The aluminum agglomerate size distribution plays an important role in influencing the particle distributed combustion in motor, which subsequently affects the performance of solid rocket motor significantly. In this work, a three-phase model to describe distributed combustion of aluminum agglomerates is established based on the Eulerian-Lagrangian method. Then, the agglomerate size, including mono size and distributed size, is studied to reveal its effect on aluminum combustion and motor flow field. The simulated results indicate that the increasing agglomerate mono size observes the obvious decrease of the average temperature inside the motor combustion chamber, implying the low combustion efficiency of large agglomerate size. When considering the agglomerate size distribution, the size distribution mode and the mean size D43 determine the combustion efficiency together. In particular, even the mean size is similar, with different distribution mode, like skewed distribution, bimodal or trimodal distribution, the combustion efficiency and flow field parameters are nonnegligible different. However, when the size distribution mode is the same and the peak range is similar, the mean size D43 becomes the only and predominant factor as the mono size.