Plasmonic Nanoaperture Research Articles

Resonant optical trapping of Janus nanoparticles in plasmonic nanoaperture

Controlled trapping of light-absorbing nanoparticles with low-power optical tweezers is crucial for remote manipulation of small objects. This study takes advantage of the synergetic effects of tightly confined local fields of plasmonic nanoaperture, self-induced back-action (SIBA) of nanoparticles, and resonant optical trapping method to demonstrate enhanced manipulation of Janus nanoparticles in metallic nanohole aperture. We theoretically demonstrate that displacement of Au-coated Janus nanoparticles toward plasmonic nanoaperture and proper orientation of the metal coating give rise to enhanced near-field intensity and pronounced optical force. We also explore the effect of resonant optical trapping by employing a dual-laser system, where an on-resonant green laser excites the metal-coated nanoparticle, whereas an off-resonant near-infrared laser plays trapping role. It is found that, at the optimum nanoparticle configuration, the resonant optical trapping technique can result in threefold enhancement of optical force, which is attributed to the excitation of surface plasmon resonance in Janus nanoparticles. The findings of this study might pave the way for low-power optical manipulation of light-absorbing nanoparticles with possible applications in nanorobotics and drug delivery.

Mirror-Enhanced Plasmonic Nanoaperture for Ultrahigh Optical Force Generation with Minimal Heat Generation.

Double Nanohole Plasmonic Tweezers (DNH) have emerged as a powerful approach for confining light to sub-wavelength volume, enabling the trapping of nanoscale particles much smaller than the wavelength of light. However, to circumvent plasmonic heating effects, DNH tweezers are typically operated off-resonance, resulting in reduced optical forces and field enhancements. In this study, we introduce a novel DNH design with a reflector layer, enabling on-resonance illumination while minimizing plasmonic heating. This design efficiently dissipates heat and redistributes the electromagnetic hotspots, making them more accessible for trapping nanoscale particles and enhancing light-matter interactions. We also demonstrate low-power trapping and release of small extracellular vesicles. Our work opens new possibilities for trapping-assisted Surface Enhanced Raman Spectroscopy (SERS), plasmon-enhanced imaging, and single photon emission applications that demand strong light-matter interactions.

Single-Exosome Counting and 3D, Subdiffraction Limit Localization Using Dynamic Plasmonic Nanoaperture Label-Free Imaging.

Blood-circulating exosomes as a disease biomarker have great potential in clinical applications as they contain molecular information about their parental cells. However, label-free characterization of exosomes is challenging due to their small size. Without labeling, exosomes are virtually indistinguishable from other entities of similar size. Over recent years, several techniques have been developed to overcome the existing challenges. This paper demonstrates a new label-free approach based on dynamic PlAsmonic NanO-apeRture lAbel-free iMAging (D-PANORAMA), a bright-field technique implemented on arrayed gold nanodisks on invisible substrates (AGNIS). PANORAMA provides high surface sensitivity and has been shown to count single 25 nm polystyrene beads (PSB) previously. Herein, we show that using the dynamic imaging mode, D-PANORAMA can yield 3-dimensional, sub-diffraction limited localization of individual 25 nm beads. Furthermore, we demonstrate D-PANORAMA's capability to size, count, and localize the 3-dimensional, sub-diffraction limited position of individual exosomes as they bind to the AGNIS surface. We emphasize the importance of both the in-plane and out-of-plane localization, which exploit the synergy of 2-dimensional imaging and the intensity contrast.

Plasmon mediated extra-ordinary optical transmission through an apertureless plasmonic metagrating

Extra-ordinary optical transmission (EOT) through subwavelength plasmonic nanoapertures is possible due to the funneling of light via surface plasmons (SPs) at the resonant wavelengths through the apertures. In this Letter, we experimentally demonstrate EOT through a plasmonic metagrating which does not have any open apertures. The plasmonic metagrating was fabricated by deposition of silver (Ag) on a one-dimensionally patterned flexible and transparent polydimethylsiloxane grating obtained via pattern imprinting and subsequent peeling off a commercially available blue ray disk. For normal incidence of transverse magnetic-polarized light on the top surface of plasmonic metagrating, transmission of light through it was obtained in the visible wavelength range of electromagnetic spectrum. Control experiments on variation of Ag film thickness were performed to attain optimal parameters for maximum transmission, followed by polarization and refractive index (RI) dependent performance of the plasmonic metagrating. Electric fields and Poynting vector profiles were simulated using a finite element method to explain the interaction of light with the plasmonic metagrating and the mechanism of plasmon mediated optical transmission. Such a large optical transmission is possible because the SP modes generated at metal–air interface penetrate through metagrating and couple with those supported by the metal–substrate interface. As a model application, RI sensing using the plasmonic metagrating was demonstrated. The present study shows that optical transmission is possible from apertureless structures and enriches literature with better understanding of EOT. Moreover, it opens avenues for development of flexible, cost-effective plasmonic metagratings for sensors, spectral filters, polarizers, etc.

Enhancement of pattern quality in maskless plasmonic lithography via spatial loss modulation

Plasmonic lithography, which uses the evanescent electromagnetic (EM) fields to generate image beyond the diffraction limit, has been successfully demonstrated as an alternative lithographic technology for creating sub-10 nm patterns. However, the obtained photoresist pattern contour in general exhibits a very poor fidelity due to the near-field optical proximity effect (OPE), which is far below the minimum requirement for nanofabrication. Understanding the near-field OPE formation mechanism is important to minimize its impact on nanodevice fabrication and improve its lithographic performance. In this work, a point-spread function (PSF) generated by a plasmonic bowtie-shaped nanoaperture (BNA) is employed to quantify the photon-beam deposited energy in the near-field patterning process. The achievable resolution of plasmonic lithography has successfully been enhanced to approximately 4 nm with numerical simulations. A field enhancement factor (F) as a function of gap size is defined to quantitatively evaluate the strong near-field enhancement effect excited by a plasmonic BNA, which also reveals that the high enhancement of the evanescent field is due to the strong resonant coupling between the plasmonic waveguide and the surface plasmon waves (SPWs). However, based on an investigation of the physical origin of the near-field OPE, and the theoretical calculations and simulation results indicate that the evanescent-field-induced rapid loss of high-k information is one of the main optical contributors to the near-field OPE. Furthermore, an analytic formula is introduced to quantitatively analyze the effect of the rapidly decaying feature of the evanescent field on the final exposure pattern profile. Notably, a fast and effective optimization method based on the compensation principle of the exposure dose is proposed to reduce the pattern distortion by modulating the exposure map with dose leveling. The proposed pattern quality enhancement method can open new possibilities in the manufacture of nanostructures with ultrahigh pattern quality via plasmonic lithography, which would find potentially promising applications in high density optical storage, biosensors, and plasmonic nanofocusing.

Complex 10-nm resolution nanogap and nanowire geometries for plasmonic metasurface miniaturization.

Emerging electromagnetic inverse design methods have pushed nanofabrication methods to their limits to extract maximum performance from plasmonic aperture-based metasurfaces. Using plasmonic metamaterial-lined apertures as an example, we demonstrate the importance of fine nanowire and nanogap features for achieving strong miniaturization of plasmonic nanoapertures. Metamaterial-lined nanoapertures are miniaturized over bowtie nanoapertures with identical minimum feature sizes by a factor of 25% without loss of field enhancement. We show that features as small as 10 nm can be reliably patterned over the wide areas required of metasurfaces using the helium focused ion beam microscope. Under imperfect fabrication conditions, we achieve 11-nm-wide nanogaps and 12-nm-wide nanowires over an area of 13 µm2, and successfully validate our results with optical characterization and comparable full-wave simulations.

Superchiral hotspot enhanced circular dichroism in coaxial plasmonic nanoaperture

Circular dichroism (CD) spectroscopic is a common method to identify the chirality of molecules, which is a powerful tool in the field of chemistry, biology, and life sciences. However, chiral sample with high density is required since the weak chirality of natural materials would give rise to weak CD signals. In this work, we theoretically studied the superchiral light–matter interaction in axially symmetric coaxial plasmonic nanoaperture (CPN) structure. Under the illumination of circularly polarized light, the interplay of enhanced E- and H-fields would lead to the generation of superchiral localized hotspot in the annular gap of the CPN structure. By placing chiral molecules near the hotspot, the CD signal can be significantly enhanced. The origin of the enhanced CD effect is attributed to the inherent CD signals of the chiral molecules and the background absorption is negligible. With the reduced annular gap of 5 nm, the volume-averaged chirality of the localized hotspot can be further increased up to 143-fold, leading to the improved CD enhancement factor of 71-fold. This finding paves the way towards the development of practical and scalable platforms for new chiroptical applications.

FIB-milled plasmonic nanoapertures allow for long trapping times of individual proteins

SummaryWe have developed a fabrication methodology for label-free optical trapping of individual nanobeads and proteins in inverted-bowtie-shaped plasmonic gold nanopores. Arrays of these nanoapertures can be reliably produced using focused ion beam (FIB) milling with gap sizes of 10–20 nm, single-nanometer variation, and with a remarkable stability that allows for repeated use. We employ an optical readout where the presence of the protein entering the trap is marked by an increase in the transmission of light through the nanoaperture from the shift of the plasmonic resonance. In addition, the optical trapping force of the plasmonic nanopores allows 20-nm polystyrene beads and proteins, such as beta-amylase and Heat Shock Protein (HSP90), to be trapped for very long times (approximately minutes). On demand, we can release the trapped molecule for another protein to be interrogated. Our work opens up new routes to acquire information on the conformation and dynamics of individual proteins.

Purcell radiative rate enhancement of label-free proteins with ultraviolet aluminum plasmonics

The vast majority of proteins are intrinsically fluorescent in the ultraviolet, thanks to the emission from their tryptophan and tyrosine amino-acid constituents. However, the protein autofluorescence quantum yields are generally very low due to the prevailing quenching mechanisms by other amino acids inside the protein. This motivates the interest to enhance the radiative emission rate of proteins using nanophotonic structures. Although there have been numerous reports of Purcell effect and local density of optical states control in the visible range using single dipole quantum emitters, the question remains open to apply these concepts in the UV on real proteins containing several tryptophan and tyrosine amino acids arranged in a highly complex manner. Here, we report the first complete characterization of the Purcell effect and radiative rate enhancement for the UV intrinsic fluorescence of label-free β-galactosidase and streptavidin proteins in plasmonic aluminum nanoapertures. We find an excellent agreement with a calibration performed using a high quantum yield UV fluorescent dye. Demonstrating and intensifying the Purcell effect is essential for the applications of UV plasmonics and the label-free detection of single proteins.

Fabrication of Plasmonic Nano-Aperture Platform for Singe-Molecule Detection and Self-Cooling Thermal Emission

In this report, the optical emission characteristics from the nano-apertures on the Au nano-plasmonic platform will be reported. Regardless of the nano-aperture type of either circular type or nanoslit type, the spp-mediated optical emission characteristics dependent upon the sample thickness and aperture size are observed. However, the spp mediated optical characteristics are found to be increasing with decreasing the aperture size, and to be independent of the nano-aperture shape, which observation fits to Lord Raleigh’s diffraction theory of small particle with its size much smaller than the wavelength and Babinet principle. The fabricated nanometer slit arrays with its size of (~10 nm width and ~ 300 nm length) with its optical characterization are provided in Figure 1. The fabricated platform device can be utilized as various applications such as plasmonic single molecule sensors and plasmomic self- cooling device from its broad emission spectra from visible to infrared regime. Figure 1

Enhancing Single-Molecule Fluorescence Spectroscopy with Simple and Robust Hybrid Nanoapertures.

Plasmonic nanoapertures have found exciting applications in optical sensing, spectroscopy, imaging, and nanomanipulation. The subdiffraction optical field localization, reduced detection volume (~attoliters), and background-free operation make them particularly attractive for single-particle and single-molecule studies. However, in contrast to the high field enhancements by traditional "nanoantenna"-based structures, small field enhancement in conventional nanoapertures results in weak light-matter interactions and thus small enhancement of spectroscopic signals (such as fluorescence and Raman signals) of the analytes interacting with the nanoapertures. In this work, we propose a hybrid nanoaperture design termed "gold-nanoislands-embedded nanoaperture" (AuNIs-e-NA), which provides multiple electromagnetic "hotspots" within the nanoaperture to achieve field enhancements of up to 4000. The AuNIs-e-NA was able to improve the fluorescence signals by more than 2 orders of magnitude with respect to a conventional nanoaperture. With simple design and easy fabrication, along with strong signal enhancements and operability over variable light wavelengths and polarizations, the AuNIs-e-NA will serve as a robust platform for surface-enhanced optical sensing, imaging, and spectroscopy.

Photonic-plasmonic mode coupling in nanopillar Ge-on-Si PIN photodiodes

Incorporating group IV photonic nanostructures within active top-illuminated photonic devices often requires light-transmissive contact schemes. In this context, plasmonic nanoapertures in metallic films can not only be realized using CMOS compatible metals and processes, they can also serve to influence the wavelength-dependent device responsivities. Here, we investigate crescent-shaped nanoapertures in close proximity to Ge-on-Si PIN nanopillar photodetectors both in simulation and experiment. In our geometries, the absorption within the devices is mainly shaped by the absorption characteristics of the vertical semiconductor nanopillar structures (leaky waveguide modes). The plasmonic resonances can be used to influence how incident light couples into the leaky modes within the nanopillars. Our results can serve as a starting point to selectively tune our device geometries for applications in spectroscopy or refractive index sensing.

Plasmonic fork-shaped hologram for vortex-beam generation and separation.

We introduce a multifunctional compact device that integrates a polarization beam splitter and an orbital angular momentum generator based on a plasmonic nano-aperture assisted detour phase meta-hologram. The proposed metasurface, which combines a phase singularity characterized fork hologram and polarization featured Λ-shaped antenna, achieves vortex generation and spin-based vortex splitting in transmission mode. Experimental demonstrations are launched under a linearly polarized incident beam, with polarization tomography as the analysis method. We expect this work to have applications in chip-level beam shaping and high-capacity communication.

Phase singularity annihilation in plasmonic nano-apertures via epsilon-near-zero metamaterials

In this work, we performed an extensive theoretical and experimental study to unveil the underlying mechanisms related to the intensified transmittance in epsilon-near-zero (ENZ)-integrated plasmonic nano-apertures. The occurrence of phase singularities at the incident side of plasmonic nano-apertures results in the reduction in transmittance. We show that transmittance enhancement in ENZ-integrated nano-slits is attributed to the annihilation of the phase singularities by the ENZ layer and subsequently the modification in plasmonic fields of metallic apertures. The singularity annihilation via ENZ metamaterials eliminates the abrupt changes in the phase of the Poynting vector underneath the slit, which results in a stronger cavity resonance inside the aperture. Due to this fact, a nano-aperture on top of an ENZ metamaterial is the only effective configuration to enhance the transmittance in ENZ-integrated nano-apertures. Hence, our study reveals the physics of the transmittance enhancement through ENZ-integrated plasmonic nano-apertures.

Fast and efficient nanoparticle trapping using plasmonic connected nanoring apertures

The manipulation of microparticles using optical forces has led to many applications in the life and physical sciences. To extend optical trapping towards the nano-regime, in this work we demonstrate trapping of single nanoparticles in arrays of plasmonic coaxial nano-apertures with various inner disk sizes and theoretically estimate the associated forces. A high normalized experimental trap stiffness of 3.50 fN nm−1 mW−1 μm−2 for 20 nm polystyrene particles is observed for an optimum design of 149 nm for the nanodisk diameter at a trapping wavelength of 980 nm. Theoretical simulations are used to interpret the enhancement of the observed trap stiffness. A quick particle trapping time of less than 8 s is obtained at a concentration of 14 × 1011 particles ml−1 with low incident laser intensity of 0.59 mW μm−2. This good trapping performance with fast delivery of nanoparticles to multiple trapping sites emerges from a combination of the enhanced electromagnetic near-field and spatial temperature increase. This work has applications in nanoparticle delivery and trapping with high accuracy, and bridges the gap between optical manipulation and nanofluidics.

Spin‐Symmetry‐Selective Generation of Ultracompact Optical Vortices in Nanoapertures without Chirality

Nanoscale optical vortices (OVs) carrying orbital angular momenta can be generated via photonic spin–orbit interaction (SOI) in nanostructures and have important applications in many emerging fields such as quantum communication and optical manipulations. Existing OV generators such as metasurfaces and chiral structures suffer from discontinuous wavefront modulation, single‐spin response, and bulk size. The photonic SOI in highly symmetric structures has been overlooked. Furthermore, there is no experimental study on the near‐field formation mechanism of nanoscale OVs. Here, by studying the SOI in a plasmonic annular nanoaperture, a simple and reliable way for generating ultracompact OVs and OV array in nanoapertures without chirality is reported. The generation of a 3 × 3 OV array within a small area of 6 × 6 μm2 is demonstrated experimentally. Using a homemade spin‐selective and phase‐resolved near‐field microscopic system, in the spin basis, the dynamic evolution of the wavefront of the generated OV is directly probed from the near field to the far field with subwavelength resolution, which intuitively reveals the SOI process. The findings provide a simple and effective solution for large‐scale, low‐cost OV beam generation and offer a powerful tool for experimental exploration of the nanoscale photonic SOI.

Extraordinary optical transmission and second harmonic generation in sub–10-nm plasmonic coaxial aperture

Abstract Recent development in nanofabrication technology has enabled the fabrication of plasmonic nanoapertures that can provide strong field concentrations beyond the diffraction limit. Further utilization of plasmonic nanoaperture requires the broadband tuning of the operating wavelength and precise control of aperture geometry. Here, we present a novel plasmonic coaxial aperture that can support resonant extraordinary optical transmission (EOT) with a peak transmittance of ~10% and a wide tuning range over a few hundred nanometers. Because of the shadow deposition process, we could precisely control the gap size of the coaxial aperture down to the sub–10-nm scale. The plasmonic resonance of the SiNx/Au disk at the center of the coaxial aperture efficiently funnels the incident light into the sub–10-nm gap and allows strong electric field confinement for efficient second harmonic generation (SHG), as well as EOT. In addition to the experiment, we theoretically investigated the modal properties of the plasmonic coaxial aperture depending on the structural parameters and correlation between EOT and SHG through finite-difference time-domain simulations. We believe that our plasmonic coaxial apertures, which are readily fabricated by the nanoimprinting process, can be a versatile, practical platform for enhanced light–matter interaction and its nonlinear optical applications.

Correction to “Direct Particle Tracking Observation and Brownian Dynamics Simulations of a Single Nanoparticle Optically Trapped by a Plasmonic Nanoaperture”

ADVERTISEMENT RETURN TO ISSUEPREVAdditions and Correc...Additions and CorrectionsNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to “Direct Particle Tracking Observation and Brownian Dynamics Simulations of a Single Nanoparticle Optically Trapped by a Plasmonic Nanoaperture”Zhe XuZhe XuMore by Zhe Xu, Wuzhou SongWuzhou SongMore by Wuzhou Song, and Kenneth B. Crozier*Kenneth B. CrozierMore by Kenneth B. Crozierhttp://orcid.org/0000-0003-0947-001XCite this: ACS Photonics 2020, 7, 4, 1076–1077Publication Date (Web):March 26, 2020Publication History Received13 March 2020Published online26 March 2020Published inissue 15 April 2020https://doi.org/10.1021/acsphotonics.0c00408Copyright © 2020 American Chemical SocietyRIGHTS & PERMISSIONSArticle Views633Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-AlertsSUBJECTS:Stiffness,Plasmonic nanoparticles,Fluorescence,Nanoparticles,Optical trapping Get e-Alerts

Algorithmic approach for designing plasmonic nanotweezers.

We use machine learning (simulated annealing) to design plasmonic nanoapertures that function as optical nanotweezers. The nanoapertures have irregular shapes that are chosen by our algorithm. We present electromagnetic simulations that show that these produce stronger field enhancements and extraction energies than nanoapertures comprising double nanoholes with the same gap geometry. We show that performance is further improved by etching one or more rings into the gold surrounding the nanoaperture. Lastly, we provide a direct comparison between our design and work that is representative of the state of the art in plasmonic nanotweezers at the time of writing.

Temperature Measurement in Plasmonic Nanoapertures Used for Optical Trapping

Plasmonic nanoapertures generate strong field gradients enabling efficient optical trapping of nano-objects. However, because the infrared laser used for trapping is also partly absorbed into the metal leading to Joule heating, plasmonic nano-optical tweezers face the issue of local temperature increase. Here, we develop three independent methods based on molecular fluorescence to quantify the temperature increase induced by a 1064 nm trapping beam focused on single and double nanoholes milled in gold films. We show that the temperature in the nanohole can be increased by 10{\deg}C even at the moderate intensities of 2 mW/$\mu$m$^2$ used for nano-optical trapping. The temperature gain is found to be largely governed by the Ohmic losses into the metal layer, independently of the aperture size, double-nanohole gap or laser polarization. The techniques developed therein can be readily extended to other structures to improve our understanding of nano-optical tweezers and explore heat-controlled chemical reactions in nanoapertures.