Photochemical Formation Research Articles

EDA mediated S-N bond coupling of nitroarenes and sodium sulfinate salts.

Despite their long-known photochemical properties and their industrial value, the use of nitroarenes as a productive photochemical handle in organic synthesis has remained relatively unexplored. More specifically, the photochemical formation of nitrogen-sulfur bonds from nitroarenes remains to be demonstrated. Herein, we report the design and application of a sulfinate-nitroarene electron donor-acceptor (EDA) complex and its subsequent use in the first light mediated catalyst-free synthesis of N-hydroxy-sulfonamides. The presence of the EDA was assessed spectroscopically and studied via DFT and TD-DFT calculations. A total of 32 examples including both electron withdrawing and electron donating groups were synthesized under our oxygen- and water-tolerant conditions.

Life Cycle Assessment of Integrated Municipal Organic Waste Management Systems in Thailand

The majority of municipal solid waste in Thailand is organic waste including food and garden waste. Improper waste management has caused negative impacts on the environment. This study aimed to find a hypothetical municipal organic waste management scenario with the lowest environmental impacts using life cycle assessment (LCA). The system boundary of organic waste management includes collection and transportation; treatment, including centralized and on-site treatment technologies; and by-product utilization. The two main waste management systems considered in this study were centralized and on-site waste management systems. The first two scenarios take into account all the amount of the municipal organic waste collected and transported and then treated by centralized waste treatment technologies (composting, anaerobic digestion, and landfill). The remaining three scenarios are integrated between 10% on-site (home composting, food waste processor, and composting bin) and 90% centralized (composting, anaerobic digestion, and incineration) waste treatment technologies; the scenario combining centralized (food waste anaerobic digestion, garden waste composting, and incineration) and on-site (home composting) systems yielded the lowest environmental impacts (except short-term climate change, freshwater, and marine eutrophication). On-site systems can help reduce collection, transportation, and treatment impacts, particularly photochemical oxidant formation, which was proportional to the amount of waste or distance reduced. Benefits from the by-product utilization can offset all impacts in terms of fossil and nuclear energy use and freshwater acidification, and result in a negative impact score or impact reduction. This research can be used as guidance for developing countries with conditions and waste composition similar to Thailand for making initial decisions on environmentally sustainable municipal organic waste management.

How does sharing economy advance cleaner production? Evidence from the product life cycle design perspective

The sharing economy is a recent worldwide development; however, its impact on sustainability remains unclear, particularly in regards to the advancement of cleaner production. In order to explore the potential and contribution of specific sharing economy business practices in the transition to cleaner production, this study empirically analyzed how China's free-floating bike-sharing (FFBS) improved environmental sustainability through optimization of product life cycle design. Specifically, the impact on climate change and human health of three generations of shared bike products was quantitatively analyzed by using product environmental footprint (PEF) approach. The results show that sustainable product lifecycle design can effectively improve the sustainability of FFBS. Through optimized design and product upgrades, the environmental impact intensity of FFBS has decreased by approximately 25.09% –34.34%. This causes FFBS to gradually evolve from exerting negative impacts on climate change to achieving considerable climate benefits (22.18 CO2-eq/pkm). The environmental benefits on ozone depletion and photochemical ozone formation also increased by about 2.46 μg CFC11eq/pkm and 85.77 mg NMVOC eq/pkm with the upgrade of shared bikes from the first generation to the third generation. In addition, although the negative effects of FFBS on respiratory inorganics, non-cancer human health effects and cancer human health effects have been significantly reduced, the corresponding positive environmental benefits still need to be achieved by significantly increasing the utilization rate of shared bikes. Furthermore, this suggests that the sustainable production life cycle design of FFBS can follow the principles of safety, ease of maintenance, durability, ease of use, universality, resource conservation, and recyclability. This empirical study can not only help authorities, managers and the public better understand the contribution of the sharing economy to cleaner production, but also provides new insights and valuable references for improving the sustainability of the sharing economy.

Template for Evaluating Cradle-to-Site Environmental Life Cycle Impacts of Buildings in India.

A massive amount of building construction is expected in economically developing nations such as India over the next few years. The first step in ensuring that the new construction takes place in a sustainable manner is the knowledge about the building's impact on multiple environmental domains. Life cycle assessment (LCA) is a promising tool for this, but its application in the Indian construction sector is hampered by a lack of access to detailed inventory data on amounts of all building materials used and the per unit environmental footprints of individual materials (characterization factors). Here, we overcome these limitations by proposing a novel approach that connects the building bill of quantity data with publicly available analysis of rate documents to obtain the detailed material inventory. The approach then combines the material inventory data with the newly available India-specific environmental footprint database of construction materials to calculate the impacts of a building during its different life cycle stages (cradle to site). We demonstrate the new approach through a case study of a residential building within a hospital in North-East India and quantify its environmental footprint on six domains of the environment: energy use, global warming, ozone depletion, acidification, eutrophication, and photochemical oxidant formation potential. Results show that out of 78 materials used, bricks, aluminum sections, steel bars, and cement are the major contributors to the building's total environmental impact. The material manufacturing stage is the hotspot in the building's life cycle. Our approach can act as a template for conducting "cradle-to-site" LCA of buildings for which BOQ data becomes available in India and other countries in the future.

Life cycle energy consumption, environmental impact, and costing assessment of coal to ethylene glycol processes via dimethyl oxalate and formaldehyde.

The popularization of conventional dimethyl oxalate to ethylene glycol (DMOtEG) has kept ongoing in the past decade in China. Recently, a northern China factory in construction attracts attention using alternative formaldehyde to ethylene glycol (FtEG) route. Thus, a question arises about the individual comparative advantages of these two processes. So, this paper conducts a systematic modeling analysis of DMOtEG and FtEG, and the life cycle assessment is performed by SimaPro v9 to compare their impact. The results indicate the inferiority of life cycle energy consumption and life cycle cost of FtEG to those of DMOtEG due to the high energy consumption and pollutant emissions. Moreover, most impact categories of FtEG are worse than the DMOtEG as global warming, and photochemical oxidant formation potential. Despite this, FtEG still wins for better potentials in ozone formation, fine particulate matter formation, and terrestrial acidification because of less nitride emissions. In addition, the decrease in energy consumption and external cost will significantly decrease the life cycle cost under controllable catalyst costs of FtEG. These results describe the impact categories of DMOtEG and FtEG and provide a basis to help decision-makers develop coal to ethylene glycol processes.

Comparison of science-based and policy-based distance-to-target weighting in life cycle assessment - Using the example of Europe

Weighting of impacts is frequently applied to enable the prioritization of life cycle assessment (LCA) results for the support of decision making. Most Distance-to-Target (DtT) weighting approaches consider policy targets, whereas potential is seen in the weighting of environmental impacts on a more scientific basis. This study aims at the comparison of science-based (SB) to policy-based (PoB) DtT weighting approaches as well as the application in a comparative case study for the domestic footprint of the European Union. The developed approaches integrated SB targets from ten environmental impact categories into the DtT weighting method of the Ecological Scarcity Method in an effort to derive SB eco-factors. In addition to SB eco-factors based on existing weighting factors for Europe from the literature, weighting factors for the European Union were developed. The application of the eco-factors in the case study showed that the SB approach led to three times higher absolute weighting results in contrast to PoB results. SB weighting was dominated by the impact category climate change with the strictest weighting factors in all approaches considered and a share of 87–92%. For the remaining impact categories, common PoB weighting factors were generally stricter. PoB results showed a more balanced distribution, with shares of 64% for climate change, 10% for photochemical ozone formation, 7% for acidification, and 7% for terrestrial eutrophication. Science-based targets can not replace conventional PoB weighting approaches but should be integrated into the weighting step to provide a more comprehensive view of the environmental performance of product systems. SB weighting results are an additional source of information on environmental sustainability regarding environmental carrying capacity that can broaden the basis for decision making.

Novel BODIPY-Fluorene-Fullerene and BODIPY-Fluorene-BODIPY Conjugates: Synthesis, Characterization, Photophysical and Photochemical Properties.

Two new BODIPY-fluorene-fullerene (3) and BODIPY-fluorene-BODIPY (4) conjugates were designed, synthesized, and characterized for the first time. The structural properties of compounds were investigated with elemental analysis, mass, 1H, and 13C NMR techniques. Absorption and fluorescence spectroscopy were used to examine the photophysical (absorption and emission profiles, fluorescence quantum yields, and lifetimes) and photochemical (formation of singlet oxygen (1O2)) properties. It was observed that the novel compounds (3) and (4) showed high molar extinction coefficients and good 1O2 quantum yields. 1O2 formation ability of the BODIPY-fluorene-fullerene conjugate (3) was more efficient than that of the BODIPY-fluorene-BODIPY conjugate (4). Furthermore, photosensitization ability of both conjugate systems was more remarkable than some commonly used BODIPY based photosensitizers. The data presented in this work indicate that these two novel systems are effective 1O2 photosensitizers that might be used for various areas of applications such as photodynamic therapy and photocatalysis.

Urban Green Space Prioritization to Mitigate Air Pollution and the Urban Heat Island Effect in Kathmandu Metropolitan City, Nepal

The rapid population growth and unplanned urbanization within Kathmandu Metropolitan City (KMC) have induced land use and land cover (LULC) changes that have exacerbated problems of air pollution and the Urban Heat Island (UHI) effect. These issues, as well as potential mitigations and possible counteractions, are currently under investigation by numerous research communities, resulting in various solutions being put forward including the creation of Urban Green Spaces (UGS). Establishing UGS would increase carbon dioxide extraction, minimizing photochemical ozone formation and liberation, while simultaneously cooling the microclimate of an area such as KMC. Optimized implementation of UGS throughout KMC requires an understanding of and prioritization of locations based on degraded air quality and the UHI effect. Unfortunately, such studies in these areas appear to be severely lacking, which has acted as a catalyst for this study. This research includes prioritization on two different spatial units—(i) at the administrative ward level and (ii) 0.0025° fishnet level. The result identifies the high-need locations where UGS establishment is recommended to mitigate air pollution and the UHI effect. Information obtained also heightened the existing UGS’s current sparsity and deplorable conditions. Findings from this study indicate that the utilization of rooftops are potential locations for new UGS, and enhancement of the existing UGS would prove to be an efficient use of currently underutilized spaces.

Pollution mechanisms and photochemical effects of atmospheric HCHO in a coastal city of southeast China

Formaldehyde (HCHO) is a vital reactive carbonyl compound, which plays an important role in the photochemical process and atmospheric oxidation capacity. However, the current studies on the quantification of HCHO impacts on atmospheric photochemistry in southeast coastal areas of China with an obvious upward trend of ozone remain scarce and unclear, thus limiting the full understanding of formation mechanism and control strategy of photochemical pollution. Here, systematic field campaigns were conducted at a typical coastal urban site with good air quality to reveal HCHO mechanism and effects on O3 pollution mechanism during spring and autumn, when photochemical pollution events still frequently appeared. Positive Matrix Factorization model results showed that secondary photochemical formation made the largest contributions to HCHO (69 %) in this study. Based on the photochemical model, the HCHO loss rates in autumn were significantly higher than those in spring (P < 0.05), indicating that strong photochemical conditions constrain high HCHO levels in certain situations. HCHO mechanism increased the ROx concentrations by 36 %, and increased net O3 production rates by 31 %, manifesting that the reduction of HCHO and its precursors' emissions would effectively mitigate O3 pollution. Therefore, the pollution characteristics and photochemical effects of HCHO provided significant guidance for future photochemical pollution control in relatively clean areas.

Life Cycle assessment of biorefinery technology producing activated carbon and levulinic acid

Life Cycle Assessment (LCA) is applied to eco-design the H3PO4-assisted hydrothermal carbonization (HTC) process converting biomass residue into high-value products. The main innovation of the process relies on the combination of the H3PO4-assisted HTC with the activation treatment of the obtained hydrochar, resulting in activated carbon that is then functionalized. In addition, the liquid phase obtained from HTC is eventually purified to extract levulinic acid. Under average conditions at the laboratory scale (reference), the LCA showed that electricity consumption is the main contributor (45–70%) to impacts on climate change, photochemical ozone formation, acidification, freshwater eutrophication, freshwater ecotoxicity and fossil resources use. Pyridine, the main chemical used in the functionalization stage, contributes to impacts on human toxicity and on marine eutrophication respectively by 77.3% and 47.3%. Building on these results, two further scenarios were studied, one considering the maximum capacity of each equipment and another one assuming the potential improvements once the process will be upscaled. The scenarios were validated in a series of laboratory scale tests. Depending on the environmental impact category chosen, the results showed a reduction potential of 30–65% as compared to the reference scenario. These findings confirm the added value of LCA in the ecodesign of technologies and pave the way to further improvements of the technology itself but also of the LCA methodology used for the assessment.

Comparison on environmental impacts of cereal and forage production in the Loess Plateau of China: Using life cycle assessment with uncertainty and variability analysis

The increasing demand for high-quality animal protein calls for parts of cereal cropping systems converting to forage or forage-livestock integrated systems. This study aimed at evaluating potential environmental impacts of this transition at the farm level on the Loess Plateau of China through a life cycle assessment (LCA) approach. Four dominating crops: alfalfa, wheat, grain maize and silage maize were studied based on the ten impact categories. Based on standard unit land area (1 ha) and timestamp (2018–2020) settings, alfalfa production indicated the lowest environmental impact in nine categories compared to other crops, while wheat indicated better performance in seven of ten impact categories than other crops except alfalfa. With respect to the environmental loads of grain maize and silage maize production, both systems were very comparable. Because of the common adoption of open-land burning of straws (mainly for fuel and winter heating) in the local region, the respiratory inorganics and photochemical oxidant formation potential impact of alfalfa and silage maize per hectare produced is much lower than those of wheat and grain maize. Great differences in environmental impacts between the two types of cropping systems (cereal vs forage) indicate that transitioning from cereal to forage production should effectively reduce air pollution and enhance environmental sustainability on the Loess Plateau. Besides, uncertainty and variability of LCAs results were analyzed in this study.

Recycling, disposal, or biodegradable-alternative of polyethylene plastic film for agricultural mulching? A life cycle analysis of their environmental impacts

Plastic mulching is widely used in croplands to improve yields, while its mismanagement leads to plastic pollution in rural areas. China has explored different approaches to manage post-use plastic mulching, while there is still inadequate research regarding their corresponding environmental impacts. This study establishes five plastic mulching management scenarios, i.e., plastic mulching disposed of in nature, substituting biodegradable plastic, recycling, incineration, and landfilling, and maize cultivation in rural areas of northern China was taken as the studied case. We determine the comprehensive environmental impacts through a life cycle assessment (LCA) approach and completed a field investigation to obtain local datasets. The impurity content of used polyethylene mulching (PEM), an essential parameter for the entire life-cycle environmental impact assessment, is 80.1% ± 9.5%, examined by on-site sampling and scanning electron microscope. Results show that: 1) the use of biodegradable mulching (BM) instead of traditional PEM reduces carbon emissions by 22.6%; 2) the increment of soil carbon flux caused in the application stage is more significant than that in the post-use stage; 3) incineration of post-use mulch causes relatively significant photochemical oxidant formation effect; furthermore, recycling of plastic mulching leads to negative impacts in terms of human toxicity effect, meanwhile the positive environmental impact of fossil depletion effect is 2.3 times higher than that of incineration. Reducing the rate of impurity content in wasted plastic mulching can reduce transportation costs and promote sustainable plastic pollution management in rural areas.

Attributing Increases in Ozone to Accelerated Oxidation of Volatile Organic Compounds at Reduced Nitrogen Oxides Concentrations.

Surface ozone (O3) is an important secondary pollutant affecting climate change and air quality in the atmosphere. Observations during the COVID-19 lockdown in urban China show that the co-abatement of nitrogen oxides (NOx) and volatile organic compounds (VOCs) caused winter ground-level O3 increases, but the chemical mechanisms involved are unclear. Here we report field observations in the Shanghai lockdown that reveals increasing photochemical formation of O3 from VOC oxidation with decreasing NOx. Analyses of the VOC profiles and NO/NO2 indicate that the O3 increases by the NOx reduction counteracted the O3 decreases through the VOC emission reduction in the VOC-limited region, and this may have been the main mechanism for this net O3 increase. The mechanism may have involved accelerated OH-HO2-RO2 radical cycling. The NOx reductions for increasing O3 production could explain why O3 increased from 2014 to 2020 in response to NOx emission reduction even as VOC emissions have essentially remained unchanged. Model simulations suggest that aggressive VOC abatement, particularly for alkenes and aromatics, should help reverse the long-term O3 increase under current NOx abatement conditions.

Single-Handed Helicene Nanoribbons via Transfer of Chiral Information.

Here we show the access to single-handed helicene nanoribbons by utilizing a [6]helicene building block to induce diastereoselective, photochemical formation of [5]helicene units. Specifically, we have synthesized nanoribbons P1 and P2 with different ratios of [6]helicene "sergeants" to [5]helicene "soldiers", which on average consist of between ∼50 and 60 ortho-annulated benzene rings. These are the longest, optically active helicene backbones that have been prepared to date. The chiroptic properties of P1 and P2 reveal the transfer of stereochemical information from "sergeants" to "soldiers". To gain further insight into the stereo-information relay, we apply the same molecular design to discrete, model oligomers 1-5 and confirm that they also preferentially adopt homochiral geometries.

Particulate-Bound Polycyclic Aromatic Hydrocarbons (PAHs) and their Nitro- and Oxy-Derivative Compounds Collected Inside and Outside Occupied Homes in Southern Sweden

This study presents indoor and outdoor levels of airborne fine particles (PM2.5), particle bound polycyclic aromatic compounds (PACs) including parent-, alkylated-, nitro-, and oxy-PAHs. Week-long simultaneous measurements were conducted inside and outside 15 occupied homes in southern Sweden during wintertime. The homes were single-family houses or apartments located in urban, semi-urban, and rural areas. The PM2.5 and PACs levels were low compared to studies worldwide. There was great variation in concentrations between sites, which likely is due to proximity to road and traffic intensity. The lower concentrations of nitro and oxy-PAHs compared to parent PAHs in this study, compared to other studies, could possibly be due to lower atmospheric photochemical formation outdoors because the cold climate. This assumption could not be confirmed and need to be further tested. The results point to that particle PAC levels found inside arise primarily from outdoor. This correlation was not as clear for PM2.5. The results of a comparison between residences before and after energy renovation did not indicate an improvement in indoor air regarding PACs. To understand exposure and assess risks it is important to measure wide range of PACs both in gas and particle phase.

Last Mile Logistics Life Cycle Assessment: A Comparative Analysis from Diesel Van to E-Cargo Bike

With the proliferation of e-commerce, the field of last-mile logistics has grown increasingly, highlighting the need to manage the environmental consequences of this phenomenon, especially to achieve decarbonization targets for cities and to improve citizens’ quality of life. Within this framework, the authors carried out a last-mile logistics life cycle assessment, to analyse and compare different logistics vehicle options performing the same service in an urban context: an electric four-wheel cargo bike, an electric van, a plug-in hybrid van, and a diesel van. The assessment shows that the e-cargo bike performs better for all the impact categories considered. The second-best option is the e-van, while the diesel van shows the worst environmental results. Focusing on decarbonization, the replacement of a diesel van with an electric one or with an e-cargo bike allows a reduction of 173 g CO2 eq/km and 250 g CO2 eq/km, respectively. Similar results are obtained for Photochemical Ozone Formation with associated emissions of 0.18, 0.31, 0.45 and 0.49 g NMVOC eq/km for the e-cargo bike, e-van, plug in hybrid van and diesel van, respectively. The only exceptions are Human Health impact categories, Acidification and Respiratory inorganics, for which the plug-in hybrid van performs worst, and Resource use, Mineral and Metals, for which the electric van performs worst.

A Closure Study of Secondary Organic Aerosol Estimation at an Urban Site of Yangtze River Delta, China

Secondary organic aerosols (SOA) are crucial components of ambient particulate matters. However, their composition and formation mechanisms remain uncertain. To investigate the SOA formation and evaluate various SOA estimation approaches, a comprehensive measurement was conducted at an urban site, Changzhou, in Yangtze River Delta (YRD) region. 98 kinds of volatile organic compounds (VOCs) were measured by an online gas chromatography-mass spectrometer/flame ionization detector (GC-MS/FID). Non-refractory submicron particulate matters (NR-PM1) were measured by an Aerodyne Aerosol Chemical Speciation Monitor (ACSM). Both bottom-up approaches, i.e., VOCs oxidation yield method, and top-down approaches, i.e., elemental carbon (EC) tracer method and ACSM, combined with positive matrix factorization (PMF) method, were utilized to estimate SOA. ACSM-PMF method estimated the highest SOA concentration, followed by EC tracer method. SOA from VOCs oxidation yield method accounted for 43.2 ± 41.9% of that from EC tracer method, suggesting the existence of missing SOA precursors, e.g., semivolatile organic compounds. The influencing factors of SOA formation were investigated and a good correlation of SOA with odd oxygen rather than aerosol liquid water content was found, suggesting the importance of photochemical formation of SOA.

Evaluating municipal solid waste management using life cycle analysis: a case study

ABSTRACT Every municipality in Türkiye regulates and implements its own specific waste management plan in line with the laws and regulations determined by the Ministry of Environment and Urbanization. Ümraniye District Municipality is selected as a case in the region for this study on solid waste management. Considering the solid waste characteristics in the district, seven different scenarios were defined for a systematic evaluation of solid waste management including the current method. The software program SimaPro 9.0 was used in the life cycle assessment, for the impact of the proposed scenarios on the environment and human health. 1 ton has been determined as a functional unit in the system. The scenarios were designed according to the waste characteristics of the region. Data obtained from the field and data obtained from similar literature studies have been utilized. The scenarios were compared through the methods EF (Environmental Footprint) Method 1.0 and ReCiPe 2016 Endpoint H. The evaluations were done for midpoint categories such as climate change, ozone layer depletion and eutrophication. The results from the LCA studies indicate that S-0 has the most negative impact in all the categories that were analyzed, except ozone depletion and resources-energy category, because of generating LFG (Landfilling Gas). The program outputs that seen from the program outputs, the S-0 CO2 emission value is 1.85E +08 kg CO2 eq with a high emission value. Similarly, S-0 is the scenario that has the most negative impact on human health, with 0.00071 kg of cadmium load due to the high rate of landfilling. Besides, S-4 has the lowest ozone depletion effect with its −0.00913 kg CFC11eq value. Finally, it is understood from the study, that an integrated waste management system (S-6) including incineration, composting, recycling, and a small percentage of landfilling- has lower environmental impact than current practice and other scenarios according to Climate change, photochemical ozone formation, non-cancer human-health effects, respectively, with 1.33E8 kg CO2 eq, 1.18E6 kg NMVOC eq and 4.02 CTUh values. Therefore, choosing the most sustainable waste management option can help to create a world-wide model environment friendly and smart city managements.

Life cycle assessment of environmental impacts of cold and hot break tomato paste packaged in steel drums and exported from Xinjiang, China

The purpose of this study was to conduct a life cycle assessment (LCA) of the environmental impact of highly concentrated tomato paste produced by cold break and hot break methods. We considered the environmental impact and environmental hot spots related to tomato cultivation, tomato paste processing, packaging, and transportation, and then identified potential improvements for each stage. The research site was in Xinjiang, China, which is the main production area of high-concentration tomato paste for export in China. Taking 240 kg tomato paste packed in 220-L steel drums as the functional unit, the main data were obtained from studies on production enterprises and agricultural statistics. Ten environmental impacts were calculated using eFootprint: primary energy demand (PED), resource depletion-water (WU), climate change (GWP), ozone depletion (ODP), acidification (AP), particulate matter (RI), photochemical ozone formation (POFP), eutrophication (EP), ecotoxicity-freshwater (ET), and human toxicity-cancer effects (HT-cancer); their respective values for cold break paste were 5947 MJ, 82400 kg, 490 kg CO2 eq, 4.07E-06 kg CFC-11 eq, 5.150 kg SO2 eq, 1.600 kg PM2.5 eq, 0.270 kg NMVOC eq, 1.000 kg PO43− eq, 4.230 CTUe, and 3.70E-07 CTUh. The results showed that the environmental impact of cold break paste was lower than that of hot break paste because of lower steam consumption. The cultivation phase was the main contributor to WU, AP, EP, ET, and HT-cancer. In the processing phase, mashed tomatoes are concentrated using a large amount of steam to obtain a concentrated paste product. The energy consumption in the processing phase contributed >50% of PED, GWP, and RI. Although the packaging and transportation phases had smaller environmental impacts, the use of steel drums for packaging cannot be ignored. We conducted sensitivity analyses to evaluate the overall benefits that could be achieved by different mitigation schemes. In the whole supply chain, improving irrigation and fertilization methods and replacing the primary energy for steam production are the best strategies to improve environmental sustainability.

Chula model for sustainable municipal solid waste management in university canteens

Managing the large amount and variety of waste produced by university canteens is challenging. This study used life cycle assessment (LCA) to investigate sustainable municipal solid waste (MSW) management solutions for Chulalongkorn University (CU) canteens. This study assessed three scenarios for MSW management in CU canteens: the past scenario (prior to the Chula Zero Waste Project in 2016; S1); the current scenario (2017–2021, when the Chula Zero Waste Project’s MSW management system was used; S2); and the future scenario (after 2021 with the new MSW management option for CU canteens under Chula Zero Waste; S3). The obtained results were characterized by eight impact categories: climate change, ozone depletion, terrestrial acidification, freshwater eutrophication, human toxicity, photochemical oxidant formation, particulate matter formation, and fossil depletion. The LCA results show that the future scenario (S3) under the Chula Zero Waste Project is sustainable for MSW management. The most environmentally sustainable MSW plan for CU canteens is to reduce, separate it at the source, and reuse materials instead of landfilling mixed waste.