AbstractHigh‐frequency heating processes are widely used in industry, for example, for food processing, wood drying, or plastic welding. A recent development in this field uses radio‐frequency heating to fuse particle foam beads to complex components. The aim of using the modified process is to reduce the energy consumption of particle foam fusion. Within this process, the molds used must be electrically insulating to ensure the building of an electrical field. For this purpose, mold made of two different plastics were analyzed. Additional to the dielectric, mechanical, and thermal expansion, the thermal conductivity of the mold materials are of great interest. Although welding is finished quickly, cooling to the demolding temperature is comparably long. To achieve shorter cooling and therefore shorter process times, the mold materials were modified by two different thermal conductive but electrically insulating fillers. By the use of the thermally optimized mold materials, a reduction in cooling time of up to 40% was possible. At the same time, the heating step was hardly affected. Mechanical properties were enhanced while thermal expansion was reduced.