Seawater sea-sand (SWSS) concrete is a promising sustainable construction material that could mitigate the detrimental environmental impact because of the overuse of freshwater and natural sand (FWNS). Physical and chemical properties of seawater sea-sand (SWSS) concrete are significantly different than those of conventional concrete due to a high concentration of certain destructive ions in seawater and sea sand. When a fire accident occurs, the elevated temperature could alter the chemical composition and microstructure of concrete material. This study first examined the effects of elevated temperatures on the pertinent properties of SWSS and FWNS concretes and then proposed methodologies for improving the fire-resistance capability of SWSS concrete by application of fibre additions. Polypropylene (PP) and polyvinyl alcohol (PVA) fibres with volume fractions of 0.1–0.5% were employed for the above purpose. All the parameters of mass loss, residual thermal strain, compressive strength, elastic modulus, splitting tensile and flexural strength, and fracture toughness of the concrete specimens were examined after exposure to different elevated temperatures ranging from 100 to 750 °C. Furthermore, the alterations in the microstructure of the mixes after exposure to the elevated temperatures were investigated by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) images, water absorption and porosity tests. From the experimental results, the SWSS mix exhibited a lower mass loss, a higher residual thermal strain, and a slightly lower residual compressive strength and elastic modulus and tensile strength than those of conventional FWNS concrete. Additional porosity created by fibre decomposition appears to provide extra rooms for concrete expansion, which led to the formation of finer and lower number of cracks. Generally, incorporation of PP or PVA fibres improved SWSS concrete properties after exposure to the elevated temperatures tested. Compared with PP fibres, PVA fibre was more efficient for improving all the tested concrete properties after the exposure of high temperatures.
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