Performance Of Lithium-ion Batteries Research Articles

In-situ characterization approach for heat-generating performances of a pouch lithium-ion battery

The heat generated of the lithium-ion battery raises its own temperature, and accurately demonstrating the battery’s heat-generation is of significance for the battery pack’s thermal safety management. This work presents a novel thermal compensation method that accounts for heat loss, significantly enhancing the accuracy of heat generation assessments in large-format pouch batteries under both high and low temperature-rise conditions. The results show that the battery’s heat generation exhibits a U-shaped pattern under high temperature-rise conditions, while displaying an increasing tendency of “fast-slow-fast” under low temperature-rise condition. By considering heat loss, the current method achieves a 93.5% accuracy rate compared to measurements that omit this factor. Specifically, under low temperature-rise conditions, the heat generations at discharge rates of 0.7C, 1.0C, and 1.2C are 4.74%, 11.56%, and 16.25% higher than those under high temperature-rise conditions, respectively. Accurately and cost-effectively, present method to measure battery heat-generation without resorting to costly equipment. The results would be valuable for one to characterize battery’s heat-generating performance under the conditions of high and low temperature-rises.

Effect of Different Surface States of Electrolytic Copper Foils on the Performance of Lithium-Ion Batteries

Currently, the field of lithium-ion batteries faces an urgent challenge, which is how to effectively inhibit the growth of dendrites, thereby improving the coulombic efficiency of plated/stripped lithium on copper foils and enhancing the cycling stability of the batteries. In this paper, the surface of copper foil is roughened by annealing post-treatment, which in turn improves the interfacial adhesion between the copper foil and the active material. This treatment helps the anode current collector to form a flat graphite electrode sheet and a uniform solid electrolyte interphase film, reducing the growth of lithium dendrites as well as extending the cycle life of the batteries. Among them, the annealed electrode exhibits extremely high roughness (0.533 μm) and elongation (9.91%), with the initial discharge capacity of the prepared lithium battery reaching as high as 384.22 mAh g−1. It also maintains good cycling performance at different rates, which confirms the gain effect of surface roughening on battery capacity.

One-step fabrication of binder-free nanoSi-CNT-carbon black/cyclized PAN composite anode for high-performance lithium-ion batteries

Silicon is one of the most promising anode materials for lithium-ion batteries (LIBs) due to its high theoretical capacity. However, its non-conductive nature and significant volume expansion during lithiation pose challenges. In this study, we developed a novel electrode comprising silicon nanoparticles (nanoSi), carbon nanotubes (CNTs), and carbon black (CB) in cyclized polyacrylonitrile (cPAN), referred to as nanoSi-CNT-CB/cPAN. This electrode is fabricated through a one-step thermal process by heating a cast nanoSi-CNT-CB/PAN film on Cu foil at 310 °C. The LIB performance using the nanoSi-CNT-CB/cPAN electrode shows an impressive initial coulombic efficiency of 93.1 % at 0.1 A g−1, a high specific capacity of 2267.2 mAh g−1 at 0.5 A g−1, and a retention of 89.2 % over 390 cycles, achieving 783 mAh g−1 at 5 A g−1. We attribute these results to the fused cPAN, which provides good adhesion to nanoSi, CNTs, CB, and Cu foil, acting as a binder, active material, and ionic conductive medium. The well-dispersed CNTs and CB form an effective conductive network in the electrode. Additionally, the one-step electrode fabrication is a simple and cost-effective process for next-generation Si-based LIBs.

Unlocking enhanced new type of safe open system lithium-ion battery performance: Mn3O4 nano-cubes and their sulfur mixers cathode material

In the pursuit of advancing lithium-ion (Li-ion) battery technology towards enhanced safety and performance, we present research study on the synthesis and evaluation of manganese oxide-based cathode materials. Different phases of manganese oxides (Mn3O4 and MnO2), alongside their different ratio of two manganese oxides phases and Mn3O4 with sulfur (S) combination, we employed a simple hydrothermal and solid-state grinding techniques. Characterized by field emission transmission electron microscopy (FE-TEM), our synthesized materials revealed distinct phases of MnO2 and Mn3O4 accompanied by nanorods (NRs) and nanocubes (NCs) morphologies, respectively. We conducted a comprehensive assessment of the Li-ion battery performance of these materials, initially without S, within a new type of safe open system framework. Notably, Mn3O4 NCs (MNCs) developed as important, exhibiting a maximum discharge capacity of 346.03 mAh/g at a constant current discharging rate of 0.5 A/g. We introduced 30 % of S into 70 % of the MNCs matrix to form the MNCSs-73 composite, resulting in rather moderate enhancement in capacity performance. The MNCSs-73 displayed an exposed discharge capacity of approximately 394.8 mAh/g under identical testing conditions. Our findings underscore the exceptional potential of MNCs and MNCSs-73 composites cathode materials for highly suitable for open system novel safe Li-ion battery applications and other energy storage research field.

Effect of NMC-doping Concentration on the Structural Feature and Electrical Properties of Lithium Iron Phosphate Cathode for Use in Lithium-ion Batteries

T his study investigates the synthesis of Lithium Iron Phosphate (LFP) with NMC-doped cathode materials, aiming to enhance the performance of lithium-ion batteries. The NMC content was varied from 0.02 to 0.10wt%, and 1wt% of (NH4)3PO4 was added to all conditions to prevent phosphate loss during the calcination process. The composite powder was prepared using a straightforward mixed oxide method, with a calcination temperature of 600 °C for 5 hours under an argon gas flow. X-ray diffraction (XRD) analysis confirmed the successful formation of pure LFP with an orthorhombic crystal structure, devoid of any secondary phases. To further explore the impact of NMC doping on the structural characteristics, FTIR and Raman spectroscopy were employed. Results revealed that increasing NMC doping concentration beyond 0.02wt% led to the broadening of the PO43− symmetric stretching band at approximately 947 cm−1, indicating a higher degree of disorder in the LFP structures. This disorder was found to adversely affect electrochemical performance, resulting in decreased discharge capacity and increased impedance, as determined by electrochemical impedance spectroscopy (EIS), with higher concentrations of NMC and (NH4)3PO4. Scanning Electron Microscopy (SEM) analysis unveiled the presence of agglomerated particles ranging in size from 0.5 to 0.9 microns. Optimal conditions were identified with the addition of NMC doped at 0.02wt%, which exhibited a discharge capacity of approximately 119.41 mAh/g at 0.2 C, along with a low impedance of 200 Ohm. Moreover, the 0.02wt% sample demonstrated a promising linear trend in cycle performance, suggesting its potential for future applications in lithium-ion batteries.

Research on thermal runaway characteristics and mechanism of NCM811 Lithium-ion batteries under cross-seasonal and wide-temperature condition at −10 °C ∼ 33 °C: A case study in Qingdao, China

Multiple heat sources and extreme ambient temperatures pose more severe challenges to the safety performance of lithium-ion batteries (LIBs), and the kinetic characterization of thermal runaway (TR) of LIBs at extreme temperatures has yet to be improved. Through the establishment of a dual heat source coupled stimulation experimental platform, this study investigates the TR mechanism and flame jet dynamics of LIBs under broad temperature ranges corresponding to spring, summer, autumn, and winter (−10 °C ∼ 30 °C). The results indicate that the increase in ambient temperature leads to a gradual reduction in the TR onset time (tonset), in the order of Tonset-Winter>Tonset-Spring>Tonset-Autumn>Tonset-Summer; for example, with 100% SOC (State of Charge), Tonset-Winter = 2528 s, Tonset-Summer = 2211 s, which was accelerated by 14.3%. However, TR maximum temperature (Tmax) showed the opposite trend, Tmax-summer = 687.2 °C, Tmax-winter = 796.5 °C, which decreased by 15.9%. When SOC ≥ 75%, the average warning time for TR disaster of LIB (from venting to the beginning of TR) is 254 s less than that of winter in the summer with higher temperature, which makes the adoption of emergency measures and escape more urgent. When SOC ≥ 50%, the TR process was accompanied by flame generation, and the flame eruption process was the most intense at 100% SOC, with a maximum flame area of about 4400 cm2, and its flame temperature was likewise the highest at 986.4 °C. Carbon and metal oxides were detected in the TR ejecta, and the lower the ambient temperature, the finer the ejecta particles were. The results of the study provide an important scientific reference for improving the theory of TR of LIBs, guiding the investigation of TR and fire in new energy vehicles, and formulating relevant standards.

Vanadium-doped Li6.7La3Zr1.7V0.3O12 and PVDF-HFP enhanced the ionic conductivity and cycling stability of composite solid electrolytes for All-Solid-State lithium batteries

Solid electrolytes receive widespread attention due to their high safety, high energy density and simplicity of processing. However, the poor interface stability between the solid electrolyte and the electrode leads to a significant increase in interface resistance, greatly reducing the electrochemical performance of lithium-ion batteries (LIBs). Here we designed and prepared a new type of solid composite electrolytes (SCEs), which were composed of poly (ethylene oxide) (PEO) blended with poly (vinylidene fluoride-hexafluoro propylene) (PVDF-HFP) and doped with cubic phase Li6.7La3Zr1.7V0.3O12 (LLZVO) particles. Compared with our previous work, the addition of PVDF-HFP can further reduce the crystallinity of PEO, limit the formation of lithium dendrites, and make the electrolyte/electrode interface more stable. The SCEs had better ionic conductivity of 2.04 × 10-4 S cm−1 and 2.03 × 10-3 S cm−1 at 30 ℃ and 80 ℃, respectively, and the Li/SCEs/Li symmetrical battery cycled for 1800 h without short circuit. Moreover, the coulombic efficiency of LiFePO4/SCEs/Li battery remained at 98 % after 300 cycles. This opens up a new direction for the research of garnet-type composite solid electrolytes with lower interface resistance.

Predicting doping strategies for ternary nickel–cobalt–manganese cathode materials to enhance battery performance using graph neural networks

The exceptional electrochemical performance of lithium-ion batteries has spurred considerable interest in advanced battery technologies, particularly those utilizing ternary nickel–cobalt–manganese (NCM) cathode materials, which are renowned for their robust electrochemical performance and structural stability. Building upon this research, investigators have explored doping additional elements into NCM cathode materials to further enhance their electrochemical performance and structural integrity. However, the multitude of doping strategies available for NCM battery systems presents a challenge in determining the most effective approach. In this study, we elucidate the potential of ternary NCM systems as cathode materials for lithium-ion batteries. We compile a comprehensive database of lithium-ion batteries employing NCM systems from various sources of prior research and develop a corresponding data-driven model utilizing graph neural networks to predict optimal doping strategies. Our aim is to provide insights into the NCM-based battery systems for both fundamental understanding and practical applications.

The Impact of Wide Discharge C-Rates on the Voltage Plateau Performance of Cylindrical Ternary Lithium-Ion Batteries

Battery voltage plateau characteristics are crucial for designing and controlling battery management systems. Utilising the plateau period attributes to their fullest extent can enable optimal battery control, enhance battery performance, and prolong battery lifespan. This research aimed to investigate the performance of cylindrical ternary lithium batteries at various discharge rates, focusing on the variations in terminal voltage, capacity, and temperature. The battery performance at different discharge rates was meticulously examined through cyclic charge/discharge experiments. The convexity of the voltage curve was used to analyse the voltage plateau characteristics at different rates. The findings revealed significant differences in battery performance under varying discharge rates. Higher discharge rates resulted in shorter discharge times and lower battery voltages at corresponding residual capacities. The discharge time, capacity, and voltage during the plateau phase decreased as the discharge rate increased. At discharge rates of 1 C, 3 C, 5 C, 7 C, 9 C, and 11 C, the proportion of discharged battery capacity ranged from 86.45% to 78.42%. At the same time, voltage and temperature variations during the plateau period decreased significantly compared to those before and after discharge. This research provides a crucial reference point for advancing battery design and thermal management systems.

Modeling and simulation of chemo-elasto-plastically coupled battery active particles

AbstractAs an anode material for lithium-ion batteries, amorphous silicon offers a significantly higher energy density than the graphite anodes currently used. Alloying reactions of lithium and silicon, however, induce large deformation and lead to volume changes up to 300%. We formulate a thermodynamically consistent continuum model for the chemo-elasto-plastic diffusion-deformation behavior of amorphous silicon and it’s alloy with lithium based on finite deformations. In this paper, two plasticity theories, i.e. a rate-independent theory with linear isotropic hardening and a rate-dependent one, are formulated to allow the evolution of plastic deformations and reduce occurring stresses. Using modern numerical techniques, such as higher order finite element methods as well as efficient space and time adaptive solution algorithms, the diffusion-deformation behavior resulting from both theories is compared. In order to further increase the computational efficiency, an automatic differentiation scheme is used, allowing for a significant speed up in assembling time as compared to an algorithmic linearization for the global finite element Newton scheme. Both plastic approaches lead to a more heterogeneous concentration distribution and to a change to tensile tangential Cauchy stresses at the particle surface at the end of one charging cycle. Different parameter studies show how an amplification of the plastic deformation is affected. Interestingly, an elliptical particle shows only plastic deformation at the smaller half axis. With the demonstrated efficiency of the applied methods, results after five charging cycles are also discussed and can provide indications for the performance of lithium-ion batteries in long term use.

Single-phase static immersion-cooled battery thermal management system with finned heat pipes

Effective thermal management is of critical importance to the performance and safety of lithium-ion batteries. However, research on small and medium-sized battery packs remains scarce. This paper proposes a new immersion cooling method. It combines finned heat pipes with a single-phase static immersion fluid, achieving optimal battery pack homogeneity in existing studies while outperforming the performance of conventional immersion cooling. The method is particularly suitable for energy storage batteries and small and medium-sized battery pack cooling applications. This paper presents a verification of the cooling performance of the cooling method through a combination of simulation analysis and experimental validation. The results demonstrate that the cooling method can enable small and medium-sized battery packs to meet the heat dissipation requirements of 3C or even higher discharge rate under natural convection conditions. In the active cooling scenario, when the battery pack is discharged at a 3C multiplier, the cooling scheme of 9 finned heat pipes can reduce the maximum temperature of the flow-submerged cooled battery pack by 6.4 °C and the maximum temperature difference between cells by 5.3 °C. Even when the battery is discharged at an extreme multiplication rate of 6C, the maximum temperature of the battery pack can be maintained at approximately 60 °C, with a maximum temperature difference between cells of around 15 °C. Based on the aforementioned simulation and experimental results, this paper also validates and analyses the main factors affecting the cooling effect of the method, namely the type of submerged liquid and the number of finned heat pipes.

Development of an Efficient Process for the Separation of Co(ii), Mn(ii), and Ni(ii) from Chloride Solution by Precipitation

ABSTRACT The demand for nickel, cobalt, and manganese is increasing owing to their critical role in the performance of lithium-ion batteries. Precipitation is simpler to operate than solvent extraction in the separation of metal ions. In this work, precipitation-based procedures were developed to separate Co(II), Mn(II) and Ni(II) from synthetic chloride solutions. Dimethylglyoxime (DMG) was effective in selectively precipitating Ni(II) from the chloride solutions containing Co(II) and Mn(II). Solution pH greatly affected the precipitation of Ni(II) by DMG. In the first procedure, Ni(II) was first precipitated using DMG from solution with initial pH 6 at a DMG/Ni(II) molar ratio of 3, a reaction time of 30 min and then Co(II) was separated from the filtrate by precipitation with Na2S, with optimal conditions being an initial pH of 6, a Na2S/Co(II) molar ratio of 2 and a reaction time of 15 min. In the second procedure, both Ni(II) and Co(II) was simultaneously precipitated with Na2S, leaving Mn(II) in the filtrate. Then the mixed sulfides of Co(II) and Ni(II) were dissolved by using HCl solution containing NaClO as an oxidizing agent. From the leaching solution, Ni(II) was separated by precipitation with DMG. Optimum conditions for the separation conditions were obtained. In both procedures, the separation degree among the three metal ions was higher than 99%. The developed procedures were simple and effective for the separation of the three metal ions compared to solvent extraction.

Synergistic Effects of Bisalt Additives in High-Voltage Rechargeable Lithium Batteries.

The stability of high-energy-density lithium metal batteries (LMBs) heavily relies on the composition of the solid electrolyte interphase (SEI) formed on lithium metal anodes. In this study, the inorganic-rich SEI layer was achieved by incorporating bisalts additives into carbonate-based electrolytes. Within this SEI layer, the presence of LiF, polythionate, and Li3N was observed, generated by combining 1.0 м lithium bis(trifluoromethanesulfonyl)imide in ethylene carbonate: ethyl methyl carbonate:dimethyl carbonate in a 1 : 1 : 1 volume ratio, with the addition of 2 wt% lithium difluorophosphate and 2 wt% lithium difluoro(oxalato)borate additives (EL-DO). Furthermore, this formulation effectively mitigated corrosion of aluminum current collectors. EL-DO exhibited outstanding performance, including an average coulombic efficiency of 98.2 % in Li||Cu cells and a stable discharge capacity of approximately 162 mAh g-1 after 200 cycles in a Li||LiNi0.8Co0.1Mn0.1O2 (NCM811) configuration. Moreover, EL-DO displayed the potential to enhance the performance not only of LMBs but also of lithium-ion batteries. In the case of Gr||NCM811 cell using EL-DO, it consistently maintained high discharge capacities, even achieving around 135 mAh g-1 after the 100th cycle, surpassing the performance of other electrolytes. This study underscores the synergistic impact of bisalts additives in elevating the performance of lithium batteries.

High entropy alloy nanoparticles decorated carbon-based electrode as interfacial Li-ion localized accelerators for anode-free lithium metal batteries

Lithium metal is deemed as the main representative of the material for next-generation energy storage cells. Nevertheless, the problems of lithium dendrite growth and anode electrode volume expansion have become difficult problems in practical applications. Here, we introduced lithophilic CuInNiSnCd HEA-NPs on the surface of three-dimensional (3D) carbon hosts through a high-temperature redox strategy (HEA/CF). The application of the HEA/CF 3D framework can effectively decrease the non-uniform current density of the anode electrode, thereby slowing down the volume expansion of lithium metal during cycling. The introduction of CuInNiSnCd HEA-NPs improves the lithophilic of the carbon substrate and reduces the nucleation potential of lithium. Meanwhile, their evolution process was monitored in situ by the dynamic electrochemical impedance spectroscopy (DEIS) with relaxation time (DRT) distribution analysis, and the introduction of the HEA was beneficial to improving Li+ migration kinetics. Consequently, the symmetric battery with Li@HEA/CF anode has an excellent cycle life of over 3000 h (10 mA cm−2/10 mAh cm−2). Furthermore, the anode-free HEA/CF assembled full cell has excellent rate performance with a stable CE of more than 99.2 % after 160 cycles at 1C. This research contributes to the use of high-entropy materials in advanced energy storage batteries and provides valuable guidance for enhancing the performance of lithium batteries.

Rational Design of Electrolyte Additives for Improved Solid Electrolyte Interphase Formation on Graphite Anodes: A Study of 1,3,6-Hexanetrinitrile

The construction of a thin, uniform, and robust solid electrolyte interphase (SEI) film on the surface of active materials is pivotal for enhancing the overall performance of lithium-ion batteries (LiBs). However, conventional electrolytes often fail to achieve the desired SEI characteristics. In this work, we introduced 1,3,6-hexanetrinitrile (HTCN) in the baseline electrolyte (BE) of 1.0 M LiPF6 in Ethylene Carbonate/Dimethyl Carbonate (EC/DMC) (3:7 by volume) with 5 wt.% fluoroethylene carbonate (FEC), denoted as BE-FH. By systematically investigating the influence of FEC: HTCN weight ratios on the electrochemical performance of graphite anodes, we identified an optimal composition (FEC:HTCN = 5:4 by weight, denoted as BE-FH54) that demonstrated greatly improved initial Coulombic efficiency, rate capability, and cycling stability compared with the baseline electrolyte. Deviations from the optimal FEC:HTCN ratio resulted in the formation of either small cracks or excessively thick SEI layers. The enhanced performance of BE-FH54-based LiB is mainly ascribed to the synergistic effect of FEC and HTCN in forming a robust, thin, homogeneous, and ion-conducting SEI. This research highlights the importance of rational electrolyte design in enhancing the electrochemical performance of graphite anodes in LiBs and provides insights into the role of nitrile-based additives in modulating the SEI properties.

Modeling and research on high-frequency AC heating system for lithium-ion battery based on bidirectional buck-boost topology

Lithium-ion battery (LIB) performance decreases in cold climates, preheating is necessary to improve the output power and life decay of low-temperature LIB. At present, a variety of internal alternative current (AC) heating methods are used to achieve fast and temperature-consistent heating. However, existing AC heating devices are constrained by the problems of changing the battery structure, and also need for an additional power supply to power the battery, which have effect on the battery life. Meanwhile, the conventional model is not suitable for AC preheating simulation, especially at high frequencies. Under above scenarios, a high-frequency AC heating method using a bidirectional boost converter is designed and a high-frequency thermoelectric model based on lithium-ion transmission is developed. In the paper, the proposed high-frequency AC heating structure and thermal-electrical coupling model are verified by experimental results to test the validity of different AC heating frequencies, which solves the lack of comprehensive theoretical and experimental verification in the field of high-frequency AC heating. The experimental results show that increasing the AC heating frequency at the same current multiplicity can significantly increase the heating rate. An optimal frequency is acquired, the optimal heating rate can reach 4.65 K/min at 800 Hz without affecting the service life of the battery. The high-frequency AC heating method provides a new solution framework for the LIB performance enhancement in cold climates.

Enhanced electrochemical performance of a cost-effective Sm2O3-coated spinel LiNi0.5Mn1.5O4 cathode for high-voltage lithium-ion batteries

Spinel LiNi0.5Mn1.5O4 (LNMO) has gained significant attention as a promising cathode material for lithium-ion batteries due to its high working voltage (>4.7 V) and energy density. However, challenges such as electrolyte decomposition-induced material interface erosion and transition metal dissolution under high operating voltage hinder its commercial use. In this study, a thin and uniform Sm2O3 layer has been successfully deposited on the surface of LNMO using a wet chemical method. A comprehensive investigation of surface morphology, crystal structure, and electrochemical performance of the modified LNMO is conducted. The results demonstrate that the Sm2O3 surface modification acts as a robust multifunctional protective layer, effectively shielding against hydrofluoric acid-induced chemical attack and enhancing the migration efficiency of lithium ions. Notably, the capacity retention rate of LNMO@Sm2O3 (3 wt%) remains up to 88 % after 280 cycles, significantly surpassing the uncoated counterpart. The coated material exhibits a capacity of 114 mAh g−1 even under 10 C rate conditions. Moreover, the AC impedance values and manganese dissolution of the modified material in the organic electrolyte are considerably lower than those of the uncoated counterpart. Theoretical calculations strongly support the experimental findings, revealing higher Mn vacancy formation energy and density of states at the Fermi energy level for the Sm2O3-modified electrodes. This research contributes to the field of surface modification and paves the way for further enhancements in the electrochemical performance of other high-voltage manganese-based lithium-ion batteries (LIBs).

In Situ Polymerized Zwitterionic Copolymer Ionic Gel Electrolytes with High Performance for Lithium-Ion Batteries.

Gel electrolytes are a promising research direction due to their high safety. However, its poor room temperature conductivity along with complex preparation process hinder its practical application. In this article, a type of zwitterionic gel electrolyte is prepared by in situ polymerization. The introduction of charged but nonmigrating zwitterionic copolymer in the polymer chain is beneficial to the dissociation of the lithium salt, improving the ion transport of the electrolyte on this account. At room temperature, the conductivity of lithium ion reaches 9.1 × 10-4 S cm-1, which contributes to achieve excellent electrochemical performance at high rates. The assembled Li|LiFePO4 cell also shows a capacity retention rate of 90.5% after 150 cycles at 0.5 C at room temperature as well as remarkable cycle stability at 1 C. These offer a novel tactic for the efficient and safe commercial application of lithium-ion batteries.

Co-Assembly of Polyoxometalates and Porphyrins as Anode for High-Performance Lithium-Ion Batteries.

Polyoxometalates (POMs) have been considered one of the most promising anode candidates for lithium-ion batteries (LIBs) in virtue of their high theoretical capacity and reversible multielectron redox properties. However, the poor intrinsic electronic conductivity, low specific surface area, and high solubility in organic electrolytes hinder their widespread applications in LIBs. Herein, a novel hybrid nanomaterial is synthesized by co-assembling POMs and porphyrins (PMo12/CoTPyP) through a facile solvothermal method. The POM clusters are stabilized by porphyrin units through electrostatic interactions, which simultaneously realize the uniform dispersion of POMs and porphyrin units. Benefiting from the generated sub-1nm channels for fast ion transport and the synergistic effect between evenly distributed PMo12 clusters and high-conductive CoTPyP units, the LIB based on the optimized PMo12/CoTPyP anode exhibits significantly improved Li+ storage capability as well as superior rate and cycling performance. The results of density functional theory simulations further reveal that the co-assembly of PMo12 and CoTPyP can accelerate the mobility of Li+ and electrons, which in turn promotes the enhancement of LIBs performance. This work paves a strategy for synthesizing POMs-based anode materials with simultaneously high dispersibility, redox activity, and stability.

Enhancing electrochemical performance of lithium-ion batteries with diverse nanomaterials

Abstract Although lithium-ion batteries (LIBs) can be widely used, there are some challenges such as safety risks, lower energy density compared to fossil fuels, high cost, long charging times and limited range in electric vehicles. Nanomaterials, with their unique properties and surface effects, can effectively address these challenges and improve the electrochemical performance of LIBs. This research introduces six types of nanomaterials used in LIBs, including TiS3 nanoflakes, ZnMn2O4 nanobundles, ZrO2 surface-modified cathode material, nitrogen-doped carbon fibers with tin (Sn) nanoparticles, carbon nanosheets, and nanostructured bismuth-carbon composites. These recent advancements in nanomaterials can improve electrochemical performance of LIBs, such as specific capacity, cycling ability and stability. The study offers some innovative insights and approaches in using nanomaterials and synthesizing them for emerging battery technologies. In addition, this research is wished to provide a fresh perspective and methodology that can advance the performance and design of LIBs, and provide a new design approach for nanomaterials.