Broad temperature range ferrielectric liquid crystal mixture FerriLCM-1 was previously developed in 2022 (Pozhidaev et al. 2022). In that work dielectric and electro-optical properties of the mixture were studied at room temperature. Electrically induced birefringence index reached 0.01 at a wavelength of 532 nm with response times of 300 μs. In this paper we continue the FerriLCM-1 properties investigation in a wide temperature range from the room ones till the isotropic phase transition temperature. It is found that one of the critical electric fields is almost temperature independent, while the Kerr coefficient of quadratic electro-optical effect in deformed helix ferroelectric (DHF) mode grows with temperature increase. This leads to an increase in the depth of phase modulation. Another critical electric field decreases smoothly with temperature rising. At 47–50 °C two critical electric fields merge, while temperature dependencies of all other dielectric and electro-optical parameters of the mixture are continuous and smooth functions. At about 50 °C the maximum electrically induced birefringence in DHF-mode is ΔneffE=0.022 under the applied electric field E=0.4 V/μm and with 80 μs response time. FerriLCM-1 mixture operating in the DHF-mode exhibits a giant Kerr coefficient of 1700 nm/V2 (or even up to 2900 nm/V2 at λ=400nm) at the temperature of 85 °C combined with a 50 μs response time. This is the highest value of Kkerr coefficient among liquid crystals. All these properties make ferrielectric liquid crystal mixture FerriLCM-1 suitable for solving various problems of phase modulation of light and use in low-voltage devices.