in improved tensile strength, while the film with HDI alone showed improved percent elongation at break. By adding chain extenders into PLA/PBAT resin, the cold crystallization temperature (Tcc) and decomposition temperature (Td) of the produced bio composite films increased. It revealed that the addition of two types of chain extenders was efficient way to get PLA/PBAT film with improved strength and elongation.

Structure and properties of organically modified poly(butylene adipate-co-terephthalate) based nanocomposites

Poly (butylene adipate-co-terephthalate (PBAT) nanocomposites were prepared by melt blending PBAT with 5 wt.% of modified or unmodified montmorillonites (MMT). The effect of the presence of organic modifiers in MMT on the morphological, crystalline, thermal, and mechanical properties of PBAT nanocomposites was evaluated. The dispersion and distribution of the clays were studied by using wide angle X-ray analysis (WAXS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) analysis. Materials characterization techniques included: contact angle measurements, differential scanning calorimetry (DSC), thermogravimetry (TGA) and surface hardness analysis. As general results, nanocomposites exhibited different level of clay dispersion depending on the clay/organic modifier’s chemical affinity with the polymer. Contact angle measurements show increases in the hydrophobicity level of PBAT based CLO30B, this could depict its high potential for packaging applications. In addition, Thermal analysis showed that clays partially hindered kinetics and extent of PBAT crystallization on cooling. In general, thermal properties of PBAT were improved by addition of clays, for a barrier effect of the nanoparticle towards polymer decomposition products ablation. In parallel, addition of clays led to enhancements in polymer hardness. These properties were found to be apparently influenced by clay dispersion level and chemical compatibility between the organic modifier and polymer matrix.

Effect of polybutylene adipate-co-terephthalate on properties of polyethylene terephthalate thin films

The aim of this research is to study the mechanical, thermal properties and morphology of polybutylene adipate-co-terephthalate (PBAT) blended with polyethylene terephthalate (PET) thin films. Effect of TiO2 and ZnO is also investigated on mechanical and thermal properties of PBAT/PET thin films. PBAT and PET are blended by a twin screw extruder and film is casted by film extruder. Mechanical, thermal properties and morphology are studied by using universal testing machine, differential scanning calorimeter, thermogravimetric analyzer and scanning electron microscope. From the results, higher PBAT content led to the increment of elongation at break with the sacrifice of modulus of PET thin films. In addition, thermal stability of PBAT/PET thin films is lower than neat PET films. Moreover, modulus and tensile strength could be improved by adding 1-2 wt% ZnO into PET/PBAT film. However, the addition of TiO2 has no significant effect on tensile properties of PET/PBAT film.

Melt extruded nanocomposites of polybutylene adipate‐co‐terephthalate (PBAT) with phenylbutyl isocyanate modified cellulose nanocrystals

ABSTRACTTraditional commodity polymers are widely used in several disposable or short‐life items and take hundreds of years to decompose in nature. These polymers could be replaced in several uses by biodegradable polymers, like polybutylene adipate‐co‐terephthalate (PBAT) studied in this work. For this, nonetheless, it is necessary to improve some of the PBAT properties, like mechanical resistance and barrier properties. In this work, cellulose nanocrystals (CNC) were incorporated in PBAT with this intention, through melt extrusion. Aiming to avoid CNC aggregation during the drying and extrusion process, a CNC chemical modification with phenylbutyl isocyanate was done. It was possible to obtain PBAT‐CNC melt extruded composites with an elastic modulus 55% higher and water vapor permeability 63% lower than the values of the pure polymer, without compromising PBAT biodegradation. Therefore, the composites prepared with these enhanced properties have great potential as substitutes for traditional commodity polymers. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43678.

Use of biodegradable driftnets to prevent ghost fishing: physical properties and fishing performance for yellow croaker

When synthetic non-biodegradable fishing nets are lost, abandoned or discarded at sea, they may continue to catch fish and other animals for a long period of time. This phenomenon is known as ‘ghost fishing’. Biodegradable fishing nets, on the other hand, are intended to degrade or decompose after a certain period of time under water and thereby lose their ghost fishing capacity more quickly than conventional gear. A biodegradable net material, a blend of 82% polybutylene succinate (PBS) and 18% polybutylene adipate-co-terephthalate (PBAT), was developed. We examined the physical properties and degradability of the biodegradable monofilament, and compared the fishing performance of driftnets made of conventional nylon and of the biodegradable material. When dry, conventional nylon monofilament exhibited a greater breaking strength and elongation than biodegradable monofilament of the same diameter. When wet, the biodegradable monofilament exhibited a stiffness of c. 1.5-fold than nylon monofilament. This suggests that a net made of the less flexible biodegradable monofilament would have lower fishing efficiency than conventional nets. The fishing performance comparisons between the biodegradable and conventional nylon nets, however, revealed similar catch rates for yellow croaker Larimichthys polyactis. Biodegradable monofilament started to degrade after 24 months in seawater by marine organisms. We conclude that biodegradable netting may become a feasible alternative to conventional nylon netting and can contribute to reducing the duration of ghost fishing. Nonetheless, there remain many uncertainties, challenges and knowledge gaps that have to be solved before we are able to draw firm conclusions about the overall benefits of these materials in driftnet fisheries.

Functionalized blown films of plasticized polylactic acid/chitin nanocomposite: Preparation and characterization

Bionanocomposite films prepared with melt compounding and film blowing were evaluated for packaging applications. The nanocomposite masterbatch with 75wt.% polylactic acid (PLA), 5wt.% chitin nanocrystals (ChNCs) and 20wt.% glycerol triacetate plasticizer (GTA) was melt compounded and then diluted to 1wt.% ChNCs with PLA and polybutylene adipate-co-terephthalate (PBAT) prior to film blowing. The morphological, mechanical, optical, thermal and barrier properties of the blown nanocomposite films were studied and compared with the reference material without ChNCs. The addition of 1wt.% ChNCs increased the tear strength by 175% and the puncture strength by 300%. Additionally, the small amount of chitin nanocrystals affected the glass transition temperature (Tg), which increased 4°C compared with the reference material and slightly enhanced the films degree of crystallinity. The chitin nanocomposite also had lower fungal activity and lower electrostatic attraction between the film surfaces; leading to easy opening of the plastic bags. The barrier and optical properties as well as the thermal degradation of the films were not significantly influenced by the addition of chitin nanocrystals.

Green Composites from Residual Microalgae Biomass and Poly(butylene adipate-co-terephthalate): Processing and Plasticization

Innovative biocomposites from residual microalgae biomass (RMB), a byproduct of biodiesel production, and PBAT (poly(butylene adipate-co-terephthalate)) have been prepared in this study. RMB was characterized by Fourier transform infrared spectroscopy (FT-IR) and its thermal stability was determined. Subsequently, RMB and PBAT biocomposites were prepared by extrusion and injection molding. Incorporation of 10, 20 and 30% RMB in the biocomposites was studied. The biocomposites were characterized using FT-IR and thermogravimetric analysis, and their mechanical properties were compared, including tensile, flexural and impact strength. The effect of RMB on the morphology of the polymer matrix was analyzed by scanning electron microscopy and confocal laser scanning microscopy. RMB plasticization was performed with glycerol and urea, comparing different proportions of glycerol and urea. The studies show that it is possible to use RMB in the manufacture of biocomposites with PBAT, obtaining the best extrusion results with 20% RMB. Optimal result was achieved with 30% glycerol and 7.5 phr of urea.

Microbial degradation of aliphatic and aliphatic-aromatic co-polyesters

Biodegradable plastics (BPs) have attracted much attention since more than a decade because they can easily be degraded by microorganisms in the environment. The development of aliphatic-aromatic co-polyesters has combined excellent mechanical properties with biodegradability and an ideal replacement for the conventional nondegradable thermoplastics. The microorganisms degrading these polyesters are widely distributed in various environments. Although various aliphatic, aromatic, and aliphatic-aromatic co-polyester-degrading microorganisms and their enzymes have been studied and characterized, there are still many groups of microorganisms and enzymes with varying properties awaiting various applications. In this review, we have reported some new microorganisms and their enzymes which could degrade various aliphatic, aromatic, as well as aliphatic-aromatic co-polyesters like poly(butylene succinate) (PBS), poly(butylene succinate)-co-(butylene adipate) (PBSA), poly(ε-caprolactone) (PCL), poly(ethylene succinate) (PES), poly(L-lactic acid) (PLA), poly(3-hydroxybutyrate) and poly(3-hydoxybutyrate-co-3-hydroxyvalterate) (PHB/PHBV), poly(ethylene terephthalate) (PET), poly(butylene terephthalate) (PBT), poly(butylene adipate-co-terephthalate (PBAT), poly(butylene succinate-co-terephthalate) (PBST), and poly(butylene succinate/terephthalate/isophthalate)-co-(lactate) (PBSTIL). The mechanism of degradation of aliphatic as well as aliphatic-aromatic co-polyesters has also been discussed. The degradation ability of microorganisms against various polyesters might be useful for the treatment and recycling of biodegradable wastes or bioremediation of the polyester-contaminated environments.

Preparation of TiO<sub>2</sub>/Bio-Composite Film by Sol-Gel Method in VOCs Photocatalytic Degradation Process

Biodegradable of polylactic acid (PLA), polybutylene adipate-co-terephthalate (PBAT) and polybutylene succinate (PBS), which were biodegradable aliphatic polyesters, composite films were contained with titanium dioxide (TiO2) as a photocatalyst to evaluate the photocatalytic activity of bidegradable composite films for toluene removal. The synthesized TiO2 was prepared by sol-gel method between titanium isopropoxide with acetic acid. To form the anatase structure, it was calcined at 500°C. TiO2 were added to PLA/PBAT/PBS as a biopolymer blend at 0, 5 and 10 wt% .The TiO2/Bio-composite films were fabricated via blown film technique to produce 40 μm films. Photocatalytic activity efficiency of TiO2/Bio-composite films was performed in an annular closed system under UV light. Since the amount of TiO2 affected the efficiency of the photocatalytic activity, this work was mainly concentrated on the effort to embed the high amount of TiO2 in the biopolymer matrix. The developed photocatalyst was characterized by XRD, UV-Vis spectrophotometer and SEM. The SEM images revealed the high homogeneity of the deposition of TiO2 on the biopolymer matrix. The X-ray diffraction (XRD) ensures the deposition of TiO2 as crystalline anatase phase. In addition, the photocatalytic results shown that the toluene removal efficiencies increased with an increasing TiO2 dosages at 0 wt%, 5 wt%, and 10 wt% , respectively. As aspects, the photocatalytic degradation results showed the highest tolune photocatalytic degradation efficiency of 52.0% at 10 wt% TiO2 .

Newspaper fiber-reinforced thermoplastic starch biocomposites obtained by melt processing: Evaluation of the mechanical, thermal and water sorption properties

Fully biodegradable composites were obtained by melt processing of thermoplastic starch (TPS) reinforced with cellulosic fibers obtained from recovered newspaper up to 30wt%. The influence of reinforcement content on the mechanical, thermal and water sorption properties were evaluated. In addition, it has been evaluated the effect caused by the incorporation of the biodegradable poly (butylene adipate-co-terephthalate (PBAT)) with content varying from 0 to 30wt% based on the thermoplastic matrix. The materials were characterized by mechanical tests dynamic mechanical thermal analysis and water absorption tests. Mechanical testing evidenced that fibers from recovered newspaper acted effectively as reinforcement, increasing the tensile strength and the Young's modulus of TPS. The incorporation of the highly hydrophobic biodegradable PBAT to the composite formulations caused a sharp decrease in the water uptake of the composites. However, even though PBAT has a higher tensile strength than TPS, its incorporation failed to strengthen the materials.

Biodegradable composites from polyester and sugar beet pulp with antimicrobial coating for food packaging

AbstractTotally biodegradable, double‐layered antimicrobial composite films were introduced for food packaging. The substrate layers of the sheets were prepared from poly(lactic acid) (PLA) and sugar beet pulp (SBP) or poly (butylene adipate‐co‐terephthalate (PBAT) and SBP by a twin‐screw extruder. The active layer consisting of antimicrobial in either PLA or chitosan was formed on the surfaces of the substrates by solution coating followed by solvent evaporation. Air‐coupled ultrasonic evaluation and microscopic examination showed a homogeneous structure for the composite sheets. Mechanical analysis and acoustic emission demonstrated the double‐layered composites possessing appropriate tensile strength and fracture characteristics for the use as light weight‐bearing materials. The release of Nisaplin® or allyl isothiocyanate (AIT) effectively suppressed the growth of Listeria monocytogenes and Salmonella cells, respectively; the co‐release of Nisaplin® and AIT played a synergistic effect on inhibition of L. monocytogenes. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

Preparation of Polymer Blends Between Poly (L-Lactic Acid), Poly (Butylene Succinate-Co-Adipate) and Poly (Butylene Adipate-Co-Terephthalate) for Blow Film Industrial Application

The preparation of polymer blends of poly(lactic acid) (PLA), Poly(butylene-succinate-co-adipate)(PBSA) and poly)butylene adipate-co-terephthalate( (PBAT) were studied with the objectives to apply to blown film extrusion method. The blends were prepared using twin-screw extruder. The ratio of PLA and PBSA was fixed at 80/20 and the PBAT content was investigated with 0, 10, 20, 30, 40 and 50 wt%. The speed of screw was 80 rpm with the die temperatures of 220, 200, and 180 °C. It was found that the melt flow index )MFI( and tensile strength of blends decreased with increasing amount of PBAT, whereas the percentage strain showed contrastive results. The maximum tensile strength and impact strength were reached with the blend of equal amount 20 wt% of PBAT. Then, the correspondent condition was used in the blown film extrusion process. The morphology investigation using scanning electronic microscopy )SEM( of PLA/PBSA/PBAT blends showed an excellent compatibility between the three polymers.