Piston Cores Research Articles

Contourite on the Limpopo Corridor, Mozambique margin: Long‐term evolution, facies distribution and Plio‐Quaternary processes

AbstractBottom currents are key processes that contribute to the shaping of submarine slopes, with the redistribution of sediments in contourite systems. Despite numerous recent studies on contourite systems, the complexity and diversity of these sedimentary systems are still not fully understood and often underestimated. Their understanding requires comprehensive works integrating all scales from seismic architecture to microfacies. This paper focuses on a contouritic ridge located between 2000 m and 2500 m water depth on the Mozambique margin. Bathymetry, seismic data and piston cores collected during the PAMELA‐MOZ3 cruise allow a multi‐scale study from large depositional geometries to sedimentary facies. At the seismic scale, the contouritic ridge shows three stages of evolution with: (i) initiation and development of the drift/moat system; (ii) an intermediate stage with successive incisions and aggradations; and (iii) moat infill and drift erosion during the Plio‐Quaternary. Plio‐Quaternary deposits are composed of hemipelagic, turbiditic and contouritic facies filling the moat. Coarse‐grained contouritic facies, dominated by planktonic foraminifera, are identified on the western flank of the ridge between the moat infill and the erosional area at the top of the ridge. They consist of condensed deposits, with sedimentation rate about 0.3 cm/ka, indicating a strong and stable bottom current that winnows away the fine‐grained component. This facies could be present more generally in an intermediate position between erosion and depositional areas in contourite systems. At present, the contourite system is located at the transition depth between North Atlantic Deep Water and Antarctic Intermediate Water. Trajectories of bottom currents are complex and interact with sporadic turbidity currents and anti‐clockwise eddies that participate in reshaping the sea floor morphology. Although Plio‐Quaternary depositional geometries indicate the end of drift/moat development, the moat filling and drift erosion are also related to bottom currents and constitute atypical contouritic sedimentation.

A synthesis of monsoon exploration in the Asian marginal seas

Abstract. The International Ocean Discovery Program (IODP) conducted a series of expeditions between 2013 and 2016 that were designed to address the development of monsoon climate systems in Asia and Australia. Significant progress was made in recovering Neogene sections spanning the region from the Arabian Sea to the Sea of Japan and southward to western Australia. High recovery by advanced piston corer (APC) has provided a host of semi-continuous sections that have been used to examine monsoonal evolution. Use of the half-length APC was successful in sampling sand-rich sediment in Indian Ocean submarine fans. The records show that humidity and seasonality developed diachronously across the region, although most regions show drying since the middle Miocene and especially since ∼ 4 Ma, likely linked to global cooling. A transition from C3 to C4 vegetation often accompanied the drying but may be more linked to global cooling. Western Australia and possibly southern China diverge from the general trend in becoming wetter during the late Miocene, with the Australian monsoon being more affected by the Indonesian Throughflow, while the Asian monsoon is tied more to the rising Himalaya in South Asia and to the Tibetan Plateau in East Asia. The monsoon shows sensitivity to orbital forcing, with many regions having a weaker summer monsoon during times of northern hemispheric Glaciation. Stronger monsoons are associated with faster continental erosion but not weathering intensity, which either shows no trend or a decreasing strength since the middle Miocene in Asia. Marine productivity proxies and terrestrial chemical weathering, erosion, and vegetation proxies are often seen to diverge. Future work on the almost unknown Paleogene is needed, as well as the potential of carbonate platforms as archives of paleoceanographic conditions.

Multiple sulfur isotope systematics of pyrite for tracing sulfate-driven anaerobic oxidation of methane

Sulfate-driven anaerobic oxidation of methane (SD-AOM) is ubiquitous in marine sedimentary environments, governing the global methane budget and the redox evolution of Earth's surface. Tracing SD-AOM and organoclastic sulfate reduction (OSR) from the pyrite archive is key to the reconstruction of SD-AOM activity and paleoenvironmental interpretation. However, discriminating the origins of pyrite – basically SD-AOM and OSR – is commonly challenging due to frequent overlap of δ34Spy values. Multiple sulfur isotopes of pyrite are expected to be an effective tool to distinguish between OSR and SD-AOM, yet variable uncertainties and unknowns remain. Here we investigated the δ34S and Δ33S values of pore-water sulfate and authigenic pyrite from a piston core taken on the continental slope of the South China Sea. A positive Δ33S - δ34S correlation of pore-water sulfate is observed in the upper OSR-dominated zone, resulting in Δ33S and δ34S values of sulfate diffusing into the sulfate-methane transition zone (SMTZ) >0.1‰ and >30‰ larger than the corresponding values of seawater sulfate. A negative Δ33S - δ34S trajectory of pore-water sulfate and pyrite is observed for the SMTZ, agreeing with low sulfur isotope fractionation characteristic for SD-AOM and a diagnostic large Δ33S - δ34S field of SD-AOM-derived pyrite. These findings elucidate that the multiple sulfur isotope systematics of pyrite in methane-bearing sediment depends on (1) mass transport effects of dissolved sulfate and sulfide, (2) the relative contribution of OSR and SD-AOM to the pore-water sulfide and pyrite pools, and (3) the sulfur isotope fractionation during microbial sulfate reduction. Our study highlights the importance of mass transport dynamics on the isotopic composition of pyrite, a factor that needs to be considered in any attempt to reconstruct the origin of early diagenetic pyrite and the paleoenvironmental setting with multiple sulfur isotopes.

Southern Hemisphere Westerly Winds have modulated the formation of laminations in sediments in Lago Fagnano (Tierra del Fuego, Argentina) over the past 6.3 ka

Tierra del Fuego in Argentina is a unique location to examine past Holocene wind variability since it intersects the core of the Southern Hemisphere Westerly Winds (SHWW). The SHWW are the most powerful prevailing winds on Earth. Their variation plays a role in regulating atmospheric CO2 levels and rainfall amounts and distribution, both today and in the past. We obtained a piston core (LF06‐PC8) from Bahía Grande, a protected sub‐basin at the southern margin of Lago Fagnano, the largest lake in Tierra del Fuego. This article focuses on the uppermost 185 cm of this core, corresponding to laminated sediment from the last ~6.3 ka. Laminations consist of millimetre‐scale paired dark and light layers. Previous studies and new geochemical analysis show that the dark and light layers are characterized by differing concentrations of Mn and Fe. We attribute the distribution of Mn and Fe to episodic hypolimnic oxic–anoxic variations. The age model suggests an approximately bidecadal timescale for the formation of each layer pair. We propose a new model of these redox changes with the SHWW variations. The most likely phenomenon to produce complete water‐column mixing is thermobaric instability, which occurs in colder winters with low‐intensity SHWW (El Niño‐like conditions). In contrast, windier winters are characterized by higher temperatures and reduced mixing in the water column, facilitating a decline in oxygen concentration. Laminations, and the inferred presence of periodic hypolimnion redox changes, are common features of the past ~6.3 ka. Geochemical proxy variability is compatible with an intensification of El Niño/Southern Oscillation activity during the past ~2 ka.

Factors affecting thickness and frequency of turbidites triggered by earthquakes in Kumburgaz Basin, Sea of Marmara

Submerged fault ruptures generate earthquake-triggered mass flow deposits, which are extensively used as a tool in subaqueous paleoseismology. In tectonically active deep sedimentary basins, such as the Sea of Marmara (SoM), these mass flow deposits are defined as turbidite-homogenite units (THUs), consisting essentially of a coarse basal part and an overlying homogeneous mud (homogenite). Detailed characterization of THUs is crucial in order to establish meaningful criteria to link these units with earthquakes events and to identify their transport routes and depositional mechanisms. Here, we combine μ-X-ray Fluorescence (μ-XRF), Anisotropy of Magnetic Susceptibility (AMS) and additional rock magnetism analyses of a 21-m long piston core from the Kumburgaz Basin of SoM to define the upper stratigraphic boundary of THUs with hemipelagic sediments and investigate the controls of hydrological changes on turbidite frequency and thickness over the last 15 kyrs BP. The sedimentary succession of this period includes a lower lacustrine and an upper marine unit with two Holocene sapropel intervals. The sequence is interrupted by a total of 70 THUs, characterized by a significant magnetic foliation related to the depositional setting rather than the magnetic signature. Magnetic mineralogy of the coarse basal parts of THUs have more ferromagnetic particles than the overlying homogenites and background sediments. While the homogenite parts have a more constant mineralogy than the basal parts, they do not differ the background sediments.Based on an event-free chronostratigraphic model derived from radiocarbon ages and the published age of lacustrine-marine (L-M) transition, the average THU occurrence intervals in the lacustrine (14.8–12.6 kyrs BP), lower sapropel (11.2–5.7 kyrs BP), upper sapropel (5.4–2.7 kyrs BP) and non-sapropelic part of the marine unit (2.7 kyrs BP-present) are 235 yrs., 287 yrs., 114 yrs. and 160 yrs. respectively. The average thickness of the THUs in the same units are 20.8 cm, 15.7 cm, 6.1 cm and 6.1 cm. The variability of average THU occurrence intervals and THU thicknesses are controlled by the sea level rise and salinity increase following the full marine connection of the SoM at 12.6 kyrs BP, which caused changes in slope stability, sediment composition and sediment deposition in different parts of the basin. Geomechanical properties of the lower sapropel appears to have been important in resulting long THU recurrence intervals and relatively high THU thicknesses.

Possible links with methane seepage and gas hydrate dynamics inferred from authigenic barite records in the northern south china sea

Numerous methane seepage events occurred in periods of low or falling sea level since 330 ka BP, which is attributed to decrease in hydrostatic pressure and subsequent gas hydrate dissociation in the northern South China Sea (SCS). The seepage intensity likely decrease due to gas hydrate stabilization once there was a relatively high-stand sea level. However, there are few geochemical records of decline in upward methane flux in the northern South China Sea. Here, combing porewater and solid-phase analyses, the geochemical cycling of barium was investigated in two piston cores from sites HD109 and HD319 within two areas with inferred gas hydrate occurrence in the Taixinan Basin of the northern SCS, in order to track the net decrease in the upward methane flux and to estimate the total duration time of these events in the studied sediments. The results indicate that there are four intervals with barium enrichments in the sediment section overlying the occurrent sulfate-methane transition zone (SMTZ) at both cores, suggesting the SMTZs have downward migrated through time. Based on the excess barium contents and the diffusive Ba2+ fluxes above the current SMTZ, we estimate the total time for barium accumulation at both cores is about ten thousand years. It is suggested that some methane seepage events temporarily enhance the upward flux of methane, inducing anaerobic oxidation of methane and associated SMTZ close to the sediment surface before the Holocene. After the most intensive seepage event ceased in the post-glacial period, the upward methane flux decreased and the SMTZ migrated downward gradually, preserving enrichments of diagenetic barite. Overall, these new data confirm the episodic decrease in upward methane flux recorded by authigenic barite after the last glacial maximum, which is likely related to the stabilization of underlying gas hydrate reservoir. This study may fill in the gap of the geochemical records of the variations in methane seepage and gas hydrate system during the post-glacial period in the northern SCS.

700,000 years of tropical Andean glaciation

Our understanding of the climatic teleconnections that drove ice-age cycles has been limited by a paucity of well-dated tropical records of glaciation that span several glacial–interglacial intervals. Glacial deposits offer discrete snapshots of glacier extent but cannot provide the continuous records required for detailed interhemispheric comparisons. By contrast, lakes located within glaciated catchments can provide continuous archives of upstream glacial activity, but few such records extend beyond the last glacial cycle. Here a piston core from Lake Junín in the uppermost Amazon basin provides the first, to our knowledge, continuous, independently dated archive of tropical glaciation spanning 700,000 years. We find that tropical glaciers tracked changes in global ice volume and followed a clear approximately 100,000-year periodicity. An enhancement in the extent of tropical Andean glaciers relative to global ice volume occurred between 200,000 and 400,000 years ago, during sustained intervals of regionally elevated hydrologic balance that modified the regular approximately 23,000-year pacing of monsoon-driven precipitation. Millennial-scale variations in the extent of tropical Andean glaciers during the last glacial cycle were driven by variations in regional monsoon strength that were linked to temperature perturbations in Greenland ice cores1; these interhemispheric connections may have existed during previous glacial cycles.

Statistical Inference of Sound Speed and Attenuation Dispersion of a Fine-Grained Marine Sediment

Acoustic recordings of signals in the 1.5–4.0-kHz band were analyzed for information about the sound speed and attenuation frequency dispersion of a fine-grained sediment found in the New England Mudpatch. Analysis of piston cores established prior bounds for a geophysical parameterization of a seabed model that predicts Kramers–Kronig dispersion relations. Sediment layers are described by the Buckingham viscous grain shearing (VGS) model that accounts for the effects of overburden pressure of compressional and shear speeds and attenuations. A statistical inverse problem was solved by using multiple samples of received levels recorded on two vertical line arrays as a function time and hydrophone depth for six frequencies in the 1.5–4.0-kHz band. A statistical inference model that assumed both model parameters and data samples are random variables quantified information content from marginalization of a conditional posterior probability distribution for the geophysical parameters that characterize the mud layer. From the inferred geophysical parameter point estimates the sediment sound speed and attenuation frequency dispersion are predicted and compared to previously reported direct measurements. Also, the predicted sound-speed gradient in the mud sediment from the VGS model is compared to a previous inference that utilized explosive sources.

Contrasting Along-Slope vs. Downslope Sedimentation Style on the High-Latitude Eastern Canadian Continental Margin During the Last 40 ka

Late Pleistocene Labrador Sea depositional systems developed in front of ice streams and glacier outlets from the Laurentide Ice Sheet (LIS) are documented by Huntec and 3.5 kHz seismic profiles and piston cores. Due to efficient grinding by the LIS, massive amounts of fine-grained sediments and meltwater in addition to the icebergs linked to the Heinrich events (H events) of the last glaciation were delivered to the neighboring Labrador Sea. The position of the Hudson Strait ice stream during the periodic expansion and contraction on the Labrador margin allowed fine-grained sediments and meltwater direct delivery on the lower shelf and upper slope. These discharges were then transported southward by the Labrador Current and western boundary current. In contrast to the lower shelf and upper slope, sediments delivered on the mid to the lower Labrador Slope were transported by the Northwest Atlantic Mid-Ocean Channel to distal sites. The nepheloid flow layer at or near the sea bottom or at mid-water depths developed from meltwater loaded with an excessive charge of fine-grained sediments. Contrastingly, the non-discriminatory ice rafting process delivered detritus of all sizes, but its total contribution to the sediment column was only minor, notwithstanding its paleoclimatic significance during H events. Heinrich H1, H2, and H4 layers were identified by their characteristic nepheloid flow layer deposits, that is, alternating coarse silt and clay-sized laminae with thin ice-rafted debris interspersed by coarse- to fine-grained dropstone. Furthermore, the progressive thinning and eventual disappearance of the fine-laminae (i.e., coarse and fine silt/clay) in H layers at the distal sites suggest the exhaustion and raining out of fines due to long-distance transport. However, the H3 layer was identified by a combination of nepheloid flow layer deposits (upper slope) and finely laminated mud turbidites (lower slope and deep basin) at proximal sites. In the lower Labrador Slope and Basin, the H3 stratigraphic equivalent layer was identified by exorbitantly thick finely laminated carbonate-rich mud turbidites. The divergent sedimentation style (i.e., reflected by the sediment facies) and the thickness of the H3 layer compared to other H events suggest that the Hudson Strait ice stream position was different from other H events. Therefore, our data imply that the divergence in the H3 layer between the eastern and western North Atlantic might lie with the position of the Hudson Strait ice stream on the Labrador continental margin.

Geochemistry of Early Diagenesis in Sediments of Russian Arctic Glacial Lakes (Norilo–Pyasinskaya Water System)

The Russian Arctic region is lacking in studies on geochemical changes reflecting early sediment diagenesis in lake environments. The paper presents new data on the compositions of bottom sediments and sediment pore water from two lakes of the Norilo–Pyasinskaya water system in Arctic Siberia. Lakes Pyasino and Melkoye occupy basins left by glaciers that originated from the Putorana Plateau during the Last Glacial Maximum (LGM). Clayey sediments were continuously deposited in the lakes, and the depositional environment has changed only slightly for the last ca. 20 ka. Two sediment cores with lengths of 4.0 and 3.2 m were collected in Lakes Pyasino and Melkoye, respectively, with a Livingstone-type piston corer providing undisturbed, stratigraphically consistent sedimentary sequences. Their analyses revealed a change from oxidized to reduced conditions at a depth of ~10 cm. The concentrations of Ca2+, Mg2+, Na+, and K+, as well as the HCO3−/Ca2+ ratio in pore water, showed a depthward increase indicating the progressive degradation of organic matter. Another trend was the gradual decrease in SO42− alongside increasing HCO3−/SO42− caused by bacterial sulfate reduction, although this was rather weak, judging by the low concentrations of S (II) bound to Fe-sulfides, H2S, etc. Additionally, the microbial digestion of organic matter caused a release of its mobile components, which led to the enrichment of the water in NO3−, PO43−, and DOC. Most of the analyzed elements (Al, B, Ba, Co, Cu, Mo, Ni, Si, Sr, V, and Zn) reach higher concentrations in the pore water than in the lake water above the water-sediment boundary, which is evidence of diagenetic processes. As a result of redox change, immobile Fe (III) and Mn (IV) natural oxides were reduced to mobile Fe (II) and Mn (II) species and migrated from the solid phase to the pore water, and eventually precipitated as authigenic Fe sulfides and Mn carbonates. The results are useful for better understanding the early diagenesis processes in different geographical settings over the huge Eurasian continent.

Geological, geophysical, and geochemical characteristics of deep-routed fluid seepage and its indication of gas hydrate occurrence in the Beikang Basin, Southern South China Sea

Deep-routed fluid seepage conduits are widely distributed in the Southern South China Sea (SSCS), and gas hydrates have been discovered inside these conduits through drilling and logging. Due to a lack of integrated geological, geophysical, and geochemical data, deep-routed fluid seepage conduits and their relationship to gas hydrate occurrence are still unclear. In this study, a comprehensive investigation of fluid seepage was conducted through systematic analysis of high-resolution 2-D seismic data, multibeam bathymetry data, headspace gas and carbon isotope components, authigenic carbonates, pore water, biomarkers, and hydrate phase equilibrium simulation. Multiple types of deep-routed conduits—which typically manifested as mud volcanoes, diapirs, fluid-escape pipes, and paleo-uplift associated faults—were identified. These manifestations were generally accompanied by Bottom Simulating Reflectors (BSRs), blanking zones, locally enhanced reflections, "pulled-up" reflections, pockmarks, mounds, and gas plumes, which indicated fluid seepage and possible gas hydrate accumulation. The Sulfate Methane Transition Zone (SMTZ) in the fluid seepage sites occurred at relatively shallow depths of 325–660 cmbsf (centimeter below the seafloor), suggesting a high methane flux and sufficient gas supply. The carbon isotope composition of the methane (−92.6‰ < δ13C < −50.2‰) and the detection of ethane, propane, and n-butane, as well as multiple geological configuration biomarkers, all indicate that deep-sourced hydrocarbons and thermogenic gas have migrated into the shallow layer through deep-routed conduits. Several geological and geochemical anomalies, including gas expansion, gas bubbling in piston core sediments, negative pore water chloride anomalies, and δ18O enrichment (3.8‰ < δ18O < 4.1‰) in the cold seep carbonates, provide evidence of hydrate dissociation during core recovery. The deep-routed fluid seepage and the accompanying hydrocarbon gas supply have a significant influence on the potential thermogenic gas-sourced hydrate accumulation and evolution. Overall, the co-existence of fracture-filling hydrates and pore-filling hydrates formed from the same supply of thermogenic gas and biogenic gas was inferred through comprehensive study and comparison with adjacent hydrate drilling areas. This article is the first systematic study of the characteristics of hydrate accumulation under the fluid seepage background in the Beikang Basin, and it provides a favorable reference for revealing the relationship between deep-sourced fluid seepage and hydrate formation. However, more exploration work needs to be conducted to confirm the above assumptions.

Benthic foraminifera as indicators of recent mixed turbidite-contourite sediment transport system in the Eastern Mediterranean upper continental slope, offshore Israel

Nile derived siliciclastic sediments are the main source of sedimentation along the Levant continental margins of the Mediterranean Sea. These sediments are transported along the southeastern Mediterranean coast via well-documented longshore currents, mainly operating along the shelf. However, the cross shelf component of sediment transport, responsible for conveying sediments toward the upper slope, is less known. To better understand the cross-shelf vs. the longshore component of sediment transport we studied a ~6 m long piston core (DOR280) sampled on the upper continental slope (280 m water depth) and analyzed benthic foraminiferal assemblages and their shell taphonomy alongside the particle size distribution and mineralogy of bulk sediments, to document both the source and the transport mechanism of those upper continental-slope sediments. The radiocarbon dating at the core-base is ~650 Cal. Yrs BP, indicating an exceptionally high average sedimentation rate of ~800 cm/kyr.DOR280 consists of two alternating distinct sedimentary facies: (1) laminated (L) intervals up to ~40 cm thick each and showing a high ratio of allochthonous vs. autochthonous (allo/auto) benthic foraminiferal species and a high percentage of broken shells, indicating contribution of transported sediments originating from mid-shelf habitats; (2) non-laminated (NL) intervals up to ~200 cm thick each and showing a low allo/auto ratio and low percentages of broken shells, indicating mostly in-situ hemipelagic deposition. The L intervals are interpreted here as turbidites. The sedimentation rates calculated only for the NL intervals are still exceptionally high, thus excluding hemipelagic sedimentation as the sole mechanism for the NL deposition. Therefore, a contour bottom current transported component is suggested here as a source of the NL sedimentation.We conclude that a mixed contourite-turbidite system actively prevails along the upper continental slope of the Levant coast, offshore Israel. The mid-shelf to upper slope sediment transport is nearly continuous and presents occasional turbidite events of average decadal reoccurrence time.

Late-Holocene paleomagnetic secular variation records from Lake Turkana, East Equatorial Africa

We have carried out a paleomagnetic study of three piston cores collected from Lake Turkana. The goal is to recover a Holocene paleomagnetic secular variation (PSV) record for this lake and to correlate it with other Holocene PSV records from the East Africa Rift Valley (EARV). All three cores were sampled with u-channels and magnetic measurements of magnetic susceptibility, the natural remanence (NRM), and two artificial remanences, anhysteretic remanence (ARM) and saturation isothermal remanence (SIRM), were made on them. The remanences were routinely step-wise demagnetized and measured at 10 mT steps up to 60 mT. The NRMS had a simple pattern of demagnetization with a characteristic direction (ChRM) removed between 10 and 60 mT. ARM and SIRM demagnetization indicated that the magnetic grains were relatively soft with median destructive fields (MDF) less than 30 mT. We interpret the magnetic grains to be multi-domain (silt-sized) magnetite/titanomagnetite. The resulting magnetic records of all three cores could be correlated. A chronology for these cores was determined from four radiocarbon dates on core 4P. We also estimated the sediment ages by correlating the PSV to two other well-dated PSV records from the same region, Lakes Malawi and Victoria. PSV age estimation indicates that the radiocarbon dates are about 500 year too old; a correction for that offset causes three of the four radiocarbon ages to become consistent with the PSV age estimates. The final composite Lake Turkana PSV record for the last ~4000 years is the highest resolution directional record of PSV (~200 cm/ky) ever to be recovered from Africa.

The Holocene evolution of Lake St Lucia, Africa's largest estuary: Geological implications for contemporary management

The Holocene evolution of one of Africa's largest estuaries, Lake St Lucia on the east coast of South Africa, is examined and juxtaposed with previous and contemporary management practices aimed at fixing the estuary state at a single point along the system's overall evolutionary pathway. The estuary has been heavily altered over the course of the last century, mostly through mouth management activities aimed at maintaining a direct connection with the ocean. Based on a high-resolution seismic reflection dataset, LiDAR and bathymetry data of the lake system, together with palaeontological (foraminifera and diatoms) and sulfur isotope geochemical data from three long (14–16 m) piston cores, we investigate the system-wide and coeval evolution of the three different sub-basins (False Bay, North Lake and South Lake) that comprise the current estuarine lake system. The northern and southern sections of the system evolved independently of each other since the Last Glacial Maximum, with each area responding differently to early sea-level forcings. In North Lake, the lagoon evolved from fully estuarine (8300 cal. BP) to a restricted lagoon with occasional marine incursions, steadily decreasing tidal prism and the development of marginal spits by wind-driven lagoonal waves. The tidal inlet closed approximately 6200 cal. BP and fluvial conditions became more dominant as main back-barrier conditions became attuned to fluvial supply. Similar conditions prevailed in the adjacent False Bay basin, albeit with an earlier onset due to sheltering by prominent bedrock peninsulas. In contrast, South Lake evolved from a fully estuarine system (9500 cal. BP) with a persistent ocean connection, to a segmented system with a diminished tidal connection by 5500 cal. BP. The inlet sealed at this point and an isolated back barrier system developed. This prompted the system-wide impoundment of waters causing back-barrier flooding and in situ drowning of bayhead deltas and segmenting spits. By 2000 cal. BP, these areas had flooded sufficiently to connect over a bedrock high that had diverted the initial palaeo-valleys to the north and south. A new, single lagoon, representative of the modern-day system formed, with a new marine connection to the modern day Mfolozi River and contemporary estuary. Periodic desiccation of the lake sub-basins since this point has been apparent. Given the complex management plans implemented to stop excess sedimentation, hypersaline events, and the continuation of “normal” lake levels, this is at odds with the natural system's evolution to a pan or wetland-type state. This geological background should be key to informing management plans that work within the natural evolutionary trajectory of the system, as opposed to attempting to maintain an unattainable status quo.

Rising bottom-water temperatures induced methane release during the middle Holocene in the Okinawa Trough, East China Sea

It is not currently well understood how a changing climate controls methane releases in the Okinawa Trough. In this study, a piston core was collected from a seep-impacted area at a water depth of approximately 1000 m from the Okinawa Trough, East China Sea, and was studied using comprehensive analyses of carbon and oxygen stable isotopes, lipid biomarkers, and major and trace element geochemistry. Extremely low δ13C values of total inorganic carbon and organic carbon, increased Methane Index, and molybdenum (Mo) and uranium (U) enrichments at depths of 225–255 cm below the sea-floor (bsf) and 75–142.5 cm bsf were found. Combined with published pore water data, fossil and current sulfate-methane transitions (SMTs) were identified. Mass balance equations were applied to estimate the fraction and content of authigenic carbonates at the two SMTs and their corresponding δ18O values. The calculations revealed that the estimated δ18O values of authigenic carbonates for the fossil SMT (from 4.9‰ to 5.8‰) and the current SMT (from −2.1‰ to 4.4‰) were higher and lower than the theoretical equilibrium δ18O value (4.8‰), respectively. These results suggest that fossil seepage is possibly induced by the dissociation of gas hydrates. The fluids of the current seepage may be derived from the equilibrium between the ambient seawater and the fluids of gas hydrate dissociation. Based on the accumulation of authigenic carbonate in sediments, previously published pore-water calcium and magnesium fluxes, and foraminifera 14C dating, the fossil methane seepage was confirmed to have occurred during the period 8.2 to 4.5 ka B.P., with its SMT depth less than 105 cm bsf, while the present-day methane seepage with a low fluid intensity was estimated to have started before 1.0 ka and formed its SMT at approximately 250 cm bsf. The timing of this fossil methane seepage suggests that the rising temperature of the North Pacific Intermediate Water during the early and middle Holocene mainly controlled the methane release in the Okinawa Trough, whereas the ongoing methane emission was likely induced by decreased pressure driven by back-arc extension. The geochemical data demonstrate past methane release as a response to environmental changes and suggest that the Okinawa Trough gas hydrates were sensitive to temperature fluctuations during the middle Holocene.

Upslope migrating sand waves on sediment-starved shelves: An example from the southeastern continental margin of the Korean Peninsula

An uncharted field of sand waves was discovered in a low-relief submarine canyon incised in the outer shelf on the southeastern continental margin of the Korean Peninsula in water depths of 180–190 m. We characterize the nature and origin of the waves and the sand forming them using sub-bottom chirp profiles, eXpendable bathythermograph (XBT) profile, multibeam echosounder (MBES) data, and sediment samples from four piston cores. Two types of sand waves characterized by distinct height versus wavelength relationships were found in the study area. The sand waves in the upper, narrower part of the shelf-incised canyon are sinuous-crested, with amplitudes of 0.3–2.1 m (mean: ~1 m) and wavelengths of 10–45 m (mean: ~24 m). Their asymmetry indicates migration upslope in a southwesterly direction, opposite to the surface currents. In contrast, the lower part of the canyon that is wider and closer to the margin of the continental shelf hosts nine long (ca. 1 km) curvilinear-crested sand waves with symmetrical crests; these waves likely reflect transient bedforms forming under fluctuating current conditions.The sediment of the sand waves consists of a variable mixture of siliciclastic and carbonate materials. The carbonate fraction (~22–55%; mean: ~34%) is derived mainly from the remains of bryozoans, bivalves, echinoderms, foraminifers, gastropods, and serpulids. Six bioclasts were dated by the radiocarbon method between ca. 41.3 and 11.8 ka BP. These relatively old ages and palaeontological data supports reworking from a shallow-marine environment during the last glacial transgression and limited sedimentation/sediment supply in the study area. The siliciclastic fraction (~44–79%; mean: ~37%) is composed of rounded to subrounded quartz and feldspar of moderate to good sorting and a mean grain size of ~1.3 phi (medium sand). The uppermost ~30 cm of all the sand wave cores reveals a decrease in the grain size of the siliciclastic fraction coupled with an increase in the carbonate/siliciclastic ratio, suggesting episodic sediment reworking and migration of the sand waves in response to fluctuating bottom currents. The coarser sediment that forms the core of the sand waves records bedload transport during periods of stronger currents. Finer carbonate-rich pelagic sediment (i.e., plankton) accumulated at the top of the sand waves during periods of weaker bottom currents. Significantly, our results show that the grain size and mineralogy of the sediment composing the sand waves are controlled by changes in hydrodynamic conditions. Our study provides novel geomorphological evidence for the influence of SW-flowing cold-water incursions (Korean Strait Bottom Cold Water) on the seafloor sediments.

Quaternary Ostracoda and Foraminifera from the Pelotas Basin, southernmost Brazil: Assemblage variation in gas-hydrate bearing sediments

Late Quaternary ostracod and foraminifera assemblages from five piston cores in Pelotas Basin, southern Brazilian margin, were analyzed in this paper. The study revealed a diverse bathyal fauna of ostracods, with abundance of the genera Apatihowella, Cytheropteron and Cytherella, interspersed with peaks of allochthonous neritic faunas. Benthic foraminifera are represented mainly by the genera Bolivina, Bulimina, Cassidulina, Epistominella, Globobulimina, Globocassidulina, Nonion, Oridorsalis and Uvigerina. Biostratigraphic analysis of planktic foraminifera positioned the samples in Pleistocene-Holocene interval. The ostracod genera Paracytherois, Cytheropteron, Cytherella, Macropyxis and the species Krithe hunti, Krithe reversa, Henryhowella asperrima, Eucytherura fossapunctata, Rimacytheropteron longipunctatum, Apatihowella besnardi and Apatihowella convexa, and also the benthic foraminifera Bolivina, Bulimina, Nonion, Nonionellina, Oridorsalis, Uvigerina, Epistominella and Cassidulina are related to environments of gas hydrates and associated with a chemosynthetic community in eutrophic-mesotrophic environments.

The influence of the inter-tropical convergence zone on the Orinoco River and Late Quaternary tropical planktonic foraminiferal assemblages

Although deep-water oil and gas exploration offshore eastern Trinidad is becoming prevalent, the use of ecostratigraphy around eastern Trinidad are limited mostly to neritic water depths. Changes in planktonic foraminiferal assemblages of Core BGT086, offshore eastern Trinidad, are used here to indicate biozonal events useful for deep-water (&gt;1000 m water depth) exploration. Decreased proportional abundances of Globigerinella obesa and Globigerina bulloides mark the southward migration of the inter-tropical convergence zone (ITCZ) during the Younger Dryas (YD). A decrease in species richness and Globigerinoides ruberwhite proportional abundance is consistent with rising temperature during the YD. During Biozone Z2, nutrient-preferring species (G. bulloides, Neogloboquadrina dutertrei) declined in proportional abundance, while G. ruberpink increased in proportional abundance, reflecting the arrival of the ITCZ in the area. Decreases in mean diversity (measured using the Shannon Function, H) and evenness (equitability index, E), and an increase in mean dominance (max pi) support the claim that the ITCZ arrived in the area after the YD. A sudden increase in Globorotalia menardii proportional abundance marked the start of Biozone Z1, at which time there was a change from a stressed community to a less stressed one. Boundaries of SHE abundance biozones coincided with noticeably enhanced assemblage changes, being consistent with the southward migration of the ITCZ and the onset of Biozone Z1. The mean value of the pairwise assemblage turnover index (ATIs) is here used as a proxy for what we term 'assemblage stability'. Comparisons of mean planktonic foraminiferal ATIs from Core BGT086 and six other nearby tropical piston cores (Cores 1, 2 and 3 off NW Tobago, and En20-2, En20-10 and En20-16 from the Leeward Islands, Lesser Antilles) showed no statistical difference in assemblage stabilities within similar planktonic foraminiferal biozones. Kruskal-Wallis tests determined a significant difference in median ATIs values when all seven cores' ATIs were used, but the difference was not significant when data above the YD boundary (i.e., Biozone Z) were used. The lowered nutrient influx from the Orinoco River due to the arrival of the ITCZ in the area after the YD would have triggered a stable environment for planktonic foraminiferal assemblages. This implies that caution must be used to ensure data from the same biozone is used when analyzing assemblage stabilities of planktonic foraminifera.

Fish Teeth Sr Isotope Stratigraphy and Nd Isotope Variations: New Insights on REY Enrichments in Deep-Sea Sediments in the Pacific

Rare earth elements and yttrium (REY) are widely recognized as strategic materials for advanced technological applications. Deep-sea sediments from the eastern South Pacific and central North Pacific were first reported as potential resources containing significant amounts of REY that are comparable to, or greater than, those of land-based deposits. Despite nearly a decade of research, quantitative abundances and spatial distributions of these deposits remain insufficient. Age controls are generally absent due to the lack of biostratigraphic constraints. Thus, the factors controlling the formation of REY-rich sediments are still controversial. In this study, the REY contents of surface sediments (&lt;2 m depth) in 14 piston cores from the Central and Western Pacific were investigated. The results show that deep-sea sediments with high REY contents (&gt;1000 μg/g) were mainly concentrated around seamounts (e.g., the Marshall Islands). The REY contents of surface sediments generally decreased with distance from the seamounts. Biostratigraphic and fish teeth debris (apatite) Sr isotopic stratigraphy of one piston core (P10) from the Central Pacific indicates that deep-sea sediments with high REY contents were aged from early Oligocene to early Miocene. Since the opening of the Drake Passage during the early Oligocene, the northward-flowing Antarctic Bottom Water (AABW) would have led to an upwelling of nutrients around seamounts with topographic barriers, and at the same time, AABW would delay the rate of sediment burial to try for enough time for REY entering and enriching in the apatite (fish teeth debris). Understanding the spatial distribution of fertile regions for REY-rich sediments provides guidance for searching for other REY resources in the Pacific and in other oceans.

Changes in surface water masses in the northern East China Sea since the Last Glacial Maximum based on diatom assemblages

We investigated diatom assemblages for the last 19 ka in a piston core KY07-04 PC01 collected from the northern Okinawa Trough, East China Sea. Most of the diatom taxa in the Core KY07-04 PC01 were subtropical to temperate marine species throughout the core. Pronounced turnover of major diatom groups from periphytic to planktonic taxa occurred during deglaciation between 17 and 14 ka ago. During the Last Glacial Maximum (LGM) to early deglaciation, the representative taxa were Paralia spp., a periphytic diatom abundant in continental shelves of the modern East China Sea covering the Chinese Coastal Water. Relative abundances of Paralia spp. rapidly decreased during 15–14 ka ago, corresponding to sea-level rise, displaced by planktonic taxa such as Thalassionema. Thalassionema nitzschioides varieties living in subtropical water increased since 12 ka and have reached the present level at 8 ka ago, suggesting strengthening the influences of Kuroshio water in the northern East China Sea during the early to middle Holocene. Warm planktonic diatom taxa such as Nitzschia bicapitata also gradually increased from 12 to 8 ka ago. Near the core top, a sudden increase in N. bicapitata might relate to the intensifying Kuroshio during the latest Holocene.