GaAs nanowires were selectively grown by metal–organic vapour-phase epitaxy within aSiO2 mask window pattern fabricated on a GaAs(111)B substrate surface. The nanowires were100–3000 nm in height and 50–300 nm in diameter. The height decreased as the maskwindow diameter was increased or the growth temperature was increased from 700 to800 °C. The dependence of the nanowire height on the mask window diameter was compared witha calculation, which indicated that the height was inversely proportional to the maskwindow diameter. This suggests that the migration of growth species on the nanowire sidesurface plays a major role. Tetrahedral GaAs grew at an early stage of nanowire growthbut became hexagonal as the growth process continued. The calculated change in Gibbsfree energy for nucleation growth of the crystals indicated that tetrahedra wereenergetically more favourable than hexagons. Transmission and scanning electronmicroscopy analyses of a GaAs nanowire showed that many twins developed along the B direction, suggesting that twins had something to do with the evolution of the nanowireshape from tetrahedron to hexagon.
Read full abstract