Paleoclimate Studies Research Articles

In-situ provenance of brGDGTs in peat sediments: A case study from southern China and a comparison of global results

Sedimentary branched glycerol dialkyl glycerol tetraethers (brGDGTs) have been proposed as indicators of environmental change for more than a decade. However, the origin of brGDGTs in terrestrial sediments is a fundamental issue affecting their use in paleoenvironmental reconstruction. Although peat sediments are one of the best terrestrial archives for paleoclimatic studies, the origin of brGDGTs in peat sediments remains poorly constrained. Here, we report the results of a study of brGDGTs in peat surface sediments, peat core sediments, and in the surrounding surface soils of the Shiwangutian (SWGT) peatland in southern China. Comparison of the molecular distributions and absolute concentrations of the total brGDGTs extracted from these different sample types reveals the dominant in-situ origin of the brGDGTs in the SWGT peatland. We then compare the results from globally-distributed surface peat sediments and surface soils, which confirms the dominant in-situ provenance of brGDGTs at almost all of the studied peatlands. Furthermore, in specific environments, such as in peatlands in cold and alkaline environments, the origin of brGDGTs could be different to that in other environments. Our results provide fundamental evidence for the provenance of brGDGTs in peat sediments, with relevance for peat-brGDGTs-based paleoclimatic reconstructions.

ShellChron 0.4.0: a new tool for constructing chronologies in accretionary carbonate archives from stable oxygen isotope profiles

Abstract. This work presents ShellChron, a new model for generating accurate internal age models for high-resolution paleoclimate archives, such as corals, mollusk shells, and speleothems. Reliable sub-annual age models form the backbone of high-resolution paleoclimate studies. In the absence of independent sub-annual growth markers in many of these archives, the most reliable method for determining the age of samples is through age modeling based on stable oxygen isotope or other seasonally controlled proxy records. ShellChron expands on previous solutions to the age model problem by fitting a combination of a growth rate and temperature sinusoid to model seasonal variability in the proxy record in a sliding window approach. This new approach creates smoother, more precise age–distance relationships for multi-annual proxy records with the added benefit of allowing assessment of the uncertainty in the modeled age. The modular script of ShellChron allows the model to be tailored to specific archives, without being limited to oxygen isotope proxy records or carbonate archives, with high flexibility in assigning the relationship between the input proxy and the seasonal cycle. The performance of ShellChron in terms of accuracy and computation time is tested on a set of virtual seasonality records and real coral, mollusk, and speleothem archives. The result shows that several key improvements in comparison to previous age model routines enhance the accuracy of ShellChron on multi-annual records while limiting its processing time. The current full working version of ShellChron enables the user to model the age of 10-year-long high-resolution (16 samples yr−1) carbonate records with monthly accuracy within 1 h of computation time on a personal computer. The model is freely accessible on the CRAN database and GitHub. Members of the community are invited to contribute by adapting the model code to suit their research topics and encouraged to cite the original work of Judd et al. (2018) alongside this work when using ShellChron in future studies.

Premelting controlled active matter in ice.

Self-propelled particles can undergo complex dynamics due to a range of bulk and surface interactions. When a particle is embedded in a host solid near its bulk melting temperature, the latter may melt at the surface of the former in a process known as interfacial premelting. The thickness of the melt film depends on the temperature, impurities, material properties and geometry. A temperature gradient is accompanied by a thermomolecular pressure gradient that drives the interfacial liquid from high to low temperatures and hence the particle from low to high temperatures, in a process called thermal regelation. When the host material is ice and the embedded particle is a biological entity, one has a particularly different form of active matter, which addresses interplay between a wide range of problems, from extremophiles of both terrestrial and exobiological relevance to ecological dynamics in Earth's cryosphere. Of basic importance in all such settings is the combined influence of biological activity and thermal regelation in controlling the redistribution of bioparticles. Therefore, we recast this class of regelation phenomena in the stochastic framework of active Ornstein-Uhlenbeck dynamics and make predictions relevant to this and related problems of interest in biological and geophysical problems. We examine how thermal regelation compromises paleoclimate studies in the context of ice core dating and we find that the activity influences particle dynamics during thermal regelation by enhancing the effective diffusion coefficient. Therefore, accurate dating relies on a quantitative treatment of both effects.

Microstructural Mapping of Arctica islandica Shells Reveals Environmental and Physiological Controls on Biomineral Size

The shells of long-lived bivalves record environmental variability in their geochemical signatures and are thus used extensively in marine high-resolution paleoclimate studies. To possibly overcome the limitations of the commonly employed temperature proxy, the δ18Oshell value, which requires knowledge of the seawater δ18O signature and is prone to diagenetic overprint, the shell microstructures and the morphological properties of individual biomineral units (BMUs) recently attracted research interest as an alternative paleoclimate proxy. In shells of A. islandica, one of the most extensively used and best studied sclerochronological archives, the size of the BMUs increases in warmer temperatures under laboratory circumstances. This study assesses whether this relationship persists under natural growth conditions or whether additional environmental and physiological factors control the BMU size and bias temperature reconstructions. For this purpose, shells from the surface waters of NE Iceland and the Baltic Sea, as well as from deeper waters of the North Sea (100 and 243 m) were analyzed by means of SEM. The BMU sizes were measured by means of image processing software. Results demonstrate a strong effect of temperature on the BMU size at NE Iceland and in the North Sea at 100 m depth. At 243 m depth, however, temperature variability was likely too low (1.2°C) to evoke a microstructural change. At the Baltic Sea, the BMUs remained small, possibly due to physiological stress induced by low salinity and/or hypoxia. Thus, the size of BMUs of A. islandica shells only serves as a relative temperature indicator in fully marine habitats, as long as seasonal temperature amplitudes exceed ca. 1°C. Furthermore, BMU size varied through lifetime with the largest units occurring during age seven to nine. This pattern is possibly linked to the shell growth rate or to the amount of metabolic energy invested in shell growth.

A new local meteoric water line for Inuvik (NT, Canada)

Abstract. The paper presents a new local meteoric water line (LMWL) of stable oxygen and hydrogen isotopes in precipitation from Inuvik in the western Canadian Arctic. Data were obtained over 37 months between August 2015 and August 2018 resulting in 134 measurements of the isotopic composition of both types of precipitation, snow and rain. For 33 months of the sampling period each month is represented at least two times from different years. The new LMWL from Inuvik is characterized by a slope of 7.39 and an intercept of −6.70 and fills a data gap in the western Arctic, where isotopic composition data of precipitation are scarce and stem predominantly from before the year 1990. Regional studies of meteorology, hydrology, environmental geochemistry and paleoclimate will likely benefit from the new Inuvik LMWL. Data are available on the PANGAEA repository under https://doi.org/10.1594/PANGAEA.935027 (Fritz et al., 2021).

Recent Progresses in Stable Isotope Analysis of Cellulose Extracted from Tree Rings.

In this work, the challenges and progression in stable isotope investigation, from the analytical tools and technical sample preparation procedures to the dendroclimatological experiments, were reviewed in terms of their use to assess tree physiological responses to environmental changes. Since the isotope signature of whole wood is not always a reliable tool in studying the climate changes, cellulose is often preferred as the study material in paleoclimatic studies. Nevertheless, the isotope analysis of cellulose is challenging due to the difficulty to remove the other wood components (extractives, lignin, pectin, and hemicelluloses). Additionally, in the case of hydrogen isotope analysis, about 30% of the hydrogen atoms of cellulose are exchanged with the surrounding water, which complicates the isotope analysis. In recent years, more automated isotope analysis methods were developed based on high temperature pyrolysis of cellulose, followed by the chromatographic separation of H2 from CO and by their individual isotope analysis using isotope ratio mass spectrometry. When used to investigate climate factors, the combined isotope analysis δ13C and δ18O appears to be the most promising isotope tool. In contrast, the role of δ2H values is yet to be elucidated, together with the development of new methods for hydrogen isotope analysis.

Fluid-inclusion petrography in calcite stalagmites: Implications for entrapment processes

ABSTRACT Fluids trapped in speleothems have an enormous potential in frontier fields of paleoclimate and paleohydrological research. This potential is, however, hampered by diverse scientific and technical limitations, among which the lack of a systematic methodology for genetically characterizing fluid inclusions is a major one, as these can have different origins, and thus, the trapped fluid (usually water), different meanings. In this work, we propose a systematic petrological classification of fluid inclusions, based on: 1) the temporal relation between fluid inclusions and the host calcite, 2) the spatial relation between fluid inclusions and the “crystallites” and crystals aggregates, and 3) the phases (water, air) trapped inside fluid inclusions. The first criterion allows dividing fluid inclusions in two main categories: primary and secondary, whose identification is critical in any research based on trapped fluids. The other two criteria allow the definition of eight types of primary and four types of secondary fluid inclusions. Primary fluid inclusions contain the drip water that fed stalagmites at the time of crystal growth, and can be intercrystalline, i.e., located between adjacent crystallites, or intracrystalline, i.e., with the fluid trapped within crystallites. We differentiate six main types among the intercrystalline fluid inclusions (elongate, thorn-shaped, down-arrow, interbranch, macro-elongate, and bucket) and other two among intracrystalline inclusions (pyriform and boudin). In primary inclusions, water is the main phase, while gas is much less abundant. The presence of gas could be related to slow drip rates or degassing in the cave, but also to later leakage due to changes in temperature and humidity often occurring during inadequate handling of speleothem samples. Secondary fluid inclusions were clearly related to younger water inlet through stratigraphic disruptions or unconformities. They are formed after water infiltration, but sealed before the renewed crystal growth. We differentiate four main types of secondary inclusions: interconnected, rounded, triangular, and vertical fluid inclusions. The identification of primary and secondary fluid inclusions in speleothems is a key for interpretation in paleoclimate studies. Integration of petrological results allow establishment of three different genetic scenarios for the formation of fluid inclusions, whose identification can be relevant because of their predictive character.

The relationship between chrysophyte cyst assemblages and meteorological conditions: Evidence from a sediment-trap study in northeast Poland

Climate change causes alterations in lake systems, thus influencing lake biota. Studies of phytoplankton with short generation times and seasonal replacement provide an opportunity for assessing how aquatic organisms respond to changes in environmental conditions. This study explores the potential of chrysophyte cysts as indicators of seasonal and interannual changes in meteorological conditions in Lakes Łazduny and Rzęśniki, located in northern Poland. Monthly chrysophyte cyst data from sediment traps, biweekly limnological and hydrochemical data, and daily meteorological data were used to find and explain the relationships between chrysophyte cysts and changes in meteorological conditions. We showed that cyst seasonality indirectly corresponds to meteorological conditions acting through changes in the mixing regimes, which in turn influences nutrient and light availability. Statistical analyses revealed that the taxonomic structure and interannual variability of chrysophyte cysts are dependent on multiple variables. Nevertheless, air temperature was the most important meteorological variable influencing cyst assemblages. Cysts were indicative of different periods of lake physical structure, suggesting the potential of chrysophyte cysts in paleoclimatic studies.

Investigating Masking Effects of Age Trends on the Correlations among Tree Ring Proxies

Age-related trends are present in tree-ring widths (TRW), but their presence in tree rings isotope is debated. It is unclear how cambial age influences the relationships between TRW and isotopes. Tree-ring isotopes of alpine larch and cembran-pine trees showed only trends in the juvenile period (>100 years), which might mask the inter-relations between tree-ring proxies during cambial age. This work tries to unmask the age-trend influences by examining the correlations in TRW—stable isotopes with and without age-trend correction. The non-detrended and linear-detrended values of TRW, of δD and δ18O showed significant correlations for ages up to 100 years, but not afterward. However, the correlation values, after spline or first-difference time-series detrending, were not age-related. Thus, detrending methods affect the correlations in the juvenile phase and may affect climate-related interpretations. The correlations between TRW and δ13C were not age-related, while those among the isotopes were significant throughout the ages. The correlation between δ13C and δD was the exception, as it became significant only after age > 100 years, suggesting a different use of reserves in the juvenile phase. In conclusion, the relationships among the tree-ring parameters are stable in all the different detrend scenarios after the juvenile phase, and they can be used together in multi-proxy paleoclimatic studies. The data of the juvenile phase can be used after spline-detrending or first-difference time-series calculation, depending on the purpose of the analysis to remove age-related trends. The work also provides clues on the possible causes of juvenile age trends.

Snapshots of pre-glacial paleoenvironmental conditions along the Sabrina Coast, East Antarctica: New palynological and biomarker evidence

The Aurora Subglacial Basin (ASB) catchment contains 3–5 m of sea-level equivalent ice volume that drains to the Sabrina Coast, East Antarctica via the Totten Glacier system. Observed thinning and retreat of Totten Glacier indicate regional sensitivity to oceanographic and atmospheric warming. Paleoclimate studies of climatically sensitive catchments are required to understand the evolution of the East Antarctic Ice Sheet (EAIS) and its outlet glacier systems. Recent seismic and sediment studies from the Sabrina Coast document the evolution of the EAIS in the ASB catchment, suggesting that the region has long been sensitive to climatic changes. This study presents new palynological and biomarker data from Sabrina Coast continental shelf sediments. Detailed palynological records were obtained from four short jumbo piston cores (JPC; NBP14-02 JPC-30, -31, -54 and -55), enabling reconstructions of regional vegetation and environments prior to and during Cenozoic EAIS development. The Sabrina Flora is dominated by angiosperms, with Gambierina spp. often exceeding 40% of the assemblage, and diverse Proteaceae, Battenipollis spp., Forcipites spp., Nothofagidites spp., fern, and conifer palynomorphs indicative of an open shrubby ecosystem. Excellent preservation and frequent occurrence of Gambierina spp. clusters suggest that a majority of the Sabrina Flora assemblage is penecontemporaneous with sedimentation; however, some uncertainties remain whether this sedimentation occurred in the Late Cretaceous or the Paleogene. Despite that uncertainty, high abundances of Gambierina spp. and Battenipollis spp., in combination with relatively low (<10%) Nothofagidites spp. abundances indicate that the Sabrina Flora is unique in Antarctica. Evaluation of biomarkers finds evidence for penecontemporaneous and reworked components. The penecontemporaneous C30n-alkanoic acids have δ13C values of −30.2 ± 0.5‰, consistent with δ13C values in an open canopy woodland or shrubby open vegetation. Their hydrogen isotope (δD) values of −215 ± 4.5‰, indicate precipitation isotopic composition (δDprecip) of −130‰, similar to coastal snow in the same region today. Together, Sabrina Flora palynomorph and plant wax data suggest a drier, more open coastal vegetation in the Aurora Basin of East Antarctica rather than the closed rainforest vegetation often described from other parts of Antarctica for the Cretaceous to Paleogene. To directly compare records from the circum-Antarctic, additional long sedimentary records with improved biostratigraphic constraints are required. Such records will enable identification of regional climate gradients or micro-climates, and allow assessment of the environmental conditions and mechanisms driving observed differences.

Intra-annual high resolution stable isotope records of tree ring: Methods, progress and prospects

Stable isotope ratios of tree ring can effectively record climate and environmental changes during tree growth and the physiological responses of trees to such changes. Intra-annual high resolution stable isotope ratios of tree ring can provide more detailed climatic and environmental information, reveal the physiological and ecological response mechanism of trees to seasonal climatic variation, and thus with great potential in the study of paleoclimate and global change ecology. Based on the intra-annual high resolution stable isotope ratios related literature since 1990, we reviewed the research progress of intra-annual high resolution tree ring stable isotope records in the aspects of sample stripping method, chemical extraction method of α-cellulose and application, and further proposed the potential and future development direction of intra-annual high resolution tree ring stable isotope records.

Earth Ice Age Dynamics: A Bimodal Forcing Hypothesis

The Earth has gone through multiple ice ages in the past million years. Understanding the ice age dynamics is crucial to paleoclimatic study, and is helpful for addressing future climate challenges. Though ice ages are paced by variations in Earth’s orbit geometry, how various climatic system components on the Earth respond to insolation forcing and interact with each other remains unclear. A prevailing view argues that the initial responses occur in the northern high latitudes (i.e. the northern high-latitude hypothesis, NHH). This opinion is challenged by recent reports, such as the lead of climate change in the Southern Hemisphere (SH) relative to that in the Northern Hemisphere (NH), the southern control on Atlantic meridional overturning circulations (AMOC), and the potential significance of Southern Hemisphere (SH). Alternatively, the tropical hypothesis (TH) argues for a leading role of the tropics. Both the NHH and the TH belong to a single-forcing mechanism, and have difficulty in interpreting phenomena, such as the saw-tooth pattern of the ice ages. Here we present a new proposal concerning the Earth’s ice age dynamics: the bimodal forcing hypothesis (BFH). The essential assumption of this hypothesis is that for glacial-interglacial cycles, the cooling (glaciation) starts from the northern high latitudes, whereas the warming (deglaciations) starts from the SH. Particularly, the BFH emphasizes the significance of SH oceans in accumulating and transferring heat for deglaciations. Thus, it is capable to reasonably explain the saw-tooth pattern. We compiled 100 paleotemperature records globally for validation. The BFH is consistent with most of these records, and provides a straightforward and comprehensible way to interpret ice age on Earth.

Local Meteoric Water Lines in a Semi-Arid Setting of Northwest China Using Multiple Methods

The local meteoric water lines (LMWLs) reflect water sources and the degree of sub-cloud evaporation at a specific location. Lanzhou is a semi-arid city located at the margin of the Asian monsoon, and the isotope composition in precipitation around this region has aroused attention in hydrological and paleoclimate studies. Based on an observation network of stable isotopes in precipitation in Lanzhou, LMWLs at four stations (Anning, Yuzhong, Gaolan and Yongdeng) are calculated using the event-based/monthly data and six regression methods (i.e., ordinary least squares, reduced major axis, major axis regressions, and their counterparts weighted using precipitation amount). Compared with the global meteoric water line, the slope and intercept of LMWL in Lanzhou are smaller. The slopes and intercepts calculated using different methods are slightly different. Among these methods, precipitation-weighted least squares regression (PWLSR) usually had the minimum average value of root mean sum of squared error (rmSSEav), indicating that the result of the precipitation weighted method is relatively stable. Higher precipitation amount and lower air temperature result in larger slopes and intercepts on an annual scale, which is out of accordance with the summertime.

Last millennium climate variability of the varved Lake Jeinimeni geochemical record from NE Chilean Patagonia

Paleoclimate studies in Patagonia show a high Holocene climate variability, strongly controlled by the intensity and latitudinal position of the Southern Westerly Winds. In this study, environmental and climate variability, and in particular winter precipitation, was reconstructed over the last centuries through sedimentological and geochemical analyses of a core from Lake Jeinimeni in North East Patagonia. Visual description, X-ray radiographies and thin section observations point to finely laminated sediments, made by fine sands and light brown clayey silts forming an annual deposition (varves) occasionally interrupted by two Hudson volcano-related tephras and 15 pluri-millimetre to pluri-centimetre coarser sandy to gravely layers. Varve counting confirmed by 210Pb and 137Cs indicates a detrital sequence of at least 750 yr. Based on a correlation with local meteorological data for the 1930–1988AD interval, varve thickness and statistical treatment of XRF geochemical data give information on transport pathway and sedimentary deposit conditions. The sandy laminae correspond to the deposition of high sedimentary load delivered by austral spring snowmelt whereas the clayey silt laminae result of particle settling in the water column during low hydrodynamical conditions. Thicker varves observed in dry conditions underline the importance of aeolian transport in sedimentary deposition. During locally dry and windy summer, the wind may erode and remobilise the sedimentary deposits along the lake margins. The sandy and gravely layers record massive erosional events due to proximal watershed perturbation driven by climatic or tectonic mechanisms. The clastic varves of Lake Jeinimeni document environmental decadal to multidecadal variability in East Patagonia over the last centuries. The more pronounced sediment transition around 1750 CE is consistent with the inception of the Little Ice Age-type event, in agreement with North Patagonian paleoclimate reconstructions derived from glacier advances, lacustrine varve thickness and tree-ring records.

Measurements and applications of δ2H values of wood lignin methoxy groups for paleoclimatic studies

Stable hydrogen isotope values of wood lignin methoxy groups (δ2HLM) are increasingly applied to reconstruct the stable hydrogen isotope composition of precipitation (δ2Hprecip) and mean annual temperatures (MAT) of mid latitudes regions. Recently, the analytical procedure for measuring δ2HLM values was considerably improved by the availability of new reference materials that are in full accordance with the requirements of normalising stable isotope measurements. Using this improved procedure we determined the δ2HLM values of tree rings from 40 geographical locations. Using these values, we present a revised relationship between δ2HLM and δ2Hprecip which is: δ2Hprecip [mUr] = (δ2HLM [mUr] + 206 mUr)/0.67. In addition, a new equation for reconstructions of MAT is: MAT [°C] = (δ2HLM [mUr] + 272 mUr)/3.04 [mUr/°C]. We provide a simple numerical model that explains the observed biosynthetic isotope fraction pattern between δ2HLM and δ2Hprecip. Finally, we applied the new equations to a previous data set for wood samples collected close to the Hohenpeißenberg Meteorological Observatory in Germany. The data set included a 100-year-chronology (1916–2015) from nine tree ring cores removed from four beech trees. The MAT from δ2HLM values reconstructed for this geographical location was 7.96 ± 2.17 °C and in very good agreement with the observed mean MAT of 7.82 ± 0.75 °C during this time period. Therefore, we conclude that the revised relationships between δ2HLM, δ2Hprecip and MAT provide the basis for reliable application for paleoclimate reconstructions.

Automatic 3D Pollen Recognition Based on Convolutional Neural Network

The importance of automatic pollen recognition has been examined in several areas ranging from paleoclimate studies to some daily practice such as pollen hypersensitivity forecasting. This paper attempts to present an automatic 3D pollen image recognition method based on convolutional neural network. To achieve this purpose, high feature dimensions and complex posture transformation should be taken into account. Therefore, this work focuses on a three-part novel approach: constructing spatial local key points to obtain local stable points of pollen images, computing orientational local binary pattern using local stable points as the inputs, and identifying the pollen grains using convolutional neural network as the classifier. Experiments are performed on two standard pollen image datasets: Confocal-E dataset and Pollenmonitor dataset. It is concluded that the proposed approach can effectively extract the features of pollen images and is robust to posture transformation, slight occlusion, and pollution.

The influence of soil chemistry on branched tetraether lipids in mid- and high latitude soils: Implications for brGDGT- based paleothermometry

Branched glycerol dialkyl glycerol tetraethers (BrGDGTs) are a suite of orphan bacterial membrane lipids commonly used as paleo-environmental proxies for mean annual air temperature (MAT) and pH. Recent calibrations between the Methylation of Branched Tetraethers index (MBT′5ME) and MAT, based on modern surface soils (including peats), show a considerable amount of scatter, especially in mid- and high latitude soils, suggesting that brGDGT signals are influenced by additional environmental and/or biological controls at these sites. Here we test the impact of soil chemical gradients and bacterial community changes (16S rDNA sequence-based) on brGDGT distributions at two grasslands sites (Ossenkampen [NL], ForHot [IS]), and one agricultural site (Craibstone [UK]). In addition to the variation in soil chemistry, the ForHot site experiences belowground warming. Of the studied edaphic parameters, soil pH is the primary factor that explains simultaneous changes in both the bacterial community composition and the brGDGT distribution. Variations in the MBT′5ME at two sites without soil warming indeed correlate strongly to soil pH (r = 0.9–1.0, pH = 4.5–7.3), whereas pH explains part of the variation in the MBT′5ME at the site with soil warming (mean soil temperature ranging between 5 and 14 °C). At all sites, soil pH is positively related with the same brGDGTs (Ib, IIb, IIIb, IIIc, IIa′, IIb′, IIc′, IIIa′, IIb′, IIIc′) and influences the ratio between main brGDGT compounds Ia, IIa and IIIa, impacting the MBT′5ME values. This change in brGDGT distributions coincides with a change in the composition of the bacterial community at all sites. The bacterial clades that vary at the three experimental sites (specifically Acidobacteria subgroups 1, 2, 3, 6, 22) have previously been shown to also respond to soil pH on a global scale. As soil pH changes on geological timescales, the impact of changing pH on the MBT′5ME paleothermometer should be considered when performing paleoclimate studies.

On the Date of the Great Shigir Idol

The Great Shigir Idol is the largest anthropomorphic wooden sculpture in the world, a unique work of Stone Age art, and a valuable source for reconstructing the material culture and worldview of the ancient population of Northern Eurasia. Although study of it began more than 100 years ago, a number of issues, such as the place of discovery, context, date, methods of exhibition, etc., remain controversial. This article analyses archival documents relevant to the location and time of discovery of the Great Shigir Idol, and on the accompanying finds. The results of a recent comprehensive study conducted by Russian and German archaeologists and scientists in 2014 are outlined. The focus is on the analysis of AMS radiocarbon dates, spanning a period from the Late Pleistocene (~10,500 cal BC) to the Late Mesolithic/Early Neolithic (~6000 cal BC). These dates show a considerable range of variation, and they disagree with those derived from the conventional radiocarbon dating in 1997. Paleogeographic and archaeological data from the Trans-Urals do not support the early (9600–9000 cal BC) estimates of the time of the idol’s creation, but rather correspond to later ones, derived from the AMS 14 C analysis conducted in 2014. Therefore, it is necessary to continue the study of Mesolithic sites and paleoclimate of the Urals, determine the nature of primary peat formation at the Ural peatlands, and assess their age and that of the microremains of peat in early cracks in the idol, etc.

Optimizing sampling strategies in high-resolution paleoclimate records

Abstract. The aim of paleoclimate studies resolving climate variability from noisy proxy records can in essence be reduced to a statistical problem. The challenge is to extract meaningful information about climate variability from these records by reducing measurement uncertainty through combining measurements for proxies while retaining the temporal resolution needed to assess the timing and duration of variations in climate parameters. In this study, we explore the limits of this compromise by testing different methods for combining proxy data (smoothing, binning, and sample size optimization) on a particularly challenging paleoclimate problem: resolving seasonal variability in stable isotope records. We test and evaluate the effects of changes in the seasonal temperature and the hydrological cycle as well as changes in the accretion rate of the archive and parameters such as sampling resolution and age model uncertainty in the reliability of seasonality reconstructions based on clumped and oxygen isotope analyses in 33 real and virtual datasets. Our results show that strategic combinations of clumped isotope analyses can significantly improve the accuracy of seasonality reconstructions compared to conventional stable oxygen isotope analyses, especially in settings in which the isotopic composition of the water is poorly constrained. Smoothing data using a moving average often leads to an apparent dampening of the seasonal cycle, significantly reducing the accuracy of reconstructions. A statistical sample size optimization protocol yields more precise results than smoothing. However, the most accurate results are obtained through monthly binning of proxy data, especially in cases in which growth rate or water composition cycles obscure the seasonal temperature cycle. Our analysis of a wide range of natural situations reveals that the effect of temperature seasonality on oxygen isotope records almost invariably exceeds that of changes in water composition. Thus, in most cases, oxygen isotope records allow reliable identification of growth seasonality as a basis for age modeling in the absence of independent chronological markers in the record. These specific findings allow us to formulate general recommendations for sampling and combining data in paleoclimate research and have implications beyond the reconstruction of seasonality. We briefly discuss the implications of our results for solving common problems in paleoclimatology and stratigraphy.

Regional meteoric water line of the Yucatan Peninsula, Mexico

AbstractThe data set represents the Regional Meteoric Water Line (RMWL) for the Yucatan Peninsula (Mexico), a region with karstic aquifers but little knowledge of the isotopic composition of meteoric water. This data paper comprises the isotopic composition of meteoric water collected from November 2018 to November 2019 as monthly composite samples expressed as weighted monthly mean precipitation from 16 locations across the Yucatan Peninsula. The RMWL was δ2H = 7.803 δ18O + 12.075, with a slope and intercept suggesting precipitation from air that has undergone condensation, air masses with variable moisture or recycled moisture. The average δ18O is −2.57‰ (−12.23 to 1.2‰) and δ2H is −7.94‰ (−83.39 to 18.32‰). This data set was collected by the implementation of an isotopic monitoring network, gathering information useful as a tool for better understanding of the hydrology and hydrogeochemistry of karstic aquifers, and to develop proxies for paleohydrology, ecohydrology, climate change and paleoclimate studies in the Gulf of Mexico and the Great Caribbean Area.