Particle Emission Rates Research Articles

Particulate emission rates for open surfaces in Australian open cut black coal mines

Accurate estimation of particulate emissions is fundamental to assessing the air quality risks posed by existing and proposed open cut black coal mines. The currently available emission estimation techniques are based on a limited range of empirical studies, and the need for additional research and development of activity and region specific particulate emission estimation methods has been recognised. This paper presents the results of empirical testing of particulate emission rates for open area surfaces in open cut black coal mines in three Australian regions. The emission rates are provided for specific wind speeds, thus allowing adjustment of emission rates for prevailing meteorology in these regions. The influence of surface watering as a control technique is also considered. Particulate emission rates are presented for a range of coal mining sources, and for specific wind speeds. Comparison of the emission rates with the existing published research confirms the emission rates are consistent with current approaches. This research significantly expands our current understanding by presenting emission rates for a range of open area sources, for specific wind speeds and surface watering controls. This more detailed emission estimation dataset provides for adjustments to default particulate emission rates to allow site specific data to be integrated into emissions estimation. This will result in more accurate emissions estimates for existing and future projects and reduce the potential for significant over- or under-estimation of particulate emissions from surface sources in open cut coal mines.

Insights Into Emissions and Exposures From Use of Industrial-Scale Additive Manufacturing Machines.

BackgroundEmerging reports suggest the potential for adverse health effects from exposure to emissions from some additive manufacturing (AM) processes. There is a paucity of real-world data on emissions from AM machines in industrial workplaces and personal exposures among AM operators.MethodsAirborne particle and organic chemical emissions and personal exposures were characterized using real-time and time-integrated sampling techniques in four manufacturing facilities using industrial-scale material extrusion and material jetting AM processes.ResultsUsing a condensation nuclei counter, number-based particle emission rates (ERs) (number/min) from material extrusion AM machines ranged from 4.1 × 1010 (Ultem filament) to 2.2 × 1011 [acrylonitrile butadiene styrene and polycarbonate filaments). For these same machines, total volatile organic compound ERs (μg/min) ranged from 1.9 × 104 (acrylonitrile butadiene styrene and polycarbonate) to 9.4 × 104 (Ultem). For the material jetting machines, the number-based particle ER was higher when the lid was open (2.3 × 1010 number/min) than when the lid was closed (1.5–5.5 × 109 number/min); total volatile organic compound ERs were similar regardless of the lid position. Low levels of acetone, benzene, toluene, and m,p-xylene were common to both AM processes. Carbonyl compounds were detected; however, none were specifically attributed to the AM processes. Personal exposures to metals (aluminum and iron) and eight volatile organic compounds were all below National Institute for Occupational Safety and Health (NIOSH)-recommended exposure levels.ConclusionIndustrial-scale AM machines using thermoplastics and resins released particles and organic vapors into workplace air. More research is needed to understand factors influencing real-world industrial-scale AM process emissions and exposures.

Experimental study of oil particle emission rate and size distribution during milling

Metalworking fluids (MWFs) used in milling generate oil particles through impaction, action of centrifugal forces and evaporation/condensation mechanisms. The oil particles suspended in the factory...

Emission rates of ultrafine and fine particles generated from human smoking of Chinese cigarettes

The household second hand smoke problem is still severe in China due to the large number of smokers and the prevalence of smoking at home. We selected ten Chinese cigarettes, including seven best-selling products of different brands and three types of products of the same popular brand, to measure the emission rates of ultrafine particles (UFPs: particulate matter with diameter less than 0.1 μm) and fine particles (PM2.5: particulate matter with aerodynamic diameter less than 2.5 μm) with the help of two habitual smokers. The emission rate of UFPs generated from smoking popular Chinese cigarettes was 2.51 ± 0.50 × 1012 #/min or 1.98 ± 0.30 × 1013 #/cigarette, and the emission rate of PM2.5 was 2.25 ± 0.39 mg/min or 17.63 ± 1.56 mg/cigarette. The emission rates of UFPs and PM2.5 from Virginia-type cigarettes were higher than those from blended-type and exotic flavor-type cigarettes of the same brand. The emission rates of UFPs and PM2.5 from Chinese cigarettes were higher than those from Western cigarettes. The measured UFPs and PM2.5 emission rates from human smoking of Chinese cigarettes can be used to assess the population exposure and design control measures in residences.

Is oil temperature a key factor influencing air pollutant emissions from Chinese cooking?

Cooking is an important source of air pollutants in Chinese residences. Cooking emissions are influenced by many factors, among which oil temperature is one of the most influential. In this study, 15 typical Chinese dishes, prepared using oil-based cooking methods (stir-, pan- and deep-frying), were chosen. The experiment was repeated three times with each dish—freshly prepared for each subsequent analysis—considering five key factors, to determine the emission rates of fine particulate matter (PM2.5), ultrafine particles (UFPs), formaldehyde, and total volatile organic compounds (TVOC). The oil temperature and oil consumption were measured. A partial correlation analysis was performed to identify the influence of oil temperature on air pollutant emission rates during Chinese residential cooking. The zero-order correlation coefficients for all air pollutants, excluding UFPs, and partial correlation coefficients for all air pollutants, were not significant, implying that the influence of oil temperature on air pollutant emission rates was not significant, because practical peak oil temperatures (112–177 °C) were mostly below the oil smoke point (107–234 °C).

Prediction of particle deposition around the cabin air supply nozzles of commercial airplanes using measured in-cabin particle emission rates.

Enhanced soiling on the surfaces around air supply nozzles due to particle deposition is frequently observed in commercial airliners. The problem is worsened by severe outdoor air pollution and flight delays in China. The particles in an aircraft cabin originate from both outdoor and in-cabin sources. This study conducted measurements on multiple commercial flights to obtain particle emission rates from in-cabin sources. Additional experiments on a retired MD-82 airplane provided justification of the in-flight measurements. The in-cabin sources emitted more particles during boarding/deplaning than during meal servicing and sitting. The average PM2.5 emission rates were 7.2, 2.6, 1.9, and 1.8 (μg/min per person), respectively, during the boarding/deplaning, sitting on the ground, sitting in the air, and meal servicing. The corresponding PM10 emission rates were 15.4, 6.1, 5.3, and 5.4 (μg/min per person), respectively, for these four periods. The average particle emission rate from in-cabin sources varied seasonally and was the highest in winter. With the measured data, this investigation used a CFD model to predict the accumulation of particles deposited around the nozzles of an airplane, taking into account the flight routes and the outdoor particle concentrations at the airports where the airplanes were parked. For the most polluted airplane in China, the dirty spots/areas around the nozzles inside the airplane became visible after 6months. The method proposed in this study can be used for any commercial airplane to predict the accumulation of particles deposited around the air supply nozzles.

Second-hand aerosol from tobacco and electronic cigarettes: Evaluation of the smoker emission rates and doses and lung cancer risk of passive smokers and vapers

Smoking activities still represent the main, and preventable, cause of lung cancer risk worldwide. For this reason, a number of studies were carried out to deepen and better characterize the emission of cigarette-generated mainstream aerosols in order to perform an a-priori evaluation of the particle doses and related lung cancer risks received by active smokers. On the contrary, a gap of knowledge still exists in evaluating the dose and risk received by passive smokers in indoor private micro-environments (e.g. homes). For this purpose, in the present paper, an experimental campaign was performed to evaluate the exposure to second-hand aerosol from conventional and electronic cigarettes and to estimate the consequent dose received by passive smokers/vapers and the related lung cancer risk.Measurements of exposure levels in terms of particle number, PM10 and black carbon concentrations, as well as particle size distributions, were performed in a naturally ventilated indoor environment during smoking activities of tobacco and electronic cigarettes. The particle emission rates of smokers and vapers, for the different aerosol metrics under investigation, were evaluated. Moreover, for a typical exposure scenario, the dose received by the passive smokers/vapers in a naturally ventilated indoor micro-environment was estimated through a Multiple-Path Particle Dosimetry (MPPD) model able to assess the particle dose received in the different tracts of the respiratory systems. Furthermore, on the basis of scientific literature data about mass fraction of carcinogenic compounds contained in cigarette-emitted particles (i.e. Heavy Metals, Benzo-a-pyrene and nitrosamines) and the estimated doses, the excess life cancer risk (ELCR) for passive smokers/vapers was evaluated. Cumulative respiratory doses for passive smokers were up to 15-fold higher than for passive vapers. The ELCR for second-hand smokers was five orders of magnitude larger than for second-hand vapers.

Aerosol particles (0.3–10 μm) inside an educational workshop−Emission rate and inhaled deposited dose

In this study, we measured the concentrations of accumulation and coarse particles inside an educational workshop (March 31–April 6, 2015), calculated particle emission and losses rates, and estimated inhaled deposited dose. We used an Optical Particle Sizer (TSI OPS 3330) that measures the particle number size distribution (diameter 0.3–10 μm) and we converted that into particle mass size distribution (assuming spherical particles and unit density). We focused on two particle size fractions: 0.3–1 μm (referred as PN0.3−1 and PM0.3−1) and 1–10 μm (referred as PN1−10 and PM1−10). The occupants' activities included coffee brewing, lecturing, tobacco smoking, welding, scrubbing, and sorting/drilling iron. The highest concentrations were observed during welding with PN0.3−1 (PM0.3−1) was ∼1866 cm−3 (55 μg/m3) and PN1−10 (PM1−10) was ∼7 cm−3 (103 μg/m3). The lowest concentrations were observed during coffee brewing and metal turning with PN0.3−1 (PM0.3−1) was ∼22 cm−3 (0.7 μg/m3) and PN1−10 (PM1−10) was ∼0.5 cm−3 (4 μg/m3). The emissions rate of coarse particles was 85–1010 particles/hour × cm3 whereas that for submicron particle in the diameter range 0.3–1 μm was 5.7 × 104–9.3 × 104 particles/hour × cm3 depending on the activity and the ventilation rate. The coarse particles losses rate was 0.35–2.1 h−1 and the ventilation rate was 0.24–2.1 h−1. The alveolar received the majority and particles below 1 μm with a fraction of about 53% of the total inhaled deposited dose whereas the head/throat region received about 18%. This study is important for better understanding the health effects at educational workshops.

Dip coating of air purifier ceramic honeycombs with photocatalytic TiO2 nanoparticles: A case study for occupational exposure

Nanoscale TiO2 (nTiO2) is manufactured in high volumes and is of potential concern in occupational health. Here, we measured workers exposure levels while ceramic honeycombs were dip coated with liquid photoactive nanoparticle suspension and dried with an air blade. The measured nTiO2 concentration levels were used to assess process specific emission rates using a convolution theorem and to calculate inhalation dose rates of deposited nTiO2 particles. Dip coating did not result in detectable release of particles but air blade drying released fine-sized TiO2 and nTiO2 particles. nTiO2 was found in pure nTiO2 agglomerates and as individual particles deposited onto background particles. Total particle emission rates were 420×109min−1, 1.33×109μm2min−1, and 3.5mgmin−1 respirable mass. During a continued repeated process, the average exposure level was 2.5×104cm−3, 30.3μm2cm−3, <116μgm−3 for particulate matter. The TiO2 average exposure level was 4.2μgm−3, which is well below the maximum recommended exposure limit of 300μgm−3 for nTiO2 proposed by the US National Institute for Occupational Safety and Health. During an 8-hour exposure, the observed concentrations would result in a lung deposited surface area of 4.3×10−3cm2g−1 of lung tissue and 13μg of TiO2 to the trachea-bronchi, and alveolar regions. The dose levels were well below the one hundredth of the no observed effect level (NOEL1/100) of 0.11cm2g−1 for granular biodurable particles and a daily no significant risk dose level of 44μgday−1. These emission rates can be used in a mass flow model to predict the impact of process emissions on personal and environmental exposure levels.

A novel approach for the modelling of air quality dynamics in underground railway stations

Abstract Indoor air quality in subterranean train stations is a concern in many places around the globe. However, due to the specificity of each case, numerous parameters of the problem remain unknown, such as the braking discs particle emission rate, the ventilation rate of the station or the complete particle size distribution of the emitted particles. In this study the problem of modelling PM 10 concentration evolution in relation with train traffic is hence addressed with a particle-mass conservation model which parameters are fitted using a genetic algorithm. The parameters of the model allow to reproduce the dynamics and amplitude of four field data sets from the French and Swedish underground contexts and comply with realistic bounds in terms of emissions, deposition and ventilation rate.

An Experimental Study on the Energy Consumption and Emission Profile of Fused Deposition Modeling Process

Additive Manufacturing (AM) is widely considered as an environmentally friendly alternative to traditional processes. However, AM processes are not free of environmental impacts: they consume material and energy while emitting particulates and/or volatile organic compounds. Although there are efforts on characterizing energy consumption and air borne emissions, in depth analysis and understanding are generally lacking when compared with traditional processes, especially machining processes. Using fused deposition modeling (FDM) process as an example, this study explores how operating procedure and printing parameters affect the energy consumption and particulates emissions. Experimental data suggests that particle emission is mainly the result of condensing and agglomerating of semi-volatile organic compounds. The initial emission spike occurs when there is dripping of semi-liquid filament from heated nozzle and/or there is residue left in the nozzle. Printing speed and material flow have effects on particle emission rate but the effect is small. Power profile analysis indicates that print bed heating and temperature maintaining is the leading contributor to energy consumption.

Risk Assessment for Children Exposed to Arsenic on Baseball Fields with Contaminated Fill Material.

Children can be exposed to arsenic through play areas which may have contaminated fill material from historic land use. The objective of the current study was to evaluate the risk to children who play and/or spend time at baseball fields with soils shown to have arsenic above background levels. Arsenic in soils at the study sites located in Miami, FL, USA showed distinct distributions between infield, outfield, and areas adjacent to the fields. Using best estimates of exposure factors for children baseball scenarios, results show that non-cancer risks depend most heavily upon the age of the person and the arsenic exposure level. For extreme exposure scenarios evaluated in this study, children from 1 to 2 years were at highest risk for non-cancer effects (Hazard Quotient, HQ > 2.4), and risks were higher for children exhibiting pica (HQ > 9.7) which shows the importance of testing fill for land use where children may play. At the study sites, concentration levels of arsenic resulted in a range of computed cancer risks that differed by a factor of 10. In these sites, the child’s play position also affected risk. Outfield players, with a lifetime exposure to these arsenic levels, could have 10 times more increased chance of experiencing cancers associated with arsenic (i.e., lung, bladder, skin) in comparison to infielders. The distinct concentration distributions observed between these portions of the baseball fields emphasize the need to delineate contaminated areas in public property where citizens may spend more free time. This study also showed a need for more tools to improve the risk estimates for child play activities. For instance, more refined measurements of exposure factors for intake (e.g., inhalation rates under rigorous play activities, hand to mouth rates), exposure frequency (i.e., time spent in various activities) and other exposure factors (e.g., soil particulate emission rates at baseball play fields) can help pinpoint risk on baseball fields where arsenic levels may be a concern.

Surgical Space Suits Increase Particle and Microbiological Emission Rates in a Simulated Surgical Environment

BackgroundThe role of space suits in the prevention of orthopedic prosthetic joint infection remains unclear. Recent evidence suggests that space suits may in fact contribute to increased infection rates, with bioaerosol emissions from space suits identified as a potential cause. This study aimed to compare the particle and microbiological emission rates (PER and MER) of space suits and standard surgical clothing. MethodsA comparison of emission rates between space suits and standard surgical clothing was performed in a simulated surgical environment during 5 separate experiments. Particle counts were analyzed with 2 separate particle counters capable of detecting particles between 0.1 and 20 μm. An Andersen impactor was used to sample bacteria, with culture counts performed at 24 and 48 hours. ResultsFour experiments consistently showed statistically significant increases in both PER and MER when space suits are used compared with standard surgical clothing. One experiment showed inconsistent results, with a trend toward increases in both PER and MER when space suits are used compared with standard surgical clothing. ConclusionSpace suits cause increased PER and MER compared with standard surgical clothing. This finding provides mechanistic evidence to support the increased prosthetic joint infection rates observed in clinical studies.

Determination of Radionuclide Concentration in Human Teeth in Najaf Governorate, Iraq

Introduction: 238U decays with alpha particles emission into 234Th and the series ends with 206Pb. The unstable nucleus loses the energy with emitting ionizing alpha particles for reaching a stable state. It is undergoing alpha decay with decay energy (4.679 MeV). Alpha particles enter the human and animal bodies through inhalation of air or ingestion of contaminated food and water. This study aimed to perform a radiological analysis on the natural alpha particle emission rates of the human teeth as the biomarkers of radiation exposure and environmental pollution. Materials and Methods: This study was conducted on 68 teeth samples of 27 males and 41 females collected from the hospitals distributed across Najaf governorate, including many districts in Iraq. Alpha particle emission rates were measured using CR-39 nuclear track detector. Results: The mean emission rate of alpha particles in the female teeth was 0.0396±0.0070 mBq cm-2, which was relatively higher than that in the male teeth (0.0390±0.0048 mBq cm-2). Nevertheless, there was no significant difference between the female and male teeth regarding the emission rate of alpha particles. Furthermore, the emission rate of alpha particles in the teeth of the samples taken from Kufa (0.0417±0.0057 mBq cm-2) was higher than those obtained from Najaf (0.0384±0.0053 mBq cm-2). Conclusion: As the findings of this study revealed, Najaf governorate had a lower emission rate of alpha particles as compared to other sites of the worldwide. Therefore, it could be concluded that there is no negative consequence threatening the people’s health in this regard.

Ultrafine Particle Production from the Ozonolysis of Personal Care Products.

Personal care products (PCP) might be a source of ultrafine particle exposure for users owing to the reaction of ozone with terpene ingredients. The near-person emissions associated with PCP may contribute to exposures that would not be properly accounted for with indoor microenvironmental measurements. To better understand this issue, screening experiments were conducted with 91 PCP to detect the occurrence of ultrafine particle production from exposure to common indoor levels of ozone (23 ± 2 ppb). Twelve products generated measurable particle emissions; quantification experiments were performed for these to determine total particle production and peak particle production rate. A high-resolution, small volume reaction chamber was used with a heated sample plate to simulate conditions found in the human thermal plume. Ten of the quantified PCP exhibited total emissions of less than 109 particles, suggesting that they may not be significant sources of total ultrafine particle exposure. Two samples, a tea tree oil-based scalp treatment and a white lavender body lotion, exhibited relatively elevated peak particle emission rates, 6.2 × 107 min-1 and 2.0 × 107 min-1, respectively. The use of such products in the presence of significant ozone levels might materially influence personal exposure to ultrafine particles.

A modeling enterprise for chemistry of indoor environments (CIE).

A modeling enterprise for chemistry of indoor environments (CIE).

Size and mineral composition of airborne particles generated by an ultrasonic humidifier.

This study describes the size distribution and concentration of particles expelled by a portable, 3-L ultrasonic humidifier. The ultrasonic humidifier was filled with waters of varying mineral content and hardness. Aerosol size distributions were measured during 8hours of humidifier operation in a typical bedroom. Humidifiers produced approximately 1.22×1010 -2.50×1010 airborne particles per milliliter of water consumed, resulting in airborne particle concentrations of 3.01-5.91×104 #/cm3 , with modes ranging between 109 and 322nm in diameter. The emission rate of particles varied by water type from 1.02×109 to 2.27×109 #/s. Lower mineral waters produced fewer, smaller particles when compared to higher mineral waters. Chemical analyses of particles collected with a cascade impactor indicated that the minerals in emitted particles had the same relative mineral concentrations as the fill water. Our results demonstrate that ultrasonic humidifiers should be considered a source of inhalation exposure to minerals dissolved in water, and that the magnitude of exposure to inhalable particles will vary with water quality.

Characterization and Control of Nanoparticle Emission during 3D Printing.

This study aimed to evaluate particle emission characteristics and to evaluate several control methods used to reduce particle emissions during three-dimensional (3D) printing. Experiments for particle characterization were conducted to measure particle number concentrations, emission rates, morphology, and chemical compositions under manufacturer-recommended and consistent-temperature conditions with seven different thermoplastic materials in an exposure chamber. Eight different combinations of the different control methods were tested, including an enclosure, an extruder suction fan, an enclosure ventilation fan, and several types of filter media. We classified the thermoplastic materials as high emitter (>1011 #/min), medium emitters (109 #/min -1011 #/min), and low emitters (<109 #/min) based on nanoparticle emissions. The nanoparticle emission rate was at least 1 order of magnitude higher for all seven filaments at the higher consistent extruder temperature than at the lower manufacturer-recommended temperature. Among the eight control methods tested, the enclosure with a high-efficiency particulate air (HEPA) filter had the highest removal effectiveness (99.95%) of nanoparticles. Our recommendations for reducing particle emissions include applying a low temperature, using low-emitting materials, and instituting control measures like using an enclosure around the printer in conjunction with an appropriate filter (e.g., HEPA filter) during 3D printing.

Hawking radiation as tunneling in Schwarzschild anti-de Sitter black hole

The Hawking radiation from a -dimensional Schwarzschild Anti-de Sitter (SAdS) black hole is investigated within rainbow gravity. Based on the method proposed by Kraus, Parikh and Wilczek, the Hawking radiation is considered as a tunneling process across the horizon. The emission rate of massless particles which are tunneling across the quantum-corrected horizon is calculated. Enforcing the energy conservation law leads to a dynamical geometry. Both the dynamical geometry and the quantum effects of space-time yield some corrections to the emission rate. The corrected radiation spectrum is not purely thermal. The emission rate is related to the changes of modified entropy in rainbow gravity and the corrected thermal spectrum may be consistent with an underlying unitary quantum theory. The correlations between emitted particles are also investigated in order to address the recovery of information.

Particle emission rates during electrostatic spray deposition of TiO2 nanoparticle-based photoactive coating

Here, we studied the particle release rate during Electrostatic spray deposition of anatase-(TiO2)-based photoactive coating onto tiles and wallpaper using a commercially available electrostatic spray device. Spraying was performed in a 20.3m3 test chamber while measuring concentrations of 5.6nm to 31μm-size particles and volatile organic compounds (VOC), as well as particle deposition onto room surfaces and on the spray gun user hand. The particle emission and deposition rates were quantified using aerosol mass balance modelling. The geometric mean particle number emission rate was 1.9×1010s−1 and the mean mass emission rate was 381μgs−1. The respirable mass emission-rate was 65% lower than observed for the entire measured size-range. The mass emission rates were linearly scalable (±ca. 20%) to the process duration. The particle deposition rates were up to 15h−1 for <1μm-size and the deposited particles consisted of mainly TiO2, TiO2 mixed with Cl and/or Ag, TiO2 particles coated with carbon, and Ag particles with size ranging from 60nm to ca. 5μm. As expected, no significant VOC emissions were observed as a result of spraying. Finally, we provide recommendations for exposure model parameterization.