Schiff base (L) ligand is prepared via condensation of P-Anisaldehyde and ethylene diamine in 2:1 ratio in ethanol. A new complex is prepared by reacting this ligand with metallic salt CdI<sub>2</sub>. The structure of the two derivatives are confirmed using various spectroscopic techniques: C, H, N analyses, IR, UV-visible and X-ray diffraction. The IR spectrums of ligand and complex show respectively intense peaks at 1629 cm<sup>-1</sup> and 1639cm<sup>-1</sup> indicating the presence of azomethine group (N=C). The crystal structure of the ligand belongs respectively to monoclinic, space group P21/n. In the crystal packing of the ligand, molecules are linked by a pair of methyl-C-H…O(methoxy) interactions, forming to an infinite one-dimensional chain. The structural characterization of the complex reveals that it crystallizes in an orthorhombic system P with as space group Pbca with a=14.8704 Å; b=12.9618 Å; c=22.4416 Å. The crystal structure of the monomer complex shows a distorted tetrahedral geometry. The Cd<sup>II</sup> center is coordinated by the bidentate schiff base ligand via the two imine groups (N-donor) and the two chlorine atoms. Non-classical intermolecular H-bonds of the type benzene-C—H…O(methoxy) exist and link the monomeric complex, forming one dimensional chains.