Particle-bound Polycyclic Aromatic Hydrocarbons Research Articles

Risks and sources of atmospheric particulate-bound polycyclic aromatic hydrocarbons (AP-PAHs) in seven regions of China: A review

Many studies have shown that atmospheric particulate-bound polycyclic aromatic hydrocarbons (AP-PAHs) pose carcinogenic and noncarcinogenic risks to human health. However, few studies have investigated the health risks of AP-PAHs across regional or national cities. Therefore, in this literature review, >6971 individual atmospheric samples from 89 cities in seven regions of China were obtained. The PAH contents in these samples were measured in accordance with national standards (HJ 784, 2016). AP-PAH contents (0.5–1.2 × 103 ng/m3) significantly increased in Chinese cities during 2002–2017. The contamination levels based on toxic equivalent quantities (0.6–1.4 × 102 ng/m3) were lower in the four southern regions than in the three northern regions. The health risks associated with AP-PAH exposure in different age group followed the following order: infants < kindergarten students < primary school students < middle school students < adults. This study revealed that AP-PAHs pose potential ecological risks and have adverse biological effects, and the mean effect range median quotient in 73 cities (82.0% of 89 cities) indicated moderate or high risk. Clustering analysis revealed that the primary sources of AP-PAHs are coal, petroleum, and biomass combustion. These results can be used to achieve AP-PAH pollution control in Chinese cities and worldwide.

Source apportionment of particle-bound polycyclic aromatic hydrocarbons (PAHs), oxygenated PAHs (OPAHs), and their associated long-term health risks in a major European city

Many studies have drawn attention to the associations of oxygenated polycyclic aromatic hydrocarbons (OPAHs) with harmful health effects, advocating for their systematic monitoring alongside simple PAHs to better understand the aerosol carcinogenic potential in urban areas. To address this need, this study conducted an extensive PM2.5 sampling campaign in Athens, Greece, at the Thissio Supersite of the National Observatory of Athens, from December 2018 to July 2021, aiming to characterize the levels and variability of polycyclic aromatic compounds (PACs), perform source apportionment, and assess health risk. Cumulative OPAH concentrations (Σ-OPAHs) were in the same range as Σ-PAHs (annual average 4.2 and 5.6 ng m−3, respectively). They exhibited a common seasonal profile with enhanced levels during the heating seasons, primarily attributed to residential wood burning (RWB). The episodic impact of biomass burning was also observed during a peri-urban wildfire event in May 2021, when PAH and OPAH concentrations increased by a factor of three compared to the monthly average. The study period also included the winter 2020–2021 COVID-19 lockdown, during which PAH and OPAH levels decreased by >50 % compared to past winters. Positive matrix factorization (PMF) source apportionment, based on a carbonaceous aerosol speciation dataset, identified PAC sources related to RWB, local traffic (gasoline vehicles) and urban traffic (including diesel emissions), as well as an impact of regional organic aerosol. Despite its seasonal character, RWB accounted for nearly half of Σ-PAH and over two-thirds of Σ-OPAH concentrations. Using the estimated source profiles and contributions, the source-specific carcinogenic potency of the studied PACs was calculated, revealing that almost 50 % was related to RWB. These findings underscore the urgent need to regulate domestic biomass burning at a European level, which can provide concrete benefits for improving urban air quality, towards the new stricter EU standards, and reducing long-term health effects.

Source Profile Analysis, Source Apportionment, and Potential Health Risk of Ambient Particle-Bound Polycyclic Aromatic Hydrocarbons in Areas of Specific Interest

Ambient particulate matter (PM10) and its chemical composition in polycyclic aromatic hydrocarbons (PAHs) were studied in areas of specific interest, between September 2015 and July 2016. The principal aim of this study was to assess the different PAH source profiles in each area, as well as their potential health risk. In particular, the studied areas were (a) the semiurban industrialized zone of the Municipality of Peloponnese (Meligalas, Messini) of Messinia prefecture, due to the intensive olive-productive activity in the extensive area, (b) the industrialized zone of Oinofyta in Voiotia prefecture, and (c) the urban/traffic center of Athens (Aristotelous). Intense spatial and seasonal variations in PAH levels were observed among the study areas collectively, but also for each one individually. During the winter period, the total PAHs average concentration was 11.45 and 9.84 ng/m3 at Meligalas–Skala (S1, S2 stations), 8.84 ng/m3 at Messini (S3 station), and 6.30 ng/m3 at the center of Athens (Aristotelous). During the summer campaign, the corresponding levels were 0.99, 1.20, and 0.70 ng/m3 (S1, S2, and S3 stations), and 5.84 ng/m3 (Aristotelous), respectively. The highest potential cancer risk of the PAHs mixture was estimated based on winter season measurements taken at the Municipality of Peloponnese. In order to determine PAH sources, two different source apportionment techniques were applied, i.e., diagnostic ratios (DRs) and the positive matrix factorization (PMF) model.

Comparison of high mileage LPG cars in different technical condition in Czechia: Particle-bound PAHs

Liquefied petroleum gas (LPG) is represented in the literature as a transport fuel with lower regulated and non-regulated emissions compared to petrol. For the purpose of this paper, real-world emissions measurements were performed on a random sample of four commonly operated passenger vehicles with higher mileage (over 200 thousand km) and on a new one. The aim is to compare the emission factors of particle-bound polycyclic aromatic hydrocarbons (PAHs) in dual-fuelled passenger cars running on LPG and petrol, or rather to compare the emission factors of the two fuel types. PAH concentrations are determined by gas chromatography based on the analysis of particles captured on a filter during isokinetic sampling of the exhaust gas during driving in real traffic. In terms of the sum of the 8 most hazardous PAHs analysed, LPG fuelling reduced the total (summary) emission factor of only two of the vehicles analysed, by 22% and 26% respectively compared to petrol. For the remaining vehicles, there was an increase in the total emission factor ranging from 4.4 to 68.8%. The results show that in terms of particle-bound PAHs, the benefit of LPG fuel in terms of vehicle emissions may not be so clear-cut in real-world tests and it depends very much on whether a suitable propulsion system is fitted to the vehicle, how it is set up and how the vehicle is serviced (i.e. the vehicle overall condition).

Pollution characteristics, source apportionment and absorption spectra of size-resolved PAHs in atmospheric particles in a cold megacity of China

Polycyclic aromatic hydrocarbons (PAHs) have the capability for solar radiation absorption related to climate forcing. Herein, pollution characteristics and absorption spectra of size-resolved PAHs in atmospheric particles in a cold megacity were comprehensively investigated. The mean concentrations of Σ18PAHs in all the 11 particle size ranges were 3.95 ± 4.77 × 104 pg/m3 and 2.17 ± 1.54 × 103 pg/m3 in heating period (HP) and non-heating period (NHP), respectively. Except for most PAHs with 2 and 3 benzene rings in NHP, most other PAHs showed a unimodal distribution pattern with the peak at 0.56–1.0 µm in both periods, which was caused by PAH emission sources. The PAH-related climate forcing was mainly caused by the solar radiation absorptions at ∼325 (∼330) nm and ∼365 nm. In general, the absorption intensities were higher in HP than NHP. The absorption intensity in the particle size range of 0.56–1.0 µm was the highest, and benzo[e]pyrene was the dominant contributor. In colder periods in HP, higher PAH concentrations caused more intensive PAH-related climate forcing. This study provided new insights for pollution characteristics and absorption spectra of size-resolved PAHs in atmospheric particles, which will be useful for better understanding PAH-related climate forcing.

Spatiotemporal Gradients of PAH Concentrations in Greek Cities and Associated Exposure Impacts.

To study the spatiotemporal variability of particle-bound polycyclic aromatic hydrocarbons (PAHs) and assess their carcinogenic potential in six contrasting urban environments in Greece, a total of 305 filter samples were collected and analyzed. Sampling sites included a variety of urban background, traffic (Athens, Ioannina and Heraklion), rural (Xanthi) and near-port locations (Piraeus and Volos). When considering the sum of 16 U.S. EPA priority PAHs, as well as that of the six EU-proposed members, average concentrations observed across locations during summer varied moderately (0.4-2.2 ng m-3) and independently of the population of each site, with the highest values observed in the areas of Piraeus and Volos that are affected by port and industrial activities. Winter levels were significantly higher and more spatially variable compared to summer, with the seasonal enhancement ranging from 7 times in Piraeus to 98 times in Ioannina, indicating the large impact of PAH emissions from residential wood burning. Regarding benzo(a)pyrene (BaP), an IARC Group 1 carcinogen and the only EU-regulated PAH, the winter/summer ratios were 24-33 in Athens, Volos, Heraklion and Xanthi; 60 in Piraeus; and 480 in Ioannina, which is afflicted by severe wood-burning pollution events. An excellent correlation was observed between organic carbon (OC) and benzo(a)pyrene (BaP) during the cold period at all urban sites (r2 > 0.8) with stable BaP/OC slopes (0.09-0.14 × 10-3), highlighting the potential use of OC as a proxy for the estimation of BaP in winter conditions. The identified spatiotemporal contrasts, which were explored for the first time for PAHs at such a scale in the Eastern Mediterranean, provide important insights into sources and controlling atmospheric conditions and reveal large deviations in exposure risks among cities that raise the issue of environmental injustice on a national level.

Size distribution of airborne particle-bound polycyclic aromatic hydrocarbons during rice straw open burning in Hanoi, Vietnam

This study dealt with size distribution of airborne particle-bound polycyclic aromatic hydrocarbons (PAHs) during rice straw open burning (RSOB) and non-RSOB period in Hanoi. Two sampling campaigns for PAHs associated with airborne particles of six different sizes (PM0.1, PM0.1-0.5, PM0.5-1, PM1.0-2.5, PM2.5-10, PM> 10) were conducted at three sampling sites in Hanoi during 2018–2020. The average concentrations of total particle-bound PAHs were higher during RSOB period (11.7 ± 5.3 ng m−3) than during non-RSOB period (10.1 ± 5.4 ng m−3), and concentrations were significantly higher at the near-RSOB site (11.0 ± 4.9 ng m−3) than at the far-RSOB site (7.1 ± 3.4 ng m−3). Of the various PAHs, the average concentration of benz[a]anthracene (BaA) and benzo[a]pyrene (BaP) bound to PM0.1 and PM1-2.5 exhibited the greatest significant difference in between the near- and the far-RSOB site. The size distributions of total PAHs were unimodal with the maximum concentration in accumulation mode at all sampling locations. The four-ring PAHs shifted to slightly larger particles during the RSOB period (1.34–1.5 μm) compared to the non-RSOB period (0.87 μm) or with the distant site (1 μm). The concentrations of 5- and 6-ring PAHs remained stable in smaller particles, peaking at 0.8 μm. Diagnostic ratios implied biomass burning contributes to PAHs emissions in all sampling sites, while vehicular emission are the significant emission source in the far-RSOB site. This result provides a comprehensive understanding of the size distribution of particle-bound PAHs in the air during RSOB, and useful information for the intergrated air quality management in RSOB regions.

Assessment of air pollution emitted during cooking using biomass and cleaner fuels in the Shiselweni region of Eswatini (Swaziland)

In Eswatini, 62.3% of households still rely on solid fuel for cooking, especially wood (61.8%). Smoke emissions during biomass burning remain the primary source of indoor air pollution, comprising pollutants detrimental to health. This study provides a quantitative exposure assessment of fuels used in the Shiselweni region with the objectives of monitoring the carbon monoxide (CO) and carbon dioxide (CO2) concentrations during cooking events and evaluating cancer and noncancer risks due to exposure to particulate-bound polycyclic aromatic hydrocarbons (PAHs) during cooking events among cooking personnel in households that cook indoors by burning biomass. Real-time CO, CO2, and particulate matter (PM) monitoring was performed in seventeen kitchens during cooking events across the Shiselweni region using different cooking methods: biomass in open fires and stoves, liquefied petroleum gas (LPG), and electric stoves. PM2.5, PM10, and CO exceeded indoor exposure guidelines for biomass fuel-related homesteads. Particulate PAH intake concentrations were evaluated, and biomass fuel users exhibited high cancer risks and low embryo survival chances due to particulate PAH exposure. The average total cost of reducing the incremental lifetime cancer risk (ILCR) and hazard quotient (HQ) to acceptable levels was lower when shifting from biomass to LPG stoves than when shifting to electric stoves.Graphical abstract

Toxicity of particles derived from combustion of Ethiopian traditional biomass fuels in human bronchial and macrophage-like cells

The combustion of traditional fuels in low-income countries, including those in sub-Saharan Africa, leads to extensive indoor particle exposure. Yet, the related health consequences in this context are understudied. This study aimed to evaluate the in vitro toxicity of combustion-derived particles relevant for Sub-Saharan household environments. Particles (< 2.5 µm) were collected using a high-volume sampler during combustion of traditional Ethiopian biomass fuels: cow dung, eucalyptus wood and eucalyptus charcoal. Diesel exhaust particles (DEP, NIST 2975) served as reference particles. The highest levels of particle-bound polycyclic aromatic hydrocarbons (PAHs) were found in wood (3219 ng/mg), followed by dung (618 ng/mg), charcoal (136 ng/mg) and DEP (118 ng/mg) (GC–MS). BEAS-2B bronchial epithelial cells and THP-1 derived macrophages were exposed to particle suspensions (1–150 µg/mL) for 24 h. All particles induced concentration-dependent genotoxicity (comet assay) but no pro-inflammatory cytokine release in epithelial cells, whereas dung and wood particles also induced concentration-dependent cytotoxicity (Alamar Blue). Only wood particles induced concentration-dependent cytotoxicity and genotoxicity in macrophage-like cells, while dung particles were unique at increasing secretion of pro-inflammatory cytokines (IL-6, IL-8, TNF-α). In summary, particles derived from combustion of less energy dense fuels like dung and wood had a higher PAH content and were more cytotoxic in epithelial cells. In addition, the least energy dense and cheapest fuel, dung, also induced pro-inflammatory effects in macrophage-like cells. These findings highlight the influence of fuel type on the toxic profile of the emitted particles and warrant further research to understand and mitigate health effects of indoor air pollution.

Traffic and Industrial Contributions of Particle-Bound PAHs during an Air Pollution Event in the Metropolitan Area of Medellin-Colombia: Inhalation Intake Risk during Pregnancy

Traffic and Industrial Contributions of Particle-Bound PAHs during an Air Pollution Event in the Metropolitan Area of Medellin-Colombia: Inhalation Intake Risk during Pregnancy

Enhanced mitigation of inhalable particles and fine particle-bound PAHs from a novel hazardous waste-power plant candidate

Emissions of the inhalable particle (dp < 10 μm, PM10) and their harmful compositions from combustion sources have high potential on health risk with nearly no regulation. This study investigates the particle size distribution (PSD), as well as the removal mechanism of PM10 and fine particle (FP)-bound polycyclic aromatic hydrocarbons (PAHs) from the flue gas of a hazardous waste thermal treatment system. It has ultralow regulated emission and becomes a candidate of power generation module. A series of the advanced scrubbers, cyclonic demister, and baghouse was equipped for multi-pollutant control. The moderate or intense low oxygen dilution (MILD) combustion effectively inhibited the PM2.5 generation by volumetric oxidation. Advanced scrubbers removed PM1, PM2.5, and PM10 by 85.24, 68.68, and 97.60%, respectively, which achieved by local supersaturation, heterogeneous condensation of water vapor, and the growth of fine PM. Moreover, the scrubbers effectively scavenged the course PM10 containing the high-molecular-weight PAH homologs onto the water phase but promoted the condensation and absorption of the lighter homologs onto the fine particle surface (dp ∼5.3 μm). The size window (dp = 0.3–1.0 μm) of the minimum efficiency reporting value of a BH filtration led to the peak of FP-PAH mass and BaP equivalent (BaPeq) toxicity at dp = 0.1–0.4 and 0.1–0.8 μm, respectively. Consequently, the synergy of MILD combustion and the SCB-CYC-BH system effectively inhibited the PM2.5, PM10, PM2.5-PAHs, and FP-PAH levels from a waste thermal treatment process and further mitigated the potential health risk.

A novel exfoliated graphite-based device for passive sampling and detection of polycyclic aromatic hydrocarbons in air

Water scarcity is a major problem in the Sub-Saharan Africa, as such rainwater harvesting is considered as an alternative source of water. However, air pollution may affect the quality of taken rainwater. Specifically, particle-bound polycyclic aromatic hydrocarbons (PAHs) a class of persistent organic pollutants (POPs) known to have toxic effects on human beings and environmental sectors. In this study, a novel electrode material called exfoliated graphite (EG) was synthesized and used as sorbent material in fabrication of passive sampler and electrode device for the monitoring of polycyclic aromatic hydrocarbons (PAHs) in air. The surface morphology, structure, surface functionality of the materials were investigated using, Scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy and Fourier transform infrared spectroscopy (FTIR) techniques. A sorption kinetic’s evaluation of EG was conducted. It was found that EG has shown an outstanding affinity towards detection of PAHs with maximum partition coefficients. Moreover, EG electrode-based device was developed and utilized for detection of PAHs in air through electrochemical technique. This was conducted by exposing the sampler to PAHs gases for 12 days, thereafter it was transferred to a blank supporting electrolyte and analyzed using differential pulse voltammetry (DPV). The EG-based tubular sampler was calibrated in a laboratory flow-through exposure experiment. Furthermore, the effects of time and pollutants concentration were examined under controlled experimental conditions. Most importantly, extraction of the sampler was performed, followed by determination of PAHs using gas chromatography-mass spectrometer (GC–MS). As the result, uptake of PAHs onto the EG tubular based sampler was observed with linear uptake throughout the exposure time. Interestingly, an increasing of uptake by PAHs was indicated when the concentration of the pollutant was increased. These results imply that EG showed a great potential and preferable candidate for monitoring of PAHs in air.

Effectiveness of a covered oil-free cooking process on the abatement of air pollutants from cooking meats

Cooking events can generate household air pollutants that deteriorate indoor air quality (IAQ), which poses a threat to human health and well-being. In this study, the emission characteristics and emission factors (EFs) of air pollutants of different meats (beef, lamb, chicken, pork, and fish) cooked by a novel oil-free process and common with-oil processes were investigated. Oil-free cooking tends to emit lower total volatile organic compound (TVOC) levels and fewer submicron smoke particles and can reduce the intake of fat and calories. However, TVOC emissions during oil-free cooking were significantly different, and the lamb EFs were nearly 8 times higher than those during with-oil cooking. The particle-bound polycyclic aromatic hydrocarbon (ƩPPAH) and benzo(a)pyrene-equivalent (ƩBaPeq) EFs during with-oil cooking ranged from 76.1 to 140.5 ng/g and 7.7–12.4 ng/g, respectively, while those during oil-free cooking ranged from 41.0 to 176.6 ng/g and 5.4–47.6 ng/g, respectively. The ƩPPAH EFs of chicken, pork, and fish were lower during oil-free cooking than during cooking with oil. Furthermore, the ƩBaPeq EFs of beef, chicken, pork, and fish were lower during oil-free cooking than during cooking with oil. Therefore, it is recommended to use the oil-free method to cook chicken, pork, and fish to reduce ƩPPAH and ƩBaPeq emissions, but not recommended to cook lamb due to the increase of ƩBaPeq emissions. The with-oil uncovered cooking EFs of aldehydes ranged from 3.77 to 22.09 μg/g, and those of oil-free cooking ranged from 4.88 to 19.96 μg/g. The aldehyde EFs were lower during oil-free covered cooking than with-oil uncovered cooking for beef, chicken, and fish. This study provides a better realizing of new cooking approaches for the reduction of cooking-induced emission, but further research on the effects of food composition (moisture and fat) and characteristics is needed.

Molecular distribution, sources and potential health risks of fine particulate-bound polycyclic aromatic hydrocarbons during high pollution episodes in a subtropical urban city

Abundance of fine particulate-bound 16 priority polycyclic aromatic hydrocarbons (PAHs) was investigated to ascertain its sources and potential carcinogenic health risks in Varanasi, India. The city represents a typical urban settlement of South Asia having particulate exposure manyfold higher than standard with reports of pollution induced mortalities and morbidities. Fine particulates (PM2.5) were monitored from October 2019 to May 2020, with 32% of monitoring days accounting ≥100 μgm−3 of PM2.5 concentration, frequently from November to January (99% of monitoring days). The concentration of 16 priority PAHs varied from 24.1 to 44.6 ngm−3 (mean: 33.1 ± 3.2 ngm−3) without much seasonal deviations. Both low (LMW, 56%) and high molecular weight (HMW, 44%) PAHs were abundant, with Fluoranthene (3.9 ± 0.4ngm−3) and Fluorene (3.5 ± 0.3ngm−3) emerged as most dominating PAHs. Concentration of Benzo(a)pyrene (B(a)P, 0.5 ± 0.1ngm−3) was lower than the national standard as it contributed 13% of total PAHs mass. Diagnostic ratios of PAH isomers indicate predominance of pyrogenic sources including emissions from biomass burning, and both from diesel and petrol-driven vehicles. Source apportionment using receptor model revealed similar observation of major PAHs contribution from biomass burning and fuel combustion (54% of source contribution) followed by coal combustion for residential heating and cooking purposes (44%). Potential toxicity of B[a]P equivalence ranged from 0.003 to 1.365 with cumulative toxicity of 2.13ngm−3. Among the PAH species, dibenzo[h]anthracene contributed maximum toxicity followed by B[a]P, together accounting 86% of PAH induced carcinogenicity. Incremental risk of developing cancer through lifetime exposure (ILCR) of PAHs was higher in children (3.3 × 10−4) with 56% contribution from LMW PAHs, primarily through ingestion and dermal contact. Adults in contrast, were more exposed to inhale airborne PAHs with cumulative ILCR of 2.2 × 10−4. However, ILCR to PM2.5 exposure is probably underestimated considering unaccounted metal abundance thus, require source-specific control measures.

Combined effects of temperature and monsoon on seasonal variations of atmospheric polycyclic aromatic hydrocarbons in the coastal Shanghai, China

An intensive sampling program was conducted at two coastal sites of megacity Shanghai - the emerging town Lingang New Area (LGNA), and the petrochemical-industry zone Jinshan Area (JSA) from July 2016–June 2017, to study the occurrence, sources, environmental behavior and fate of atmospheric polycyclic aromatic hydrocarbons (PAHs). Results showed the median concentrations of total atmospheric PAHs were 18 ng m−3 and 12 ng m−3 in JSA and LGNA, respectively, which were lower than those recently detected in northern coastal China, and previously detected in urban/suburban Shanghai. There was strong/opposite temperature dependence for gaseous and particle-bound PAHs, indicating the importance of ongoing local and nearby volatilization; While the gas-particle partitions of individual PAH compound changed dramatically with seasons, with most easily adsorbed on particles during colder months. The potential source contribution function (PSCF) and concentration weight trajectory (CWT) model demonstrated the interactions of terrestrial and marine air mass regulated by the East Asian monsoon. Specifically, PAHs released by wintertime coal heating in northern China and summertime marine shipping in East China Sea, that transported through northwest and southeast monsoon, respectively, and aggravated the pollution of coastal Shanghai, especially for the background site in LGNA. The positive matrix factorization (PMF) source apportionment suggested the dominance of petrogenic sources for gaseous PAHs, coal and biomass combustion sources for particle-bound PAHs, and further demonstrated the seasonal variations of these potential sources. Atmospheric PAHs would deposit to the coastal waters, with gaseous absorption fluxes almost an order of magnitude higher than those of particle-bound deposition.

Wintertime trends of particulate-bound polycyclic aromatic hydrocarbons (PAHs) at north-east site of India: chemical characterization and source identification

Wintertime trends of particulate-bound polycyclic aromatic hydrocarbons (PAHs) at north-east site of India: chemical characterization and source identification

Fine and ultrafine particle emission factors and new diagnostic ratios of PAHs for peat swamp forest fires

Peatland fires are one of the major global sources of atmospheric particles. Emission factors for fine (PM1 and PM2.5) and ultrafine (PM0.1) particles and particle-bound polycyclic aromatic hydrocarbons (PAHs) from plants in the peat swamp forest (PSF), including Melaleuca cajuputi leaves, M. cajuputi branches, M. cajuputi bark, Lepironia articulata (Retz.) Domin, forest leaf litter and peat were measured in a laboratory combustion chamber. From these measurements, new PAH diagnostic ratios for fine and ultrafine particles were proposed for identifying the forest burning source. The new emission factors for PM were PM0.1: 0.03–0.33, PM1: 0.69–2.11 and PM2.5: 1.12–4.18 g/kg; for PM-bound PAHs, the factors were PM0.1: 5.7–166.0, PM1: 31.5–1338.9 and PM2.5: 36.3–3641.1 μg/kg. The predominant PAHs for PSF burning were Pyr, BbF, DBA (in PM0.1), Flu, DBA, BghiPe (in PM1), and BbF, DBA and BghiPe (in PM2.5). We also presented new diagnostic ratios for PSF burning, including BaP/(BaP + Chr): 0.39–0.75, BaP/(BaP + BbF): 0.21–0.47 and BaA/(BaA + Chr): 0.36–0.53. Moreover, the physical and chemical characteristics of ambient fine and ultrafine particles in the Kuan Kreng forest during the 2019 forest fire (FF) and 2021 non-forest fire (NFF) periods were investigated. The mean PM0.1, PM1 and PM2.5 concentrations during the FF period were approximately 3.5–4.4 times as high as those during the 2021 NFF period. New PAH diagnostic ratios of BaP/(BaP + BbF) versus BaP/(BaP + Chr) were able to identify PAH burning sources in PM1 and PM2.5 but were less clear for PM0.1, which was dominated by a single source – M. cajuputi. Chemical mass balance studies identified peat forest burning emissions as the main source of fine and ultrafine particles during the FF period. This study suggests that the new PAH diagnostic ratios can be used to identify the burning source for more precise source apportionment.

Polycyclic aromatic hydrocarbons including dibenzopyrenes in indoor air samples from schools and residences in Germany

Polycyclic aromatic hydrocarbons (PAH) are several hundred organic substances that are formed in the course of incomplete combustion of organic material. Of particular importance are the carcinogenic effects of PAH. Various dibenzopyrenes as well as benzo[c]fluorene (BcFl) seems to have a particular toxicological potency, which have hardly been investigated in indoor air so far.Therefore, the indoor air samples of 27 classrooms and 35 central living spaces of residences in Germany were collected to analyze 56 particle-bound PAH as well as naphthalene (Nap).The PM10 values in schools and residences ranged between 9.1 and 210 μg/m³ (mean: 93.4 μg/m³) and from 3.6 to 52.0 μg/m³ (mean: 12.0 μg/m³), respectively. For the sum of the 16 priority US EPA PAH (except acenaphthylene and naphthalene) means (95th percentiles) in classrooms and residences were 1.20 ng/m³ (2.77 ng/m³) and 0.84 ng/m³ (2.64 ng/m³), respectively. Higher values were observed for naphthalene with mean concentrations of 596 ng/m³ (2,800 ng/m³) in classrooms and 243 ng/m³ (530 ng/m³) in residences.For classrooms and residences mean concentrations of 8.3 pg/m³ and 7.4 pg/m³ for dibenzo[a,l]pyrene (DBalPyr), 16.4 pg/m³ and 11.9 pg/m³ for dibenzo[a,e]pyrene (DBaePyr), 9.2 and 5.7 pg/m³ for dibenzo[a,h]pyrene (DBahPyr), and 6.4 and 4.2 pg/m³ for BcFl were observed, respectively, while DBaiPyr was found in only one sample above LOD.The BaPeq (benzo[a]pyrene equivalents) for the sum of 20 PAH is on average 482 pgTEQ/m³ (schools) and 393 pgTEQ/m³ (residences), which corresponds to an incremental lifetime cancer risk to 42 × 10−6 and 34 × 10−6.Although dibenzopyrenes and BcFl are found only in very low concentrations in indoor air, they have a significant impact on the risk if the assumptions about the toxicological potency of this group turn out to be valid.

Toxicity of fresh and aged anthropogenic smoke particles emitted from different burning conditions

There is substantial evidence that photochemical reactions in the atmosphere cause physico-chemical transformation of combustion smoke, but how this processing modifies potential health effects in exposed populations is not well understood. Here we utilized a new approach to simulate photochemical aging of anthropogenic smoke emissions (a mixture of plastic, plywood, and cardboard smoke) from two different burning conditions (smoldering vs. flaming) and investigated their adverse outcomes associated with mutagenic activity and the relative potencies of different polycyclic aromatic hydrocarbons (PAHs). Aging resulted in increased oxygenated volatile organic compound (VOC) emissions but largely degraded particle-bound PAH components in the smoke. Chemical transformation during aging was more dramatic for flaming versus smoldering smoke. Due to the PAH degradation, mutagenicity of the aged smoke from flaming combustion was much lower (up to 4 times) than that of the fresh smoke on per-particle mass basis. However, on the basis of particle emitted per fuel mass burned, the aged and fresh smoke particles exhibited similar mutagenic activities, which were up to 3 times higher for smoldering versus flaming smoke emissions. Similarly, the PAH toxicity equivalent (PAH-TEQ) of the aged smoldering smoke was 3 times higher than that of the aged flaming smoke particles, suggesting that some PAHs (e.g., indeno[c,d]pyrene and benzo[b]fluoranthene) in the smoldering smoke were more photochemically stable during aging. These findings increase understanding of the evolution of smoke emitted at different burning conditions and the role of photochemical transformations on mutagenicity and PAH-induced toxicity.

Effects of organic carbon/elemental carbon and particle size on inhalation bioaccessibility of particle-bound PAHs

Bioaccessible fractions of particle-bound hydrophobic organic compounds (HOCs) are critical to evaluating human inhalation exposure risk. However, the key factors for controlling the release of HOCs into the lung fluid are not adequately examined. To address this issue, eight particle size fractions (0.056–18 μm) from different particle emission sources (barbecue and smoking) were collected and incubated with an in vitro method for determining inhalation bioaccessibilities of polycyclic aromatic hydrocarbons (PAHs). The bioaccessible fractions of particle-bound PAHs were 35–65% for smoke-type charcoal, 24–62% for smokeless-type charcoal, and 44–96% for cigarette. The size distributions of bioaccessible fractions of 3–4 ring PAHs were symmetric with the patterns of their masses, characterized as a unimodal distribution with both the trough and peak at 0.56–1.0 μm. Analysis from machine learning showed that chemical hydrophobicity appeared to be the most significant factor affecting inhalation bioaccessibility of PAHs, followed by organic carbon and elemental carbon contents. Particle size seemed to have little effect on the bioaccessibility of PAHs. A compositional analysis of human inhalation exposure risk from total concentration, deposition concentration, and bioaccessible deposition concentration in alveolar region showed a shift in the key particle size from 0.56−1.0 μm to 1.0–1.8 μm and an increasing in the contributions of 2–3 ring PAHs to risk for cigarette due to the high bioaccessible fractions. These results suggested the significance of particle deposition efficiency and bioaccessible fractions of HOCs in risk assessment.