The synchronized switch interface circuit is believed to boost the piezoelectric power generation. The threshold voltage of electronic components causes rectification loss and delay of peak detection. This work reports a novel design of a mechanical rectification piezoelectric vibration energy harvester (MR-PVEH). Compact and low loss mechanical rectification is achieved by double switch with 5 electrodes contact at the cantilever tip. The switch as a mechanical stopper also contributes to broadband performance. The saturation voltage and response frequency range can be adjusted in modeling and simulation of nonlinear electromechanical coupling vibration. Self-adapting Mechanical rectification optimized synchronous electric charge extraction (M-OSECE) circuit is also proposed with less electronic components in this paper and shows an extra 60% increase in generated power than the traditional standard energy harvesting circuit (SEH) in test. This novel design gives a promising solution for self-adapting synchronous switching in broadband piezoelectric vibration energy harvesting.