This study utilized the COMSOL Multiphysics software to conduct finite element analysis on the piezoelectric coupling effect of the composite layer structure. The article begins by introducing the basic principles and history of the piezoelectric effect, emphasizing the importance and widespread application of piezoelectric materials in the field of smart materials. Subsequently, it defines in detail the models of bimorph piezoelectric beams and multilayer composite piezoelectric plates, and conducts potential verification. The bimorph piezoelectric beam model uses PVDF material, and the potential distribution is monitored by boundary probes, confirming the influence of the quantity and distribution of sensor electrodes on voltage distribution. The multilayer composite piezoelectric plate model combines a Si non-piezoelectric semiconductor layer with a PZT-4 piezoelectric material layer, demonstrating the in-plane distribution of potential under lateral mechanical loads. This study not only verifies the reliability of COMSOL software in piezoelectric coupling analysis but also provides an in-depth understanding of the behavior and performance of piezoelectric materials in complex environments.