Polarization Field Research Articles

Boosting Energy-Storage in High-Entropy Pb-Free Relaxors Engineered by Local Lattice Distortion.

The high-entropy strategy has shown potential in advancing the energy-storage performance of dielectric capacitors, offering benefits to a range of electronic and electrical systems. However, designing high-performance high-entropy relaxor ferroelectrics (RFEs) presents challenges due to the unclear correlation between their core effects and local polarization heterogeneity. Here, we demonstrate that by engineering the local lattice distortion, a core effect in high-entropy systems, to manipulate the local polarization configuration, a giant energy density (Wrec) of 18.7 J cm-3 and high efficiency (η) of 85% can be achieved in (Bi0.5K0.5)TiO3-based high-entropy bulk RFE ceramics. Atomic-level local structural analysis unveils that the local lattice distortion field can be flattened by introducing ions with less size mismatch. The increase in configurational entropy from 1.54 to 2.06R is associated with a smoother polar displacement vector field and a reduction in the size of polar clusters to several unit-cell sizes with weak coupling. Consequently, a substantial decrease in hysteresis and an enhancement in the breakdown field strength can be obtained, leading to a significant improvement in energy density by over 6 times and efficiency by 3 times. Our research establishes a relationship between local lattice distortion, atomic polar displacement, and energy-storage performance in complex high-entropy systems, providing insights for enhancing energy-storage performance via a local structure design.

Enhanced energy storage performance in NBT-based MLCCs via cooperative optimization of polarization and grain alignment

Dielectric ceramics possess a unique competitive advantage in electronic systems due to their high-power density and excellent reliability. Na1/2Bi1/2TiO3-based ceramics, one type of extensively studied energy storage dielectric, however, often experience A-site element volatilization and Ti4+ reduction during high-temperature sintering. These issues may result in increased energy loss, reduced polarization and low dielectric breakdown electric field, ultimately making it challenging to achieve both high energy storage density and efficiency. To address these issues, we introduce a synergistic optimization strategy that combine polarization engineering and grain alignment engineering. First principles calculations and experimental analyses show that the doping of Mn2+ can suppress the reduction of Ti4+ in Na1/2Bi1/2TiO3-based ceramics and enhance ion off-centering displacements, thereby reducing energy loss and improving polarization. In addition, we prepared multilayer ceramic capacitors with grains oriented along the <111> direction using the template grain growth method. This approach effectively reduces electric-field-induced strain by 37% and markedly enhances breakdown electric field by 42% when compared with nontextured counterpart. As a result of this comprehensive strategy, <111 >-textured Na1/2Bi1/2TiO3-based multilayer ceramic capacitors achieve an ultra-high energy density of 15.7 J·cm−3 and an excellent efficiency beyond 95% at 850 kV·cm−1, exhibiting a superior overall energy storage performance.

A multi-instrument study of UV bursts and associated surges in AR 12957

The relationship between UV bursts and solar surges is complex, with these events sometimes being observed together and sometimes being observed independently. Why this sporadic association exists is unknown; however, it likely relates to the physical conditions at the site of the energy release that drives these events. Here, we aim to better understand the relationship between UV bursts and solar surges through a multi-instrument analysis of several associated events that occurred around the trailing sunspot in AR $12957$. We used data from Solar Orbiter, the Solar Dynamics Observatory (SDO), and the Interface Region Imaging Spectrograph (IRIS) to achieve our aims. These data were sampled on 3 March 2022 between $09$:$30$:$30$ UT and $11$:$00$:$00$ UT, during which time a coordinated observing campaign associated with the Slow Solar Wind Connection Solar Orbiter Observing Plan (SOOP) took place. Numerous small-scale negative polarity magnetic magnetic features (MMFs) were observed to move quickly (potentially up to $3.3$ km s$^ $) away from a sunspot until they collided with a more stable positive polarity plage region around $7$ Mm away. Several UV bursts were identified in IRIS slit-jaw imager (SJI) $1400$ data co-spatial to where these opposite polarity fields interacted, with spatial scales ($2$ Mm$&lt;$) and lifetimes ($20&lt;$ minutes) larger than typical values for such events. Two surges were also observed to occur at these locations, with one being short ($5$ Mm) and hot (bright in the IRIS SJI images), whilst the other was a cooler (dark in coronal imaging channels), longer surge that appeared to fill an active region loop. Magnetic reconnection between the negative polarity MMFs around the sunspot and the positive polarity plage region appears to be the driver of these events. Both the speed of the MMFs and the locally open magnetic topology of the plage region could possibly have been important for forming the surges.

FMO-LC-TDDFTB method for excited states of large molecular assemblies in the strong light-matter coupling regime.

We present a new methodology to calculate the strong light-matter coupling between photonic modes in microcavities and large molecular aggregates that consist of hundreds of molecular fragments. To this end, we combine our fragment molecular orbital long-range corrected time-dependent density functional tight-binding methodology with a generalized Tavis-Cummings Hamiltonian. We employ an excitonic Hamiltonian, which is built from a quasi-diabatic basis that is constructed from locally excited and charge-transfer states of all molecular fragments. To calculate polaritonic states, we extend our quasi-diabatic basis to include photonic states of a microcavity and derive and implement the couplings between the locally excited states and the cavity states and built a Tavis-Cummings Hamiltonian that incorporates the intermolecular excitonic couplings. Subsequently, we demonstrate the capability of our methodology by simulating the influence of the electric field polarization on the polaritonic spectra for a tetracene aggregate of 125 monomers. Furthermore, we investigate the dependence of the splitting of the upper and lower polaritonic branches on the system size by comparing the spectra of five different tetracene clusters. In addition, we investigate the polariton dispersion of a large tetracene aggregate for electric field polarizations in the x, y, and z directions. Our new methodology can facilitate the future study of exciton dynamics in complex molecular systems, which consist of up to hundreds of molecules that are influenced by strong light-matter coupling to microcavities.

Design of CdZnS/BiOCl heterostructure as a highly-efficient piezo-photocatalyst for removal of antibiotic

Facilitating the surface and bulk photocarrier separation in semiconductors is crucially important for enhancing their photocatalytic activities. In this study, we have immobilized CdxZn1−xS (x = 0.7) nanoparticles on the surface of (001)-facet-exposed BiOCl (BOC) nanosheets to form heterostructured CZS/BOC piezo-photocatalysts. Experiments and theories were performed to unveil the piezo-photocatalytic performances of the CZS/BOC heterostructures and involved mechanisms. It is corroborated that the CZS/BOC heterostructures exhibit efficient transfer/separation of photocarriers, and hence possess excellent photocatalysis for eliminating tetracycline hydrochloride (TC). When irradiated by simulated sunlight, the 20 %CZS/BOC heterostructure manifests a photocatalytic activity with η(40 min)/kapp = 95 %/0.06825 min−1, which is enhanced by 6.9 (or 1.9) times over that of bare BOC (or Cd0.7Zn0.3S). While exerting ultrasonic vibration during the simulated-sunlight illumination, i.e., for the piezo-photocatalysis, a further improvement in the TC degradation rate is observed. The synergistic factor is calculated to be 1.5, quantifying the enhancement degree achieved by piezo-photocatalysis collaboration. The enhanced piezo-photocatalysis can be interpreted by the accelerated separation of the bulk photoelectrons and photoholes in the photocatalysts resulted from ultrasonic-induced polarization field, thus elevating their utilization for redox reactions. This work could advance the application of piezo-photocatalysts in environmental remediation.

Piezoelectric field accelerating charge transfer in Z-scheme heterojunction 2D-KNbO3/1D-CdS for efficient piezo-photocatalytic H2 evolution and TCH degradation

The piezo-phototronic effect utilizes the piezoelectric polarization field to tune the photogenerated carrier separation and transport performance in heterojunctions, which portrays a promising strategy for addressing energy shortage and environmental pollutants. Herein, a novel Z-scheme piezoelectric semiconductor heterojunction, 2D-KNbO3/1D-CdS-x (KNCS-x), was fabricated using hydrothermal and solvothermal methods, resulting in enhanced redox capacity. Under the simultaneous light and strain, KNCS-15 exhibits the highest piezo-photocatalytic activity, with degradation rates of tetracycline hydrochloride degradation rate constant, H2O2 as well as H2 production rates being 1.806 × 10−2s−1, 45.56 mM·h−1·g−1 and 8.87 mmol·h−1·g−1, respectively, which are 1.4, 2.4 and 1.9 times of photocatalysis alone, and 9.8, 9.2 and 9.8 times of piezocatalysis alone. DFT calculations, EPR and PALS indicate that the Z-scheme structure realizes effective separation of electron-hole pairs with strong redox ability and a higher carrier concentration. The enhanced catalytic activity is attributed to the introduction of piezoelectric potential, which facilitates improved spatial separation of electrons with high reduction and holes with high oxidation potential.

An Antiferroelectric‐Coated Metal Foam Infiltrated with Liquid Metal as a Dielectric Capacitor

Nickel metal foams serve as both a substrate and bottom electrode for a dielectric capacitor using atomic‐layer deposition (ALD) and a eutectic gallium–indium (EGaIn) liquid metal (LQM) counter electrode. The conformal dielectric has a composition of 6.25% Al–HfO2 in the antiferroelectric phase, confirmed with polarization versus electric field measurements. Liquid EGaIn is pressure‐infiltrated within the coated foams to form the dielectric capacitor. Capacitances up to 4 μF are realized. Calorimetry of the infiltrated capacitor shows a 60 J g−1 latent heat upon melting a frozen EGaIn electrode, suggesting that the phase change can alleviate thermal deviations from pulsed power capacitor operation. Infiltrated capacitors are also shown to survive bending and freeze–thaw cycles. The metal foam–ALD dielectric–LQM capacitor shows a combined set of thermal and electrical properties not available in other classes of capacitors.

Spontaneous parametric downconversion in a laser-poled lithium niobate nonlinear photonic crystal with nanoscale resolution.

Based on quasi-phase-matching (QPM) theory, nonlinear photonic crystals (NPCs) are capable of realizing efficient spontaneous parametric downconversion (SPDC) for the generation of photonic entangled states. However, the traditional electric field poling techniques employed in NPC fabrication often result in non-negligible processing errors of a few hundred nanometers, thus impeding the production of quantum photon pairs as intended. In this work, we investigate the SPDC photon pairs generated in a laser-poled lithium niobate (LN) NPC. By using the recently developed laser poling technique, the processing error of the NPC is substantially reduced to approximately 15 nm. Consequently, the coincidence counts of the generated photon pairs in the experiment reach 83.6% of the designed value. Our result paves the way for on-demand production of high-quality quantum sources, which has potential applications in quantum communications and quantum computations.

Surface-near domain engineering in multi-domain x-cut lithium niobate tantalate mixed crystals

Lithium niobate and lithium tantalate are among the most widespread materials for nonlinear, integrated photonics. Mixed crystals with arbitrary Nb–Ta ratios provide an additional degree of freedom to not only tune materials properties, such as the birefringence but also leverage the advantages of the singular compounds, for example, by combining the thermal stability of lithium tantalate with the larger nonlinear or piezoelectric constants of lithium niobate. Periodic poling allows to achieve phase-matching independent of waveguide geometry and is, therefore, one of the commonly used methods in integrated nonlinear optics. For mixed crystals, periodic poling has been challenging so far due to the lack of homogeneous, mono-domain crystals, which severely inhibit domain growth and nucleation. In this work, we investigate surface-near (&amp;lt;1μm depth) domain inversion on x-cut lithium niobate tantalate mixed crystals via electric field poling and lithographically structured electrodes. We find that naturally occurring head-to-head or tail-to-tail domain walls in the as-grown crystal inhibit domain inversion at a larger scale. However, periodic poling is possible if the gap size between the poling electrodes is of the same order of magnitude or smaller than the average size of naturally occurring domains. This work provides the basis for the nonlinear optical application of lithium niobate tantalate mixed crystals.

Kinetic theory of vacuum pair production in uniform electric fields revisited

We investigate the phenomenon of electron-positron pair production from vacuum in the presence of a uniform time-dependent electric field of arbitrary polarization. Taking into account the interaction with the external classical background in a nonperturbative manner, we quantize the electron-positron field and derive a system of ten quantum kinetic equations (QKEs) showing that the previously-used QKEs are incorrect once the external field rotates in space. We employ then the Wigner-function formalism of the field quantization and establish a direct connection between the Dirac-Heisenberg-Wigner (DHW) approach to investigating the vacuum pair-production process and the QKEs. We provide a self-contained description of the two theoretical frameworks rigorously proving their equivalence and present an exact one-to-one correspondence between the kinetic functions involved within the two techniques. Special focus is placed on the analysis of the spin effects in the final particle distributions. Published by the American Physical Society 2024

The Role of Meridional Flow in the Generation of Solar/Stellar Magnetic Fields and Cycles

Meridional flow is crucial in generating the solar poloidal magnetic field by facilitating poleward transport of the field from decayed bipolar magnetic regions (BMRs). As the meridional circulation changes with the stellar rotation rate, the properties of stellar magnetic cycles are expected to be influenced by this flow. In this study, we explore the role of meridional flow in generating magnetic fields in the Sun and Sun-like stars using the STABLE (surface flux transport and Babcock–Leighton) dynamo model. We find that a moderate meridional flow increases the polar field by efficiently driving the trailing polarity flux toward the pole, while a strong flow tends to transport both polarities of BMRs poleward, potentially reducing the polar field. Our findings are in perfect agreement with what one can expect from the surface flux transport model. Similarly, the toroidal field initially increases with moderate flow speeds and then decreases beyond a certain value. This trend is due to the competitive effects of shearing and diffusion. Furthermore, our study highlights the impact of meridional flow on the strength and duration of stellar cycles. By including the meridional flow from a mean-field hydrodynamics model in STABLE, we show that the magnetic field strength initially increases with the stellar rotation rate and then declines in rapidly rotating stars, offering an explanation of the observed variation of stellar magnetic field with rotation rate.

Composition and temperature dependent remanent polarization and coercive field in wurtzite AlScN ferroelectric memory materials

Composition and temperature dependent remanent polarization and coercive field in wurtzite AlScN ferroelectric memory materials

Mechanism of Circular Polarization in Giant Pulses and Fast Radio Bursts

Some giant pulses and fast radio bursts (FRBs) exhibit notable circular polarization, which remains unexplained and carries significant implications for their emission mechanisms. In this study, we identify multiple nanoshot pairs uniformly spaced by approximately 21 μs within a giant pulse emitted by the Crab pulsar. Among these pairs, a subset displays left-hand and right-hand circular polarization in two distinct nanoshots. We propose that the occurrence of such nanoshot pairs with dual circular polarizations arises from the fragmentation of a linearly polarized nanoshot along the magnetic field lines under the extreme Faraday effect, leveraging highly asymmetrical pair plasma and the ultra-intense field of nanoshots. The asymmetry in pair plasmas is likely linked to discharge activities in pulsars. Moreover, the intense field of nanoshots induces cyclotron resonance within the magnetosphere, effectively slowing down the propagation velocity of the circularly polarized mode. Our findings suggest that Crab giant pulses composing nanoshots originate in its polar cap region and escape the magnetosphere along the polar magnetic field. This mechanism can also elucidate the origin of circular polarization in some FRBs and thus lends support to their magnetospheric origin.

Fabrication of hydrothermal PPKTP and its spontaneous parametric down-conversion characteristics

High-voltage electric field polarization, selective corrosion, current monitoring, and other methods are used to develop hydrothermal PPKTP. It is found that the reversal domain nucleation of hydrothermal-grown KTP crystals has four kinds of microscopic morphology, namely, strip shape, spindle shape, bullet shape and irregular shape, in the process of high voltage electric field polarization. Compared with the leakage current in the process of polarization of flux-grown KTP crystals, the hydrothermal-grown KTP crystals only exist when the applied electric field is much larger than the coercive field. The leakage current can be suppressed by multiple loading of short pulses, and the PPKTP with a poled period of 10 μm and 46 μm were fabricated, respectively. Subsequently, based on the fabricated PPKTP, the SPDC characteristics are studied. To the PPKTP with a poled period of 10 μm, the quantum entanglement source whose brightness exceeds 2.1 kHz @ 810 nm is prepared by the SPDC technique. Otherwise, the PPKTP with a poled period of 46 μm is used for SPDC, and the brightness of entangled photon pairs in channel 1 and channel 2 are 3.21 kHz @ 1560 nm and 5.31 kHz @ 1560 nm, respectively.

The relationship between chlorophyll fluorescence and polarized light field: Polarization-Curve Fluorescence Height

The impact of the un-polarized nature of chlorophyll fluorescence, which causes a dip in the degree of polarization of the underwater light field matching the fluorescence spectrum, led to the development of a theoretical relationship indicating that the resulting fractional reduction in observed polarization is linearly proportional to the magnitude of the fluorescence causing it. To evaluate this relationship, we used a vector radiative transfer code (VRTE) for the coupled atmosphere-ocean system using measured inherent optical properties (IOPs) for a variety of oligotrophic and eutrophic waters as inputs. The VRTE was used to simulate elastic components of the underwater reflectance as well as the degree of linear polarization (DoLP) for these different conditions. These values were compared with the underwater reflectances and the DoLPs measured by a multi-angular hyperspectral polarimeter to determine the magnitude of the fluorescence component in the reflectance spectra at 685 nm, and the decrease of the DoLP due to the fluorescence impact at the same wavelength. Fluorescence magnitudes retrieved from the differences between simulated and measured reflectances were found to match well the magnitudes estimated through the relationship based on the drop of the DoLP. It is noted that retrieval accuracies increase for both larger fluorescence and larger underlying DoLP values. Furthermore, a new method is evolved from the measured polarization analysis, Polarization-Curve Fluorescence Height (PCFH). Measured polarization were used to approximate the elastic signal and derive the inelastic un-polarized signal (fluorescence) from the difference in the fluorescence vicinity. These results open possibilities for estimating the magnitude of natural fluorescence using polarization measurements below or above the water surface, .in-situ, or remotely from aircraft or future satellites. Results of ongoing work on potential sensitivities and retrieval accuracies for these applications will be reported.

Internal quantum efficiency improvement of InGaN-based red LED by using double V-pits layers as strain relief layer

Micro/mini light emitting diodes (LEDs) based on AlInGaN material system have vast potential in display applications. Nevertheless, the low internal quantum efficiency (IQE) of InGaN-based red LED limits its development and application. In the epitaxial structure of our designed red LED, double V-pits layers were used as strain relief layers to reduce compressive strain and improve the IQE of the active layer. First, InGaN/GaN superlattices (SLs) were grown below the active layer to form low-density large V-pits layer. Subsequently, multi-period green and red composite quantum wells were adopted as the active layer. A high-density small V-pits layer was introduced into the active region to release the compressive strain by adjusting the growth parameters of green multiple quantum wells (MQWs). The V-shaped pits divide the continuous large-area of active layer into mutually isolated small pieces, which prevents the transmission of strain and converts the long-range strain into separated local strain. The peak IQEs of LED A2 with single V-pits layer and LED B4 with double V-pits layers were measured to be 10.5% at 613 nm and 21.5% at 612.1 nm, respectively. The IQE is greatly improved by 204.7%. The research results indicate that the double V-pits layers structure can alleviate the compressive strain of InGaN QWs more effectively, reduce the influence of piezoelectric polarization field, and improve the IQE.

Synergistic Interactions of Bulk Polarization and Built-In Electric Field Inducing 2D/2D S-Scheme Homojunction Toward Enhanced Photocatalytic Performance.

The rational design of S-scheme photocatalysts, achieved by serially integrating two different semiconductors, represents a promising strategy for efficient charge separation and amplified photocatalytic performance, yet it remains a challenge. Herein, ZnIn2S4 (ZIS) and oxygen-doped ZnIn2S4 (O-ZIS) nanosheets are chosen to construct a homojunction catalyst architecture. Theoretical simulations alongside comprehensive in situ and ex situ characterizations confirm that ZIS and O-ZIS with noncentrosymmetric layered structures can generate a polarization-induced bulk-internal electric field (IEF) within the crystal. A robust interface-IEF is also created by the strong interfacial interaction between O-ZIS and ZIS with different work functions. Owing to these features, the O-ZIS/ZIS homojunction adopts an S-scheme directional charge transfer route, wherein photoexcited electrons in ZIS and holes in O-ZIS concurrently migrate to their interface and subsequently recombine. This enables spatial charge separation and provides a high driving force for both reduction and oxidation reactions simultaneously. Consequently, such photocatalyst exhibits an H2 evolution rate up to 142.9µmol h-1 without any cocatalysts, which is 4.6- and 3.4-fold higher than that of pristine ZIS and O-ZIS, respectively. Benzaldehyde is also produced as a value-added oxidation product with a rate of 146.9µmol h-1. This work offers a new perspective on the design of S-scheme systems.

Mechanically activated and deactivated ion transport across nanopores with heterogeneous surface charge distributions

To mimic the intricate and adaptive functionalities of biological ion channels, electrohydrodynamic ion transport has been studied extensively, albeit mostly, across uniformly charged nanochannels. Here, we analyze the ion transport under coupled electric field and pressure across heterogeneously charged nanopores with oppositely charged sections on their lateral surface. We only consider such pores with symmetric hourglass-like and cylindrical shapes to focus on the effects of the non-uniform surface charge distribution. Finite-element simulations of a continuum model demonstrate that a pressure applied in either direction of the pore-axis equally suppresses or amplifies the ionic conductance, depending on the electric field polarity, by distorting the quasi-static distribution of ions in the pore. The resulting anomalous mechanical deactivation and activation of ionic current under opposite voltage biases exhibit the functional modularity of our setup, while their intensities are highly tunable, substantially greater than those of analogous behaviors in other nanochannels, and fundamentally correlated to ionic current rectification (ICR) in our pores. A detailed study of ICR subsequently reveals its counterintuitive non-monotonous variations, in the pores, with the magnitude of applied voltage and the pore length, that can help optimize their diode-like behavior. We further illustrate that while the hourglass-shaped nanopores yield the more efficient mechanical suppressors of ion transport, their cylindrical analogs are the superior rectifiers and mechanical amplifiers of ion conduction. Therefore, this article provides a blueprint for the strategic design of nanofluidic circuits to attain a robust, modular, and tunable control of ion transport under external electrical and mechanical stimuli.

Favorable Conditions for Heavy Element Nucleosynthesis in Rotating Protomagnetar Winds

The neutrino-driven wind cooling phase of proto-neutron stars (PNSs) follows successful supernovae. Wind models without magnetic fields or rotation fail to achieve the necessary conditions for production of the third r-process peak, but robustly produce a weak r-process in neutron-rich winds. Using 2D magnetohydrodynamic simulations with magnetar-strength magnetic fields and rotation, we show that the PNS rotation rate significantly affects the thermodynamic conditions of the wind. We show that high-entropy material is quasiperiodically ejected from the closed zone of the PNS magnetosphere with the required thermodynamic conditions to produce heavy elements. We show that maximum entropy S of the material ejected depends systematically on the magnetar spin period P ⋆ and scales as S∝P⋆−5/6 for sufficiently rapid rotation. We present results from simulations at a constant neutrino luminosity representative of ∼1–2 s after the onset of cooling for P ⋆ ranging from 5–200 ms and a few simulations with evolving neutrino luminosity where we follow the evolution of the magnetar wind until 10–14 s after the onset of cooling. We estimate at magnetar polar magnetic field strength B 0 = 3 × 1015 G and 1015 G that neutron-rich magnetar winds can, respectively, produce at least ∼1–5 × 10−5 M ⊙ and ∼1–4 × 10−7 M ⊙ of material with the required parameters for synthesis of the third r-process peak, within 1–2 s and 10 s, respectively, in that order after the onset of cooling. We show that proton-rich magnetar winds can have favorable conditions for production of p-nuclei, even at a modest B 0 = 5 × 1014 G.

Photo-induced BiVO4 to produce P25-like structure for enhancing piezo-photocatalytic activity

Piezo-photocatalysis is considered a promising pollutant treatment strategy. Herein, a simple strategy is proposed to construct lattice distortion in BiVO4 to realize an efficient piezo-photocatalytic degradation process. Specifically, the phase structure of BiVO4 is regulated by introducing different wavelengths of illumination, resulting in the homojunction formation. Compared with BiVO4 prepared under dark conditions (BVO), the VO bonds are shortened and the BiO bonds are elongated in the structure of BiVO4 synthesized under 460 nm illumination (BVO-460). Furthermore, the Tafel curve reveals that electrons flow from the monoclinic phase to the tetragonal phase. By the tetracycline hydrochloride degradation, it is found that the BVO-460 has excellent piezo-photocatalytic efficiency, attributed to the piezoelectric polarization field enhanced charge transfer. In this paper, the piezo-photocatalytic performance of BiVO4 is investigated in the insight of crystal phase structure, which provided a new idea for the application of layered bismuth-based materials in environmental purification.