Particle-phase Polycyclic Aromatic Hydrocarbons Research Articles

Characteristics and sources of polycyclic aromatic hydrocarbons in dew in urban ecosystems in Northeast China

The concentrations of polycyclic aromatic hydrocarbons (PAHs) in the atmospheres above major cities in Northeast China are relatively high. Dew is an effective way to settle and remove particulate and gaseous matter in the formation process. Notably, 16-PAH concentration dew analysis was conducted in four major cities (Harbin, Changchun, Shenyang and Dalian) from April to November 2023. In the study area, 2–3-ring PAHs dominated in dew in both the dissolved and particle phases, followed by 4-ring and 5–6-ring PAHs. Phe was the most common individual PAH in dew. Because PAHs in wet deposition are closely related to those in the atmosphere, the concentration of PAHs in dew was much lower than that in snow. The proportions of the gaseous-phase scavenging ratio (Wg) to the total scavenging ratio (Wt) in Harbin, Changchun, Shenyang and Dalian increased with increasing temperature, reaching 22.98%, 29.02%, 30.71% and 33.22%, respectively, which indicated that the ability of dew to remove PAHs in the particle phase was greater than that to remove PAHs in the gas phase. The concentration of dissolved-phase PAHs in dew was lower than that of particle-phase PAHs. The total PAH fluxes were 43.25, 33.35, 32.16, and 25.63 ng/m2·d in Harbin, Changchun, Shenyang and Dalian, respectively, decreasing from north to south. The dew amount was much smaller than the rainfall and snow amount (by two orders of magnitude), and the PAH flux in dew was much lower than that in rain and snow. Isomeric ratio assessment coupled with principal component analysis (PCA) indicated that the source of PAHs in dew was a combination of vehicle emissions and biomass and coal combustion. PAHs in dew mainly originated from local sources rather than from long-range atmospheric transport. This study revealed the effects of PAHs in dew on the air quality and the removal of PAHs by dew.

Modeling polycyclic aromatic hydrocarbons (PAHs) concentrations from wildfires in California

In recent years, wildfires in California have increased in frequency and intensity due to climate change and prolonged drought. The air pollutants released by wildfires cause significant health consequences, among which polycyclic aromatic hydrocarbons (PAHs) are particularly toxic. Estimating PAH emissions from wildfires is challenging due to variability in vegetation types. In this study, we estimate PAH emission rates across California at a high resolution, based on laboratory-measured PAH emission rates from 22 different vegetation types and detailed vegetation mapping. By combining these estimates with biomass burning data from the NCAR Fire Inventory, the Community Multiscale Air Quality Modeling System simulates PAH concentrations for the 2017 fire season. The modeling results compare favorably to measurements from three PAH monitoring sites in California. The peak PAH emissions from wildfire events are up to be 80 times higher in the gas phase and 32 times higher in the particle phase compared to a case without fire emissions. The population-weighted PAH concentrations from the fire case (0.053 µg/m3) are 47 % higher compared to a non-fire case (0.036 µg/m3) in the particle phase and 11 % higher in the gas phase (9.82 ppt compared to 8.83 ppt) during the study period. While highly depended on the meteorological condition, the simulated spatial distribution indicates that gas-phase PAHs are less likely to travel long distances from the fire source and are prone to aging into the particle phase during transport. Consequently, populations are more likely to be exposed to particle-phase PAHs during wildfire events. This finding has important implications for understanding the health impacts of wildfire-induced PAH concentrations, as particle-phase PAHs may have different toxicological effects compared to gas-phase PAHs.

Variations of source-specific risks for inhalable particles-bound PAHs during long-term air pollution controls in a Chinese megacity: Impact of gas/particle partitioning

Gas/particle (G/P) partitioning is a determining factor that drives the behavior of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere. To comprehend the variations and impacts of PAHs G/P partitioning on inhalation risks from different sources, atmospheric PAHs in Chengdu were studied from January 2009 to January 2021. Chengdu's air quality demonstrated improvement, with a noticeable decline in PM10 (from 238 to 103 μg m−3), PM10-bound PAHs mass concentrations (from 0.08 to 0.01 μg m−3), as well as PAHs inhalation non-cancer (from 63.5 to 7.1) and cancer risks (from 6.2 × 10−5 to 7.7 × 10−6). Decreasing trends were also observed in the concentrations of organic carbon (OC) and the values of absorptive G/P partitioning coefficient (Kp, OM) from 2009 to 2020, indicating a slight decrease in the PM absorptive capacity. A positive matrix factorization (PMF) model utilized three distinct datasets: PMFpp (particle-phase PAHs only), PMFtot (total PAHs concentrations), and PMFpp/gas (particle-phase in parallel with gas-phase PAHs). PMFpp and PMFpp/gas provide reasonable source apportionment and source-specific risk results. However, daily variations in source contributions of PMFtot were found to be unreasonable. PMFpp/gas and PMFtot could identify a source of low molecular weight PAHs (LPAHs) related to temperature, and a significantly positive correlation between LPAHs and temperature was discovered. Gas/particle partitioning of PAHs showed a notable impact on source-specific risks associated with coal and biomass combustion (CC&BC). The findings contribute to our understanding of the variation in PAHs G/P partitioning and the PM absorptive capacity resulting from effective air pollution control in China. Additionally, they offer prerequisite information for incorporating semi-volatile organic compounds in source apportionment and source-specific risk assessment.

Emission characteristic, spatial distribution, and health risk of polycyclic aromatic compounds (PAHs, NPAHs, and OPAHs) from light-duty gasoline and diesel vehicles based on on-road measurements

Vehicle exhaust is the primary source of polycyclic aromatic compounds (PACs). Real road tests using a portable vehicle measurement system on light-duty gasoline vehicles and light-duty diesel trucks were conducted to investigate gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs), nitro-PAHs (NPAHs), and oxy-PAHs (OPAHs) in vehicle exhaust with different emission standards, fuel types, and altitudes. The results showed that with the tightening of emission standards, the overall emission factors (EFs) of PACs decreased. Compared with China V diesel vehicles, the emissions of PAHs, OPAHs, and NPAHs from China VI diesel vehicles were 75.1 %, 84.4 %, and 61.2 % lower, respectively. With a ∼100 m increase in altitude, the EFs of PAHs, OPAHs, and NPAHs of diesel vehicles increased 1.88, 1.92, and 1.59 times due to incomplete combustion. In addition, the EFs of PAHs and OPAHs in gasoline vehicles were lower than those in diesel vehicles. In contrast, the proportion of PAHs with highly toxic components, such as dibenzo[a,h]anthracene (DahA) and benzo[a]pyrene (BaP), and the EFs of gas-phase NPAHs in gasoline vehicles were higher than those in diesel vehicles. Furthermore, the emissions of 1,8-DNP from diesel vehicles cannot be disregarded. 1,8-DNP was the main gas-phase NPAHs emitted by China VI and China V diesel vehicles, accounting for 49.3 % and 26.0 %, respectively. Moreover, gas-phase PACs contributed more to the EFs than particle-phase PACs, whereas particle-phase PACs have greater toxic effects. Although the EFs of PAHs are more than 100 times those of NPAHs, the toxic equivalent concentrations (TEQBaP) of PAHs in diesel and gasoline vehicles were approximately 6.5 times and 35 times those of NPAHs. The spatial distribution characteristics revealed that PACs emissions were mainly concentrated in urban areas and highways, and the differences in the toxicity of PACs emissions between different cities depended on the proportion of diesel vehicles. The average TEQBaP of PAHs and NPAHs in Haidong, Haibei, Huangnan, Hainan, Guoluo, and Yushu was 8.42 μg/m3 and 0.36 μg/m3, respectively, while those of Xining and Haixi were 0.24–0.29 μg/m3 and 0.09–0.108 μg/m3 higher, respectively. This study provides a comprehensive understanding of the emission characteristics, health risks, and spatial distribution of PACs from diesel and gasoline vehicle PACs in urban areas.

Investigations into the transition to sustainable alternative fuels in a South African underground platinum mine

Adverse environmental impacts associated with the use of fossil fuels and the over-dependence thereon has made energy security and sustainability a critical issue worldwide particularly for key energy intensive economic sectors which are heavily dependent on diesel. We thus investigated the feasibility of a transition to two different alternative fuels namely, rapeseed methyl ester (RME) biodiesel and gas-to-liquid fuel (GTL), in the platinum mining industry in South Africa. Load haul dump vehicles are the most abundant workhorses underground and were the selected vehicles to test alternative fuels at 100% without any engine modification. Potential reduction of harmful unregulated polycyclic aromatic hydrocarbon (PAH) emissions was the focus of the research due to their adverse impacts on the environment, human health and engine operations. Quantitative collection of gas and particle phase PAHs was made possible using portable denuder devices followed by analysis by two-dimensional gas chromatography coupled to time-of-flight mass spectrometry. Results showed that total PAH emissions from a high idling vehicle decreased dramatically when diesel was substituted with both biofuels (total gas phase PAH concentrations of 34; 14 and 9 µg m-3 for diesel, GTL and RME, respectively) and no substantial hinderance on engine performance was reported. This novel sector specific study on unmodified heavy duty working vehicles can potentially translate into a real-world, immediate solution, as not only would the selected biofuels be able to directly replace diesel, but both have high potential of being locally produced in South Africa and assist in the promotion of a circular economy.

Characterization of Gaseous and Particulate Phase Polycyclic Aromatic Hydrocarbons Emitted During Preharvest Burning of Sugar Cane in Different Regions of Kwa-Zulu Natal, South Africa.

Biomass burning is a significant anthropogenic source of air pollution, including the preharvest burning of sugar cane. These burn events result in atmospheric emissions, including semivolatile organic compounds, that may have adverse impacts on air quality and human health on a local, regional, and even a global scale. Gaseous and particulate polycyclic aromatic hydrocarbon (PAH) emissions from various sugar cane burn events in the province of Kwa-Zulu Natal in South Africa were simultaneously sampled using a portable denuder sampling technology, consisting of a quartz fiber filter sandwiched between two polydimethylsiloxane multichannel traps. Total gas and particle phase PAH concentrations ranged from 0.05 to 9.85 µg m-3 per individual burn event, and nine PAHs were quantified. Over 85% of all PAHs were found to exist in the gas phase, with smaller two- and three-ring PAHs, primarily naphthalene, 1-methyl naphthalene, and acenaphthylene, being the most dominant and causing the majority of variance between the burn sites. The PAH profiles differed between the different burn events at different sites, emphasizing the significant influence that the crop variety, prevailing weather conditions, and geographical location has on the type and number of pollutants emitted. The potential carcinogenicity of the PAH exposure was estimated based on toxic equivalency factors that showed varying risk potentials per burn event, with the highest value of 5.97 ng m-3 . Environ Toxicol Chem 2023;42:778-792. © 2023 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.

Emission factors for polycyclic aromatic hydrocarbons from laboratory biomass-burning and their chemical transformations during aging in an oxidation flow reactor

Atmospheric polycyclic aromatic hydrocarbons (PAHs) can be emitted from different combustion sources including domestic biomass burning, internal combustion engines, and biomass burning (BB) in wild, prescribed, and agricultural fires. With climate warming and consequent global increases in frequency and severity of wildfires, BB is a dominant source of PAHs emitted into the atmosphere.In this study, six globally and regionally important and representative fuels (Alaskan peat, Moscow peat, Pskov peat, eucalyptus, Malaysian peat, and Malaysian agricultural peat) were burned under controlled conditions in the combustion chamber facility at the Desert Research Institute (DRI, Reno, NV, USA). Gas- and particle-phase BB emissions were aged in an oxidation flow reactor (OFR) to mimic five to sevendays of atmospheric aging. To sample gas- and particle-phase BB emissions, fresh and OFR-aged biomass-burning aerosols were collected on Teflon-impregnated glass fiber filters (TIGF) in tandem with XAD resin media for organic carbon speciation. The objectives of this study were to i) quantify the emission factors for 113 PAHs emitted from the combustion of the six selected fuels, ii) characterize the distribution of PAH compounds between gas and particle phases for these fuels, iii) identify the changes in PAHs during OFR-aging, and iv) evaluate toxicity potential with characterized compounds.We found that combustion emissions of gas-phase PAHs were more abundant (>80 % by mass) than particle-phase PAHs, for emissions from all combusted fuels. The mass fraction of substituted napthalenes in Moscow peat and Malaysian peat emissions were ∼70 % & 84 %, respectively, whereas in Eucalyptus the same fraction was <50 %, which indicates that these substituted compounds can be used as tracers for peat emissions. Mass concentrations of gas- and particle-phase PAHs were reduced by ∼70 % after OFR oxidation. However, the understanding of the fate of PAHs during OFR oxidation requires further investigations. Our results also indicate that the PAH toxicity of BB samples would be underestimated by 10–100 times if only the BaPeq for the 16 US EPA priority PAHs in the particle phase are included.

Gas Particle Partitioning of PAHs Emissions from Typical Solid Fuel Combustions as Well as Their Health Risk Assessment in Rural Guanzhong Plain, China.

Air pollutants from the incomplete combustion of rural solid fuels are seriously harmful to both air quality and human health. To quantify the health effects of different fuel-stove combinations, gas and particle partitioning of twenty-nine species of polycyclic aromatic hydrocarbons (PAHs) emitted from seven fuel-stove combinations were examined in this study, and the benzo (a) pyrene toxicity equivalent (BaPeq) and cancer risks were estimated accordingly. The results showed that the gas phase PAHs (accounting for 68-78% of the total PAHs) had higher emission factors (EFs) than particulate ones. For all combustion combinations, pPAHs accounted for the highest proportion (84.5% to 99.3%) in both the gas and particulate phases, followed by aPAHs (0.63-14.7%), while the proportions of nPAHs and oPAHs were much lower (2-4 orders of magnitude) than pPAHs. For BaPeq, particulate phase PAHs dominated the BaPeq rather than gas ones, which may be due to the greater abundance of 5-ring particle PAHs. Gas and particle pPAHs were both predominant in the BaPeq, with proportions of 95.2-98.6% for all combustion combinations. Cancer risk results showed a descending order of bituminous coal combustion (0.003-0.05), biomass burning (0.002-0.01), and clean briquette coal combustion (10-5-0.001), indicating that local residents caused a severe health threat by solid fuel combustion (the threshold: 10-4). The results also highlighted that clean briquette coal could reduce cancer risks by 1-2 orders of magnitude compared to bulk coal and biomass. For oPAH, BcdPQ (6H-benzo(c,d)pyrene-6-one) had the highest cancer risk, ranging from 4.83 × 10-5 to 2.45 × 10-4, which were even higher than the total of aPAHs and nPAHs. The dramatically high toxicity and cancer risk of PAHs from solid fuel combustion strengthened the necessity and urgency of clean heating innovation in Guanzhong Plain and in similar places.

Physicochemical characteristics of polycyclic aromatic hydrocarbons in condensable particulate matter from coal-fired power plants: A laboratory simulation

The objective of this study was to examine the physicochemical characteristics of polycyclic aromatic hydrocarbons (PAHs) in condensable particulate matter (CPM) during fast condensation (within several seconds). The concentration of PAHs increased as the condensation temperature decreased, indicating that the conversion of gaseous PAHs to CPM would be enhanced at low temperatures. PAH concentrations increased in relation to the number of rings in the fragment, with the high-ring (4-,5- and 6-ring) PAHs accounting for 89.70–92.30% and 99.78–99.80% of the total concentration and total toxic equivalent of PAHs. In addition, particulate-phase PAHs (0.1–1.0 μm), developed through the synergistic effect of PAHs and fine particles, were difficult to collect by fast condensation. Inorganic fine particles could be formed when ammonia-rich conditions prevail, reducing PAH condensation further. Furthermore, CPM was morphologically and chemically characterized. During the experiment, fine and well-aggregated CPMs were detected on the membrane, and the diameter of CPMs was further enhanced by the addition of 16 PAHs. Most of the C element was collected in the rinse fluid, thus indicating that PAHs in CPM were collected through condensation. Based on these findings, basic guidelines can be provided for the control of PAHs in flue gas from coal-fired power plants.

Compositional and seasonal differences of gas and particle phase polycyclic aromatic hydrocarbons (PAHs) over the southern Baltic Sea coast

In this study, 16 USEPA-prioritized PAHs in gas- and particle-phase (PAHg+p), associated chemical and meteorological parameters, and backward trajectory simulations were explored in a coastal city in Poland, between April 2019 and May 2020. This study reports several important aspects of PAHg+p, i.e. variation, composition, distribution profiles, impact of weather conditions, and correlation analysis between target PAH compounds and influencing inorganic gaseous pollutants. Specifically, higher and more variable concentrations of total PAHg+p (mean ± SD, ng m−3) were observed during winter (36.38 ± 24.19) compared to autumn (22.3 ± 17.44), summer (21.52 ± 13.30) and spring (19.90 ± 13.13). A distribution profile of parent PAHg+p was as follows: 3-ring > 4-ring > 2-ring > 5-ring > 6-ring, although their relative contribution to the total PAHs showed statistically significant differences between seasons (p < 0.05). Precipitation-driven loss of ΣPAHg+p was lower in the warm period than in the cold one, reflecting higher PAH concentrations in winter. A seasonal model-based analysis of incremental lifetime cancer risk showed a higher potential cancer risk for children than those for adult females and males. The adverse health impacts associated with PAH exposure via inhalation route indicate the need for implementation of pollution-control policies in this region.

Determination of 16 particle-phase polycyclic aromatic hydrocarbons in herbal incense by ultrasonic extraction-gas chromatography-mass spectrometry and analysis of emission characteristics

Polycyclic aromatic hydrocarbons (PAHs) have attracted global attention because they are carcinogens and mutagenic to humans. To date, more than 200 PAHs have been found. The United States Environmental Protection Agency (USEPA) has designated 16 PAH species as priority control pollutants due to their highly toxic substances. Herbal incense is frequently used in daily life. As a result, it is critical to investigate its impact on human health and environmental safety. However, research on particle-phase PAHs is very limited and inapplicable. The current research focuses mainly on bamboo incense, which has a simpler formula than herbal incense.In this study, the emission factor and emission characteristics of particle-phase PAHs from herbal incense were described. A method combining ultrasonic and gas chromatography-mass spectrometry (GC-MS) was developed for the simultaneous determination of 16 particle-phase PAHs of herbal incense. The settings for extraction solvent, ultrasonic time, and instrument analysis conditions were optimized. In the test chamber, samples were collected by burning 0.8 g of herbal incense. After combustion, PAHs adsorbing on the particles of herbal incense were collected on a quartz filter. The whole filter sample was sliced and extracted with n-hexane-dichloromethane (1∶1, v/v). A rotary evaporator was used to concentrate the extract. GC-MS was used to analyze the prepared sample. The internal standard method was used to perform quantitative analysis on the target compounds. The linearities of the 16 target PAHs were good between mass concentrations of 0.1-5.0 μg/mL, with correlation coefficients greater than 0.998. The method detection limits (MDLs) of the 16 PAHs ranged from 0.4 to 3.8 ng/g. The 0.625 μg/g and 1.25 μg/g spiked recoveries ranged from 77.4% to 99.5% and 82.0% to 101.3%, respectively. The relative standard deviations (RSDs) of the 16 PAHs were ranged from 0.7% to 7.2% (n=6). The emission factors of particle-phase PAHs from five different kinds of herbal incense ranged from 4.60 to 11.89 μg/g. The highest concentration of phenanthrene (Phe) was found in 16 particle-phase individual PAHs of herbal incense. Fluoranthene (Flu), pyrene (Pyr), chrysene (Chr) and anthracene (Ant) concentration were ranked after Phe. The sum of these five proportions was 73.00%-89.97%. The proportion of Phe in herbal incense particle-phase PAHs was significantly higher than that of other indoor combustion sources. As a result, Phe could be used to identify individual PAHs in the particle-phase of herbal incense. The particle-phase PAHs were mainly distributed on the 3-ring and 4-ring, with a sum of 83.84% to 96.31% on the 3-ring and 4-ring. The proportion of high-molecular weight PAHs in the samples ranged from 44.25% to 63.31%. The proportion of low-molecular weight PAHs in the samples ranged from 36.69% to 55.75%. The incense source could be distinguished from other indoor combustion sources by its distinctive Phe/Flu ratio. The established method has high sensitivity, simple operation, and requires fewer samples. This method is suitable for rapidly detecting PAHs in burning incense. At the same time, it provides scientific data for further studies on the distribution and health effects of particle-phase PAHs of herbal incense.

Evaluation of Mass Spectrometric Methods for Screening Polycyclic Aromatic Hydrocarbons in the Particulate Phase of Wildfire/Biomass Smoke.

Polycyclic aromatic hydrocarbons (PAHs) are a class of compounds containing multiple aromatic rings formed during incomplete combustion. Since many of them are known mutagens and carcinogens, PAHs found in the particulate matter (PM) from the wildfire smoke may pose significant health risks to the wildland firefighters. It is pivotal to determine the levels of PAHs in the PM to evaluate the health effects of their inhalation exposure. However, the determination of PAHs using the conventional chromatographic approaches is often time-consuming and laborious. Herein, we describe a novel method for screening nonpolar and polar PAHs in the PM of smoke by direct analysis in real-time mass spectrometry (DART-MS). PM2.5 and PM10 samples were collected on the quartz filters with a sampling system consisting of a cascade impactor with a portable sampling pump. Various indoor and outdoor experiments from biomass burns were conducted to evaluate the PM sampling systems. PAHs were analyzed by DART-MS and gas chromatography-mass spectrometry (GC-MS) methods. The PM samples were collected in California during the wildfire season of fall 2020, and significant levels of multiple nonpolar PAHs and polar PAHs were detected. Overall, the DART-MS method has shown promising ability for high-throughput screening of PAHs in the PM of smoke. Further studies are currently under way to apply this method to study the particulate phase PAH exposures of wildland firefighters during their firefighting activities.

Effects of fuel injection system and exhaust gas catalytic treatments on PAH emissions from motorcycles.

The motorcycles are unignorable near-ground pollutant emission sources that increase the human exposure in the dense area. However, the information of the polycyclic aromatic hydrocarbons (PAHs) emissions under different scenarios of engine and emission control for motorcycle is limited. This study focused on the PAH emissions from two fuel-injection types of motorcycles, including the premixed fuel-injection (PFi) with carburetor and electronic fuel-injection (EFi). Specifically, the effects of throttle opening (TO), secondary air system (SAS), oxygen sensor (OS), oxidation catalytic converter (OCC), and three-way catalytic converter (TWC) on PAH emissions are investigated. Results show that the PAH emission concentrations increase 227-727%, 351-492%, and 155-408% by the increasing TO ratio, unworking SAS, and OS units in both motorcycles. For the PFi engine, the OCC unit is found to be more effective in PAH control (31-89%) than the SAS system (72-80%), especially under low TO operation. For the EFi engine which dominates the motorcycle market recently, the oxygen sensor for more accurate combustion control shows a better PAH reduction (36-76%) than TWC system (21-66%). The ultra-fine particulate phase PAHs, which is hardly removed by catalyst, needs to be further considered. Moreover, the total PAH emission level of the EFi engine is still about ten times higher than that of the PFi. By the annual emission calculation for three densely populated countries, the recent evolution significantly reduces the annual hydrocarbon (HC), carbon monoxide (CO), and nitrogen oxide (NOx) emissions but have unignorable PAH emissions. These emissions continuously affect the human health in the near-ground urban air and need to be considered in the next generation of motorcycle design.

Organic pollutant exposure and health effects of cooking emissions on kitchen staff in food services.

This study was conducted to determine the exposure and health risk to cooking fumes of a total of 88 volunteer kitchen staff aged between 18 and 65 years working in five different kitchens in Ankara. Gas- and particle-phase polycyclic aromatic hydrocarbons (PAHs), and volatile organic compound (VOCs) concentrations were evaluated in the indoor air of 5 kitchens. Serum malondialdehyde (MDA) and superoxide dismutase (SOD) levels were analyzed to determine the oxidative damage as a result of the exposure to cooking fumes among the cooks and waiters. Significant positive relationships were found between serum MDA levels of the hot kitchen workers and indoor chrysene (Chr), indeno(1,2,3-c,d)pyrene (Ind), and total VOC levels. Although the carcinogenic risks estimated for the exposed population were between the acceptable/tolerable levels, the hazard quotient (HQ) estimated for the exposure to indoor benzene exceeded the safe level. The results of the study revealed that exposure to organic pollutants in indoor air may be a risk factor for the development of oxidative stress, especially in hot kitchen workers. The importance of efficient ventilation in the kitchen has been pointed out to reduce health risks caused by cooking fumes.

Effects of hydrogenated vegetable oil (HVO) and HVO/biodiesel blends on the physicochemical and toxicological properties of emissions from an off-road heavy-duty diesel engine

In this study, the regulated emissions, gaseous toxics, and the physical, chemical, and toxicological properties of particulate matter (PM) emissions from a legacy off-road diesel engine operated on hydrogenated vegetable oil (HVO) and HVO blends with biodiesel were investigated. This is one of the very few studies currently available examining the emissions and potential health effects of HVO and its blends with biodiesel from diesel engines. Extended testing was conducted over the nonroad transient cycle (NRTC) and the 5-mode D2 ISO 8718 cycle. Nitrogen oxide (NOx) emissions showed statistically significant reductions for HVO compared to diesel, whereas the biodiesel blends statistically significant increases in NOx emissions. PM and solid particle number reductions with pure HVO and the biodiesel blends were also observed. Low-molecular weight polycyclic aromatic hydrocarbons (PAHs) were the dominant species in the exhaust for all fuels, with pure HVO and the biodiesel blends showing lower concentrations of these pollutants compared to diesel fuel. Our results showed that the oxidative stress and cytotoxicity in PM emissions decreased with the use of biofuels. Notable correlations were observed between PM emissions and oxidative stress and cytotoxicity, especially elemental carbon and particle-phase PAH emissions.

Assessment of the temporal variability and health risk of atmospheric particle-phase polycyclic aromatic hydrocarbons in a northeastern city in China.

In this study, we examined the sources and temporal variability of 16 polycyclic aromatic hydrocarbons (PAHs) found in fine particulate matter (PM2.5) in a typical industrial city in northern China. We also evaluated the incremental lifetime cancer risk (ILCR) from the inhalation of these PAHs. Atmospheric PM2.5 samples were collected for 7 consecutive days each month from 2014 to 2019, and the 16 PAHs were measured using multiplex gas chromatography-tandem mass spectrometry. The carcinogenic risk of PAH exposure was assessed using the inhalation unit risk (IUR) and cancer slope factor (CSF) methods. The annual average concentrations of PM2.5 for each year from 2014 to 2019 were 102.87±55.25, 86.92±60.43, 69.17±37.74, 58.20±59.15, 56.01±34.52, and 52.54±58.15 µg m-3, and the annual average ΣPAH concentrations were 56.03±81.09, 47.99±79.30, 40.41±57.31, 33.57±51.79, 43.23±74.80, and 25.20±50.91 ng m-3, respectively. Source identification, using diagnostic ratio analysis, indicated that the major PAH sources were coal/biomass combustion, fuel combustion, and traffic emissions. A health risk assessment showed that the ILCR from PAH inhalation decreased throughout the study period and varied with age. The IUR and CSF methods both showed that the adult ILCR exceeded 1.0×10-6. These findings demonstrate the importance of addressing the carcinogenic risk of PM2.5-bound PAHs, particularly in adults.

Gas and particle phase polycyclic aromatic hydrocarbon emission factors from a diesel vehicle engine: Effect of operating modes in a developing country context

Airborne polycyclic aromatic hydrocarbons (PAHs) arising from diesel exhaust emissions are of concern due to their significant human health and environmental impacts. Engine dynamometer experiments with a light duty diesel engine were conducted to measure PAH emissions representative of developing country conditions, and thereby determine emission factors at two different engine operating modes that are representative of idling and severe real-world conditions, respectively. We employed a portable denuder device for the simultaneous sampling of gaseous and particulate PAH emissions, the components of which were subsequently individually thermally desorbed and analysed by two-dimensional gas chromatography with time-of-flight mass spectrometric detection (TD-GCxGC-ToF-MS). Results indicated that PAH emission factors differed significantly for the different modes of engine operation with the highest emission factor being for idle mode with a total PAH emission factor of 1181.14 μg/kg. Under real-world conditions, it is expected that further variance in emission factors will be introduced as a result of brake and tyre wear, different engine technologies, engine age and maintenance, as well as fuel quality and measurement methods. • A portable denuder sampled gas and particles phase PAHs simultaneously. • Emission factors differ significantly for different engine operation modes. • Idle mode showed higher emission factors than maximum power mode. • PAHs in the exhaust emissions were predominantly found in the gas phase.

Features of Particle-Phase Pahs from Traffic Emissions Using Tunnel Measurement and Urban Roadside Observation in China

Features of Particle-Phase Pahs from Traffic Emissions Using Tunnel Measurement and Urban Roadside Observation in China

On-site measured emission factors of polycyclic aromatic hydrocarbons for different types of marine vessels

A portable emission sampling system was used to perform on-site measurements of the emission factors (EFs; quantities of pollutants emitted per unit of energy consumed) of 29 polycyclic aromatic hydrocarbons (PAHs) for five types of marine vessels using light diesel in Hainan Province, China. Both gaseous- and particulate-phase PAHs from vessel emissions were sampled and measured using gas chromatography coupled with mass spectrometry (GC-MS), and the PAH EFs were calculated based on the carbon mass balance method. The average EFs of gaseous- and particulate-phase PAHs were 6.2 ± 7.8 and 17 ± 26 mg/kg, with naphthalene (NAP) and phenanthrene (PHE) dominating the gaseous- and particulate-phase PAH emissions, respectively. Among the five types of vessels, the EFs for small fishing boats were significantly higher than those for other types of vessels, and the lowest EFs were found for tug boats. Composition profiles and typical isomer ratios of PAHs were calculated for five types of vessels. Particulate-phase PAHs accounted for 63 ± 16% of the total emissions of 29 PAH species, and the particulate/gaseous-phase partitioning of PAHs was dominated by organic carbon (OC) absorption rather than black carbon (BC) adsorption. Emission factors of PAHs under different activity conditions were measured and calculated, and relatively higher EFs were found in the maneuvering mode for medium fishing boats and in the operating mode for engineering vessels. No significant differences were found among the PAH composition profiles under different activity conditions.

Characteristics of Atmospheric Particle-bound Polycyclic Aromatic Compounds over the Himalayan Middle Hills: Implications for Sources and Health Risk Assessment

This study was conducted in the Central Himalayan middle hills to understand the nature of polycyclic aromatic hydrocarbons (PAHs) embedded in aerosol particles, their sources and human health risk assessments. The level of sum of 15 particle-phase PAHs was between 9 and 335 ng/m3, with an average concentration of 73±66 ng/m3. There were strong seasonal differences in total suspended particles (TSP) and particle-bound PAH concentrations with higher concentrations in winter, followed by pre-monsoon and lowest in monsoon. The main contributor to the suspended particles was 5-ring PAHs (32%), followed by 4-ring (29%), 6-ring (28%), and 3-ring PAHs (11%). Conversely, the gas-phase PAHs showed that 3-ring PAHs contributed utmost to the total particles. The molecular ratios and principal component analysis indicated that both petrogenic and pyrogenic sources, particularly fossil fuel combustion, biomass combustion, and car exhausts, were the major sources of PAHs. The overall average Benzo (a)pyrene equivalent concentration of particulate PAHs was 11.71 ng/m3, which substantially exceeded the WHO guideline (1 ng/m3), and indicated the potential health risks for local residents. The average lifetime inhalation cancer risk (ILCR) estimates associated with carcinogenic PAHs was 8.78×10−6 for adults, suggesting the possible cancer risk and 2.47×10−5 for children, signifying extreme carcinogenic effects of PAHs on children’s health. Therefore, strict measures should be taken to reduce PAHs emissions in the region.