Plasmon Absorption Research Articles

A Tunable Plasmonic Perfect Absorber based on Graphene and Two Metal-insulator Substructures

Background: In recent decades, numerous researchers have been keenly interested in plasmonic absorbers due to their efficiency in a variety of applications such as solar cells. This is because the surface plasmons formed at the interface between metal and insulators interact strongly with light, thereby augmenting electromagnetic (EM) waves. In most cases, plasmonic absorbers featuring metal-insulated-metal structure (MIM) are favored for their robust absorption rates, straightforward fabrication process, minuscule size, and portability. Methods: This paper proposes a tunable plasmonic perfect absorber (PPA) based on graphene and two metal-insulator substructure within the 28-60 μm wavelength range. This device is simulated by 3D finite element analysis using CST software. Also, in our proposed structure, instead of using a single micro-blade, two micro-blades are arranged opposite of each other in the absorber structure through which the electric field is locally strengthened and a sharper resonance peak with greater amplitude is obtained. Results: Simulation results demonstrate that a resonance peak is observable in the absorption spectrum of the structure and that this peak can be shifted between 30μm and 40μm by applying a gate bias voltage to the graphene nanolayer without modification of the structure's dimensions. Conclusion: The features of this absorber make it suitable for sensor applications, which will be further explored in future research. We also investigated the influence of dimensions on absorption to take into account the allowable tolerances and sensitivities associated with its fabrication. Furthermore, we proposed a structure that can enhance absorber performance in the future.

Morphological effect on Core@shell AuAg nanoparticles for detecting p‐aminothiophenol dimerization by surface‐enhanced Raman spectroscopy

AbstractA series of non‐spherical metallic Au and bimetallic core@shell AuAg nanoparticles (NPs) have been synthesized for SERS improvements. The bimetallic core@shell AuAg NPs were obtained through a controlled overgrowth of an Ag shell onto the surface of two types of non‐spherical Au NPs, used as seeds, Au nanooctaheda (Au NOc) and Au nanotriangles (Au NTs). This Ag overgrowth was able to produce bimetallic core@shell structures such as nanocubes and nanopyramids, respectively. Transmission electron microscopy (TEM) was used to determine the particle size and particle morphology for metallic and bimetallic NPs, and energy‐dispersive X‐ray (EDX) elemental mapping analysis confirmed the core@shell structure of the bimetallic NPs. The plasmonic absorption bands exhibited for each nanosystem were observed by UV–vis spectroscopy. The concentration of Au and Ag in the bimetallic systems was determined by inductively coupled plasma mass spectrometry (ICP‐MS). After synthesis and characterization, p‐aminothiophenol (PATP) was used as a model analyte to investigate the surface‐enhanced Raman spectroscopy (SERS) capabilities of the synthesized metallic and bimetallic nanosystems. In PATP, a dimerization reaction to 4,4′‐dimercaptoazobenzene (DMAB) is produced when it is adsorbed onto the surface of certain noble metals. This SERS analysis was performed at 10−4 M of PATP and by using two different laser wavelengths (532 and 785 nm) in all cases. In this context, we were able to detect the dimerization reaction of PATP to DMAB only for the bimetallic structures and under the 532 nm laser line. Moreover, we have found that the dimerization capacity also depends on the nanoparticle morphology.

Fabrication of plasmonic junction diodes based on Ag@ZnO core-shell nanostructures

In this study, Ag nanoparticles and Ag@ZnO core–shell nanostructures were prepared using the wet chemical method and these nanostructures were used for Ag@ZnO/p-Si diode fabrication. Structural, morphological, and optical characterization techniques were applied for Ag@ZnO core–shell NPs prepared by using different molarity of precursor ZnCl2 (10 mM, 20 mM, 30 mM) and showed that the effect of increasing precursor amount on these physical properties of nanoparticles is important. For Ag@ZnO, transmission electron microscopy shows an average diameter of Ag nanoparticles was 51.32 nm and Ag@ZnO core–shell nanostructures were found to be between 31 and 92 nm. The UV-visible absorbance also shows significant plasmonic resonance for NPs, with a slight red shift increasing precursor molarity. The peaks are found to be from 412 nm to 432 nm. This redshift in surface plasmon absorption of Ag@ZnO core–shell structures are consistent with XPS survey. The current–voltage (I-V) characteristic curves of heterojunction diodes were taken in the dark and at room temperature, and it was observed that they showed a rectifying feature. Ideality factor and barrier height values have been found between 2.14 and 3.87, and 0.56 and 0.78, respectively. The results revealed that Ag@ZnO was successfully synthesized and can be used in rectification applications.

Synthesis and characterization of gold/nickel oxide nanoalloy via green laser irradiation

In the present study, a gold/nickel oxide (Au/NiO) nanoalloy was generated by irradiating two nano-metallic material solutions using a green laser. The produced Au/NiO nanocomposites were characterized by UV–Vis–NIR spectroscopy, an X-ray diffraction pattern, TEM and SEM imaging, and photoluminescence and DLS tests. Depending on the concentration of Au NPs in the suspension medium, the final characteristics of Au/NiO nanocomposites vary significantly. Au NPs exhibit an extremely high plasmonic absorption peak at approximately 530 nm. They melted by absorbing the energy of the second harmonic of the laser beam, forming an Au/NiO nanocomposite. Additionally, our results demonstrated that after irradiation with a green laser, the bandgap energy of samples was reduced to 5, 4.3, and 4 eV as the number of Au NPs in nanocomposite structures increased, indicating that the addition of gold to nickel oxide NPs improves their conductivity and reduces the bandgap energy of samples. Moreover, due to composition formation, the number and size of Au NPs dropped following green laser irradiation, while NiO NPs grew in size. This work created an AuNiO nanocomposite by laser ablation, which is a highly effective approach for fabricating nanostructures.

Polymeric optical fiber biosensor with PAMAM dendrimer-based surface modification and PlGF detection for pre-eclampsia diagnosis

Pre-eclampsia (PE) is a life-threatening complication that occurs during pregnancy, affecting a large number of pregnant women and newborns worldwide. Rapid, on-site and affordable screening of PE at an early stage is necessary to ensure timely treatment and minimize both maternal and neonatal morbidity and mortality rates. Placental growth factor (PlGF) is an angiogenic blood biomarker used for PE diagnosis. Herein, we report the plasmonic fiber optic absorbance biosensor (P-FAB) strategy for detecting PlGF at femtomolar concentration using polymethyl methacrylate (PMMA) based U-bent polymeric optical fiber (POF) sensor probes. A novel poly(amidoamine) (PAMAM) dendrimer based PMMA surface modification is established to obtain a greater immobilization of the bioreceptors compared to a linear molecule like hexamethylenediamine (HMDA). Plasmonic sandwich immunoassay was realized by immobilizing the mouse anti-PlGF (3H1) on the U-bent POF sensor probe surface and gold nanoparticles (AuNP) labels conjugated with mouse anti-PlGF (6H9). The POF sensor probes could measure PlGF within 30 min using the P-FAB strategy. The limit-of-detection (LoD) was found to be 0.19 pg/mL and 0.57 pg/mL in phosphate-buffered saline and 10× diluted serum, respectively. The clinical sample testing, with eleven positive and eleven negative preeclamptic pregnancy samples, successfully confirmed the accuracy, reliability, specificity, and sensitivity of the P-FAB based POF sensor platform, thereby paving the way for cost-effective technology for PlGF detection and its potential for pre-eclampsia diagnosis.

Plasmonic Au@Ag Core-Shell Nanoisland Film for Photothermal Inactivation and Surface-Enhanced Raman Scattering Detection of Bacteria.

Plasmonic metal nanomaterials have been extensively investigated for their utilizations in biomedical sensing and treatment. In this study, plasmonic Au@Ag core-shell nanoisland films (Au@AgNIFs) were successfully grown onto a glass substrate using a seed-mediated growth procedure. The nanostructure of the Au@AgNIFs was confirmed through scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and atomic force microscopy (AFM). The UV-Vis spectra of the Au@AgNIFs exhibited a broad absorption in the visible range from 300 to 800 nm because of the surface plasmon absorption. Under simulated sunlight exposure, the temperature of optimal Au@AgNIF was increased to be 66.9 °C to meet the requirement for photothermal bacterial eradication. Furthermore, the Au@AgNIFs demonstrated a consistent photothermal effect during the cyclic on/off exposure to light. For photothermal therapy, the Au@AgNIFs revealed superior efficiency in the photothermal eradication of Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). With their unique nanoisland nanostructure, the Au@AgNIFs exhibited excellent growth efficiency of bacteria in comparison with that of the bare glass substrate. The Au@AgNIFs were also validated as a surface-enhanced Raman scattering (SERS) substrate to amplify the Raman signals of E. coli and S. aureus. By integrating photothermal therapy and SERS detection, the Au@AgNIFs were revealed to be a potential platform for bacterial theranostics.

Plasmon-exciton interactions in ZnO/AuNPs heterostructure film for high photoconductivity

This study investigatesplasmon-exciton interactions within ZnO/AuNPs heterostructure films. Elemental, structural, and morphological analyses validate the successful formation of these films. The observed shift in the plasmonic resonance band and absorption edge otowards the red region the red region is attributed to strong surface plasmon damping influenced by exciton interactions within ZnO. Irradiation with blue light induces plasmonic electrons, generation in the ZnO/AuNPs film, enhancing electrical conductivity through interaction with ZnO excitonic states. UV light irradiating generates the electron-hole pair in the ZnO film and interacts with the free electrons in AuNPs. The ZnO/AuNPs heterostructure films hold promise for applications such as high-performance UV-photodetectors, photoactive layers in solar cells, light-emitting diodes, and energy storage devices.

Multi-band THz plasmonic meta-surface absorber based on dual bias graphene disks: bio sensing application

Multi-band THz plasmonic meta-surface absorber based on dual bias graphene disks: bio sensing application

Ultra-broadband and wide-angle plasmonic absorber based on all-dielectric gallium arsenide pyramid nanostructure for full solar radiation spectrum range

Broadband and plasmonic absorbers (PAs) are key components for numerous applications in the fields of energy harvesting, thermal photonics, optoelectronic devices, and enhanced spectroscopy. In this work, we propose a simple and cost-effective metamaterial plasmonic absorber (MPA) design based on an all-dielectric GaAs pyramid nanostructure for the full solar radiation spectrum range. Simulation results demonstrate that the absorbance of the proposed MPA exceeds 85% in the full solar spectrum range, and it exceeds 90% from 0.25 μm to 3.1 μm with a relative bandwidth of approximately 170.74%, with an absorption peak up to 99% at resonance wavelength. The high absorption is attributed to the excitation of wave-guide mode, surface plasmon polariton (SPP) resonance modes combined with coupling effect and intrinsic lossy of dielectric GaAs and metallic tungsten (W). Furthermore, the proposed MPA is polarization-independent and wide incident angles for both transverse electric (TE) and transverse magnetic (TM) modes. Additionally, the MPA can tolerate certain structural parameter errors during practical fabrication applications. Furthermore, the photophysical properties of this MPA for solar cell applications are investigated, revealing the achievement of high short-circuit current density. Our proposed design is highly promising for applications in solar energy harvesting, thermoelectric, and thermal emitter applications.

Laser deposited ultra-thin silver nanoparticles on CMC-PVA blend film as sheet for wound dressings

In this study, silver nanoparticles (AgNPs) were synthesized using pulsed laser deposition and deposited on a sheet film composed of Carboxymethyl cellulose (CMC), polyvinyl alcohol (PVA), and AgNPs. These polymeric-based nano-composites were investigated for their potential application in wound healing. The structural properties of the composites were examined using X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). Morphological features were observed through field emission scanning electron microscopy (FESEM), and roughness characteristics were studied using FESEM micrographs. The CMC-PVA-AgNPs scaffolds with deposition times of 10 and 12.5 min showed minimal deviations in surface structure compared to the composites with longer deposition times, where scattered AgNPs and aggregates were observed. Furthermore, the roughness parameter (Ra) values indicated the potential of silver NPs in creating trapping sites and crystal defects, as evidenced by an increase in Ra from 18.96 nm in the pure CMC-PVA blend to 34.17 nm at a deposition time of 20 min. The optical properties of the composites were investigated by determining the band-gap of direct and indirect transition modes, which exhibited a decreasing trend. The presence of silver NPs was confirmed by the plasmon absorption band observed around 400 nm. The intensity of the plasmon peaks increased with longer laser deposition times, indicating an increase in the silver content over time. Finally, the antibacterial activity of the prepared scaffolds against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, and Micrococcusluteus was evaluated, and the results strongly support the potential of the prepared material for biological applications. In conclusion, the synthesized CMC-PVA-AgNPs nano-composites deposited using pulsed laser deposition technique exhibited promising properties for wound healing applications. The comprehensive characterization of the composites, including their structural, morphological, optical, and antibacterial properties, provides valuable insights for further research and development in the field of biomaterials.

Utilization of herbivore defensive latex from the weed Calotropis procera L in the green synthesis of silver nanoparticles and its potential application in the control of dengue vector Aedes aegypti

Milky latex produced by few and not all the plants are the treasure chest of various bioactive compounds with defensive potential against herbivores, insects and pathogens. Mankind have utilized latices in the preparation of novel plant-based therapies for centuries. Therefore, an attempt has been made to synthesis silver nanoparticles (AgNPs) using AgNO3 as a precursor and latex from C. procera as a reducing agent. The surface plasmon absorption peak at 430 nm confirmed AgNPs formation. The sharp peak with narrow width illustrated the homogenous nature. The face centre cubic structure of AgNPs was confirmed by the XRD pattern. FT-IR analysis deduced that the bio-molecules in the latex of C. procera are responsible for the reduction of AgNO3 to AgNPs. Biosynthesised L-AgNPs possessed well pronounced antibacterial activity against P. aeruginosa and K. pneumoniae. Anti-inflammatory activity of the nanoparticle determined by membrane stabilization and proteinase inhibitory assay was found to be in dose-dependent. LC50 value of L-AgNPs was found to be 63.09 µg/mL against IV instar larvae of A. aegypti. Distinct morphological changes were observed in the mosquito larva on exposure to various concentrations of L-AgNPs.

Development of silver nanoparticle-chitosan composite film for determination of total antioxidant capacity of some fruit juices and plant extracts

In this study, a silver nanoparticle-chitosan (AgNPCh) composite film was developed for the determination of antioxidant capacity of polyphenolic compounds. The optimum conditions of solid nanosensor based on chitosan-based polymeric membranes containing AgNPs such as content of the composite film, pH and incubation time were idendified. The sensor measurement is based on the fact that the addition of polyphenols to the sample solution increases the absorption of Ag(0) NPs, which exhibit a characteristic plasmon absorption band at a wavelength of 423 nm and the developed method exhibits a linear variation versus the concentrations standard polyphenolic compounds. The method was applied to the apple, peach, cherry, grape and pomegranate juices and rosemary, marjoram and sage plant extracts. This sensor may be an alternative to conventional spectroscopic methods to design portable, low-cost, simple and easy-to-use field analyses without the need for special equipment for the determination of antioxidant capacity of polyphenolic compounds.

Biosynthesis, characterization and study of the application of silver nanoparticle for 4-nitrophenol reduction, and antimicrobial activities

Silver nanoparticles (AgNPs) were synthesized from Vigna unguiculata (L) Walp extracted leaves, and characterized. The UV–Visible spectrum showed a peak between 411 and 415 nm at the Plasmon absorbance of the AgNPs. TEM showed that the size of AgNPs ranged from 5 to 13 nm. It was spherical with an average size of 11.08 nm. The size of AgNPs was 7 ± 6 nm and disperse in water. The AgNPs effectively reduced 4-Nitrophenol (4-NP) to 4-aminophenol (4-AP) in the presence of NaBH4. The AgNPs exhibited a strong antioxidant and antibacterial activity against Gram-negative bacteria: Escherichia coli (E. coli) and Klebsiella pneumonia and Gram-positive: Bacillus pumilus and Staphylococcus aureus. The average zones of inhibition of AgNPs were: 29 mm for Staphylococcus aureus, 23 mm for Bacillus pumilus, 17 mm for Klebsiella pneumonia and 15 mm for Escherichia coli (E. coli). Thus, AgNPs has exhibted good antibacterial activity compared to antibiotics drug and 4-NP reduction.

Ultrasensitive and Multiple Biomarker Discrimination for Alzheimer's Disease via Plasmonic & Microfluidic Sensing Technologies.

As the population ages, the worldwide prevalence of Alzheimer's disease (AD) as the most common dementia in the elderly is increasing dramatically. However, a long-term challenge is to achieve rapid and accurate early diagnosis of AD by detecting hallmarks such as amyloid beta (Aβ42). Here, a multi-channel microfluidic-based plasmonic fiber-optic biosensing platform is established for simultaneous detection and differentiation of multiple AD biomarkers. The platform is based on a gold-coated, highly-tilted fiber Bragg grating (TFBG) and a custom-developed microfluidics. TFBG excites a high-density, narrow-cladding-mode spectral comb that overlaps with the broad absorption of surface plasmons for high-precision interrogation, enabling ultrasensitive monitoring of analytes. In situ detection and in-parallel discrimination of different forms of Aβ42 in cerebrospinal fluid (CSF) are successfully demonstrated with a detection of limit in the range of ≈30-170 pg mL-1, which is one order of magnitude below the clinical cut-off level in AD onset, providing high detection sensitivity for early diagnosis of AD. The integration of the TFBG sensor with multi-channel microfluidics enables simultaneous detection of multiple biomarkers using sub-µL sample volumes, as well as combining initial binding rate and real-time response time to differentiate between multiple biomarkers in terms of binding kinetics. With the advantages of multi-parameter, low consumption, and highly sensitive detection, the sensor represents an urgently needed potentials for large-scale diagnosis of diseases at earlystage.

Absorption peak decomposition of an inhomogeneous nanoparticle ensemble of hexagonal tungsten bronzes using the reduced Mie scattering integration method

Recent optical analyses of cesium-doped hexagonal tungsten bronze have accurately replicated the absorption peak and identified both plasmonic and polaronic absorptions in the near-infrared region, which have been exploited in various technological applications. However, the absorption peaks of tungsten oxides and bronzes have not generally been reproduced well, including those of the homologous potassium- and rubidium-doped hexagonal tungsten bronzes that lacked evidence of polaronic subpeaks. The present study reports a modified and simplified Mie scattering integration method which incorporates the ensemble inhomogeneity effect and allows precise peak decomposition and determination of the physical parameters of nanoparticles. The decomposed peaks were interpreted in terms of electronic structures, screening effect, and modified dielectric functions. The analysis revealed that the plasma frequencies, polaron energies, and the number of oxygen vacancies decrease in the dopant order Cs → Rb → K. The coexistence of plasmonic and polaronic excitations was confirmed for all the alkali-doped hexagonal tungsten bronzes.

Progress of Mesoporous Silica Coated Gold Nanorods for Biological Imaging and Cancer Therapy.

For unique surface plasmon absorption and fluorescence characteristics, gold nanorods have been developed and widely employed in the biomedical field. However, limitations still exist due their low specific surface area, instability and tendency agglomerate in cytoplasm. Mesoporous silica materials have been broadly applied in field of catalysts, adsorbents, nanoreactors, and drug carriers due to its unique mesoporous structure, highly comparative surface area, good stability and biocompatibility. Therefore, coating gold nanorods with a dendritic mesopore channels can effectively prevent particle agglomeration, while increasing the specific surface area and drug loading efficiency. This review discusses the advancements of GNR@MSN in synthetic process, bio-imaging technique and tumor therapy. Additionally, the further application of GNR@MSN in imaging-guided treatment modalities is explored, while its promising superior application prospect is highlighted. Finally, the issues related to in vivo studies are critically examined for facilitating the transition of this promising nanoplatform into clinical trials.

Plasmonic absorption enhancement of MAPI-based perovskite solar cell with nanoparticles array

In this work, we propose a MAPI-based p-i-n perovskite solar cell with architecture ITO/PEDOT:PSS/MAPI/Rhodamine/TiO2/Ag. Although MAPI-based solar cells have prominent performance, there are some challenges for these devices. Poor optical absorption at near-infrared wavelengths is the most important challenge for MAPI-based solar cells. The effect of three kinds of periodic array nanoparticles on the absorption spectra of the perovskite layer has been investigated theoretically. The spherical bare Au nanoparticle, Au@SiO2, and Au@TiO2 core–shell nanorods have been used. Moreover, Rhodamine as a surface passivator to decrease the charge carrier recombination is used between perovskite and Electron Transport Layer (ETL). Our simulation is based on three dimensions Finite-Difference Time-Domain (FDTD) method and we use Lumerical software. The effect of these nanoparticles on electric field intensity, light absorption, short-circuit current density, and generation rate are investigated for the visible and near-infrared bands. We found that Au@TiO2 can improve light absorption more than Au and Au@SiO2 at the near-infrared band and this increment is due to the growth of plasmonic near-field of nanoparticles and light scattering enhancement from these nanoparticles.

Design of Planar Multilayer Devices for Optical Filtering Using Surrogate Model Based on Artificial Neural Network

Artificial intelligence paradigms hold significant potential to advance nanophotonics. This study presents a novel approach to designing a plasmonic absorber using an artificial neural network as a surrogate model in conjunction with a genetic algorithm. The methodology involved numerical simulations of multilayered metal–dielectric plasmonic structures to establish a dataset for training an artificial neural network (ANN). The results demonstrate the proficiency of the trained ANN in predicting reflectance spectra and its ability to generalize intricate relationships between desired performance and geometric configurations, with values of correlation higher than 98% in comparison with ground-truth electromagnetic simulations. Furthermore, the ANN was employed as a surrogate model in a genetic algorithm (GA) loop to achieve target optical behaviors. The proposed methodology provides a powerful means of inverse designing multilayered metal–dielectric devices tailored for visible band wavelength filtering. This research demonstrates that the integration of AI-driven approaches in nanophotonics leads to efficient and effective design strategies.

Ultra-broadband and wide-angle plasmonic light absorber based on all-dielectric gallium arsenide (GaAs) metasurface in visible and near-infrared region

High-performance and cost-effective broadband light absorbers are crucial for various optical applications, including solar energy harvesting, thermophotovoltaic systems, and integrated photoelectric devices. In this study, an ultra-broadband and wide-angle plasmonic light absorber (PLA) based on an all-dielectric gallium arsenide (GaAs) metasurface in the visible and near-infrared regions is proposed and numerically investigated. The unit-cell of the proposed PLA is consisted of all-dielectric GaAs cylinder resonator (CR) adhered on an ultra-thin GaAs spacer layer backed with a tungsten (W) substrate. Numerical simulation results show that the absorption peak of the proposed PLA is up to 99.85 %, 99.9 % and 99.98 % at 0.452 μm, 0.712 μm and 1.596 μm, respectively. In addition, the ultra-broadband strong absorption of over 90 % also can be achieved from 0.39 μm to 2.09 μm with a relative bandwidth of 137.1 %. The ultrabroadband strong absorption of the proposed PLA is further demonstrated by the equivalent circuit model (ECM), which displays excellent agreement with the results of the full-wave numerical simulation performed using the finite element method (FEM). The simulated electromagnetic (EM) field distributions reveal that the ultra-broadband strong absorption of the designed PLA is mainly from the excited propagating surface plasmon (PSP), located surface plasmon (LSP), cavity resonance modes combined with coupling effect between adjacent CRs. The proposed PLA is also polarization-insensitive and wide incident angles for both transverse electric (TE) and transverse magnetic (TM) modes. The absorption properties of the designed PLA can be adjusted by varying geometric parameters of the unit-cell. The PLA achieves a remarkable short-circuit current density of over 64.75569 mA/cm2 and exhibits nearly perfect solar energy trapping due to the effective coupling of multiple resonances, resulting in enhanced photovoltaic performance. Thus, the proposed PLA can be potential application in the photodetectors, thermal imaging, and solar energy harvesting devices.

99mTc-AgNPs-ICG: nanoparticle for hybrid image

Introduction: Currently nanotechnology has radically changed the diagnosis of many human pathologies. The aim of this work is to obtain silver nanoparticles for hybrid imaging (99mTc-AgNPs-ICG) having potential clinical imaging applications. Materials and method: We mixed 2 ml of ascorbic acid (1.7x10-4 M), 5 mCi of 99mTcO4- , 2 ml of citric acid (8.0x10-4 M) and 0.5 ml of silver nitrate (2.5x10-3 M). Solution pH was 5, and it was shaken for 20 minutes at 37º C. Afterwards, 2 µL of Indocyanine Green (1.3x10-3 M) was added (99mTc-AgNPs-ICG). Physiochemical properties of the solution were characterized by UV (λ1 = 420 nm, λ2 = 254 nm) and gamma detector. Fluorescence image, particle size and IR spectrum were evaluated. Results: Silver nanoparticles were obtained in aqueous solution a pH of 5. Their pH, color and spectrum were stable for seven days. Furthermore, the principal peak characterized by HPLC, UV and Gamma detector had similar retention times. Its UV spectrum showed an absorption band of 420 nm, which corresponds to the plasmon absorption band of these nanoparticles. The particle size was 46 nm ± 1.5 nm. The IR spectrum showed absorption bands in 3193, 2624, 1596 y 1212 cm-1. Conclusions: We describe for the first time in literature the synthesis of hybrid (radioactive and fluorescent) silver nanoparticles. Their physiochemical properties were characterized, being stable and their labelling was reproducible having potential biomedical applications. Received for review: November 2023. Accepted for publication: February 2024. Correspondence: Centro de Investigaciones Nucleares, Facultad de Ciencias, Universidad de la República, Montevideo, Uruguay. Mataojo 2055, P.O. 11400, Montevideo, Uruguay. Tel: (+5982) 5250901/108; fax: (+5982) 5250895. Contact e-mail: pabloc7@gmail.com This article was approved by the Editorial Committee.