The present work investigates the last phase of the biomass gasification-based cookstove, which is the combustion process of biomass producer gas (BGP). A constant volume combustion bomb and kinetic simulation are used to characterize the behavior of the biomass producer gas and its pollutant emissions under a conventional premixed combustion process. The BGP combustion processes of two types of biomasses available in Colombia (Pinus Patula and Cordia Alliodora) are studied under certain conditions of pressure, temperature, and equivalence ratio. To characterize the combustible mixture of gases obtained after biomass gasification, a combustion chamber with cylindrical geometry equipped with a Schlieren optical diagnostic system to visualize the combustion process, and a piezoelectric pressure transducer to register the instantaneous pressure are used. By visualizing the flame front, the flame propagation speed at which the flame propagates through the combustion chamber and the morphology of the flame are studied. Instantaneous pressure is the input of a two-zone diagnostic model through which variables, such as burning velocity, temperature, mass burned fraction, etc., are obtained to characterize the combustion process of the mentioned gasification gases. Experimental results are compared and complemented with kinetic modeling results obtained with the Cantera package using the Gri-Mech 3.0 and Aramko 1.3 kinetic mechanisms, in terms of laminar burning velocity and NO, NO2, CO, and CO2 exhaust emissions. Results show that Cordia Alliodora presents higher burning velocities than Pinus Patula BP. However, lower CO2 emissions are obtained during the Cordia Alliodora combustion, and NOx emissions are not influenced by the type of biomass considered.