The mid-infrared (MIR) wavelength coincides with various molecular resonances. In particular, a 13-20 µm wavelength window has fingerprints of unique groups such as organometallic, halogenated, and aromatic bonds. In this work, for the first time, to the best of our knowledge, an on-chip supercontinuum generation (SCG) source based on cadmium telluride (CdTe)/ cadmium sulfide (CdS)/ silicon heterostructure is proposed to extend the on-chip SCG beyond 13 µm (spanning 3.5 to 20 µm). CdTe has an ultra-broad transparent spectral range up to 25 µm, and almost the largest third-order nonlinear coefficient (n2∼ 5×10-17 m2/W at 1.55 µm, 1.3×10-17 m2/W at 9 µm, several times larger than that of silicon) among the MIR materials, making CdTe an excellent candidate for long-wavelength MIR on-chip SCG. The waveguide structure is designed with CdS as the intermediate cladding layer to achieve a low waveguide loss and high mode confinement. A large-core CdTe waveguide is tailored to generate a low and flat dispersion (< 30 ps/nm/km) in a spectral range spanning from 5 to 20 µm, while balancing the large effective nonlinearity and the convenience of coupling. The simulation results solved by the nonlinear Schrödinger equation manifest that the engineered large cross-section waveguide with only 2.5-mm propagation distance broadens the MIR spectrum covering 3.5 to 20 µm pumped by a 9 µm femtosecond laser. Moreover, it is found that good coherence is achieved from the designed MIR waveguide, before severe soliton fission breaks the temporal profile. 5-fold self-compression of the pump pulse down to 1.6 optical cycles is observed while propagating inside the CdTe waveguide. The detailed simulation of the CdTe/CdS/Si waveguide design with the various waveguide parameters, polarizations, pump wavelengths, and pump power are provided. With the SC spectrum covering almost the entire fingerprint regime and the excellent coherence generated from the designed CdTe waveguide, it provides abundant new opportunities for MIR microphotonics.
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