Electrospinning has received a lot of attention in recent years as a simple process to produce sub-micrometer-scale fibers. The process involves continuous stretching of polymer solution or melt in the presence of a strong electric field, which forms ultrathin fibers. A large amount of research is being carried out to achieve control of the diameter, morphology, and spatial alignment of electrospun nanofibers. Unlike other 1D nanostructures, such as nanowires and nanotubes, nanofibers exhibit a wide range of unique properties, making them far more attractive for many applications, such as filtration, catalysis, sensing, protective clothing, and tissueengineering scaffolds. Being a continuous process, electrospinning can produce extremely long fibers comparable to those formed via conventional mechanical drawing and spinning techniques. Nanofiber mats exhibit extremely high surface-to-mass ratios, greatly improving their efficiency for catalysis and filtration. Another fascinating feature of this process is that it can be applied to a wide variety of nanostructured materials. Bognitzki et al. fabricated sub-micrometerscale fibers by electrospinning ternary solutions of polylactide and poly(vinylpyrrolidone). They found that the fibers displayed an internal phase morphology, and, by selectively removing one phase, they obtained highly porous fibers. However, these morphologies were largely controlled by rapid phase separation and rapid solidification of the polymer jet, and no method for controlling these morphologies was demonstrated. In the present study, we utilize this simple process to fabricate block copolymer (BCP) nanofibers. BCP solutions and melts are known to self-assemble into a variety of nanoscale morphologies including spheres, rods, micelles, lamellae, vesicles, tubules, and cylinders, depending on the volume fraction and interaction parameter between different blocks. We have been able to produce macroscale-length fibers with diameters of a few hundred nanometers that exhibit internal structures of only tens of nanometers in size. Such materials, we believe, can combine the unique properties of continuous nanofibers and BCP self-assembly for use in a variety of applications of nanostructured materials. BCP self-assembly has attracted increasing interest in recent years for applications in nanotechnology. Precise control over the size, shape, and periodicity of these nanoscale microdomains is the key factor needed to realize nanoscale systems. Various methods, including shear and elongational deformation, compressional deformation, electric fields, and temperature gradients, have been utilized to induce orientation of the microdomains. To our knowledge, shear flow has been most extensively studied as a simple means to induce phase transitions and orient self-assembled structures in block copolymers. The phenomenon of flow-induced alignment of lamellar BCPs is very well studied in bulk systems. Three different orientations of lamellar morphology, namely, parallel, perpendicular, and transverse have been obtained as a function of shear rate, shear frequency, and temperature. We refer the reader to a review paper that elaborates on the various methods to control BCP microdomains and the potential applications of these domains as nanometersized membranes, templates for fabrication of a variety of nano-objects, and templates for fabrication of high-density information-storage media. Recently, some research has been carried out in order to obtain novel self-assembled structures, using the effect of confinement of self-assembling materials in 1D nanostructures, such as nanorods and nanowires. Shin et al. and Xiang et al. studied the effect of cylindrical confinement on the morphology of polystyrene-block-polybutadiene (PS-b-PBD) in nanoporous alumina membranes. They found that if the pore diameter is large compared to the equilibrium bulk spacing and one component preferentially segregates to the walls, then a symmetric copolymer forms with a concentric cylindrical morphology and alternating cylinders of PS and PBD. If the pore diameter is small and not an integer multiple of the bulk repeat period, the high degree of curvature imposed in cylindrical confinement causes frustration of chain packing at the interface, forming stacked PS lamellar structures along the axis of the pore. Wu et al. studied the confined assembly of SiO2/copolymer-composite mesostructures in cylinders of varying diameters using alumina nanochannels. They also carried out self-consistent field calculations for comparison with experimentally obtained self-assembled structures. However, potential applications of these distinctive nanostructures are C O M M U N IC A IO N