Solar steam generation is considered as an efficient way for addressing water shortage issues via seawater desalination and wastewater purification. In a solar evaporator, an absorber would convert optical energy to heat for evaporating nearby water. In this process, many low-boiling-point contaminants can also be evaporated along with water steam, which compromises the effectiveness of purification. There is, so far, no study on the removal of such low-boiling-point contaminants such as organic pesticides in wastewater. To address this problem, we demonstrate a versatile carbon hybrid aerogel (CHA) as a solar powered water purification platform. With an elaborate absorber design, the maximum solar evaporation rate of 2.1 kg m-2 h-1 is achieved under 1 sun illumination. More importantly, CHA can effectively suppress the evaporation of low-boiling-point contaminants including common pesticides and mercury ion via its strong adsorption and retention effect. Synergetic steaming and the adsorption of CHA will inspire more paradigms of solar steam generation technologies for applications relevant to detoxification and water remediation.