ABSTRACT Various postharvesting processes such as handling, drying, storing and transportation of pistachio nuts are affected by their equilibrium moisture content (EMC). The static gravimetric method, along with different saturated salt solutions, was used in a range of water activity of 0.11–0.88, and at 15, 25, 35 and 40C to obtain sorption isotherms of pistachio nuts. Each set of sorption data was fitted to six mathematical equations, including Brunauer, Emmett and Teller; Guggenheim, Anderson and De Boer; Smith; Oswin; Halsey; and Henderson. The Smith model gave the most appropriate results (fitness) over the entire range of the mentioned temperatures. The isosteric sorption heats were determined for adsorption and desorption of pistachio nuts using the relevant thermodynamic relations (i.e., Clausius–Clapeyron equation). Based on experimental sorption data, a noticeable hysteresis effect between adsorption and desorption processes was observed, and their EMC plots were significantly deviated and different from each other. PRACTICAL APPLICATIONSThe rehydration rate of pistachio kernels and powder when they are mixed with various ice creams, desserts and confectionary products depends mainly on their sizes, temperature, and water activity. These factors have considerable effects on texture properties and release of flavor of pistachio's final products. To enhance the organoleptic properties of the above‐mentioned products, it is important to choose proper sizes of pistachio kernels. Since hysteresis and binding energy of pistachio powder are less than those of pistachio kernels, especially at 15°C, its rehydration rate is faster, and therefore it releases more flavor to the product (water activity in the range of 0.2–0.7) than pistachio kernels. However, the crunchy taste in pistachio powder is less than that in pistachio kernels. Overall, more research is needed to choose proper sizes of pistachio kernels for mixing with different products (such as ice cream) to keep their high crispness and maximize their flavor‐releasing process during rehydration, and also to use minimum energy for cooling and freezing.
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