Abstract: In This research presents an extensive analysis of land use and land cover (LULC) classification in Chhatrapati Sambhajinagar City, a rapidly expanding urban centerin Maharashtra, India, highly susceptible to climate change. Using remote sensing and GIS techniques, the research evaluates the impact of LULC on ecosystem service values (ESV) over a nine- year period (2013-2021). Satellite-based data were utilized to quantify LULC changes, encompassing Green Area, Buildup Area, Road Area, WaterBodies, and Barren Land. The research employs five distinct classification methods and investigates the effectiveness of pre-processing techniques in improving classification accuracy during selected years (2013, 2016, 2019, and 2021). The performance of Mahalanobis Distance, Maximum Likelihood, Parallelepiped, and Support Vector Machine methods is assessed under both preprocessed and non-preprocessed conditions, using overall accuracy and Kappa accuracy as evaluation metrics. The results reveal consistent enhancements in overall accuracy, with Mahalanobis Distance, Maximum Likelihood, and Support Vector Machine methods demonstrating percentage improvements ranging from 0.43% to 5.08% after preprocessing. Particularly noteworthy are the substantial percentage increases in Parallelepiped Classification, ranging from 23.74% to 53.34%, highlighting the transformative impact of preprocessing on its accuracy. These findings emphasize the necessity for customized preprocessing strategies to refine the precision of LULC classification models, offering valuable contributions to the realms of remote sensing and geospatial analysis. Moreover, the insights gleaned from this research provide crucial guidance for urban growth management and climate resilience strategies in rapidly developing urban areas, making it a valuable resource for sustainable urban planning