Parallel Transition Research Articles

Electron velocity map imaging and theoretical study on CuXH (X = O and S) anions

Vibrationally resolved photoelectron spectra of CuOH− and CuSH− have been determined via velocity map imaging method to investigate the transitions of X1A′←X2A′ at 532nm. Adiabatic detachment energies of CuOH− and CuSH− are assigned to 0.995(12) and 1.098(12) eV, respectively. Combined theoretical calculations with Franck-Condon simulations, it allows extracting the vibrational frequencies in neutral, which yields 629(32) cm−1 with CuO stretching mode and 387(24) cm−1 with CuS stretching mode for CuXH (X=O and S). Parallel transition properties of photoelectron angular distributions (PADs) for both species are correlated to the photodetachment of SOMO orbitals, which mainly involved in the Cu atom s orbital and partial s orbital in other atoms. Based on chemical bonding analyses (Wiberg, NAO, Mayer, NRT, and ELF), it is suggested that a trend is observed with a subtle variation of covalent component from weak covalent behavior between CuO in CuOH–1/0 to stronger covalent bonding between CuS in CuSH–1/0 (especially for non-ignorable covalent component in CuSH species) though ionic bonding dominates both in CuO and CuS bonds for the two systems.

Stereodirectional images of molecules oriented by a variable-voltage hexapolar field: Fragmentation channels of 2-bromobutane electronically excited at two photolysis wavelengths.

The asymmetric-top molecule 2-bromobutane is oriented by means of a hexapole state selector; the angular distribution of the bromine atom photofragment, for the two fine-structure components, is acquired by velocity-map ion imaging. The molecular beam, spatially oriented along the time-of-flight axis, is intersected with a linearly polarized laser, whose polarization is tilted by 45° with respect to the detector surface. To obtain the mixing ratio of the perpendicular and parallel transitions, the fragment ion images and angular distributions can be appropriately simulated to give insight on the population mechanism of the specific electronic state involved at each selected excitation wavelength. The photofragment images obtained at 238.6 nm yielded an asymmetry factor β1 of 0.67, indicative of the extent of molecular orientation, and an anisotropy parameter β2 of 1.03, which is a signature of a prevailing parallel transition along the C-Br axis. When the photolysis wavelength is tuned to 254.1 nm, the corresponding angular distribution is less asymmetric (β1 = 0.24) and the obtained small value β2 = 0.12 is a characteristic of a predominantly perpendicular transition. The photofragment angular distributions are also affected by hexapole voltage, especially regarding the asymmetry factor, and this aspect provides information on the effect of molecular orientation.

Integrin β4 promotes cell invasion and epithelial-mesenchymal transition through the modulation of Slug expression in hepatocellular carcinoma

Integrin β4 (ITGB4) is a transmembrane receptor involved in tumorigenesis and the invasiveness of many cancers. However, its role in hepatocellular carcinoma (HCC), one of the most prevalent human cancers worldwide, remains unclear. Here, we examined the involvement of ITGB4 in HCC and explored the underlying mechanisms. Real-time PCR and immunohistochemical analyses of tissues from 82 patients with HCC and four HCC cell lines showed higher ITGB4 levels in tumor than in adjacent non-tumor tissues and in HCC than in normal hepatic cells. Silencing of ITGB4 repressed cell proliferation, colony forming ability and cell invasiveness, whereas ectopic expression of ITGB4 promoted the proliferation and invasion of HCC cells and induced epithelial to mesenchymal transition (EMT) in parallel with the upregulation of Slug, as shown by transwell assays, WB and immunocytochemistry. Knockdown of Slug reduced cell viability inhibited invasion and reversed the effects of ITBG4 overexpression on promoting EMT, and AKT/Sox2-Nanog may also be involved. In a xenograft tumor model induced by injection of ITGB4-overexpressing cells into nude mice, ITGB4 promoted tumor growth and metastasis to the lungs. Taken together, our results indicate that ITGB4 plays a tumorigenic and pro-metastatic role mediated by Slug and suggest IGTB4 could be a prognostic indicator or a therapeutic target in patients with HCC.

Substrate Integrated Horn Antenna Loaded With Open Parallel Transitions

The substrate integrated H-plane horn antenna has been struggling with very limited impedance bandwidth since its invention, which is coming from its natural aperture discontinuity. Apart from a variety of series transitions introduced so far, here, parallel transitions are applied to the antenna aperture in addition to narrow slots on the horn walls around the aperture to widen the antenna impedance bandwidth. It is shown that the depth of the transitions can easily determine the center frequency of the matching bandwidth. The new parallel transitions also reduce the antenna back radiation since they act as chokes around the horn aperture.

Overlapping Electronic States with Nearly Parallel Transition Dipole Moments in Reduced Anionic Flavin Can Distort Photobiological Dynamics.

Chromophoric biomolecules are exploited as reporters of a diverse set of phenomena, acting as internal distance monitors, environment and redox sensors, and endogenous imaging probes. The extent to which they can be exploited is dependent on an accurate knowledge of their fundamental electronic properties. Arguably of greatest importance is a precise knowledge of the direction(s) of the absorption transition dipole moment(s) (TDMs) in the molecular frame of reference. Such is the case for flavins, fluorescent redox cofactors utilized for ground- and excited-state redox and photochemical processes. The directions of the TDMs in oxidized and semiquinone flavins were characterized decades ago, and the details of charge redistribution in these forms have also been studied by Stark spectroscopy. The electronic structure of the fully reduced hydroquinone anionic state, FlH-, however, has been the subject of unfounded assumptions and estimates about the number and direction of TDMs in FlH-, as well the electronic structure changes that occur upon light absorption. Here we have used Stark spectroscopy to measure the magnitude and direction of charge redistribution in FlH- upon optical excitation. These data were analyzed using TD-DFT calculations. The results show unequivocally that not one but two nearly orientation-degenerate electronic transitions are required to explain the 340-500 nm absorption spectral range, demolishing the commonly held assumption of a single transition. The difference dipole moments for these states show that electron density shifts toward the xylene ring for both transitions. These measurements force a reappraisal of previous studies that have used erroneous assumptions and unsubstantiated estimates of these quantities. The results put future optical studies of reduced flavins/flavoproteins on a firm photophysical footing.

In-database batch and query-time inference over probabilistic graphical models using UDA–GIST

To meet customers' pressing demands, enterprise database vendors have been pushing advanced analytical techniques into databases. Most major DBMSes use user-defined aggregates (UDAs), a data-driven operator, to implement analytical techniques in parallel. However, UDAs alone are not sufficient to implement statistical algorithms where most of the work is performed by iterative transitions over a large state that cannot be naively partitioned due to data dependency. Typically, this type of statistical algorithm requires pre-processing to set up the large state in the first place and demands post-processing after the statistical inference. This paper presents general iterative state transition (GIST), a new database operator for parallel iterative state transitions over large states. GIST receives a state constructed by a UDA and then performs rounds of transitions on the state until it converges. A final UDA performs post-processing and result extraction. We argue that the combination of UDA and GIST (UDA---GIST) unifies data-parallel and state-parallel processing in a single system, thus significantly extending the analytical capabilities of DBMSes. We exemplify the framework through two high-profile batch applications: cross-document coreference, image denoising and one query-time inference application: marginal inference queries over probabilistic knowledge graphs. The 3 applications use probabilistic graphical models, which encode complex relationships of different variables and are powerful for a wide range of problems. We show that the in-database framework allows us to tackle a 27 times larger problem than a scalable distributed solution for the first application and achieves 43 times speedup over the state-of-the-art for the second application. For the third application, we implement query-time inference using the UDA---GIST framework and apply over a probabilistic knowledge graph, achieving 10 times speedup over sequential inference. To the best of our knowledge, this is the first in-database query-time inference engine over large probabilistic knowledge base. We show that the UDA---GIST framework for data- and graph-parallel computations can support both batch and query-time inference efficiently in databases.

Near Eastern genomes from Iran

Human Genetics![Figure][1] Genome sequencing of modern Iranian Zoroastrians reveals a previously uncharacterized ancient human population. PHOTO: ASSOCIATED PRESS The genetic composition of populations in Europe changed during the Neolithic transition from hunting and gathering to farming. To better understand the origin of modern populations, Broushaki et al. sequenced ancient DNA from four individuals from the Zagros region of present-day Iran, representing the early Neolithic Fertile Crescent. These individuals unexpectedly were not ancestral to early European farmers, and their genetic structures did not contribute significantly to those of present-day Europeans. These data indicate that a parallel Neolithic transition probably resulted from structured farming populations across southwest Asia. Science , this issue p. [499][2] [1]: pending:yes [2]: /lookup/doi/10.1126/science.aaf7943

Early Neolithic genomes from the eastern Fertile Crescent.

We sequenced Early Neolithic genomes from the Zagros region of Iran (eastern Fertile Crescent), where some of the earliest evidence for farming is found, and identify a previously uncharacterized population that is neither ancestral to the first European farmers nor has contributed substantially to the ancestry of modern Europeans. These people are estimated to have separated from Early Neolithic farmers in Anatolia some 46,000 to 77,000 years ago and show affinities to modern-day Pakistani and Afghan populations, but particularly to Iranian Zoroastrians. We conclude that multiple, genetically differentiated hunter-gatherer populations adopted farming in southwestern Asia, that components of pre-Neolithic population structure were preserved as farming spread into neighboring regions, and that the Zagros region was the cradle of eastward expansion.

Low-Frequency Noise Characterization of CoFeB/MgO/CoFeB MTJ-Based Perpendicular Field Sensor

We report low-frequency electrical resistance noise of Co40Fe40B20/MgO/Co20Fe60B20-based magnetic tunnel junction field sensors with reference and sensing layer magnetization directions along the out-of-plane and in-plane directions, respectively. The devices are fabricated using the sputter deposition and conventional lithography techniques with a short axis of $\sim 6~\mu \text{m}$ long and long axes of $\sim 6$ –12 $\mu \text{m}$ long. Noise power spectra under different bias currents indicate increase in noise power with increasing bias current. A close 1/ $f$ dependence of the noise according to Hooge’s relation, $S_{V}(f)= AV^{2}/f^{\alpha }$ ( $A$ is Hooge’s like constant) is observed with an average value of $\alpha = 1.03 \pm 0.08$ . In smaller devices, the magnetic field dependence of noise amplitude follows similar trend of magnetoresistance (MR) behavior without any distinct peak near antiparallel–parallel states transition of the devices, which is generally observed for magnetic defects-induced resistance fluctuation. The experimental observations infer the resistance noises in those devices that are related to the defects associated with the spin independent charge trapping at structural defects near or in the barrier layer. The device with the smallest lateral size exhibits the Lorentzian contribution, whereas the device with the largest size shows magnetic contribution in total noise. Numerically deduced magnetic fluctuations $\Delta B_{\mathrm{rms}}$ of all the devices shows an average magnetic fluctuation of $\sim 10$ nT except for one device. The devices show the highest MR% of $\sim 27$ % under perpendicular magnetic field with a dynamic range of $\sim \pm 25$ Oe and a sensitivity of $\sim 0.3$ %/Oe. The observed low-frequency noise levels are suitable for the perpendicular field detection application and can be reduced more by improving the crystallinity of the device films stacks and their interfaces.

Spectroscopy and high-spin structure ofFr210: Isomerism and potential evidence for configuration mixing

The structure of Fr-210 has been established up to an excitation energy of similar to 5.5 MeV and spins of similar to 25h, via time-correlated gamma-ray spectroscopy and using the Au-197(O-18, 5n)Fr-210 reaction with pulsed beams at an energy of 97 MeV. A significantly different level scheme has been obtained compared to previous publications. Several isomers are reported here, including a J(pi) = (23)(+), tau = 686(9)-ns state at 4417 keV and a 10(-), 29.8(11)-ns state at 1113 keV. The former isomer has been associated with the pi(h(9/2)(3)i(13/2)(2))v(p(1/2)(-2)f(5/2)(-1)) configuration and decays via proposed E3 transitions with strengths of 8.4(3) and 21.2(8) W.u. There are only very few known cases of a high-spin isomer decaying via two parallel E3 transitions. Indeed, this is not seen in other Fr nuclei, and consequently these strengths differ from related decays in the neighboring isotopes. However, by examining the systematics of E3 transitions in trans-lead nuclei, we suggest that the weaker of the two transitions decays to a mixed 20-state. Systematics of the 10-isomer are also discussed. Comparisons are made between the observed spectrum of states and those predicted from semiempirical shell-model calculations.

Predissociation dynamics in the 3pπD(1)Πu (±)υ=3 and 4pσB(″) (1)Σu (+)υ=1 states of H2 revealed by product branching ratios and fragment angular distributions.

The predissociation dynamics of H2+XUV→H2 (*)→H(1s)+H(2s,2p) has been studied by measuring the fragment branching ratios between the H(2s) and H(2p) states and the fragment angular distributions using the XUV (extreme ultraviolet) laser pump and UV(ultraviolet) laser probe method. The fragment angular distributions for the predissociation of the 3pπD(1)Πu (+)υ=3 state show parallel transitions, demonstrating that the main components of the dissociating state have (1)Σu (+) symmetry. The measured fragment branching ratios, H(2s)/(H(2s) + H(2p)), for the transitions R(0), R(1), and P(2) in 3pπD(1)Πu (+)υ=3←X(1)Σg (+)υ(″)=0 are in good agreement with one of the previous theoretical predictions. The predissociations of the 3pπD(1)Πu (-)(υ=3) state arising from the Q(1), Q(2), and Q(3) lines have also been observed. The angular distributions and the state distributions of the excited fragments (all found from the H(2p) state) illustrate that the dissociating states for the Q lines have the expected Πu (-) symmetry. The predissociation dynamics of the transition 4pσB(″1)Σu (+)υ=1←X(1)Σg (+)υ(″)=0 was also studied. Their fragment angular distributions show the expected parallel transitions, and most of the fragments are in the H(2s) states. The Beutler-Fano profiles and the associated spectroscopic parameters for the predissociations have also been obtained by measuring the fragment yield of H(2s, 2p) as a function of excitation photon energies.

Parking permits management and optimal parking supply considering traffic emission cost

Given a many-to-one bi-modal transportation network where each origin is connected to the destination by a bottleneck-constrained highway and a parallel transit line, we investigate the parking permit management methods to minimize traffic time cost and traffic emission cost simultaneously. More importantly, the optimal supply of parking spots is also discussed in the policies of parking permit. First, we derive the total travel costs and emission costs for the two cases of sufficient and insufficient parking spot provisions at the destination. Second, we propose a bi-objective model and solve the Pareto optimal parking permit distribution, given a certain level of parking supply. Third, we investigate the optimal parking supply in the policy of parking permit distribution, with the objectives of minimizing both total travel cost and traffic emission. Fourth, we provide a model of optimizing parking supply, in the policy of free trading of parking permits. Finally, the numerical examples are presented to illustrate the effectiveness of these schemes, and the numerical results show that restricting parking supply at the city center could be efficient to reduce traffic emission.

High-Resolution Experimental Study on Photodissocaition of N2O

We study the photodissociation dynamics of nitrous oxide using the time-sliced ion velocity imaging technique at three photolysis wavelengths of 134.20, 135.30, and 136.43 nm. The O(1SJ=0)+N2(X1∑+g) product channels were investigated by measuring images of the O(1SJ=0) products. Vibrational states of N2(X1∑+g products were fully resolved in the images. Product total kinetic energy releases (TKER) and the branching ratios of vibrational states of N2 products were determined. It is found that the most populated vibrational states of N2 products are v=2 and v=3. The angular anisotropy parameters (β values) were also derived. The β values are very close to 2 at low vibrational states of the correlated N2(X1∑+g products at all three photolysis wavelengths, and gradually decrease to about 1.4 at v=7. This indicates the dissociation is mainly through a parallel transition state to form products at lower vibrational states, and the highly vibrational exited products are from a more bent configuration. This is consistent with the observed shift of the most intense rotational structure in the TKER as the vibrational quantum number increases.

Infrared radiative decay dynamics from the γ 1u ((3)P2), H 1u ((3)P1), and 1u ((1)D2) ion-pair states of I2 observed by a perturbation facilitated optical-optical double resonance technique.

We report the spectroscopic and temporal analyses on the amplified spontaneous emission (ASE) from the single rovibrational levels of the Ω = 1u ion-pair series, γ 1u ((3)P2), H 1u ((3)P1), and 1u ((1)D2), of I2 by using a perturbation facilitated optical-optical double resonance technique through the c (1)Πg ∼ B (3)Π(0u (+)) hyperfine mixed valence state as the intermediate state. The ASE detected in the infrared region was assigned to the parallel transitions from the Ω = 1u ion-pair states down to the nearby Ω = 1g ion-pair states. The subsequent ultraviolet (UV) fluorescence from the Ω = 1g states was also observed and the relative vibrational populations in the Ω = 1g states were derived through the Franck-Condon simulation of the intensity pattern of the vibrational progression. In the temporal profiles of the UV fluorescence, an obvious delay in the onset of the fluorescence was recognized after the excitation laser pulse. These results revealed that ASE is a dominant energy relaxation process between the Ω = 1u and 1g ion-pair states of I2. Finally, the lifetimes of the relevant ion-pair states were evaluated by temporal analyses of the UV fluorescence. The propensity was found which was the longer lifetime in the upper level of the ASE transitions tends to give intense ASE.

Transport And Health: A Marriage Of Convenience Or An Absolute Necessity

BackgroundThe recent diesel scandal has again highlighted the impact that the transport sector can have on public health. AimTo describe the current impact of transport planning on public health. ResultTransport is fundamental to our cities' economic and social development, but causes large health effects and impact through accidents, air pollution, noise, green space and lack of physical activity. ConclusionThere is an urgent need to rebalance and provide better and safer infrastructures and policy support for transport, and particularly, active transport modes, building a new culture for it. A parallel transition in transport and urban planning is needed to improve, in a global and structural way, the relations between urban mobility and health.

Solid solution Pb1−xEuxTe: constitution and thermoelectric behavior

The thermoelectric properties of polycrystalline materials on the basis of the solid solution Pb1−xEuxTe prepared by spark-plasma-sintering are characterized. The solid solution undergoes a metal–semiconductor transition in parallel to the p–n transition around 500 K.

Multi-photon dissociation dynamics of Freon 1110 induced by femtosecond laser pulse

The ozone layer which absorbs harmful solar UV radiation is an essential umbrella for human beings. However, a large number of exhausts of chlorine compounds including freon released by people in the atmosphere pose a great threat to the ozone layer. Freon dissociates into the product of chlorine radicals induced by UV sunlight radiation, which are found to be the main culprit for the destruction of atmospheric ozone. In this paper, time-of-flight mass spectrometry and velocity map imaging technique are coupled for investigating the multiphoton dissociation dynamics of Freon 1110 (C2Cl4, Tetrachloroethylene) induced by ultrafast short laser pulse on a femtosecond time scale at 800 nm. Fragments mass spectra of C2Cl4 are measured by time-of-flight mass spectrometry. Together with the parent ion C2Cl4+, two dominant fragment ions C2Cl3+ and C2Cl2+ are discovered in the multi-photon ionization and dissociation process in the experiment. By analyzing the above mass spectra, two corresponding photodissociation mechanisms are discussed and listed as follows: 1) C2Cl4+C2Cl3+ +Cl with single CCl bond breaking and direct production of Cl radical; 2) C2Cl4+C2Cl2+ +2Cl with double CCl bonds breaking and production of two Cl radicals. Also, ion images of these two observed fragment ions C2Cl3+ and C2Cl2+ are measured by velocity map imaging apparatus. The kinetic energy distributions of these two fragment ions are determined from the measured velocity map images. The kinetic energy distributions of both C2Cl3+ and C2Cl2+ can be well fitted by two Gaussion distributions. It indicates that both fragments C2Cl3+ and C2Cl2+ are from two production channels. The peak energies for each channel are fitted. More detailed photodissociation dynamics is obtained by analyzing the angular distribution of the generated fragment ions. The anisotropy parameter values are measured to be 0.46 (low energy channel) and 0.52 (high energy channel) for the fragment C2Cl3+, and 0.41 (low energy channel) and 0.66 (high energy channel) for the fragment C2Cl2+, respectively. The ratios between parallel transition and perpendicular transition are determined for all the observed channels for producing fragments C2Cl3+ and C2Cl2+. In addition, density functional theory calculations at a high-precision level are also performed on photodissociation dynamics for further analysis and discussion. The optimized geometries of ground state and ionic state of C2Cl4 are obtained and compared with density functional theory calculation at the level of B3LYP/6-311G++(d,p). The different structures of the ground and ionic states are given and discussed. The calculated information about ionic states of C2Cl4, including energy level and oscillator strength for the ionic excited states, is also given for analyzing the photodissociation dynamics of the C2Cl4 ions.

Multi-photon dissociation dynamics of Freon 114B2 under UV radiation by femtosecond laser pulse

The ozone layer which absorbs harmful solar UV radiation is a necessary umbrella for human beings and biosphere. A large amount of alkyl halide including freon exhausted by human into the atmosphere poses a great threat to the ozone layer. Freon dissociates into the product of halogen radical, like Br and Cl, induced by UV sunlight radiation, which is found to be the main culprit for the destruction of atmospheric ozone. In this paper, time-of-flight (TOF) mass spectrometry and velocity map imaging technique are employed for investigating the multiphoton dissociation dynamics of Freon F114B2 (C2F4Br2) induced by femtosecond UV radiation at 267 nm. Fragment mass spectra of C2F4Br2 under UV radiation at 266 nm are obtained by TOF mass spectrometry. Three daughter ions C2F4Br+, C2F4+ and CF2Br+are discovered together with the parent ions C2F4Br2+. And three corresponding photodissociation mechanisms are concluded as follows: 1) C2F4Br2+C2F4Br++Br with single CBr bond breaking and direct production of Br radical; 2) C2F4Br2+C2F4++2Br with double CBr bonds breaking and production of two Br radical; 3) C2F4Br2+CF2Br++CF2Br with CC bond breaking. Velocity map images of the strongest daughter ion C2F4Br+with CBr breaking are measured by imaging apparatus. The kinetic energy distribution of C2F4Br+ ions is obtained from the measured velocity map images. And it can be well fitted by three Gaussian curves which describe normal distribution. It indicates that the production of the fragment C2F4Br+ stems from three different dissociation channels. Additional photodissociation dynamics is obtained by analyzing the angular distribution of the measured image. The values of anisotropy parameter are measured to be 0.1 (for the low energy channel), 0.8 (for the middle energy channel) and 1.4 (for the high energy channel) for the fragment C2F4Br+, respectively. The ratios of parallel transition to perpendicular transition are determined for three different channels. In addition, density functional theory calculations are also performed for further analysis and discussion. The optimized geometries of ground state and ionic state of C2F4Br2 are obtained and compared at the level of B3LYP/6-311G++(d, p). The calculated information about ionic states, including energy level and oscillator strength for the ionic excited states, are given.

Performance limits of multilevel and multipartite quantum heat machines.

We present the general theory of a quantum heat machine based on an N-level system (working medium) whose N-1 excited levels are degenerate, a prerequisite for steady-state interlevel coherence. Our goal is to find out the extent to which coherence in the working medium is an asset for heat machines. The performance bounds of such a machine are common to (reciprocating) cycles that consist of consecutive strokes and continuous cycles wherein the periodically driven system is constantly coupled to cold and hot heat baths. Intriguingly, we find that the machine's performance strongly depends on the relative orientations of the transition-dipole vectors in the system. Perfectly aligned (parallel) transition dipoles allow for steady-state coherence effects, but also give rise to dark states, which hinder steady-state thermalization and thus reduce the machine's performance. Similar thermodynamic properties hold for N two-level atoms conforming to the Dicke model. We conclude that level degeneracy, but not necessarily coherence, is a thermodynamic resource, equally enhancing the heat currents and the power output of the heat machine. By contrast, the efficiency remains unaltered by this degeneracy and adheres to the Carnot bound.

Contrasting Solid-State Fluorescence of Diynes with Small and Large Aryl Substituents: Crystal Packing Dependence and Stimuli-Responsive Fluorescence Switching.

There has been a significant current interest in solid state luminescence of organic molecules and their stimuli responsive fluorescence switching behavior. Although small organic derivatives with olefinic, acetylenic, phenylenevinylenic, phenyleneethynylenic spacers are widely documented as solid state emitters in the literature, the solid state photophysics of organic derivatives with "butadiyne" spacer still remains unexplored. We provide detailed investigation on the solid state fluorescence properties of a series of butadiynyl fluorophores. Replacement of a phenyl ring, which is at periphery of the butadiyne bridge, with a large moiety such as pyrenyl group furnishes contrasting emissions in the solid state. While the butadiyne bridged phenyl derivatives show a blue shift of emission maxima in the solid powder with respect to monomer spectra in solution state, the butadiyne bridged pyrenyl derivatives exhibit a red shift in the solid state. The blue shift of the emission maxima of the butadiyne bridged phenyl derivatives in the solid powder is attributed to allowed excitonic transition in aggregates with nearly parallel transition dipoles. On the other hand, formation of pyrenyl excimer accounts for the red shift of the butadiyne bridged pyrenyl derivatives in the solid powder. In addition to that, the solid state fluorescence of the pyrenyl analogues is reversibly switched between two aggregate forms through external heating and rubbing stimuli.