Element Pollution Research Articles

Unveiling concentrations of trace elements in the Lower Indus River: risks to aquatic life and human health

Concentration of trace elements (CTEs) is a significant environmental concern worldwide. This study assessed CTE levels in the Lower Indus River (LIR) by analyzing CTEs in water, sediments, tissues of fish (Cirrhinus mrigala), and macrophytes using electrothermal atomic absorption spectrometry (ETAAS) and flame atomic absorption spectrometry (FAAS). The study shows that CTE range—arsenic (As, 58.7–112.1 μg/L), lead (Pb, 59.9–95.6 μg/L), cadmium (Cd, 3.8–8.1 μg/L), nickel (Ni, 40.9–63.4 μg/L), and zinc (Zn, 590.7–847.6 μg/L)—and water parameters (temperature, pH, COD, BOD, turbidity, and alkalinity) exceeded WHO (World Health Organization) acceptable limits. The CTEs (mg/kg dried basis) were analyzed in fish tissues, and As, Cd, Cr, Cu, Hg, Ni, and Zn have the following accumulation order: liver > gill > muscle. In contrast, Ag and Pb were present in higher amounts in gills than in the liver (gill > liver > muscle). Prediction of bioavailability of CTEs, with the extraction of sediment load with EDTA, revealed that As, Cd, and Zn were among the most bioavailable elements in the LIR. Health risk assessment indicated that the presence of CTEs in the fish could pose potential adverse health effects on humans. The study emphasizes significant ecological and health concerns due to fish consumption in the affected region, noting high risks of non-carcinogenic effects. These insights are essential for policymakers and stakeholders in Sindh Province to manage and reduce trace element pollution.

Identification of copper and lead pollution elements based on spectra of corn leaves in different leaf layers

With the development of industrialization, environmental heavy metal pollution has become increasingly serious, and the growth of crops has been seriously affected by heavy metal pollution in the soil environment. Therefore, it is necessary to establish methods for distinguishing and monitoring heavy metal pollution. The application of hyperspectral remote sensing in heavy metal pollution monitoring demonstrates the great potential of using crop leaf spectra to accurately distinguish heavy metal pollution elements. At the same time, new spectral processing methods and models are required to provide support for accurate identification. In this study, greenhouse experiments were conducted to simulate the growth of corn plants under heavy metal Cu and Pb stress. Collect hyperspectral data from different leaf layers of maize plants during the heading stage. Multivariate empirical mode decomposition (MEMD) was introduced, and the spectral data were preprocessed using MEMD, First derivative (FD), and second derivative (SD). At the same time, chemical analysis was used to examine the changes in copper (Cu), lead (Pb), and chlorophyll content in corn leaves. Competitive adaptive reweighted sampling (CARS) and iteratively retaining informative variables (IRIV) were used to screen characteristic bands that were sensitive to copper and lead. Finally, machine learning SVM, ELM, and XGBoost were utilized to construct and propose a series of models such as MEMD-CARS-ELM for accurate discrimination of Cu and Pb pollution elements. The results indicated that the discriminative model established after the MEMD transformation of the spectrum exhibited the best performance. Among them, whether it is tender leaves, functional leaves, or basal leaves, the accuracy of the MEMD-CARS-SVM and MEMD-CARS-ELM models in the training group and validation group for distinguishing Cu and Pb elements is greater than 80%. Other models established by MEMD spectral transformation are also significantly better at identifying Cu and Pb than those established by FD and SD transformations. The signal time–frequency analysis method MEMD is feasible and excellent for hyperspectral data processing. Based on this method, the Cu and Pb pollution element identification method proposed in this study was reliable. The research results provide a new method for the preprocessing of hyperspectral data and a new perspective for the accurate identification of soil heavy metal contamination elements. This study showed that corn leaf spectra can be used to accurately identify heavy metal pollution elements, providing a powerful scientific reference for hyperspectral remote sensing to monitor heavy metal pollution in large areas.

Magnetic response and bioaccessibility of toxic metal pollution in outdoor dustfall in Shanghai, China

Toxic metal content testing, environmental magnetic monitoring and in vitro bioaccessibility experiments each have their own advantages and are often used independently for environmental monitoring, but there are few studies that combine the three to evaluate the hazards of toxic metals to humans. This paper investigated the total content, magnetic properties and bioaccessibility of nine potentially toxic metal elements (Zn, Sn, Pb, Cu, Fe, Ni, Cr, Sr, Mn) in dustfall from different functional zones in Shanghai, China, and systematically compared the related results. The results show that these nine metal elements have different degrees of contamination and enrichment in outdoor dustfall, and their content distribution shows the following trend: Zn>Sn>Pb>Cu>Fe>Ni>Cr>Sr>Mn. Magnetic characteristics χlf and SIRM are mostly positively correlated with the metal elements, indicating that the higher the content of magnetic minerals in the sample, the higher the concentration of metal elements. It was also found that χlf, SIRM, and χARM can well reflect the characteristics of dustfall pollution. The magnetic minerals have a certain degree of enrichment, and the particle size of the magnetic minerals is relatively coarse, mainly in the form of coarse multi-domain and pseudo-single-domain particles, which are largely derived from anthropogenic pollution. The χlf and PM10 concentrations in the precipitation show relatively similar spatial trends, so χlf, SIRM, and χARM can be used as air pollution indices to facilitate the evaluation of metal elements pollution in dustfall. The overall trend in gastric bioaccessibility is Pb>Zn>Mn>Cu>Cr. Due to the increase in the pH of digestive fluid, the bioavailability of toxic metals decreases significantly from the gastric stage to the intestinal stage. χlf, SIRM, and χARM/SIRM are all related to the bioaccessibility of toxic metals in the intestinal stage, so they can be used as toxicity indicators to evaluate the bioaccessibility of toxic metals in dustfall.

“There is a crack in everything, That's how the light gets in”. Maintaining hygiene and striving for purity: An interdisciplinary study

ContextThe concept of hygiene plays a significant role in human life, dividing spaces into opposing categories (clean vs. dirty, pure vs. taboo, familiar and uncanny, etc.) in the pursuit of a long and meaningful life. Across multiple disciplines, hygiene encompasses both physical-material and also mental-spiritual-abstract dimensions, and is studied through various lenses—medicine, religious and cultural studies, psychiatry and psychoanalysis, philosophy and more. ObjectivesThe article aims to describe and critically analyze the pattern that defines hygiene maintenance mechanisms in multiple spheres of human activity. The analysis include physical and cultural hygiene in external aspects of our lives, as well as mental-spiritual hygiene in the internal spheres. The investigation explores how the mechanism of pursuing the hygiene works to preserve the “clean” or the “pure” by preventing the intrusion of the “dirty” and “polluting” and examines the implications of strict hygiene practices on life and vitality. MethodThis is a theoretical study drawing on interdisciplinary approaches, including medical research on the formation of the concept of hygiene, leading to the presentation of the “hygiene hypothesis”, religious and cultural analysis of concepts of purity and pollution, as explored by Mary Douglas, and Freud's psychoanalytic theory with focus on the concept of the uncanny (unheimlich) as a sphere of life that seems to “pollute” our inner world. The implications of Freud's ideas are further examined in the works of Winnicott and others. ResultsThe study reveals that the strict enforcement of hygiene mechanisms, while aiming to eliminate the polluting element entirely, can paradoxically threaten the very vitality it seeks to protect. This paradox appears in different ways but follows a common pattern: the excessive pursuit of cleanliness may inadvertently harm the source of life that hygiene is intended to safeguard. InterpretationsThe article interprets the findings within a broader theoretical framework, and poses questions regarding the balance between the aspiration for purity and the preservation of life's essential vitality. Theoretical implications suggest a need for caution in how hygiene is approached in health policy, and also in contexts like psychology or psychoanalysis. Future research should explore how this balance can be maintained across other fields, such as ethics, media policy in consumer-driven society or education.

Unveiling mercury's hidden threat: An integrated methodology for soil mercury risk assessment in Syr Darya River Basin, Central Asia

Mercury (Hg) contamination of soil poses a significant threat to ecological and human health. Integrating risk assessment with a comprehensive analysis of the physical and chemical properties of soil enables macroscopic understanding of the potential risks associated with Hg. The integrated risk assessment framework was achieved by applying a projection pursuit clustering (PPC) model that considered ecological and human health risks, soil environmental factors derived from the SHapley Additive Explanation–eXtreme Gradient Boosting (SHAP-XGBoost) model, and exposure risk vulnerability. It was found that the concentrations of Hg in the soils of the Syr Darya River Basin ranged from 3.70 to 40.10 ng/g and Fe2O3, Al2O3, and soil organic carbon (SOC) were important factors in the variation in Hg concentrations. Regions with a high risk of soil Hg were identified using the proposed integrated risk assessment framework, with the geographical distribution concentrated near the cities of Kyzylorda and Kazalinsk. From the perspective of different land use types, shrub soil sampling sites had the largest percentage of high Hg risk values, followed by cropland, bare land, and grassland. These findings confirm that the combined risk values depend not only on Hg concentrations, but also on environmental variables and socioeconomic conditions. Integrated risk assessment of soil Hg is based on machine learning and projection pursuit clustering models, which can provide a novel perspective for potential toxic element pollution evaluation, prevention, and treatment.

Sustainable management of drinking water quality in the locality of Massouro, Chad

This study evaluates the quality of drinking groundwater in the city of Moussoro using geochemical, bacterial, and multivariate statistical methods. Access to safe drinking water is a major concern for the population in these regions, as the distribution of this resource is unequal across continents and is often affected by human activities, making it vulnerable. The analysis revealed two categories of water: potable and non-potable. The presence of pollutant indicators, such as Escherichia coli (E. coli) and total coliforms, was observed in most samples. This presence indicates water contamination and requiring monitoring and treatment before it is consumed by the population. Overall, most of the physicochemical parameters comply with the World Health Organisation guidelines for drinking water. However, the concentration of ammonium (NH4+) was high. Pollution elements such as ammonium (NH4+) and E. coli, indicate that human activities also contribute to water mineralisation. The study could ensure sustainable access to safe drinking water, thereby enhancing the overall quality of life in Moussoro.

Risk assessment and sources associated with potentially toxic elements in suspended particulate matter: A karst river perspective in active mining area

Study regionDaiyang River Basin, a typical karst river basin impacted by mining activities in Guizhou, Southwest China. Study focusRivers are fundamental components of regional water security, but they are facing potentially toxic elements (PTEs) pollution caused by mining activities. This study investigated the concentration, behavior, risks and sources of nine PTEs in suspended particulate matter (SPM) from mining-impacted karst rivers, which are essential for the safety and management of karst water environments. New hydrological insights for the regionThe contents of Cr, Ni, Cu, Zn, As, Cd, Sb and Hg exceeded the corresponding local soil background values, with Zn and Cu being the most important pollutants. These elements caused a very high potential toxicity risk to the basin and unacceptable carcinogenic and non-carcinogenic risks to the local residents. Correlation analysis and the positive matrix factorization (PMF) model indicated that Ni, Cd, Zn and Cu were mainly derived from mixed sources of geological background and anthropogenic activities (30.95 %), Hg, Sb, and As were related to coal mining and combustion sources (28.91 %), while Pb, As, Cr and Sb were mainly contributed by natural sources (40.15 %). Furthermore, mixed sources, mining-related sources and As were identified as priority control factors in the study area. These insights can provide powerful support for decision-makers to develop control policies and reduce PTEs pollution in karst areas.

Assessment of Spatial Variability of Major and Micro Nutrients in Soils of Satara District, Maharashtra, India

Georeferenced surface soil samples from eleven (11) tehsils were delineated using stratified random soil sampling method investigation was carried out at All India Co-ordinated Research Project on Micro and Secondary Nutrients and Pollutant Elements in Soils and Plant under Department of Soil Science, Dr. Panjabrao Deshmukh Krishi Vidyapeeth, Akola, Maharashtra to assess the chemical properties, major and micronutrients status in soils of Satara district in the year 2022-2023 of three hundred and thirty soil (330) samples at the depth of (0-20 cm) were collected across the Satara district of Maharashtra and analysed in the laboratory. The results revealed that pH, EC, CaCO3 and OC of soils collected across different tehsils of Satara district varied from 6.00 to 9.43,0.10 to 0.98 dS m-1, 1.50 to 29.25 % and 0.72 to 7.80 g kg-1. The DTPA -Zn, Fe, Cu and Mn in soil of Satara district ranged from 0.18 to 1.85 mg Kg-1, 1.89 to 12.50 mg Kg-1, 0.36 to 2.15 mg Kg-1 and 3.91 to 38.44 mg Kg-1 respectively. The CaCl2-B in soils of all the tehsils ranged from 0.18 to 1.69 mg Kg-1. The results obtained clearly showed a large variability in physio-chemical properties of soil across the Satara district with low nutrient indices were in nitrogen (1.12) and iron (1.51), medium for phosphorus (1.99), Sulphur (2.08) and zinc (1.88), high for potassium (2.92), copper (2.96), manganese (2.77) and boron (2.47).

Assessment of contamination levels, potential ecological and human health risks due to trace elements pollution in the vicinity of the Lolodorf uranium deposit, Southern Cameroon.

The current study assessed the contamination levels and associated ecological and health risks due to hazardous trace elements in soils from Awanda and Mvengue, located in the vicinity of the Lolodorf uranium deposit in Southern Cameroon. Qualitative and quantitative analyses of the soil samples were performed using energy-dispersive X-ray spectrometry. The results indicated that the mean concentrations of metallic and trace elements in soil samples increased in the following order: U < As < Th < Pb < Cu < Ni < Zn < Cr < Mn < Fe < Al. The average concentrations of U, As, Th, Pb, Cu, Ni, Zn, Cr, Mn, Fe, and Al ranged between 0.9-3, 2.9-3.8, 9.2-15, 13.1-20.3, 11.5-42.5, 31.1-60.7, 42.9-91.6, 94.50-170.9, 100.45-500.57, 4874.8-88340 and 226147.5-324240.0mg/kg, respectively. The contamination levels of trace elements were assessed and the human health risk of chemical elements was determined. The investigated elements' average contamination factors (CF) results showed the highest mean CF recorded for Al followed by Cr, Th, Pb, Zn, Cu, Ni, Fe, U, Mn, and As. Furthermore, the findings showed that 90% of soil samples can be classified as considerably contaminated with Al, 100%, and 60% as moderately contaminated with Cr and Th, respectively. The Geo-accumulation indices of Mn, Cr, Th, U, Ni, Zn, Cu, As, and Pb were lower than 1, suggesting low contamination levels for these elements. The ecological factors and risk indices indicated a low ecological risk in the investigated area. In terms of human health risk, ingestion was identified as the primary pathway for both carcinogenic and non-carcinogenic risks, with children found to be more exposed to both risks than adults. Al, Cr, and Fe were found to be the main contributors to non-carcinogenic health risks, while Cr and Ni were the main contributors to carcinogenic health risks.

Bioaccumulation Patterns of Trace Elements in Jellyfish (Crambionella orsini and Cassiopea andromeda) from Northwestern Coastal Waters of the Persian Gulf

Trace element pollution in the Persian Gulf originates from industrial activities, urbanization, shipping, and oil extraction, leading to accumulation in sediments, water, and marine life such as jellyfish. This study investigated trace element bioaccumulation in two jellyfish species, Crambionella orsini and Cassiopea andromeda, across different locations. Jellyfish samples were collected from the Mahshahr and Dilam ports, and their trace element concentrations were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). The study revealed no significant differences in trace element concentrations between C. orsini and C. andromeda. However, levels of copper, iron, manganese, and nickel were significantly higher in specimens from Mahshahr compared to those from Dilam. No significant differences were observed for cadmium, mercury, vanadium, tin, magnesium, and selenium across sites. Lower concentrations of lead, arsenic, zinc, and cobalt were found in C. orsini from Dilam compared to Mahshahr. Additionally, the study found no significant correlation between trace element concentrations in the water and their accumulation in jellyfish bodies. These findings offer valuable insights into the distribution and bioaccumulation of trace elements in jellyfish populations across different marine environments in the Persian Gulf.

Trace Metal Elements (TMEs) in Groundwater Around the Former Industrial Gold Mine of Poura in Burkina Faso – West Africa

The objective of this study is to assess the quality of groundwater around the first industrial mine in Burkina Faso, whose activities have been closed since 1999. The diagnosis of pollution by trace metal elements of groundwater around the old Poura gold mine was carried out through the determination of the contents of Trace Metal Elements (TME) at MP-AES and the measurements of the physicochemical parameters in situ on 38 samples of borehole water. These data made it possible to calculate the pollution risk index, to establish correlations between the different physicochemical parameters on the one hand and with the trace metal elements on the other hand, from the Pearson matrix and to carry out a multivariate statistical analysis, in particular that in principal components (PCA), with a view to determining the origin of the polluting elements. The results obtained made it possible to identify four samples of groundwater with an acidic pH (GWF18 (6.44), GWF19 (6.39), GWF23 (6.1) and GWP01 (5.99)) and 34 samples of groundwater whose Cd, Al, Fe, As, Pb, or Hg contents are higher than the standards in force in Burkina Faso. The Pollution risk Index (PI) indicates that 35 groundwater samples are slightly polluted and 3 groundwater samples are very heavily polluted (GWP01 (PI = 456%), GWF06 (PI = 132.5%), GWF03 (PI = 105.1%)). The Pearson correlation matrix and the principal component analysis (PCA) show that the origin and mobilization of the trace metal elements involved (Al, As, Cd, Cr, Fe, Hg and Pb) are linked to natural mineralization and anthropogenic activities such as mining and agricultural activities, favored by the infiltration of water into the subsoil through geological structures such as fractures and faults.

Health Risk Assessment for Potential Toxic Elements in the Soil and Rice of Typical Paddy Fields in Henan Province.

The accumulation of potential toxic elements in agricultural soil and rice is of particular concern in China. However, studies on the risk assessment of these elements in regional soil-rice systems remain limited. The aim of this study is to evaluate the pollution status and potential health risk of potential toxic elements in typical paddy soil and rice in Henan Province. A total of 80 soil samples and corresponding rice samples were collected to determine the contents of Cd, Pb, As, Cr, Cu, Zn, and Ni, and to assess their potential health risks to local consumers. Results showed that the average contents of these elements in soils were below the national risk screening values in GB15618-2018. Only the average content of Cr in rice exceeded the limit in GB 2762-2022 specified by the national food safety standard. The rates of exceeding the limits for Cd, Pb, As, and Cr in rice samples were 13.89%, 15.28%, 15.28%, and 27.78%, respectively. The health risk assessment indicated that rice intake for both adults and children caused carcinogenic and non-carcinogenic health risks to varying degrees. Local residents are advised to purchase rice from outside the study area to meet their daily needs and strictly regulate the pollution of potential toxic elements within the area.

Spatial Distribution, Leaching Characteristics, and Ecological and Health Risk Assessment of Potential Toxic Elements in a Typical Open-Pit Iron Mine Along the Yangzi River

Potential toxic elements (PTEs) pollution in the soil of abandoned open-pit mines can lead to great ecological risk to the areas around the mining districts. This study selected a typical abandoned open-pit iron mine along the Yangzi River in southeast China to investigate the spatial distribution, leaching characteristics, and ecological and health risk of the soil PTEs (As, Pb, Cd, Ni, Cr, Cu, and Zn). Leaching tests and sequential extraction were applied to study the migration of PTEs under the condition of rainfall. Different risk assessment methods were used to analyze the pollution and ecological risk of PTEs. The contents of As and Cu exceeded the background value of the Chinese soil guideline, with average contents of 50.71 ± 1.59 and 197.47 ± 16.09, respectively. The leaching test and sequential extraction indicated that sites 8 and 9 posed the greatest risk of PTE migration. According to the map of the Nemerow integrated pollution index (NIPI), the pollution level of the middle bare area of the study area was the highest, and Cu possessed the highest pollution index (PI) of 3.92. The average geo-accumulation index (Igeo) of As and Cu was between 1 and 2, reaching the pollution level of moderately contaminated. The average potential ecological risk coefficient (Ei) of As was the highest, and the contributions of As, Cu, and Cd to the potential ecological risk of the whole study area were 46.7%, 29.7%, and 14.3%, respectively. The range of the hazard index (HI) and the range of the As carcinogenic risk (CRAs) of all the sampling sites for children were 1.30–3.94 and 2.19 × 10−4–7.20 × 10−4, and As accounted for more than 85% of the total noncarcinogenic risk, indicating that the comprehensive pollution of PTEs in the study area posed great carcinogenic and noncarcinogenic risks to children. This study can be a proper reference for the subsequent recovery methods and environmental management of the whole mining area.

ОЦІНКА ПОТОЧНОГО СТАНУ РАДІАЦІЙНОГО ЗАБРУДНЕННЯ ТЕРИТОРІЇ МАЙДАНЧИКУ УРАНОВОЇ СПАДЩИНИ КОЛИШНЬОГО ВО «ПХЗ»

The article summarizes the results of long-term radioecological monitoring of the environment radioactive state within the former 'Prydniprovsk chemical plant' and adjacent territories at the preparatory stage life cycle of uranium legacy site. Data analysis have been determined the background activity levels of natural radionuclides (in particular 238U, 226Ra, 230Th, 210Pb, 210Po) in soils, underground and surface waters, air (fall density and volume activity), exhalation of 222Rn from the soil surface and its volume activity. The results of the determined dynamics and trends in the formation of pollution of environmental elements, which form the main factors of exposure of workers and the population, are presented. Areas with elevated dose rate (≥0.5 μSv·h-1) occupy more than 30% of the entire legacy site territory. In the soil activity may be 10 to 1000 times higher than background (30-50 Bq·kg-1) and can exceed 1000 times the exemption level. In aerosols 238U and 226Ra activitis exceeding the background (0.1 µBq·m-2·s-1, 11.5 µBq·m3) by 100-200 times only during periods of earthworks, under normal conditions they are up to 1.5-2.0 times. The monthly average activity 222Rn in the air of open space are 4-5 times higher of the background (median 200±68 Bq∙m-3), in some areas they can exceed by up to 50 times. In the buildings premises on the site 222Rn can exceed the reference level (250 Bq∙m-3) by 1-5 times, and in individual basements by up to 100 times. The data analysis proves that main ways of exposure of workers are external gamma radiation, the inhalation exposure routes from aerosol pollution and the spread of OA 222Rn in the air can be significant only for workers work at the legacy site and do not pose a threat to the city's population. Radiation assessment contamination of underground and surface water showed in present conditions aquatic pathways cannot form any significant contributions to the radiation exposure dose of the public. The obtained results and data analysis of monitoring observations were used to substantiate the measures of the remediation strategy legacy site.

Investigating soil physicochemical factors influencing trace element contamination at the semi-urban-rural home gardening interfaces on the Fiji Islands

Due to its ecological and public health implications, home gardening soil pollution is challenging. However, the physicochemical factors of trace element pollution in semi-urban-rural home gardening soil interfaces in Fiji are unclear. Self-organizing map (SOM), chemometrics, compositional data analysis (CDA), and soil quality indices were used to evaluate spatial patterns, contamination characteristics, sources, and factors affecting trace element contamination in 55 soil samples from semi-urban and rural Fiji. The average contents of diethylenetriaminepentaacetic acid (DTPA)-extractable forms of trace element levels (mg/kg) increased in rural areas as Fe (55.7) > Mn (40.4) > Zn (9.4) > Cu (5.9) and semi-urban areas as Fe (55.2) > Zn (35.9) > Mn (37.1) > Cu (16.1). Rural soils have less ecological risks to home gardening than semi-urban soils. SOM and CDA analysis showed four spatial clusters: clusters 1 and 3 are natural geogenic in rural regions while clusters 2 and 4 are human-induced non-point sources in semi-urban areas. Principal component analysis (PCA) and hierarchical cluster analysis showed that semi-urban Cu-Zn was more affected by manufacturing emissions or fertilization, whereas rural Fe-Mn was more likely to be lithogenic. The research found that pH and organic matter significantly affect Cu and Zn pollution in semi-urban soils (p < 0.05). For rural and semi-urban soils, trace element subsets explained 44 %–87 % of soil contamination changes using the stepwise regression model. These findings aid to establishing a primary database of eco-environmental risks and facilitate comprehensive strategies for assessing soil contamination and potential threats to food safety.

Evaluation of Some Potentially Toxic Elements and Associated Ecological and Health Risks in Topsoil Samples Adjacent to an Industrial Zone in Turkey.

Potentially toxic element (PTE) pollution as a result of industrial activities remains a global problem that poses serious threats to human and ecological health. PTEs (Al, Fe, Ti, Mn, V, Zn, Cu, Cr, Ni, Pb, Co, and As) are metals or metalloids with biological toxicity. This study analyzed the concentrations of these PTEs and the physicochemical properties of topsoil samples collected from areas near industrial districts in the Samsun province of Turkey to evaluate ecological and health risks, estimating various indexes. The average concentrations of Al, Fe, Ti, Mn, V, Zn, Cu, Cr, Ni, Pb, Co, and As analyzed in 23 topsoil samples by energy-dispersive X-ray fluorescence spectrometry were found as 93,822, 82,410, 6623, 1642, 406, 278, 207, 149, 78, 68, 32, and 10 mg/kg dry weight, respectively. Zn, Cu, Cr, Ni, Pb, and Co levels exceed the maximum contaminant levels in the Turkish Regulation on the Control of Soil Pollution. The average pH values, organic matter, total organic carbon, and nitrogen measured in soil samples were 7.14, 6.11, 0.96, and 0.04%, respectively. The ecological and health evaluation reveals that the studied area is polluted with V, Cu, Zn, As, Ni, and Pb, which may pose a risk to people living in settlements near the industrial district.

Comparative assessment of Brassica cultivars for genotypic variability in phytoremediation of soil exposed to lead (Pb) contamination.

The soil pollution caused with accretion of pollutant elements like lead (Pb) is the major environmental concern nowadays. Phytoremediation of contaminated soils using Brassica cultivars that act as hyperaccumulator plants for Pb emerges as an important technique for decontamination of Pb spiked soils. Therefore, pot study was carried out to compare the efficiency of three Brassica cultivars and select the most efficient cultivar for phytoremediation of Pb spiked soils. The experimental soil was contaminated with Pb applied @ 0, 125, 250, 500, 750, and 1,000 mg kg-1 soil. Our outcomes reflected that increased rates of Pb pollution in soil from 125 to 1,000 mg kg-1 soil resulted in decline of yield but enhanced the Pb acquisition of all Brassica cultivars. Comparison of cultivars indicated the highest biomass production (16.7 g pot-1), Pb acquisition (4,011.7 μg pot-1), contamination indices i.e., tolerance index (70.6), and bioaccumulation coefficient (17.03) by Brassica juncea produced thereby proving it as the most efficient cultivar for phytoremediation of Pb spiked soil.

О необходимости повышения экологичности экономического развития Казахстана

The problems of environmental development of the economy of the Republic of Kazakhstan are considered. The purpose of the study is to consider the results of the impact of economic activity on the ecological state of the natural environment. Methods of research – theoretical analysis, statistical analysis, logical method. Data on the main emissions of harmful substances, the structure of total expenditures on environmental protection activities, data on the neutralized polluting elements are given. The directions of ecologically sustainable development are suggested.

Analysis and probabilistic health risk assessment of vertical heavy metal pollution in the water environment of reservoir in the west coast new area of Qingdao, China

The West Coast New Area is a typical city in China where water supply is predominantly sourced from reservoirs. Heavy metal pollution in these reservoirs directly impacts the safety of drinking water and human health. Therefore, this study comprehensively evaluated the status of heavy metal pollution in the water environment and sediment of the main water supply reservoir in the study area, revealing the interaction relationship and pollution sources, as well as assessing the probabilistic health risks to human beings. The results show that there are different degrees of pollution in the main water supply reservoirs in the study area, and the pollution increases with the increase of water depth. The heavy metal pollution index was up to 2681, indicating heavily pollution. The main polluting elements were Mn and Fe, and the maximum contents were 4.11 mg L−1 and 0.68 mg L−1, respectively, which far exceeded the Class III standard limit of drinking water in China. The main source of pollution is human activities, and Mn release from sediment aggravates deep water pollution. The non-carcinogenic risk index of heavy metals in the reservoir, ranging from 4% to 14%, is higher than 1, indicating a potential non-carcinogenic threat. Furthermore, heavy metals have a much greater impact on children compared to adults, among which Mn is the main contributor to human non-carcinogenic risk, contributing more than 60%. Therefore, controlling the content of Mn and Fe can effectively reduce the heavy metal pollution of reservoir and human health risk. The research results are of great significance for the utilization of reservoir water resources and the protection of the ecological environment in the study area.

Effects of mining activities and municipal wastewaters on element accumulation and integrated biomarker responses of the European chub (Squalius cephalus)

This study aimed to determine concentrations of 29 elements in the gills and liver as well as biomarker response in gills, liver, and blood of European chub from Pek River (exposed to long-term mining activities), and to compare these findings with individuals from Ibar River (influenced by emission of treated municipal wastewater) and Kruščica reservoir (source of drinking water) using inductively-coupled plasma optical emission spectrometry (ICP-OES). The metal pollution index (MPI) was also calculated. Supporting analyses for the detection of the municipal wastewater presence at investigated localities included analyses of microbiological indicators (total coliforms and Escherichia coli) of faecal pollution. We have assessed biomarker responses from molecular to organism level using the condition index, comet assay, micronucleus test, oxidative stress parameters, histopathological alterations, and fluorescence spectroscopy parameters. Multibiomarker analysis was summarized by Integrated Biomarker Response v2 (IBRv2). Among these locations, Kruščica exhibited the lowest, whereas the Pek River displayed the highest values for both categories of indicator bacteria. Due to the porphyry copper ores mining, individuals from Pek River had several times higher Cu concentrations in both gills and liver compared to the other localities which was confirmed by biomarker responses and IBRv2 value. On the contrary, fish from Kruščica reservoir were the least affected by elemental pollution which is also confirmed by low MPI and IBRv2 values. Responses of biomarkers correspond to the elemental accumulation in the liver and gills of the Ibar River are positioned between the Pek River and Kruščica reservoir. Of all the biomarkers analyzed in this study, the condition index was the least sensitive. The results of this study showed that fluorescence spectroscopy may be a method for fast screening of structural changes in gills caused by the pollution burden.