Pinning Effect Research Articles

Polar orientation and extension in a novel crystallographic model for PbTiO3-based perovskites explaining the experimental ferroelectric thermal anomalies

PbTiO3-based ferroelectric solid-solution ceramics have been widely used for electromechanical devices. However, it is still challenging to separate and control the contributions to the electromechanical functionalities, mainly as a function of temperature, where thermal anomalies and phase transitions can be observed. This study investigates the ultrasonic velocity and attenuation and the dielectric, ferroelectric and structural features of Pb0.55Ca0.45TiO3 ceramics from low temperatures (10 or 115 K) up to room temperature as an example of A-site isovalent substitution in PbTiO3. Such a combination of information makes possible the phenomenological deconvolution of the effects of ferroelectric domain wall pinning and structural features on spontaneous electric polarization. The room-temperature symmetry was determined as Pna21. The results show that this model refined by the Rietveld method for synchrotron X-ray diffraction patterns from 115 K to room temperature can explain the polarization extension features of these materials during heating. This study shows a correlation between structural thermal anomalies and low-temperature electric polarization in PbTiO3-based ferroelectric ceramics.

Effect of the cycle number of multistep sintering on the properties of FeSe0.4Te0.6 superconductors

AbstractFeSe0.4Te0.6 polycrystal bulks were synthesized using the solid‐state sintering method. We developed a novel multistep sintering process and studied the impact of the sintering cycle number. Different cycles of multistep sintering, ranging from one to four cycles were systematically arranged. It was found that the superconducting properties of the FeSe0.4Te0.6 polycrystal bulk using three cycles of sintering surpassed those of other samples, reaching a maximum of = 13.4 K, = 14.7 K, and a minimum of ∆ = 1.3 K. And the superconducting current density at 4 K reached 1.77 × 104 A/cm2, exhibiting a weak fishtail effect. At 9 K, a composite pinning effect emerged, consisting of normal point pinning and ∆κ surface pinning. The enhancement in superconductivity is attributed to improve uniformity in grain arrangement and more effective element diffusion. After multiple sintering cycles, the stacked grains exhibited increased thickness and the grain arrangement became dense.

Giant coercive-field (Hc @ 2 K > 17 T) by freezing of magnetic domains in BaFe2(PO4)2

In the 2D-Ising BaFe2(PO4)2 ferromagnet (FM), the competition between giant magneto-crystalline anisotropy and strong FM couplings creates remarkably narrow magnetic domain walls. These domains freeze below TF ≈ 15 K which is accompanied by progressive “soft-magnet” → “super-hard magnet” transition at both sides of TF. In the hard-regime, the coercive force is above 17 T at 2 K. At 5 K, we calculate a B.Hmax figure of merit (i.e., energy product) of 6.5 MG Oe superior to what observed in most permanent magnet oxides. This allows for the printing above TF and robust locking below TF of any magnetization between the saturation limits. The outstanding Hc value surpasses the standards by far, and brings questions about origin of such unusually strong pinning effects. They have to be surely attributed to narrow domain walls, estimated to be only ∼16 Å thick. Besides the observation of the domain wall structure by magnetic-force microscopy in various conditions, their thermodynamic signature appears in the specific heat data.

Fluctuations in misfit volume by interstitial carbon atoms contribute to the unusual dislocation loop evolution in high-entropy alloys under irradiation

Dislocation loops play a pivotal role for the irradiation behavior and associated mechanical properties of materials. This study employs advanced transmission electron microscopy, nanoindentation and first-principles calculations to elucidate the impact of interstitial carbon atoms on the evolution of dislocation loops in an Fe49.5Mn30Co10Cr10C0.5 high-entropy alloy under ion irradiation at temperatures ranging from 420 °C to 540 °C with a peak dose of 50 DPA. Interstitial carbon atoms have been revealed to broaden the size distribution of dislocation loops, rendering their morphologies more jagged, and consequently inducing a more substantial pinning effect. These outcomes can be attributed to the enhancement of misfit volume fluctuations of the alloying elements, which drives more severe local lattice distortions and larger variation of local chemical environments. As a result, these fluctuations promote the local pinning of dislocation loops, lead to their rugged movement and contribute to the rise in hardening. Our findings bring previously unrecognized insights into the role of interstitial carbon atoms in influencing the nature of dislocation loops in high-entropy alloys, and provide important clues to the design of alloys for nuclear applications.

Research on bonding mechanism of Cu/Al corrugated composite plates rolled by flat finish roll bonding

Cu/Al composite plates with excellent properties were prepared using a new type of corrugated cold roll bonding (CCRB) + flat finish roll bonding (FFRB) process. In this paper, the bonding mechanism and interface strengthening mechanism of FFRB process were studied by experimental and numerical simulation methods. Furthermore, the mechanical properties of typical positions were studied. The results indicate that the FFRB process reduces the difference in bonding properties between the peak II and trough II. The bonding strength increases with the increase of reduction. When the reduction reaches 60%, the peel strength of interface at peak II and trough II is 45.04 N/mm and 35.83 N/mm, respectively. Meanwhile, the strong bond at the interface is conducive to transferring the center of strain localization (SL) to the Al side with excellent plasticity, delaying the necking and fracture of Cu/Al composite plates. After FFRB, Cu/Al composite plates develop from the annealed metallurgical bonding interface to the staggered distribution of metallurgical bonding and new bonding interface. The newly formed bonding interface and the particle pinning effect of the intermediate metal compounds (IMC) fragments work together to strengthen the bonding performance of the composite plates.

Effect of Cu addition on the thermal conductivity and mechanical properties of Mg–Zn-xCu-Ce alloys

Thermal conductivity and mechanical properties of Mg–Zn-xCu-Ce alloys with different Cu contents under low extrusion temperature were systematically investigated in this work. The results shows that MgZnCu and Ce-rich (Mg, Zn, Cu, Ce) phase were formed in Mg–Zn-xCu-Ce alloys with high Cu content, which have significantly effect on the thermal conductivity and dynamic recrystallization (DRX). The distribution of grain morphology and LAGBs indicates that CDRX is the main mechanism. The addition of Cu element has an inhibitory effect on the DRX behavior, greatly refining the DRXed grains. After extrusion, a large amount of nano-phase is dispersed in the MZEC alloy, which has a strong pinning effect on dislocations. The formation of MgZnCu phase with high thermal conductivity sacrifices the solute atoms of Zn and Cu in α-Mg matrix, which leads to reduction of lattice distortion of Mg matrix, thereby ensuring high thermal conductivity of Mg–Zn–Cu–Ce ternary magnesium alloys. With the increase of Cu content, the strength and thermal conductivity of the alloy gradually increases. When the Cu content is 3.6 wt%, UTS (ultimate tensile strength), YS (yield strength), EL (elongation) and thermal conductivity are 350 MPa, 317 MPa,15.8% and 135 W/m∙K, respectively.

Oxygen solutes-regulated low temperature embrittlement and high temperature toughness in vanadium

The plasticity of body-centered cubic (BCC) metals is sensitive to interstitial trace impurities. Owing to high oxygen affinity, vanadium (V) shows a tendency of embrittlement with increasing oxygen concentration. However, how oxygen solutes affect the ductile-to-brittle transition (DBT) behavior of V remains unclear. In this study, we investigate the DBT behavior of V with different oxygen solute concentrations using small-punch test. As oxygen content increases, the DBT temperature (DBTT) rises incrementally accompanied by a widening of the semi-brittle transition zone. The reduction of the lower fracture energy plateaus indicates a classical low-temperature embrittlement, while the rising of the upper fracture energy plateaus manifests a remarkable high-temperature toughening. Below DBTT, owing to the strong pinning effect of oxygen-vacancy complexes on dislocations, only a limited number of slip systems were activated with very low dislocation density, and all screw dislocations are immobile. Above DBTT, owing to the intensive interactions between dislocation and oxygen-vacancy complexes, frequent dislocation cross-slips trigger multiple slip systems and accelerate dislocation multiplication and storage, all of which contribute to the high-temperature toughness. These findings clarify the effect of oxygen solute on the DBT of V and guide the design of high-performance refractory metals.

Twinning initiation from edge dislocations pinned by hydrogen atoms in bcc iron: A molecular dynamics study

Understanding how hydrogen affects the slip and twinning behaviors in metals is paramount for ensuring safe material use in a hydrogen environment and contributing to the development of hydrogen-resistant structural metals. Despite recent reports highlighting an increase in hydrogen-induced twinning in metals under applied deformations, the root case remains elusive. Here, we use molecular dynamics simulations to investigate how high hydrogen concentrations and shear direction affect edge-dislocation behavior in bcc iron. Our findings reveal that the pinning effect increases with hydrogen density along the dislocation line. This effect becomes more pronounced when shear is applied along the twinning direction. We demonstrate the nucleation of micro-twinning, characterized by a three atomic-layer thickness, originating from the dislocation under these conditions. The growth mechanism of this phenomenon aligns with Mahajan's model. Our findings identify the high shear stress as the primary driver for twinning, owing to the hydrogen's strong pinning effect.

In situ high-temperature transmission electron microscopy investigation of dynamic element migration for Sm-Co-Fe-Cu-Zr sintered magnets

The investigation delved into the dynamic migration of elements and the evolution of interface structures within the Sm(CobalFe0.09Cu0.09Zr0.03)7.2 magnet as temperature increased, employing high-temperature transmission electron microscopy. Notably, the Cu distribution exhibited temperature susceptibility. Elevating the temperature from room temperature (RT) to 400 °C led to a notable expansion in the distribution width of Cu, ranging from 28.5 to 50.8 nm. Simultaneously, the average Cu content at the cell boundaries decreased from 14.4 to 11.6 at.%. According to the high-temperature in-situ experimental results of the transmission electron microscopy thin-film samples, the derived diffusion coefficients, D300°Cand D400°C, were determined as 0.0525 nm2/s and 1.414 nm2/s, respectively. The significantly higher D400°C compared to D300°C underscores the considerable influence of temperature on Cu element diffusion behavior. The simulation results demonstrate that the trend of magnetic properties variation at different temperatures closely aligns with the observed trend. Subsequent calculation of the temperature coefficient of intrinsic coercivity (β) reveals that |β300–400°C| is notably higher than |βRT-300°C|. This suggests a substantial impact of Cu diffusion-induced deterioration on the β. Moreover, micromagnetic simulation results delineated the reverse magnetization process for magnets at varying temperatures, revealing that the presence of the Cu diffusion region diminished the pinning effect of the cell boundary phase. Furthermore, a wider Cu diffusion region facilitated easier magnetic moment reversal at the cell boundary phase, resulting in a marked deterioration of intrinsic coercivity. This elucidates that the formation of the Cu diffusion region stands as one of the primary reasons for the sharp decline in magnetic properties of Sm2Co17-type magnets under high-temperature conditions.

Compromise Design of Resonant Levels in GeTe‐Based Alloys with Enhanced Thermoelectric Performance

AbstractResonant levels (RLs) are expected to increase the density of states (DOS) abruptly, thereby increasing the Seebeck coefficient for a high thermoelectric figure of merit (ZT). However, the negative effects of RLs on reducing the carrier mobility and band gap have rarely been explored. In this work, the pros and cons of resonant‐state doping of group IIIA elements (In, Ga) in GeTe‐based alloys are studied by experimental transport properties and density‐functional‐theory calculations. RLs effects of Fermi level pinning and increased effective mass are strong in Ge0.9‐xInxSb0.1Te but weak in Ge0.9‐y(In0.5Ga0.5)ySb0.1Te, which shows dependence on the hump DOS relative to the background, location of RLs, and energy width of RLs. Using the In‐Ga co‐doping strategy to make a compromise between the DOS, carrier mobility, and bipolar transport, combined with beneficial alloying effects of Pb and Sb, a peak ZT≈ 2.1 at 773 K and a high average ZT≈ 1.43 within 300–773 K can be obtained in Ge0.78In0.005Ga0.005Pb0.1Sb0.07Te. The corresponding single‐leg device shows a remarkable energy conversion efficiency of 13.7% at a temperature difference of 451 K. This work suggests that RLs are not always beneficial for improving ZT, and the compromise design of RLs should be carefully considered to advance ZT.

Dramatically Enhanced Mechanical Properties of Nano-TiN-Dispersed n-Type Bismuth Telluride by Multi-Effect Modulation.

Bismuth telluride (Bi2Te3)-based alloys have been extensively employed in energy harvesting and refrigeration applications for decades. However, commercially produced Bi2Te3-based alloys using the zone-melting (ZM) technique often encounter challenges such as insufficient mechanical properties and susceptibility to cracking, particularly in n-type Bi2Te3-based alloys, which severely limit the application scenarios for bismuth telluride devices. In this work, we seek to enhance the mechanical properties of n-type Bi2Te2.7Se0.3 alloys while preserving their thermoelectrical performance by a mixed mechanism of grain refinement and the TiN composite phase-introduced pinning effect. These nanoscale processes, coupled with the addition of TiN, result in a reduction in grain size. The pinning effects of nano-TiN contribute to increased resistance to crack propagation. Finally, the TiN-dispersed Bi2Te2.7Se0.3 samples demonstrate increased hardness, bending strength and compressive strength, reaching 0.98 GPa, 36.3 MPa and 74 MPa. When compared to the ZM ingots, those represent increments of 181%, 60% and 67%, respectively. Moreover, the thermoelectric performance of the TiN-dispersed Bi2Te2.7Se0.3 samples is identical to the ZM ingots. The samples exhibit a peak dimensionless figure of merit (ZT) value of 0.957 at 375 K, with an average ZT value of 0.89 within the 325-450 K temperature range. This work has significantly enhanced mechanical properties, increasing the adaptability and reliability of bismuth telluride devices for various applications, and the multi-effect modulation of mechanical properties demonstrated in this study can be applied to other thermoelectric material systems.

Efficient Modulation of Schottky to Ohmic Contact in MoSi2N4/M3C2 (M = Zn, Cd, Hg) van der Waals Heterostructures.

A strong Fermi level pinning (FLP) effect can induce a large Schottky barrier in metal/semiconductor contacts; reducing the Schottky barrier height (SBH) to form an Ohmic contact (OhC) is a critical problem in designing high-performance electronic devices. Herein, we report the interfacial electronic features and efficient modulation of the Schottky contact (ShC) to OhC for MoSi2N4/M3C2 (M = Zn, Cd, Hg) van der Waals heterostructures (vdWHs). We find that the MoSi2N4/M3C2 vdWHs can form a p-type ShC with small SBH with the calculated pinning factor S ≈ 0.8 for MoSi2N4/M3C2 contacts. These results indicate that the FLP effect can be effectively suppressed in MoSi2N4 contact with M3C2. Moreover, the interfacial properties and SBH of MoSi2N4/Zn3C2 vdWHs can be effectively modulated by a perpendicular electric field and biaxial strain. In particular, an efficient OhC can be achieved in MoSi2N4/Zn3C2 vdWHs by applying a positive electric field of 0.5 V/Å and strain of ±8%.

Evaluation of the Central Copper Contact Pin Effect in High-Energy Region in Gamma-ray Spectrometry

The detector must be modeled in the most accurate way when Monte Carlo simulation method is used for efficiency calculation in gamma-ray spectrometric studies. This study aims to investigate the effect of the copper contact pin inside the detector on the efficiency of the HPGe detector for high gamma-ray energies. Simulated efficiencies were determined for 6 different energies in the energy range of 1460.8 keV up to 2614.5 keV in point and cylindrical source geometry. According to the modeling using PHITS Monte Carlo simulation code, the presence of copper contact pin at high gamma-ray energies caused a decrease of up to 6% in detector efficiency. It was emphasized that this ignored parameter should be included in the modeling like all other geometric parameters used in detector modeling, by showing the effect on the efficiency.

In-situ thermal annealing effects on domain wall velocity in Pt/Co/Pt trilayer thin films with perpendicular magnetic anisotropy

The Pt/Co/Pt trilayer system is widely studied for its perpendicular magnetic anisotropy (PMA). In this work we delve into the effects of thermal annealing from the perspective of magnetic domain wall dynamics. We find that the coercivity of the films remains constant while the domain wall velocity decreases drastically with thermal annealing (≤473 K). The decrease in the creep scaling constant with annealing temperature, confirm the enhanced pinning effect. Our results demonstrate that annealing temperature can significantly affect the magnetic micro-structure as well as magnetic domain dynamics in Pt/Co/Pt films with PMA.

The effect of network cementite dissolution on the nucleation and growth of prior austenite grains in high carbon low alloy steels

The state of austenite grains has an essential role in the microstructure transformation and mechanical properties of alloy steel during heat treatment or subsequent hot working. The initial microstructure of alloy steel is inseparable from the nucleation and growth of austenite grains. Hence, in this work, high carbon low alloy steel with the initial microstructure of lamellar pearlite and grain boundary cementite was selected, and the effect of cementite dissolution on austenite grain growth was analyzed from the perspective of the phase transition dilatometer curve. Three nucleation sites in high carbon low alloy steel were found by multi-perspective characterization, forming two types of austenite grains: pearlite-austenite grain and cementite-austenite grain. Under cementite pinning and solute drag effect, the growth of the prior austenite grains was retarded during the isothermal temperatures process. The average size of prior austenite grains increased only from 65.1 μm (1050 °C) to 69.8 μm (1150 °C). This work provides a foundation for optimizing the prior austenite grains state by utilizing grain boundary cementite dissolution.

Insights into primary carbides and nanoparticles in an additively manufactured high-alloy steel

This paper reports the use of combined electron microscopy and small-angle neutron scattering (SANS) to probe into the compositional and size evolution of the primary carbides and nanoparticles (defined by a size threshold of 100 nm) in an additively manufactured high-alloy steel before and after heat treatment. The primary carbides exhibit marginal changes in their total volume fraction and size after the austenitising and tempering. However, those carbides located at the prior-austenite boundaries provide a pinning effect to impede grain growth during the austenitising. The grain size increases from 1.7 µm in the as-manufactured to 2.8 µm in the as-tempered conditions, resulting in a limited strength loss of 33–126 MPa as estimated by using the Hall-Petch relationship. Atom probe tomography, which offers atomic spatial resolution examining a sample volume of 6.6 × 105 nm3, reveals the presence of numerous V and Cr-enriched nanoparticles with sizes of 1 to 10 nm within the steel matrix after the tempering. In contrast, the complementary SANS which examines a significantly larger sample volume of 0.9 mm3 but lacking spatial resolution, provides nanoparticle size information. It reveals a radius reduction from 7.6 to 1.0 nm and a volume fraction increase from 1.6 % to 2.3 %, in the as-manufactured and as-tempered conditions, respectively. The nanoparticles induced during tempering can contribute to a strength enhancement of 691 MPa, primarily through the Orowan bypass mechanism. This suggests that the combination of limited prior-austenite grain growth and the presence of nanoparticles is the key factor responsible for the unprecedented material strength.

Topological domain characteristics during the transition from ferroelectric to antiferroelectric in hexagonal manganites

Hexagonal manganites can exhibit the low-symmetry ferroelectric (FE) P63cm and partially undistorted anti-ferroelectric (PUA) P-3c1 states. The two states are accompanied by distinct sixfold vortex domain structures. The transition from the FE P63cm and PUA P-3c1 states (FE-PUA transition) is an effective means to control domain structures with distinct FE properties, which is of rich physical properties and potential applications. The FE-PUA transition can only be achieved by doping Ga on the Mn site of InMnO3, but the actual transition path and the associated domain structure evolution are still unclear. Namely, whether this transition goes through an intermediate P3c1 state remains an issue. In this work, we start from the Landau phenomenological theory to investigate the FE-PUA transition by directly tracking the domain structure evolution. The emerging 12-fold vortex domain structure at the intermediate stage of this transition indicates that this transition is not direct, and its actual path follows the P63cm → P3c1 → P-3c1 sequence, demonstrating the essential role of the intermediate P3c1 state. Besides, a pinning effect as a by-product is also discussed. This work comprehensively illustrates the characteristics of domain structure evolution during the FE-PUA transition, refining our understanding of the whole phase transition and topological physics associated with vortex domain structures in hexagonal manganites.

A Wooden Pin Reinforcement of Ancient Chinese Wooden Temple: A Case of Daxiong Hall

Post and lintel frame is a prominent architectural structure in Chinese temple architecture, characterized by its wooden construction. Mortise–tenon joints (MTJs) serve as the primary connection method for these wooden structures, employing straight mortise nodes (SMNs) and through-mortise joints (TMNs). This study presents a method that utilizes wooden pins to reinforce MTJs, enhancing the seismic performance of timber frame structures. Finite element (FE) simulation verifies the effectiveness of wooden pins in reinforcing both SMNs and TMNs, leading to improved load-bearing capacity and ductility of the MTJs. Additionally, the study confirms that reinforced nodes help to restrict the displacement changes within the wooden frame. The paper also investigates the optimal distribution of MTJs reinforced by the wooden pins throughout the structure, with the aim of enhancing the wood frame’s seismic performance. The results show the bearing capacity of MJT reinforced with wooden pins is approximately 11.3% higher compared to that of MTJ without reinforcement. The reinforcement of wood pins effectively controls the horizontal displacement of the overall structure of the wooden frame, which is reduced by about 50%–62% compared with the unreinforced wooden frame. The locating the wooden pin-reinforced MTJs in the outer columns and middle layer columns reduces the structural displacement, which is 31.53% in X direction, 5% in Y direction, and 25.86% in Z direction.

Effect of intermediate cooling rate normalizing on microstructure and creep rupture strength of P91 Steel

In this work, the P91 sample bearing intermediate normalizing cooling rate(200 ℃/h) was prepared. Its mechanical and creep properties were compared with the air-cooling (2000 ℃/h) normalized sample, and the differences of microstructure evolution were also compared by employing OM, SEM/EBSD and TEM/EDS. Results showed that after normalizing, twin martensite appeared in P91 steel with intermediate cooling rate, and its microstructure was coarser than the air-cooled one. Strength and hardness of the slow-cooled P91 steel were somewhat lower than the air-cooled one, but it had much lower toughness because of the formation of twin martensite. After tempering, P91 steel with intermediate cooling rate recovered more completely with twin martensite disappearing. Its strength and hardness dropped evidently, and were still lower than the air-cooled one, but it witnessed a predominant improvement in toughness. Creep rupture strength of the slow-cooled P91 steel was markedly lower than the air-cooled one. The main cause of that was the coarsening and different distributions of M23C6 carbides, which weakened the pinning effect and ultimately resulted in degradation acceleration.

First‐Principles Study of Schottky Barrier Heights on Metal/4H‐SiC Polar Interfaces

4H‐SiC based devices have garnered significant interest within the realm of high‐voltage and high‐frequency electronic equipment. Schottky barrier heights (SBHs) play a pivotal role in determining the properties of metal/4H‐SiC contacts and holding significance for electrical performance of 4H‐SiC devices. Herein, the first‐principles method is utilized to investigate the interface properties between various metals (Sc, Mg, Zr, Ag, Al, Ru, Rh, Pd, Ni, Au, Ir, and Pt) and 4H‐SiC. The results reveal an approximate linear relationship between SBH and work function of these metals. Fermi‐level pinning factors are determined to be 0.27 and 0.32 for the Si‐face and C‐face interfaces, respectively. The disparity in pinning factors arises from polarization differences between the two interfaces, which stem from uneven net charge distribution on the Si‐face and C‐face. Meanwhile, the SBH values indicate a strong pinning effect, due to the charge transfer occurring at the metal/4H‐SiC interface. Through further analysis of layer density and differential charge density, the interatomic interaction and charge transfer between metal and SiC atoms are analyzed. This work offers fundamental insights into the structural changes in metal/4H‐SiC interfaces and provides valuable guidance in the potential prediction and optimization of device performance.