With a primary focus on sunlight and building shadows, we studied the impact of residential building orientation angles, building heights, and area combinations, as well as the underlying surface materials, on the outdoor thermal environment in Changsha, a city located north of the Tropic of Cancer. On the basis of Changsha’s regulations, the research results indicate that building orientation angles of 15–45° and 315–345° can generate more building-shadow areas and have a better effect on improving the outdoor thermal environment. Based on the study of many common residential block building layouts in Changsha, we believe that, for point-pattern residential blocks, an increase in building lengths can be very effective for increasing building-shadow areas and thermal comfort. For row-pattern residential blocks, an increase in building heights can be regarded as more effective for increasing building-shadow areas and reducing air temperatures. Shadow areas formed on impervious surface material areas, such as concrete pavements, reduce the air temperature more than shadow areas formed on natural surfaces, such as grasslands. For the planning and regeneration of residential areas, urban planners should focus on placing more green spaces in areas which are seldom or never covered by building shadows; they should also focus on installing more impervious surfaces in areas covered by building shadows. These strategies are beneficial for making full use of building shadows to reduce air temperatures in residential areas.