A study was made of the mechanism of formation of punctures in obtaining relief images using negative photoresists consisting of a polymer-diazide system. It was found that resistive properties of the photoresist layer depend on supermolecular organization of the polymer-diazide system, particularly on the selectivity of diazide distribution in the hydrophilic micro-regions of the polymer. With selective distribution of diazide molecules in hydrophilic microregions, puncture formation is only due to the natural permeability of the photoresist layer, which may be reduced considerably by increasing the rigidity of the matrix. When this molecular distribution of diazide is disrupted in the photoresist layer, cavities may form when nitrogen is liberated during photo-decomposition of diazide. Cavity formation may also cause punctures. The organization of the photoresist layer is determined by its prehistory.
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