Piezoelectric Devices Research Articles

Superelastic electromechanical behaviors in ferroelectric PbTiO[formula omitted] ceramics under coupled mechanical-electric fields: Higher-order piezoelectric constitutive equations from first-principles

With the recent discovery of superelastic behaviors of ferroelectric (piezoelectric) ceramics, understanding their non-linear mechanical and electromechanical responses under high stress and electric field conditions is crucial for engineering and designing advanced piezoelectric devices, such as ultrasmall actuator systems. In this study, we carry out first-principles finite electric field calculations to clarify the mechanical and electromechanical properties under the electric field for typical ferroelectric ceramics of PbTiO3. Superelastic-like non-linear deformation behavior is enhanced or suppressed depending on the electric field direction, suggesting the possible design of superelasticity. We clarified that positive and negative electric fields to spontaneous polarization promote and inhibit deformation due to strain loading, thereby providing tunable superelasticity. We also investigate the mechanical loading and electric field dependence of the piezoelectric coefficient of PbTiO3. The tunable piezoelectric response can be provided with a coupling of mechanical loading and electric field. Finally, we present higher-order piezoelectric constitutive equations applicable for superelastic-like non-linear deformations under an electric field. The present results will open promising paradigms for functional piezoelectric devices, and the proposed piezoelectric constitutive equations broaden the design scope through finite element method analysis.

Bone lid technique versus standard technique for treatment of mandibular lesions

BackgroundJaw lesions are frequent in the oral and maxillofacial areas. Different methods for enucleating jaw lesions in the oral and maxillofacial sites have been proposed, including the bone lid technique.PurposeThe aim of this study was to compare the clinical and radiographic results of the bone lid technique employing a piezoelectric surgery to the traditional technique in individuals with mandibular lesions.Materials and methodsA randomized controlled trial was conducted on 24 patients with mandibular lesions. They were randomly allocated into two groups (n = 12 for each group). Group I: the mandibular lesion was excised with bone lid technique using a piezoelectric device, followed by the fixation of the bony window after its repositioning. Group II: the lesion was excised with the traditional method using rotatory burs. Pain, soft tissue healing, bone exposure, bone lid integration, and the volume of the residual bone defect were all assessed clinically and radiographically after one week, one month, and six months.ResultsAll patients in both groups showed adequate soft tissue healing except for one case in group I experienced wound dehiscence and bone lid exposure. The bone lid group reported significantly less pain than the usual approach at the 3rd and 7th days. After six months, the volume of bone defect filling was considerably higher in the bone lid group compared to the conventional group.ConclusionThe bone lid technique was an effective procedure in the management of mandibular lesions compared to the standard method. Besides, this technique provides better bone healing and reduces bone loss.Trial registrationThis clinical trial was registered at clinicaltrials.gov on 14/8/2023 and had registration number NCT05987930.

Piezoelectric device use in sinus osteotomy for equines is feasible but may extend time to accomplish frontonasal bone flap.

Sinus osteotomy is currently performed in equine surgery with conventional surgical methods, such as trephines and oscillating bone saw, leading to subsequent trauma to the bone during cutting. Piezoelectric devices are now used in maxillofacial surgery in humans as a standard tool as it is less traumatic than the oscillating bone saw and shortens the healing period. The aim of this study was to show that the piezoelectric device can be used for equine sinus surgery, compare its use with the oscillating bone saw, and describe the outcome of cases involving osteotomy performed with a piezoelectric surgical device. 10 horse specimens for cadaveric study and 11 client-owned equines for clinical evaluation. Each cadaveric head underwent a frontonasal bone flap on a randomly assigned side with the piezotome and the oscillating bone saw on the opposite side. Surgical time was recorded for every procedure, and gross examination was performed. A Welch t test was used to compare the surgical time between piezoelectric and oscillating saw use. For the clinical study, animals presented for sinonasal surgery at the hospital from March through October 2023 were included. Osteotomy was possible with the piezotome in all animals. Surgical time was significantly increased when using the piezotome in comparison with the oscillating saw (P < .05). All clinical patients were treated adequately for the sinonasal disorder they were presented for using the piezotome instead of the oscillating saw. No adverse effects nor long-term complications related to its use have been noted, and preservation of the surrounding soft tissues was evident. The use of a piezoelectric device in equine surgery is feasible. However, the cadaveric study showed an increased surgical time to perform a frontonasal bone flap.

Novel Piezoelectric Device for Inducing Strain on Biological Tissue At High Speed

Novel Piezoelectric Device for Inducing Strain on Biological Tissue At High Speed

Optimizing Piezoelectric Energy Harvesters: A Comprehensive Review of GWO-GA Techniques

The process of turning the environment's discarded vibrational energy into useful electrical energy is known as energy harvesting. The approach of vibration energy collecting is selected because it can be used to develop devices that are smaller and more effective. Piezoelectric Energy Harvesters (PEHs) are preferred over other forms of energy collecting devices including electrostatic, electromagnetic, and piezoelectric ones because of their versatility and adaptability. Lead zirconate titanate, or PZT-5H, is the most widely used piezoelectric material. It is selected for its power generating efficiency and versatility. The analysis indicates that more time is needed to determine the proper dimensions of the energy harvester for the planned piezoelectric devices. By applying optimisation approaches, the design factors of the piezoelectric energy harvester are optimised, contributing significantly to the system's increased efficacy. The PEH's design parameters are optimised through the application of optimisation techniques including Genetic Algorithm (GA), Grey Wolf Optimisation (GWO), and GWO-based GA (GWO-GA). Keywords— Energy Harvesting, Piezoelectric Energy Harvesters (PEH), Grey Wolf Optimization (GWO), Genetic Algorithm (GA), etc.

Improved piezoelectric performance in CBN-based ceramic through triple-doping (Li, Bi, Ce) strategy

Bismuth layered structural ferroelectrics (BLSFs) with high Curie temperature (TC) and low aging rate establish the groundwork for the advancement of high-temperature piezoelectric devices. CaBi2Nb2O9 (CBN) is an excellent candidate for possessing the highest TC value (∼940 °C) among BLSFs. However, its poor piezoelectricity impedes practical applications. Generally, the excellent piezoelectric properties of CBN-based ceramics depend on intrinsic and extrinsic contributions. Here, Aurivillius ferroelectrics with triple-doping ions, Ca1–2x(LiBi0.7Ce0.3)xBi2Nb2O9 (CBN-xLBC), were fabricated to achieve large piezoelectric constant (d33∼23.3 pC/N) and high Curie temperature (∼906 °C) simultaneously due to tetragonal distortion and smaller nanodomains. Besides, the DC resistivity of optimal sample is still above 1×105 Ω·cm at 600 °C. At the same time, the ferroelectricity is improved significantly with large Pr (∼18.9 μC/cm2) when x=0.275. The improved comprehensive performance of CBN-based ceramic indicates that proper various ions synergetic effect plays an important role and CBN-0.275LBC ceramic is expected to apply in practical industry.

Piezoelectric, Thermoelectric, and Photocatalytic Water Splitting Properties of Janus Arsenic Chalcohalide Monolayers.

In this study, we systematically investigate the piezoelectric, thermoelectric, and photocatalytic properties of novel two-dimensional Janus arsenic chalcohalide monolayers, AsXX' (X = S and Se and X' = Cl, Br, and I) using density functional theory. The positive phonon spectra and ab initio molecular dynamics simulation plots indicate these monolayers to be dynamically and thermally stable. The mechanical stability of these monolayers is confirmed by a nonzero elastic constant (C ij ), Young's modulus (Y 2D), and Poisson ratio (ν). These monolayers exhibit strong out-of-plane piezoelectric coefficients, making them candidate materials for piezoelectric devices. Our calculated results indicate that these monolayers have a low lattice thermal conductivity (κl) and high thermoelectric figure of merit (zT) up to 1.51 at 800 K. These monolayers have an indirect bandgap, high carrier mobility, and strong visible light absorption spectra. Furthermore, the AsSCl, AsSBr, and AsSeI monolayers exhibit appropriate band alignment for water splitting. The calculated value of the corrected solar-to-hydrogen conversion efficiency can reach up to 19%. The nonadiabatic molecular dynamics simulations reveal the prolonged electron-hole recombination rates of 1.52 0.98, and 0.67 ns for AsSCl, AsSBr, and AsSeI monolayers, respectively. Our findings demonstrate these monolayers to be potential candidates in energy-harvesting fields.

Spatially-resolved in-situ/operando structural study of screen-printed BaTiO3/P(VDF-TrFE) flexible piezoelectric device

The incorporation of lead-free BaTiO3 particles into P(VDF-TrFE) provides a versatile way for tuning dielectric and piezoelectric properties. Screen-printing enables the easy production of flexible capacitors. To prevent particle aggregation, the BaTiO3 particles are functionalized with a surfactant. Initially, 60 % vol. BaTiO3 particles are deposited in the second layer out of three layers. After annealing and cooling, the particle distribution is successfully homogeneous in the whole film. After poling at 80 °C, the relative permittivity and the piezoelectric coefficient d33 significantly increase up to 159 and 8 pC/N respectively. In situ/operando spatially-resolved X-ray techniques allow exploring the structural evolution of the composite device during annealing and during an applied electric field. The application of an electric field leads to the quasi-disappearance of the P(VDF-TrFE) ferroelectric state. As a matter of fact, the interactions between the P(VDF-TrFE) and the surfactant may limit the rotation of P(VDF-TrFE) chains near the particles. Hence, paraelectric polymers could be chosen on a mechanical or economic basis for the matrix in piezoelectric composite devices. Regarding BaTiO3, the lattice strain evolves from an extrinsic strain at RT to an intrinsic strain after annealing and cooling. At the cooled state, the tetragonality c/a is higher than 1.01, leading to improved piezoelectric properties. The increase of the average domain size leads to the increase of the composite permittivity. Finally this knowledge facilitates the development of tailored flexible piezoelectric composite devices.

Realization of ultra-high temperature stability and excellent electrical properties in LTO-based ceramics via A/B-site co-doing

La2Ti2O7 (LTO) ceramics, ideal for ultra-high temperature applications with a Curie temperature near 1460 °C, were previously limited by a low piezoelectric coefficient (d33) of 1.5 pC/N. In this work, the incorporation of Bi3+ and V5+ dopants have been employed to augment the piezoelectric properties of LTO. An enhanced d33 ∼ 4.0 pC/N is achieved in La1.91Bi0.09Ti1.97V0.03O7 (LBTV9) ceramics, while maintaining an ultra-high Curie temperature of 1437 °C. This improvement is attributed to local heterogeneity in the lattice structure induced by the doping. LBTV9 ceramics also exhibit excellent high-temperature stability and insulation properties, maintaining a d33 at 4.0 pC/N after annealing at 1000 °C for 48 h and stabilizing at 4.2 pC/N across temperatures from 200 °C to 1600 °C, with a DC resistivity of 1.7 × 106 Ω·cm at 1000 °C. These enhancements make LBTV9 ceramics suitable for extreme condition applications, thus unlocking new possibilities for their use in ultra-high temperature piezoelectric devices.

Piezoelectric Enhancement in P(VDF-TrFE) Copolymer Films via Controlled and Template-Induced Epitaxy.

The surge in wearable electronics and Internet of Things technologies necessitates the development of both flexible sensors and a sustainable, efficient, and compact power source. The latter further challenges conventional batteries due to environmental pollution and compatibility issues. Addressing this gap, piezoelectric energy harvesters emerge as one kind of promising alternative to convert mechanical energy from ambient sources to electrical energy to charge those low-energy-consumption electronic devices. Despite slightly lower piezoelectric performance compared with those inorganic materials, piezoelectric polymers, notably poly(vinylidene fluoride-co-trifluoroethylene) P(VDF-TrFE), offer compelling properties for both flexible mechanical energy harvesting and self-powered strain/stress sensing, though their piezoelectric performance is expected to be further enhanced via varieties of modulation strategies of microstructures. Herein, we reported the controlled epitaxy process of micrometer-thick copolymer films with the cooperation of friction-transferred poly(tetrafluoroethylene) templates and precise modulation of the annealing conditions. Epitaxial P(VDF-TrFE) films present averaged d33 piezoelectric coefficient of -58.2 pC/N between 50 Hz and 1 kHz with good electromechanical and thermal stability. Owing to the nature of anisotropic crystallization, the epitaxial films exhibit an anisotropic transverse piezoelectric property. Epitaxial films were further utilized for mechanical energy harvesting and monitoring of human pulsation and respiration. This study provided a feasible route for the development of high-performance flexible piezoelectric devices to meet the requirement of flexible electronics.

Variable-Length Pendulum-Based Mechatronic Systems for Energy Harvesting: A Review of Dynamic Models

The ability to power low-power devices and sensors has drawn a great deal of interest to energy harvesting from ambient vibrations. The application of variable-length pendulum systems in conjunction with piezoelectric or electromagnetic energy-harvesting devices is examined in this thorough analysis. Because of their changeable length, such pendulums may effectively convert mechanical vibrations into electrical energy. This study covers these energy-harvesting systems’ basic theories, design concerns, modeling methods, and performance optimization strategies. This article reviews several studies that look at dynamic models, the effects of damping coefficients, device designs, and excitation parameters on energy output. The advantages and disadvantages of piezoelectric and electromagnetic coupling techniques are demonstrated by comparative research. This review also looks at technical advances and future research prospects in variable-length, pendulum-based energy harvesting. An expanded model for an energy harvester based on a variable-length pendulum derived from the modified, swinging Atwood machine is more specifically presented. This model’s numerical simulations, estimated current and voltage outputs, and produced power from the electromagnetic and piezoelectric devices integrated at various points in a 4-DOF variable-length pendulum model all indicate encouraging results. This necessitates extra study, changes, and optimizations to improve the usefulness of the proposed model. Finally, important dynamic models on developing variable-length, pendulum-based energy harvesters for usage in a range of applications to create sustainable energy are summarized.

Energy transfer, conversion and mechanical regulation in graded piezoelectric semiconductor bipolar junction transistor

While the effective regulation of carrier redistribution in piezoelectric semiconductor devices by mechanical loads through piezoelectric polarized electric fields is well-studied, there is a scarcity of reported research on the influence of energy transfer and conversion characteristics in a non-thermal equilibrium state of these devices. This paper establishes a nonlinear multi-field coupling model for piezoelectric semiconductor graded bipolar junction transistor (PS-GBJT) and proposes a corresponding multi-gradient iterative algorithm. We regard the product of current and built-in electric field as the work done by electric field force on carriers. By incorporating the energy absorbed/released during carrier recombination/generation process, we observe that non-equilibrium carriers act as a medium that facilitates energy conversion between these two mechanisms. Additionally, the non-uniformly distributed doping extends the influence of space charge region throughout entire transistor. In terms of external input electrical energy, the emitter, base, and collector regions play roles of input energy, transfer energy, and output energy, respectively. The study concludes by demonstrating the regulation of energy transfer or conversion efficiency in emitter, base, and collector regions through mechanical loads, thereby altering the heating behavior of entire GBJT and reshaping its energy transfer path. This leads to the significant finding that distinct energy transfer paths fundamentally define the various operational states of GBJT. The novel insights gained from this research hold reference value for thermal design and energy management of electronic devices.

High Performance Piezoelectric Nanogenerators Based on Polyvinylidene Fluoride-Graphene Nanoribbon Composite Thin Films.

In this study, a highly efficient, sensitive, and lightweight piezoelectric nanogenerator (PENG) is developed using graphene nanoribbons (GNRs) incorporated into the polyvinylidene fluoride (PVDF) matrix. Unzipping multi-walled carbon nanotubes is an effective and scalable strategy for synthesizing graphene nanoribbons. The synthesized GNRs are employed to prepare nanometer-scale piezoelectric polymer composite films showing higher piezoelectric performance than neat PVDF. The impact of GNR concentration in the PVDF matrix on the electroactive phase content and piezoelectric properties of the composites is systematically investigated. X-ray diffraction (XRD) and Fourier-transformed infrared spectroscopy (FT-IR) analysis demonstrate an increase in the electroactive β and γ phases of PVDF by incorporating GNRs in the composites. With the optimized concentration of GNRs (1 wt%), the fabricated piezoelectric device can generate open-circuit voltage and an output power density of 26V and 16.52 µWcm2, respectively. It is also found that the PVDF-GNR 1 nanogenerator can be used to generate electrical power by converting mechanical energy from different human activities such as wrist bending, palm tapping, and toe tapping. The findings indicate that (PVDF-GNR 1) PENGcan be applied in self-powered portable and wearable electronic devices.

A scandium doped aluminum nitride thin film bulk acoustic resonator

Currently, we stand at the forefront of revolutionary advancements in communication technology. The escalating demands of advanced communication necessitate enhanced performance from materials and radio frequency devices. This paper aims to enhance film performance by depositing scandium-doped aluminum nitride (ScAlN) directly onto a Si substrate. Additionally, ScAlN was deposited on SiO2/AlN/Mo functional layers for comparison purposes. The ScAlN directly deposited on Si demonstrated superior performance in terms of crystalline quality and surface roughness, with a full width at half maximum of 1.7° and a roughness of 1.76 nm. Furthermore, a film bulk acoustic resonator (FBAR) based on the ScAlN film directly deposited on Si was successfully fabricated through thin-film transfer, with critical processes achieved via bonding and wet-etching of the substrate. The ScAlN in the fabricated resonator exhibited a favorable c-axis preferred orientation. The resulting ScAlN-based FBAR displayed a quality factor of 429. This study lays the groundwork for exciting opportunities in the development of higher-performance piezoelectric materials and devices.

Coupling Response of Piezoelectric Semiconductor Composite Fiber under Local Temperature Change

This paper details the thermal–mechanical–electrical response of a piezoelectric semiconductor (PS) composite fiber composed of a PS layer and two piezoelectric layers under local temperature change. The phenomenological theory of thermal piezoelectric semiconductors (PSs) is adopted to obtain the analytical solution for each field in the composite fiber under local temperature change. Our findings reveal that such temperature fluctuations induce local polarization, leading to the formation of local potential barriers and potential wells that effectively impede the flow of low-energy electrons along the fiber. Furthermore, the initial carrier concentration and geometric parameters of the composite fiber exert significant influence on its individual fields. The results contribute to the structural design and practical application of piezoelectric semiconductor devices.

Compressive stress reduction in sputter-deposited yttrium aluminum nitride (Y0.2Al0.8N) thin films for BAW resonators with high electromechanical coupling

In the past decade, rare earth elements have found increasing interest in enhancing the piezoelectric coefficient of aluminum nitride (AlN) thin films. Until now, scandium has been the most successful rare earth element to enhance the piezoelectric coefficient (d33) up to 600 %. In this research paper, we present a 250 % increase in d33 to 12.5 pC/N for sputter-deposited yttrium alloyed aluminum nitride (Y0.2Al0.8N) thin films compared to pure AlN. However, this increase in d33 comes with a substantial increase in compressive layer stress well above 1 GPa. Therefore, a chamber pressure sweep technique is introduced, resulting in a 40 % reduction in the stress level without significantly affecting the crystallographic film parameters to facilitate device integration. Even more, high compressive stress in thin films is a critical concern in piezoelectric MEMS devices such as bulk acoustic wave (BAW) resonators, as it can adversely affect the piezoelectric material properties and hence, the electromechanical performance. For this purpose, we demonstrate that the pressure sweep technique improves the electromechanical coupling factor of Y0.2Al0.8N to 7.02 %, being substantially above the reference value of 6.02 % set by pure AlN. In summary, the findings from this study may stimulate further effort to integrate YxAl1-xN thin films in BAW filter devices for future telecommunication applications.

A first-principles prediction of novel Janus ZrGeZ3H (Z = N, P, and As) monolayers: Raman active modes, piezoelectric responses, electronic properties, and carrier mobility.

In this article, an attempt is made to explore new materials for applications in piezoelectric and electronic devices. Based on density functional theory calculation, we construct three Janus ZrGeZ3H (Z = N, P, and As) monolayers and study their stability, piezoelectricity, Raman response, and carrier mobility. The results from phonon dispersion spectra, ab initio molecular dynamics simulation, and elastic coefficients confirm the structural, thermal, and mechanical stability of these proposed structures. The ZrGeZ3H monolayers are indirect band gap semiconductors with favourable band gap energy of 1.15 and 1.00 eV for the ZrGeP3H and ZrGeAs3H, respectively, from Heyd-Scuseria-Ernzerhof functional method. It is found that the Janus ZrGeZ3H monolayers possess both in-plane and out-of-plane piezoelectric coefficients, revealing that they are potential piezoelectric candidates. In addition, the carrier mobilities of electrons and holes along transport directions are anisotropic. Notably, the ZrGeP3H and ZrGeAs3H monolayers have high electron mobility of 3639.20 and 3408.37 cm2 V-1 s-1, respectively. Our findings suggest the potential application of the Janus ZrGeZ3H monolayers in the piezoelectric and electronic fields.

2D Janus TeMoZAZ’ (A = Si,Ge; Z,Z’ = N, P, As; Z ≠ Z'): First‐Principles Insight into the Electronics, and Piezoelectric Properties

AbstractJanus materials possess a diverse array of properties resulting from the breaking of mirror and inversion symmetries, holding significant potential for nanodevices. This study explores the novel TeMoZAZ' (A = Si,Ge; Z,Z' = N, P, As; Z ≠ Z') monolayers derived from the MoA2Z4 monolayer. Utilizing first‐principles calculations, the stability, electronic, transport, mechanical, and piezoelectric properties of the TeMoZAZ' monolayers are investigated. Among the 12 investigated structures, only five‐ TeMoNSiP, TeMoNSiAs, TeMoPSiAs, TeMoAsSiP and TeMoAsGeP monolayers‐ are found to be stable. The electronic properties analysis reveals metallic behavior in the TeMoNSiAs monolayer, while the remaining structures exhibit indirect or direct band gap semiconductor properties. Futher examination of the semiconducting monolayers indentifies the TeMoAsSiP monolayer with notably high hole carrier mobility along the y‐direction, reaching up to 3622.33 cm2 s−1 V−1. Moreover, investigation into the piezoelectric properties of these four semiconductor structures suggests their suitability for diverse applications in piezoelectric devices. Additionally, the effects of biaxial strain on the electronic and piezoelectric properties of these four semiconductor structures are explored. These findings propose a novel approach for designing 2D Janus materials, expanding the repertoire of 2D MA2Z4‐based Janus family and offering promising candidates for optoelectronic devices, wearable devices, and electromechanical systems.

Engineered Lysozyme: An Eco‐Friendly Bio‐Mechanical Energy Harvester

Eco‐friendly and antimicrobial globular protein lysozyme is widely produced for several commercial applications. Interestingly, it can also be able to convert mechanical and thermal energy into electricity due to its piezo‐ and pyroelectric nature. Here, we demonstrate engineering of lysozyme into piezoelectric devices that can exploit the potential of lysozyme as environmentally friendly, biocompatible material for mechanical energy harvesting and sensorics, especially in micropowered electronic applications. Noteworthy that this flexible, shape adaptive devices made of crystalline lysozyme obtained from hen egg white exhibited a longitudinal piezoelectric charge coefficient (d ~ 2.7 pC N−1) and piezoelectric voltage coefficient (g ~ 76.24 mV m N−1) which are comparable to those of quartz (~2.3 pC N−1 and 50 mV m N−1). Simple finger tapping on bio‐organic energy harvester (BEH) made of lysozyme produced up to 350 mV peak‐to‐peak voltage, and a maximum instantaneous power output of 2.2 nW cm−2. We also demonstrated that the BEH could be used for self‐powered motion sensing for real‐time monitoring of different body functions. These results pave the way toward self‐powered, autonomous, environmental‐friendly bio‐organic devices for flexible energy harvesting, storage, and in wearable healthcare monitoring.

Chromium‐substituted bismuth titanate–niobate exhibiting superior piezoelectric performance for high‐temperature applications

AbstractHigh‐temperature piezoelectric ceramics with excellent piezoelectric properties are key materials for high‐temperature piezoelectric devices. In this context, bismuth titanate–niobate (Bi3TiNbO9) is one of the most promising candidates, owing to its high Curie temperature (TC) &gt; 900°C. However, the relatively low piezoelectric response of prototype Bi3TiNbO9 does not satisfy the requirements of high‐precision and high‐sensitivity applications. Herein, chromium‐substituted Bi3TiNbO9 with a nominal composition, Bi3Ti1−xCrxNbO9 (BTN‐100xCr), was prepared using the solid‐state reaction method. Raman spectroscopy and X‐ray diffraction refinements revealed structural distortions induced by the substitution of chromium. Piezo‐response force microscopy and ferroelectric hysteresis loops showed facile polarization reversal and domain wall movement in chromium‐substituted Bi3TiNbO9. The resultant structural distortion and domain wall movement served as intrinsic and extrinsic contributions to the enhancement of the piezoelectric properties, respectively. Consequently, BTN‐1.5Cr exhibits a high piezoelectric constant (d33) of 17.7 pC/N, which is four times that of Bi3TiNbO9 (4.2 pC/N), a high TC of 908°C, and an excellent thermal stability of piezoelectric and electromechanical coupling properties up to 500°C. These results indicate that chromium substitution enhances the high‐temperature piezoelectric properties of Bi3TiNbO9, and chromium‐substituted Bi3TiNbO9 is a promising candidate for high‐temperature piezoelectric applications.