Perchlorate Salts Research Articles

Chemical and morphology characteristics of mimic enzyme Zinc-cyclen integrated with polyvinyl alcohol (PVA) - polyethersulfone (PES) membrane

Carbon dioxide (CO2) released from fossil fuel industries into the atmosphere had contributed to the global warming effect and climate change. The development of CO2 separation process through membrane technology had been introduced to capture CO2 from the flue gas. Integration between membrane technology with the biological approach using carbonic anhydrase (CA) enzyme has been explored to enhance carbon capture technology. However, because of the pH and temperature changes, the CA activity had been permanently disturbed. Thus, in this present study, amimic enzyme (Zn-cyclen) was introduced to resemble the active site of CA enzymes and mimic the bio-catalytic process of CA. Mimic enzyme (Zn-cyclen) was synthesized using the precipitation method of Zinc perchlorate salt solution. The white precipitate of Zn-cyclen was analyzed and characterized for functional group, morphology, and crystallinity behaviour. Then, the developed Zn-cyclen was mixed with the polyvinyl alcohol (PVA) solution and cast onto polyethersulfone (PES) membrane using the dip-coating method to form a complex PES + PVA + Zn-cyclen membrane. The effect of mimic enzyme (Zn-cyclen) loading in the PVA solution were evaluated for swelling and hydrophilic characteristic. The finding shows that Zn-cycle possesses a crystalline structure that is significant in catalytic reaction and the functioning group analysis indicated that the presence of N-H and O-H groups at 1630 cm−1 and 3274 cm−1, respectively, which reflect the protein molecular structure of CA. Integration of Zn-cyclen onto PVA membrane shows that Zn-cyclen has improved the swelling ability of the membrane and increased the hydrophilicity of the complex membrane. Thin film PVA with 3 mg of Zn-cyclen gave the lowest contact angle at 36.4° which possesses the highest hydrophilic. Furthermore, higher swelling ability was observed at Zn-cyclen loading less than 6 mg. The presence of Zn-cycle in the complex PES + PVA membrane was validated with the appearance of the peaks associated with the N – H group at 1629 cm−1. The surface of the complex membrane was rough and the presence of Zn-cyclen cluster or aggregate was observed on the surface of the membrane. The finding indicated addition of Zn-cyclen particle into the PES + PVA membrane formulation has improved the swelling and hydrophilic characteristic of the PES + PVA membrane which is significant in the CO2 hydration application.

Structure and Properties of Electroactive Composites Based on Oligomers of Different Molecular Weight Doped with Lithium Perchlorate Salt

Structure and Properties of Electroactive Composites Based on Oligomers of Different Molecular Weight Doped with Lithium Perchlorate Salt

Exploring the influence of counterions on a hysteretic spin-transition in isomorphous iron(ii) complex salts

The hysteretic spin transition shown by [FeL2][BF4]2is quenched in its isomorphous perchlorate salt, which reflects more sluggish lattice dynamics in the presence of the larger ClO4−ion.

Preparation of Tris-Tetrazole-Based Metallogels and Stabilization of Silver Nanoparticles: Studies on Reduction Catalysis and Self-Healing Property

An ionic multifunctional gelator molecule triethylammonium 5-(3,5-bis((1H-tetrazol-5-yl)carbamoyl)benzamido)tetrazol-1-ide G7 is synthesized and characterized by spectroscopic tools and mass spectrometry. G7 tends to form a stable organogel in a mixture of N,N-dimethylformamide/dimethylsulfoxide (DMF/DMSO) and water. Introduction of different metal perchlorate salts in a DMSO solution of G7 furnished a series of metallogels M1G7, M2G7, M3G7, M4G7, M5G7, M6G7, and M7G7 [M1 = Fe(III), M2 = Co(II), M3 = Cu(II), M4 = Zn(II), M5 = Ag(I), M6 = Ni, and M7 = Fe(II)]. Among them, M1G7, M3G7, M4G7, M6G7, and M7G7 help individually in the synthesis and stabilization of bimetallic nanocomposites containing silver nanoparticles (AgNPs). Iron(III)-containing nanocomposites M1G7AgNPs have been utilized in the form of catalysts in the reduction reaction of nitroaromatic compounds to corresponding amines with a quantitative yield. The organogel G7 has also shown the abilities to absorb different metal ions from aqueous solutions and allow selective transition of M1G7 from the gel state to the crystalline state. Fe(III) formed dual metallogels with Zn(II), which can be used for further applications. Furthermore, the nanocomposite M1G7AgNP powder, in the presence of the organogel G7, gets converted into a nanostructured metallogel, which shows exclusive self-healing properties. This is the first example where a nanocomposite powder contains the dual-metal system (Fe(III) and Ag(0)) and shows a reduction catalytic property, and its nanostructured dual-metallogel form manifests the self-healing property in a fabricated metallogel.

Desolvation–Solvation-Induced Reversible On–Off Switching of Two Memory Channels in a Cobalt(II) Coordination Polymer: Overlay of Spin Crossover and Structural Phase Transition

Desolvation–Solvation-Induced Reversible On–Off Switching of Two Memory Channels in a Cobalt(II) Coordination Polymer: Overlay of Spin Crossover and Structural Phase Transition

Impact of the Solid‐Electrolyte Interface on Dendrite Formation: A Case Study Based on Zinc Metal Electrodes

AbstractThe formation of dendrites is the bottleneck to harvest the high theoretical capacities of metal anodes. In this study, we investigated the impact of the solid‐electrolyte interface (SEI) layer on the electroplating of zinc metals in organic and aqueous electrolytes by using electrochemical techniques coupled with SEM, FTIR, and XPS. First, the electrochemical response of Zn plating in organic or aqueous electrolytes was compared with the ones for Li and Na metal plating by using analogous perchlorate salt dissolved in the same organic solvent. Under similar charge conditions, the cycle life of the metal electrodes was longer in the order of Zn (aqueous)>Li>Zn (organic)>Na. In organic electrolytes, the cycle life of the PAO‐Zinc is almost three‐fold longer than the as‐received zinc electrodes. The methodology established here can be used to study the impact of electrolyte salt and additives on the formation of dendrites on metal electrodes.

Spectral Studies on Impact of Alkali Perchlorate (Li/Na/K-ClO4) Salts on the Properties of PVA-Ag-Cr3+ Polymer Nanocomposite Films

Poly (Vinyl alcohol) metal (PVA-Ag-Cr) nanocomposites were prepared by a slow evaporation method with the help of a refluxing procedure. The effect of alkali perchlorate (Li/Na/K-QlO4) salts embedded in PVA-metal nanocomposites were analysed with SEM, XRD, EPR, and optical techniques. The surface structure and topology of the synthesized composites were studied using scanning electron microscopy. The crystallinity of the prepared polymer films has been determined using the X-ray diffraction pattern. Existing changes in some diffraction angle with the alkali salts results the fluctuations in the degree of crystallinity. EPR studies reveal the ‘g’ values at 1.96, 1.93, and 1.98 due to the oxidation exchange-coupled pair. The observed absorption spectra of Cr3+ ions corresponding to Li, Na & KClO4 salts in PVAAgSe polymer films revealed the band positions centered at 220, 275, 480, 535, and 1030 nm of all the alkali chlorates with small shifting in-band positions. This may be due to the inter/intramolecular hydrogen bonding.

Effect of new crystalline phase on the ionic conduction properties of sodium perchlorate salt doped carboxymethyl cellulose biopolymer electrolyte films

Dopant induced modifications in the microstructure of sodium carboxymethyl cellulose (NaCMC) were characterized by FTIR, XRD, DSC and EIS techniques. FTIR analysis exhibited a considerable microstructural modification in NaCMC upon NaClO4⋅H2O doping invoked through complex formation via Lewis acid-base interaction and hydrogen bond formation between ions and dipoles. This resulted in the modification in the orderliness/disorderliness of polymer chains as observed from XRD deconvolution. At higher salt concentrations, the complexity of the network causes the formation of new amorphous and crystalline phases as reflected in the XRD studies. DSC analysis showed an increase in Tg as the salt concentration increased, indicating a reduction in polymer chains flexibility. The contribution of free ions has masked over the enhancement in amorphous content to conductivity at a lower concentration of salt in the matrix, later on, the formation of a new crystalline phase due to transient crosslinks by Na+…ClO4−…Na+ has affected the ion transport process.

Synthesis and structure of macrocyclic dinickel(II) complex with 5-(4-pyridyl)tetrazolate as coligand

The dinuclear nickel(II) complex [Ni2LmClO4] + , where Lm represents a 24-membered macrocyclic hexaaza-dithiophenolate ligand, reacts with 5-(4-pyridyl)tetrazole (PyrCN4H) to give the dinuclear complex [Ni2Lm(PyrCN4)]+ . The new complex was both isolated as perchlorate or tetraphenylborate salts and characterised by elemental analysis and IR spectroscopy. The structure of [Ni2Lm(PyrCN4)]BPh4 ⋅ MeCN was determined by single crystal X-ray diffraction, showing that tetrazolate units are in a N2,N3-bridging mode to generate dioctahedral N3Ni(µ-S)2(µ-N4CPyr)NiN3 core.

Fluorite-like hydrolyzed hexanuclear coordination clusters of Zr(IV) and Hf(IV) with syn-syn bridging N,N,N-trimethylglycine in soft crystal structures exhibiting cold-crystallization

Tetravalent metal ions are hydrolyzed under presence of N,N,N-trimethylglycine hydrochloride (betaine hydrochloride, [Hbet]Cl) in aqueous solutions to afford [M6(μ3-O)4(μ3-OH)4(μ-bet)8(κ-bet)4(H2O)4]12+ (M4+ = Zr4+ (1), Hf4+ (2)) as hydrated perchlorate salts. These compounds were characterized by single crystal X-ray diffraction, elemental analysis and IR spectroscopy. As a result, we have found that fluorite-like [M6O8] coordination clusters are formed through octahedral arrangement of six M4+ linked by μ3-O atoms. Additionally, each pair of neighboring M4+ are connected by the μ-bet ligand through a syn-syn bridging coordination of its carboxylate moiety. This interaction seems to prevent further growth of the fluorite structure leading to formation of MO2. It was difficult to directly distinguish each μ3-O atom to be μ3-OH− or μ3-O2− due to its strongly anisotropic thermal displacement in the obtained structures. Bond valence sum analysis suggested that four μ3-OH− and four μ3-O2− are alternately arranged in the [M6O8] core motifs. Indeed, such a symmetric structure of [M6(μ3-O)4(μ3-OH)4] was confirmed in another phase of 1 at 296 K, where 1 transforms to a monoclinic structure (1′). The number of ClO4− counteranions found in the structure determination is not enough to compensate + 12 charge of [M6(μ3-O)4(μ3-OH)4(μ-bet)8(κ-bet)4(H2O)4]12+ in any unit cells of 1, 1′ and 2. Instead, large solvent/ion accessible voids have been actually observed in their crystal structures, indicating that the missing ClO4− are located therein and are significantly disordered to make them invisible in the crystallography. DSC analysis revealed that ClO4− and H2O/H3O+ in the crystal lattice of 1 undergo unique structure relaxation and rearrangements pronounced by cold-crystallization to induce the phase transition from 1 to 1′ with elevating temperature.

Synthesis and characterization of energetic salts based on a new coplanar bicyclic cation-5-amino-3-(5-amino-1,2,4-oxadiazol-3-yl)-1H-1,2,4-triazolium

A novel coplanar bicyclic cation 3-(5-amino-1H-1,2,4-triazol-3-yl)-1,2,4-oxadiazol-5-amine (AOAT) was proposed to widen the research of energetic cations, and four salts were synthesized via neutralization reaction in high yield. The single-crystal X-ray diffraction, multinuclear NMR (1H and 13C), IR, MS spectra, elemental analysis, differential scanning calorimetry (DSC), and thermos-gravimetric (TG) analysis techniques were employed to verify and characterize the structures and thermal stability of the four salts respectively. Based on the combination of experimentally determined densities and enthalpies of formation, the energetic properties of the two energetic salts AOATP and AOATN were determined using EXPLO5 program. Compared with those known energetic salts, AOATP and AOATN exhibited high densities (1.829–1.871 g·cm−3), acceptable detonation performance (D: 8359–8465 m·s−1; P: 28.4–30.3 GPa), good thermal stability (Td: 177–238 °C), as well as satisfied mechanical sensitivities (IS: 16–22 J; FS: 188–216 N). Hirshfeld surfaces and assiciated 2D fingerprint plots as well as non-covalent interactions were adopted to examine the intermolecular interactions of the four salts. The results indicate that ionic bonds, hydrogen bonds, and π-π stacking interactions are responsible for the high densities and excellent properties of 5-amino-3-(5-amino-1,2,4-oxadiazol-3-yl)-1H-1,2,4-triazolium perchlorate and nitrate salts, suggesting that the AOAT is a potential cation in the construction of high-performance energetic materials and that cations with coplanar conjugated structures could effectively improve the detonation properties and stability.

M(II)Al4 Type Layered Double Hydroxides-Preparation Using Mechanochemical Route, Structural Characterization and Catalytic Application.

The synthesis of the copper-poor and aluminum-rich layered double hydroxides (LDHs) of the CuAl4 type was optimized in detail in this work, by applying an intense mechanochemical treatment to activate the gibbsite starting reagent. The phase-pure forms of these LDHs were prepared for the first time; using copper nitrate and perchlorate salts during the syntheses turned out to be the key to avoiding the formation of copper hydroxide sideproducts. Based on the use of the optimized syntheses parameters, the preparation of layered triple and multiple hydroxides was also attempted using Ni(II), Co(II), Zn(II) and even Mg(II) ions. These studies let us identify the relative positions of the incorporating cations in the well-known selectivity series as Ni2+ >> Cu2+ >> Zn2+ > Co2+ >> Mg2+. The solids formed were characterized by using powder X-ray diffractometry, UV–Vis diffuse reflectance spectroscopy, Fourier-transform infrared spectroscopy, thermogravimetric analysis and scanning electron microscopy. The catalytic potential of the samples was investigated in carbon monoxide oxidation reactions at atmospheric pressure, supported by an in situ diffuse reflectance infrared spectroscopy probe. All solids proved to be active and the combination of the nickel and cobalt incorporation (which resulted in a NiCoAl8 layered triple hydroxide) brought outstanding benefits regarding low-temperature oxidation and increased carbon monoxide conversion values.

Perchlorate salts confer psychrophilic characteristics in \u03b1-chymotrypsin

Studies of salt effects on enzyme activity have typically been conducted at standard temperatures and pressures, thus missing effects which only become apparent under non-standard conditions. Here we show that perchlorate salts, which are found pervasively on Mars, increase the activity of α-chymotrypsin at low temperatures. The low temperature activation is facilitated by a reduced enthalpy of activation owing to the destabilising effects of perchlorate salts. By destabilising α-chymotrypsin, the perchlorate salts also cause an increasingly negative entropy of activation, which drives the reduction of enzyme activity at higher temperatures. We have also shown that α-chymotrypsin activity appears to exhibit an altered pressure response at low temperatures while also maintaining stability at high pressures and sub-zero temperatures. As the effects of perchlorate salts on the thermodynamics of α-chymotrypsin’s activity closely resemble those of psychrophilic adaptations, it suggests that the presence of chaotropic molecules may be beneficial to life operating in low temperature environments.

Polymer-garnet composite electrolyte based on comb-like structured polymer for lithium-metal batteries

Polymer-inorganic solid-state electrolyte membranes for lithium-metal batteries have attracted considerable attention among the scientific community because of their flexibility, stability, and better electrodes to electrolyte interaction. This work reports the preparation of polymer-garnet composite electrolyte (PGCE) membranes consisting of polyethylene oxide polymer, LLZA (Li6.28Al0.24La3Zr2O12) garnet filler, LiClO4 (lithium perchlorate salt), and as-synthesized comb-like structured polymer (CLSP). The CLSP has an ethylene oxide backbone chain with ester/carboxyl/hydroxyl functional groups that smoothly facilitate Li-ion mobility. The polymer-garnet composite electrolyte (PGCE-3, prepared with CLSP) membrane showed an enhancement in the Li-ion conductivity of 1.29 × 10−5 S/cm at 25 °C with a potential stability window > 4.6 V compared with the pristine polymer-garnet blank electrolyte (PGBE—prepared without CLSP). The PGCE-3 membrane exhibited a Li-ion transference number of 0.21 compared with that of 0.13 for the PGBE membrane with superior interfacial compatibility over lithium metal for 300 h at a current density of 0.09 mA/cm−1. The fabricated full cell Li||PGCE-3||LFP resulted in an initial to final discharge capacity of 140 mAh/g to 120 mAh/g at 0.1 C with a coulombic efficiency of 98.30% for 50 cycles. This full cell was stable enough to discharge its power after eight months without recharging. The PGCE membranes containing CLSP architecture as polymer electrolyte show promising results for high energy density lithium-metal rechargeable batteries.

Evaluation of grainflow mechanisms for martian recurring slope lineae (RSL)

Recurring slope lineae (RSL) are dark narrow features that incrementally lengthen and fade at least once each Mars year. Their origin has remained enigmatic. We report quantitative modeling of three hypotheses related to triggering of over-steepened sand caches that result in dry-grain flow. First, sand could be supplied by either wind blowing upslope from within the crater or by wind blowing into the crater from the outside. Without cementation, grain flows should be directly correlated with temporal variations in potential sediment transport. Second, deliquesced perchlorate salts could increase soil cohesion; with the loss of water this soil cohesion may be reduced. The timing of accumulation versus release can be distinct from each other. Third, seasonal water frost could act in a similar cementation capacity. We assess these hypotheses using atmospheric modeling to determine wind speed, wind direction, temperature, and relative humidity at three craters (Rauna, Krupac, and Palikir) that host confirmed RSL and that cover a large latitudinal range. Overall, we find no convincing support for any of these hypotheses. Deliquescence is predicted to occur only at Rauna crater and its formation does not correlate with RSL activity. The occurrence of frost is inconsistently correlated with RSL activity among the three craters. Upslope winds at Palikir crater transport a significant amount of sediment only when RSL are active. However, the largest sediment flux into the crater is also during periods of RSL activity, thus supporting both internal and external contributions. Sediment transport into Krupac crater to S- and SW-facing slopes is also maximized when RSL are active, but there is no correlated upslope transport. This supports the hypothesis that RSL formation is dominated by external sediment supply alone. On the other hand, W- and NW-facing Krupac and all RSL at Rauna show no correlations with any directional sediment transport. Nonetheless, we suggest that the mixed success of the external sediment transport model is still quantitatively better than any competitor (including water), and that we simply lack the model and data resolution to treat RSL at the required meter scales. In all of the aeolian models, favorably-directed potential sediment flux greatly exceeds the volume of sand that must be displaced to form RSL. We conclude that RSL may require a particular combination of favorable strong winds, local sediment traps, and a supply of sand grains that easily saltate on Mars (~100 μm in diameter).

THERMAL AND ELECTROCHEMICAL PROPERTIES OF SOLID BIOPOLYMER ELECTROLYTES FROM STARCH OF DIFFERENT BOTANICAL ORIGIN

Background: Solid biopolymer electrolytes are a type of material with high technological potential used in the development of solar cells, batteries, fuel cells, among others, due to their biodegradable nature and low environmental impact. Aim: This study aimed to evaluate the effect of the botanical origin of the starch used to prepare solid biopolymeric electrolyte films on its electrochemical and thermal properties and to establish the variations in thermal decomposition temperatures and redox potentials depending on the botanical origin of the starch used. Methods: Films of solid biopolymer electrolyte were made by thermochemical synthesis processes using corn starch, cassava starch, potato starch, glycerol, polyethylene glycol, and glutaraldehyde as plasticizers and lithium perchlorate salt. The synthesis solutions were taken to an oven at 70 °C for 48 hours. The films were characterized electrochemically by cyclic voltammetry using a dry electrochemical cell and thermally by differential scanning calorimetry and thermogravimetric analysis. Results and Discussion: The results showed that the electrochemical behavior of the films was similar in terms of registered redox processes. However, the potential values of the oxidation and reduction were different, as are the stability and intensity of the processes. On the other hand, the thermal analysis allowed establishing two decomposition processes in each of the films studied; the first process was due to dehydration and depolymerization phenomena in the films. The temperatures recorded were 59.0 °C, 58.9 °C, and 89.9 °C for potato starch, cassava starch, and corn starch films. The second process evidenced the thermal decomposition at different temperatures, 267.7 °C in potato starch films, 280.6 °C in corn starch films, and 287.1 °C in cassava starch films. Conclusions: It could be concluded that the botanical origin of the starch used in the synthesis of solid biopolymer electrolyte films affects its behavior and electrochemical and thermal stability.

Supramolecular hydrogelation via host-guest anion recognition: Lamellar hydrogel materials for the release of cationic cargo

Supramolecular hydrogelation via host-guest anion recognition: Lamellar hydrogel materials for the release of cationic cargo

Mining for Perchlorate Resistance Genes in Microorganisms From Sediments of a Hypersaline Pond in Atacama Desert, Chile.

Perchlorate is an oxidative pollutant toxic to most of terrestrial life by promoting denaturation of macromolecules, oxidative stress, and DNA damage. However, several microorganisms, especially hyperhalophiles, are able to tolerate high levels of this compound. Furthermore, relatively high quantities of perchlorate salts were detected on the Martian surface, and due to its strong hygroscopicity and its ability to substantially decrease the freezing point of water, perchlorate is thought to increase the availability of liquid brine water in hyper-arid and cold environments, such as the Martian regolith. Therefore, perchlorate has been proposed as a compound worth studying to better understanding the habitability of the Martian surface. In the present work, to study the molecular mechanisms of perchlorate resistance, a functional metagenomic approach was used, and for that, a small-insert library was constructed with DNA isolated from microorganisms exposed to perchlorate in sediments of a hypersaline pond in the Atacama Desert, Chile (Salar de Maricunga), one of the regions with the highest levels of perchlorate on Earth. The metagenomic library was hosted in Escherichia coli DH10B strain and exposed to sodium perchlorate. This technique allowed the identification of nine perchlorate-resistant clones and their environmental DNA fragments were sequenced. A total of seventeen ORFs were predicted, individually cloned, and nine of them increased perchlorate resistance when expressed in E. coli DH10B cells. These genes encoded hypothetical conserved proteins of unknown functions and proteins similar to other not previously reported to be involved in perchlorate resistance that were related to different cellular processes such as RNA processing, tRNA modification, DNA protection and repair, metabolism, and protein degradation. Furthermore, these genes also conferred resistance to UV-radiation, 4-nitroquinoline-N-oxide (4-NQO) and/or hydrogen peroxide (H2O2), other stress conditions that induce oxidative stress, and damage in proteins and nucleic acids. Therefore, the novel genes identified will help us to better understand the molecular strategies of microorganisms to survive in the presence of perchlorate and may be used in Mars exploration for creating perchlorate-resistance strains interesting for developing Bioregenerative Life Support Systems (BLSS) based on in situ resource utilization (ISRU).

Perchlorate Salts Exert a Dominant, Deleterious Effect on the Structure, Stability, and Activity of α-Chymotrypsin.

The presence of perchlorate ions on Mars raises the question of how these ions influence the biochemistry of any contaminant life introduced into the martian environment, or what selection pressures perchlorate ions exert on any environment that contains these ions, such as the Atacama Desert. In this study, we investigated the structure, stability, and enzyme activity of the model enzyme α-chymotrypsin in the presence of five Mars relevant salts, MgSO4, MgCl2, Mg(ClO4)2, Ca(ClO4)2, and NaClO4. We found that all the perchlorate salts reduced the enzyme activity of α-chymotrypsin in a concentration-dependent manner, with Mg(ClO4)2 and Ca(ClO4)2 having the greatest effect. This observation extends to our structural studies, which show that 1 M Mg(ClO4)2 and Ca(ClO4)2 greatly alter the tertiary structural environment of α-chymotrypsin. We also found that all the perchlorate salts assayed reduced the melting temperature of α-chymotrypsin, whereas the sulfate and chloride salts were able to increase the protein melting temperature. We also demonstrated that a brine containing both perchlorate and sulfate ions exerts the same deleterious effects on α-chymotrypsin's melting temperature and enzyme activity as that of a perchlorate-only brine. This suggests that the perchlorate salts exert a dominant, deleterious effect on protein biochemistry. These results indicate that although perchlorate salts are beneficial to the presence of liquid water due to low eutectic points, they also hamper the habitability of their own environment. Life in such brines would, therefore, have to adapt its cellular machinery to the perchlorate ion's presence or find a way of excluding it from said machinery.

Pyrolysis of Oxalate, Acetate, and Perchlorate Mixtures and the Implications for Organic Salts on Mars

AbstractOrganic salts, such as Fe, Ca, and Mg oxalates and acetates, may be widespread radiolysis and oxidation products of organic matter in Martian surface sediments. Such organic salts are challenging to identify by evolved gas analysis but the ubiquitous CO2and CO in pyrolysis data from the Sample Analysis at Mars (SAM) instrument suite on the Curiosity rover indirectly points to their presence. Here, we examined laboratory results from SAM‐like analyses of organic salts as pure phases, as trace phases mixed with silica, and in mixtures with Ca and Mg perchlorates. Pure oxalates evolved CO2and CO, while pure acetates evolved CO2and a diverse range of organic products dominated by acetone and acetic acid. Dispersal within silica caused minor peak shifting, decreased the amounts of CO2evolved by the acetate standards, and altered the relative abundances of the organic products of acetate pyrolysis. The perchlorate salts scrubbed Fe oxalate CO releases and shifted the CO2peaks to lower temperatures, whereas with Ca and Mg oxalate, a weaker CO release was observed but the initial CO2evolutions were largely unchanged. The perchlorates induced a stronger CO2release from acetates at the expense of other products. Oxalates evolved ∼47% more CO2and acetates yielded ∼69% more CO2when the perchlorates were abundant. The most compelling fits between our organic salt data and SAM CO2and CO data included Martian samples acquired from modern eolian deposits and sedimentary rocks with evidence for low‐temperature alteration.